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By G. L. Dyer, R. D. Alorro, R. E. Browner

A potential new rare earth extraction process has been suggested (Lazo, et al., 2017) (Lazo, et al., 2018) based on converting the rare earth elements to solid phase rare earth oxalates in an oxalic acid leach. Oxalic acid consumption is a significant issue in the process, therefore to improve the viability of this proposed new extraction method, a process to recover oxalate from the leach solution and recycle oxalic acid is required. A review of the literature and confirmation through thermodynamic analysis of the potential options identified precipitation of calcium or ferrous oxalate as the best potential options. The use of metallic iron to both provide ferrous ions as a precipitant and reduce ferric ions in solution would provide the most economical option, however slow kinetics and unreacted iron created significant issues with this process. The direct use of ferrous ions, while faster and more efficient, produced a precipitate with relatively poor solid/liquid handling characteristics and would require an intermediate stage utilising calcium in regenerating the oxalate. Utilising calcium chloride and oxide created very similar precipitates with better physical properties than the ferrous oxalate and that a reasonable proportion of the oxalate could be recovered before neutralisation of the solution induced precipitation of other phases such as iron oxy-hydroxides and calcium phosphate. The produced calcium oxalate was easily converted to oxalic acid and gypsum via immersion in sulphuric acid. It was also found that there is a significant loss of oxalic acid due to factors other than rare earth oxalate precipitation during leaching. This leads to a maximum oxalate recovery in the range of 50 %.

Jan 1, 2020

In this study, selective flocculating of diaspore using anion macromolecular reagent as flocculant was tested to separate diaspore from alum-silicate minerals. Firstly, the effect of pH on settling behavior of diaspore and kaolinite dispersions has been investigated. The results show that the maximum settling speed of diaspore and kaolinite appeared re-spectively at pH7 and pH3.33 which is close to the point of zero charge (PZC) of diaspore (6.8) and kaolinite(3.5). This result is in well agreement with the double electric layer theory. Secondly, the settling behavior of diaspore and kaolinite particles in different anion flocculant solution have been researched. The results indicate that flocculant solution concentration significantly affect the selectivity and the flocculating performance of anion molecular. In high concentration solution, both diaspore and kaolinite have faster settling rate compared to blank solution. How-ever, in low concentration solution, the anion macromolecular can enhance the settling rate of diaspore remarkably but has no apparent effect on the settling rate of kaolinite. This result suggests that the tested anion flocculant is a promising reagent for de-silica of diasporic bauxite. Lastly, FTIR method was employed to probe the adsorption mechanism of flocculant on diaspore and kaolinite. The results reveal that there are anion flocculant characteristic bands on the spectra of diaspore but no obvious characteristic bands of flocculant on the FTIR spectrum of kaolinite. This result is in good correspondence with settling test.

Jan 1, 2014

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By G. Song

Magnesium has excellent bio-compatibility in terms of its density, strength, elastic modulus and toxicity. However, due to its poor corrosion performance, so far magnesium has not been successfully used in the human body as a permanent implant material. Nevertheless, there is a possibility to utilize the low corrosion resistance of magnesium to make magnesium into a temporary implant component that can gradually dissolve in the human body after surgical region heals. This will avoid the secondary operation to remove the temporarily implanted component and the chronic inflammatory discomfort caused by the implant. This paper is aimed at exploring the possibility of using magnesium as a degradable bio-material through investigating the corrosion behaviors of pure magnesium and surface treated magnesium in a simulated body fluid (SBF) solution. It was found that magnesium corroded rapidly in the SBF solution, resulting in vigorous hydrogen evolution and a strong alkalization effect. Hence, it is impractical to use magnesium as a permanent implanted material or even a degradable implant. However, a proper anodizing treatment can significantly improve the corrosion resistance of magnesium, and hence slower down the hydrogen evolution and alkalization processes, which will allow to control the corrosion or degradation of magnesium at a desired rate in the human body. With a controllable corrosion rate, it is believed that magnesium as a degradable implanted material will be eventually achievable.

