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By K. Kalgraf

The motion and stability of the metal/electrolyte interface is determined by Navier-Stokes equation. The equation may be decomposed into two independent equations by taking the divergence and curl of Navier-Stokes equation. The divergence determines the motion and stability of magneto-gravitational waves. The curl of Navier-Stokes equation gives an equation containing only velocity and magnetic field, and states that the magnetic field is driving a circulation pattern in the cell, and this magneto-flow has its own stability conditions. The waves are called Alfven waves, and their stability properties are related only to magnetic field and geometry.

Jan 1, 2001

By R. Cottam

The deformation and recrystallisation of magnesium yttrium alloys containing 0.23, 0.84 and 2.71wt% yttrium and commercially pure magnesium extrusion has been investigated at temperatures between 200 and 350°C. The alloys were produced as billets 7.5 cm diameter, solution treated at 525 °C for 8 h and extruded into 3 cm diameter bar at 390°C. Channel die compression was employed to deform the samples at a strain rate of 1x10-3s-1. For the 0.23 wt% yttrium alloy and the pure magnesium, dynamic recrystallization (DRX) occurred at all temperatures and the amount of DRX increased as the temperature was raised. In the alloys containing 0.84 and 2.71 wt% yttrium DRX was almost completely suppressed at all temperatures. The absence of DRX in the 0.84 and 2.71 wt% yttrium alloys was accompanied by a decrease in the ductility, except at 350°C the highest deformation temperature. It was observed that this increase in ductility was accompanied by a reduction in deformation twinning and the initiation of pyramidal slip. This work highlights the important role that DRX plays in enhancing the ductility of magnesium alloys.

Jan 1, 2006

By Joon H. Jang

At a selected pH, hydrothermal oxidation of chalcopyrite was carried out under controlled F+,, at elevated pressures and temperatures (172-200°C) by balancing the rate of oxygen injection against the rate of consumption. Chalcopyrite was converted to covellite (CuS) and digenite (CU1.8S) with rejection of iron and sulfur to the solution. Covellite forms in the first stage, followed by nucleation and growth of digenite in the second stage. The effects of rapid and slow injection of stoichiometric quantities of oxygen are compared. Both the covellite and digenite form a porous layer occupying the same volume as the original chalcopyrite grain. An electrochemical kinetic model is presented to correlate the observed results.

Jan 1, 1993

By W. van der Merwe

ABSTRACT With the gold industry processing more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more critical. This paper compares the two commonly employed ‘free’ cyanide online analysis methods (amperometric and potentiometric endpoint silver nitrate titration) with the rhodanine endpoint silver nitrate titration and ion selective electrode methods common at site laboratories. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared using these measurement techniques.

Jan 1, 2013

By C A. Brannon, C A. Dipas, H A. Vega, D Villa

The development and construction of the Grasberg block cave mine (GBC) is in progress, currently targeting initiation of caving in late 2018. Current production planning anticipates ramping up to full production of 130 000 to 160 000 t/d by 2027. As GBC approaches the production phase, there is a high priority on increasing the accuracy and level of detail in the production plan. The advance of the cave front directly controls the drawbell opening rate that is achievable. Therefore, an essential component of this plan is to produce an undercutting and drawbell sequence that honours the caving parameters that have been set for the mining blocks by the GBC production planning team.The PT Freeport Indonesia (PTFI) mine planning team and the Geovia caving business unit have developed a computational tool (Undercut Tool) capable of generating an undercutting sequence that follows a set of caving rules, such as advance rate per tunnel, maximum blasted area per period, control of lead-lag and shape of the undercut face. This tool also produces a drawbell sequence that honours the undercutting advance sequence, which is ultimately used to generate a life-of-mine production plan. This paper describes the inputs and outputs of the Undercut Tool that have been used to compute the long-term production plan for the GBC mine. It will further describe how the Undercut Tool takes into account operational constraints and geotechnical considerations that must be considered when developing a defendable production plan. Included is a discussion of the initial results of the planning outcomes from the tool; it will demonstrate how this work will support specific aspects of the plan such as the detailed undercut production drill and blast plans for the drill ring sequence, as well as how that plan will drive the drawpoint opening plan.CITATION:Villa, D, Brannon, C A, Dipas, C A and Vega, H A, 2017. Integrated drawbell and undercut scheduling using a computational tool at the Grasberg block cave mine, in Proceedings 13th AusIMM Underground Operators’ Conference 2017, pp 271–276 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 16, 2017

By Chris Harris, Kamal Adham

The use of HCl acid is gaining momentum among hydrometallurgical processes. However, the issue of environmentally efficient and economically viable ways to regenerate HCl acid (from various metal chloride intermediate products) remains a technology and operational challenge. The authors provide a state-of-technology review based on Hatch’s years of testing, design and commissioning experience with high-temperature units (fluid bed and spray roasters), plus the recent efforts in the area of low-temperature HCl regeneration.