Jan 1, 2006

By Amri Priambodo, Ian Leslie, Valérie Laflèche, Agustina Ratnaningrum, Robin Paine, Andrianus Sinaga, Willem de Beer

Freeport Indonesia consists of surface, civil and underground mining areas exposed to numerous geotechnical risks and hazards. PTFI uses various monitoring systems (Micro-Seismic, Firefly Light System, Mira Geoscience machine learning, etc.) to effectively manage these risks. The significant volumes of data from these sensors must be integrated into actionable information to provide the expected risk management. This occurs at the GeoEngineering Integrated Monitoring Centre (GIMC), a centralized department within the GeoEngineering Division, tasked with the responsibility to manage all geotechnical monitoring systems. The main hazard the GIMC is responsible for managing in real time is mine seismicity within the underground mining areas and the potential impacts on safe operations. Seismic system engineers achieve this objective through 24 hours a day and seven days a week operations of the GIMC, providing a centralized point of communication, alerts, evacuations and control during seismic events and emergencies. This paper will describe how the GIMC achieves its goal using reliable procedures and strategies based on detailed Triggered Action Response Plan (TARP), concise communications, novel technologies (FireFly Lighting System), and proven seismic re-entry programs to manage risk within the underground mining operations. The integration of geotechnical monitoring and reporting into a centralized group has improved the effectiveness and management of seismic risks and hazards at PT Freeport Indonesia (PTFI) mining operations.

Apr 26, 2022

By M. F. He

The depression of pyrite in marmatite flotation by a new depressant Sodium Glycerine-xanthate (SGX) has been investigated through microflotation, zeta potential, and adsorption measurements in systems open to the atmosphere. The flotation tests of single mineral show that in the presence of SGX, marmatite can be activated by Cu2+ and shows good flotability, while pyrite can?t be activated and therefore shows poor flotability, as a result these two minerals can be separated using butyl xanthate as the collector. The depression mechanism of SGX on sulfide minerals is discussed based on Zeta potential and adsorption isotherm. Zeta potential experiments demonstrate that at the presence of Cu2+, SGX can strongly adsorb on the surface of pyrite, while it can?t adsorb on the surface of marmatite, thus the results are in accordance with those of flotation experiments; the results of adsorption isotherms show that the adsorption density of SGX on pyrite is greater.

Jan 1, 2014

The ore studied occurred in the Three Rivers area in China and was a silver-lead-zinc complex ore containing 400.52 g/t silver, 4.77 % lead and 3.47 % zinc. Silver, lead and zinc were the major valuable elements in the ore and copper, cadmium and tin were the associated elements to be comprehensively recovered, whereas arsenic was the harmful element. The element silver occurred mainly in freibergite with small proportion in dyscrasite and other silver minerals. The carrier minerals for silver were mainly galena and oxidized lead minerals and then sphalerite, arsenopyrite and pyrite. The ore contained numerous minerals with complex mosaic texture and the lead and zinc minerals enclosed each other multiply, which made the separation of the minerals in the ore very difficult. Experimental investigation on the beneficiation of the ore indicated that with flotation separation process it was very hard to obtain single lead concentrate or single zinc concentrate that would meet the requirement of market. In the meantime, during the separation process of lead and zinc, silver tended to be dispersed, resulting in a low recovery of silver. Therefore, a rational utilization technique for the ore should be a combined process of bulk flotation to reduce arsenic? sulphating roasting of silver-lead-zinc bulk concentrate-leaching with diluted sulphuric acid to separate silver, lead and zinc. With this process quality lead concentrate containing silver and high grade zinc product and silver product could be obtained. The recovery of silver, lead and zinc in flotation was 85.10%, 84.48% and 82.48%, respectively. The total recovery of silver, lead and zinc in chemical processing was 97.07%(sum of recovery of silver ingot and lead concentrate), 99.61% and 90.93%, respectively.

Jan 1, 2014

By T Tan, C P. Holmes, C E. Hartford

Transportation of iron ore from the mine to the plant is critical to business success. Ore from the mine may have to be transported across states, countries and even continents to get to the processing plant or export facilities, and ultimately to the client. Numerous transportation steps may result in potential logistical difficulties. Companies are continually seeking ways to increase production rates, decrease delivery times and reduce operating costs. Transportation cost is a major component of the total cost of mining iron ore and therefore requires effective use of transport systems.Bottlenecks in iron ore transport systems, due to material handling issues, can result in loss in profit in the order of millions of dollars per hour. Bottlenecks can be seen anywhere in the transport system where the desired flow rate cannot be achieved. These bottlenecks occur for various reasons such as increasing throughput in a transport system originally designed for a lower throughput resulting in plugged transfer chutes, changing material characteristics (eg finer material, increased moisture content), changing to a new type of material or blend that again alters handleability, or changes in operational philosophy due to equipment availability or process utilisation.Stockpiles may have limited live capacity such that an adequate amount of ore may not be readily reclaimed when required (eg to fill a complete train’s railcars). In bins and hoppers, material may discharge through a central flow channel resulting in the formation of a stable rathole, which can then collapse causing material to flood the downstream system and cause significant downtime for clean-up (eg railcars beneath train load outs). In transfer chutes, bottlenecks can be caused by pluggages or downtime required for the change-out of liners due to excessive wear. In ship loading, long settling or de-aeration time, or material exceeding its transportable moisture limit (TML) may result in further bottlenecks. These bottlenecks all have associated costs because of the need to address their causes and because of the lost opportunities for throughput.This paper will discuss how bulk material technology and proper understanding of material flow characteristics can be applied to mitigate bottlenecks. It will discuss how to predict potential bottleneck locations through a scientific method of analysis and evaluation to determine if an increase in throughput of an existing transport system is possible, as well as whether or not a new material will flow reliably through an existing system.CITATION:Hartford, C E, Holmes, C P and Tan, T, 2015. De-bottlenecking iron ore transportation from mine to plant, in Proceedings Iron Ore 2015, pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By K. K. Kershner, J. G. Donaldson

This investigation was conducted to obtain data on optimum conditions for chloridizing metal sulfides . Salt- roasting galena at 450° C for 8 hours chloridized 75 percent of the lead ; in an equal time of treatment at 750° C , the process chloridized 42 percent of the zinc in sphalerite . Hydrogen chloride at 500° C completely chloridized galena in 15 minutes , and at 600° C converted all of the zinc in sphalerite to the chloride in 4 hours .

Jan 1, 1963

By Wm. W. Odell

A study of certain gas making and fuel problems peculiar to the gas industry of California has been made by the Bureau of Mines. The work was done at the request of, and in cooperation with The California Gas Research Council 2, for the purpose of obtaining basic information on the gas-making fuels available to California, and their applicability to the present and future needs of the gas industry in that State. The data obtained have been applied in outlining a construction program, and indicate the possibilities in efficiently utilizing fuels in making gas by other than the oil-gas process. This paper presents an outline of the study and a summary of the principal results obtained, with some of the more important conclusions and recommendations based on this data. Gas is produced in California by processes which are both unique and different from those common to other parts of the United States. The bulk of the manufactured gas is made in and distributed from two main districts which are centers of population - namely, the Los Angeles district and the San Francisco Bay district. The gas manufactured in the Bay district is, almost exclusively oil-gas, whereas that produced in the southern part of the State, where natural gas is available, is mostly mixed natural gas and reformed-gas, but oil-gas is the chief product when the supply of natural gas is inadequate. Practically all of the gas companies are equipped with oil-gas generating apparatus, and anticipate using it in the future. As the continued use of the oil-gas process to the exclusion of all other processes, depends upon a continued supply of oil at a low cost, and the prospect of obtaining such low-priced oil in the future is somewhat uncertain, the questions have arisen: What will the future gas-making process or processes be? When will it be necessary to make plans for the installation of different gas generating equipment, and what will that equipment comprise?

Jan 1, 1926

By Ragnhild E. Aune, Mark William Kennedy, Shahid Akhtar, Jon Arne Bakken

"To determine the heating rate of billets using ‘short coils’, an appropriate correction factor must be applied to the theoretical relationship. In 1945, Vaughan and Williamson published a semi-empirically modified Nagaoka coefficient applicable for moderate frequency induction heating processes (10 kHz). Recently it was demonstrated that the method of Vaughan and Williamson gives <10% error in the estimated power when heating aluminum billets at 50 Hz.In the present study, experiments have been conducted on aluminum billets in order to verify an empirical frequency corrected ‘short coil’ equation. Measurements of electrical conductivity (<± 0.5%), current (± 1%), heat (± 1-3%), and magnetic flux density (± 1-2%) have been performed. The results are compared with 1D analytical calculations, and 2D axial symmetric FEM modeling using COMSOL 4.2®. The frequency corrected equation has proven to provide accurate predictions of power (<4% error) within the frequency range 50 Hz to 500 kHz.IntroductionInduction heating is commonly applied to the re-heating of billets before forging or extrusion processes. The resistive heating produced by eddy currents in the solid or semi-solid work piece during this procedure, is driven by the time varying magnetic flux density in the air-gap between the work piece and the coil. The flux in the air-gap is created by the current flowing in the induction coil, i.e. the magneto-motive force. In Figure 1 it can be seen that the currents present in the work piece are concentrated in the outer ‘shell’, or the first electromagnetic penetration depth (dw), and flow in a direction which opposes the magnetic field produced by the induction coil."

Jan 1, 2012

By Daguang Lu

The section of sintering and BF (blast furnace) is very important in iron-making process. In practice, the scheduling is so extensive that three faults unfavorable to continuous product will be easier to happen. This paper introduces the integration Petri Net and GA (genetic algorithm) as suitable tools for simulation and optimization of scheduling to section of sintering- BF under a certain hot iron or-der. The situation of the iron plant Chongqing Iron and Steel Company is researched in approach above mentioned. By analysis, the conclusion is drawn that scheduling with optimized values can maintain continuity of key operations , can satisfy order of hot iron in maximal degree and can keep the best stability of key storages.

Jan 1, 2009

By V. A. Chanturiya

In Pt- and Au-keeping complex ores processing, about 10% ~ 15% of noble metals are lost with true tailings that are due to low floatability of Pt- and Au-keeping minerals by the conventional collectors. With the aim to achieve the effective recovery of noble metals at flotation of Pt-Cu-Ni and Au-keeping ores organic complex reagents keeping electron-donating atoms of nitrogen, oxygen, sulfur or phosphorus may be offered as selective collectors for the indicated minerals. These rea-gents tend to form complex compounds with PGM. Besides this, Cu-Ni-Pt and complex Pt and Au carbonated mica ores are characterized by finely disseminated (up to nanometer size) mineral forms of Pt in multivalent states. In this connection, the use of a combination of the strong ionic collectors with nonionic reactants that are capable to derivate complex compounds with multivalent PGM seems to be expedient for this type of ores. In the research new complex reactants were tested such as cyclic alkylene-trithiocarbonates, oxyalkyl butylxanthogen acid ethers, a combination of the collectors ? mercaptobenzothiazole (MBT) and dialkyldithiophosphates (DTP). Sorption and flotation tests were made with monomine-ralic samples of chalcopyrite, pentlandite, pyrrhotite, pyrite, and Pt-Cu-Ni sulfide ore samples. Sorption properties were examined by the extractive UV spectrophotometric method and potentiometric measurements. To indicate a structure of modified xanthate solutions the method of a thin-layer chromatography (TLC) was applied. The chromatographic behavior of the basic components of modified xanthate solution ? ButX, cyclic propylene-trithiocarbonate (PTTC), diethyl-dithiocarbamate (DEDC) and the product of its modification ? oxypropyl-S-ether of dithiocarbamatic acid was studied on plates ?Silufol UV ? 254?. The composition of organic solvents and its ratio in a mobile phase was deter-mined for simultaneous chromatography of the main components of a reaction mixture. It was found that operating selectivity of MBT, DTP and cyclic alkylene-trithiocarbonates incorporated in modified xanthate in relation to Pt-Cu-Ni and Au-containing sulfide minerals might be explained by an electoral sorption of this nonionic collector on a surface of the minerals studied. It was demonstrated that the application new reagent modes with the use of a combination of designed complex reactants helped to increase the extraction index of Pt- and Au-keeping minerals from complicated ores.

Jan 1, 2014

By C. Lupi

In 1996 the Italian Agency for Environmental Protection (ANPA) has initiated a study of the environmental impact of the industrial sector of steel produced by Electric Arc Furnace (EAF). Within the framework of this study a hydrometallurgical process to treat EAF dusts was considered and developed. The paper describes the zinc and lead recovery from fumes coming from carbon steel production. The zinc extraction consists in acidic leaching followed by SX-EW steps. The leaching sludge containing lead sulfates was treated to obtain pure lead salt and inert solid residue. The whole process, that minimizes effluents by recycling the main liquid streams, has been developed to obtain marketable products. The solid waste, containing spinels, was subjected to elution tests in order to verify its compatibility with environmental regulation. The process, that has been set-up and tested in the laboratories of the University of Rome, will be transferred and studied on a pilot plant in order to assess its industrial and economical feasibility.

Jan 1, 1999

By E Vargas, A Egana, M Alarcon, X Emery, A Barberan, A Lopez, N Morales, C Friedrich

"As the cost in time and money of data from sensors and small-scale tests has reduced, additional challenges have arisen. Although many mine data sets are not big relative to those in other disciplines, they are complex in other ways, and becoming too large to manage efficiently on personal computers. In order to take advantage of the opportunity offered by increased data, a diverse team from Universidad de Chile and CSIRO Mineral Resources has developed a virtual geometallurgical laboratory to support the computational requirements linking data acquisition with data-driven business decisions. A particular focus to date has been the development of user-guided workflow ensembles to enable comparison between plausible geometallurgical hypotheses.A case study has been undertaken using publicly available data from the Rocklea Dome iron deposit in Western Australia. A hypothetical mining schedule was produced from geochemical and hyperspectral drill core/chips data via the following steps: data preprocessing, exploratory data analysis, geochemical interpolation, block modelling, ultimate open pit design and scheduling. The key outcome of this study was the integration of workflow stages through new plug-in methods or modification of existing software. Outcomes from this study will be described in the paper in terms of geological and metallurgical data quality, analytical software support and ongoing computing infrastructure requirements.CITATION:Lopez, A, Barberan, A, Alarcon, M, Vargas, E, Ortiz, J, Morales, N, Emery, X, Egana, A, McFarlane, A and Friedrich, C, 2016. Progress towards Data-driven Mine Planning via a Virtual Geometallurgical Laboratory, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 287–294 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By Markus Reifferscheid

Industry 4.0, Digitalization, Internet of Things (IoT) and Cloud Computing are predominant topics in the world economy at the moment. At the ABM week 2017 Dr. Markus Reifferscheid, Head of Research &amp; Development of SMS-group, will talk about the proceeding digitalization in the steel industry with selected examples of SMS-group. He will present advanced concepts and solutions which are currently being developed.

Oct 30, 2017

By A Marton

Concerns with crest losses have seen changes to a number of design and operating parameters to retain the integrity of the wall and the berms of the Kidston Gold MinesÆ Eldridge Pit. Until trials began in 1999 most final wall designs utilised large diameter blastholes up to the presplit row to achieve the wall angle. The berm crests were being lost, wall support requirements were increasing and affecting mining schedules and several fault areas were putting pit access at risk. Standard designs had been determined during the early mining years and while periodic modifications had been made there was a need for major blast pattern revision. This paper traces the development of wall control blasting programs over the years, relating designs to the geology and the evidence in the walls with the theories of the day and includes the recent trials that were conducted in what is a most unforgiving geology. Trials and improvements to ensure the walls were safe were conducted even as the mine neared its economic life. Instrumented monitoring of trials blasts has greatly increased the understanding of the damage criteria and enabled rapid revision of designs. Recent changes included reduction in presplit energy, charge redistribution and use of smaller blast holes for the trim patterns. Determination of a minimum proximity-to-final wall limit for production blastholes, establishment of the correct standoff to berm crests and walls and selective use of presplitting techniques for protecting crests have resulted in cost effectiveness, improved bench crest retention and an overall reduction in visible wall damage.

Jan 1, 2001

By Peter M. Fozzard

A review is made of the actual costs of recent foreign mineral exploration programmes in third world countries. Target identification leading to the selection of areas, or macro-targets, must follow a well planned and defined series of steps. Suggestions are made with respect to this inter-active project development work. Potential revenues in the broad sense will always determine the overall economics of exploration but clear objective philosophy, good planning and adequate financing are essential for exploration success. Considerable opportunities exist for making important foreign mineral discoveries and broad selected suggestions are made for the identification of exploration areas in relation to high-grade and precious metal mineralization.

Jan 1, 1984

By M. J. Scoble, H. L. Francis, D. F. Salter, G. R. Baiden

Intelligent ore delineation refers to the ability reliably to characterize the geological setting of a mineralized body and its grade distribution. This necessitates using all available geological information in a timely and efficient manner, such that effective geological control is achieved. The importance of geological control is paramount to improving the efficiency and competitiveness of underground mines. As a result, the development of new geosensing tools designed to provide more reliable and timely information should be a priority. However, as the sensing tools advance then so, too, must the decision support system in order to allow the full benefits of these tools to be achieved. One potential system considered able to provide this architecture is ’true 3D-GIS’ (Geographical Information System). GIS promises to provide a seamless data flow and to connect information currently unavailable to the underground mine operations by bringing together previously disparate and spatial data sets in a visually effective and timely way. This paper considers the potential revolution GIS offers over the flow and use of data in mining by focusing on the integration of geosensing data and GIS to facilitate intelligent ore delineation.

Jan 1, 2000

By G. Gerbeth, Y. Gelfgat, A. Cramer, A. Bojarevics

The production of highly porous metallic substrates requires an effective and well controlled production of metallic fibres with diameters in the range of 50 to 200 microns. The melt extraction, where a quickly rotating wheel extracts fibres directly out of the inductively heated melt, is a promising technology for that purpose. The main limitations of this process are due to turbulence within the melt and a wavy motion on the surface. Both effects give rise to strong and time dependent deformation of the melt surface which, in turn, causes non-stationary conditions of the contact zone between the extraction wheel and the melt. In the patent literature many examples can be found which try to overcome these problems by submersing mechanical parts directly into, or placing them at least in close vicinity to the melt, aiming at a stabilisation of that contact region. Even made of heat resistant ceramics they suffer from corrosion or cracks and do not work reliable at all. The present work describes a non invasive control mechanism by means of a magnetic field. Model experiments were carried out to study the calm down of the turbulent surface of a inductively stirred melt. The stabilisation of the melt surface has been demonstrated in practise by the installation of a solenoid at a working extraction facility under rough industrial conditions like a powerful induction heating and vacuum.

Jan 1, 1999