Jan 1, 2014

By C. Cardoso, G. Bermudez, A. Jalili

Bigger flotation cells can result in larger froth surface areas and longer froth transport distances, this has been credited to impact froth recovery. Thanks to recent advancements, the newer flotation machines can be designed with different launder and crowder arrangements to enhance froth management. Nevertheless, lower head grades, complex ores and even larger mechanical flotation cells can lead to insufficient froth collection, even if the cell is equipped with the most recent flotation advancements like the center launder design. Aforementioned issue can become critical at the end of the flotation row. Increased crowding has been proven to be a solution to overcome inadequate froth recovery. However, scaling-up crowders for larger flotation cells can rise challenges, particularly in terms of structural limits and design for service. This paper presents the development journey for the Spider Crowder Upgrade, an advancement to improve froth collection in large flotation cells that are already equipped with center launders.

Feb 1, 2024

By Henry Mackay

THE interesting paper recently submitted by Messrs. Tobelmann and Potter' shows that chemical problems have developed which are of great interest in this new and important branch of metallurgy. Those who realize what a process of this kind really involves will agree that it deserves a better name than "leaching process." The word leaching conveys the idea that the copper is simply leached out of the ore with acid and then precipitated on iron; the chemistry of such a process would be of little interest. As, however, during the first year's operation of this plant 24,400,532 lb. (11,067,837 kg.) or about two-thirds of the produce, was electrolytic copper, while 7,992,033 lb., or about one-third, was cement copper, it would seem more appropriate to term the process electrochemical. It further appears, from the particulars given, that efforts have been made to have the entire production in the form of electrolytic copper. -This could be done if the chemistry of the problem were kept in balance, so that it would not be necessary to discard any solutions that carried copper and acid of commercial value. A process, such as that under consideration, in which the copper is precipitated from solution by electrolysis, the solvent being at the same time regenerated, is one that requires special chemical and electrochemical knowledge and experience if all the -copper in solution that has been extracted from the ore is to be successfully and economically produced as electrolytic copper. The object of this paper is to discuss, from the practical and theoretical standpoints, the chemical and electrochemical problems involved in the working of a process of this kind, and' which must be solved to keep it in chemical and electrochemical equilibrium. In such a process, if the chemical balance is maintained, a solution can be used alternately as a

Jan 9, 1919

By F H. Henrfquez, A G. Oroz

Design and operating conditions of large size mechanical flotation cells were evaluated by comparing them with actual operating conditions in a plant. The objective was to determine the time scale-up factor, typically based on empirical rules. Experiments were conducted on the rougher flotation circuit at Minera Escondida Ltd. The circuit consisted of self-aerated mechanical cells of 160 m3, arranged in six parallel banks with nine cells each. The rougher circuit flotation kinetics were evaluated from direct sampling and local mass balances around each cell of the bank. Adjusted overall mass balances were also developed. This information was used to fit different kinetic flotation models, and it was found that the rectangular distribution function was the most appropriate to describe the distributed rate constant for industrial operation. Then, a rougher flotation simulator was developed to describe the actual operation in terms of the operating variables (mass flowrate, solid percentage, feed grade) and the actual volumetric flowrate entering to each cell. In this study feed pulp samples were taken in parallel from the rougher circuit and were simultaneously floated in the laboratory. The kinetic behaviour was then modelled at a laboratory batch scale in order to determine the time scale-up factor between laboratory batch flotation data and industrial size flotation. The time scale-up factor observed for large sized cells, 160 m3, was found to be reasonably similar to those previously determined for self-aerated mechanical cells, but of lower size, operating at similar recoveries. In addition, the relative effect of mixing, between laboratory batch and an industrial flotation bank, was quantified by the parameter, separating the impact that kinetic and mixing changes have on the time scale-up factor. In general, the rougher flotation operation was found to reach the predicted metallurgical target, and the optimal separability criterion was also respected. The diagnostic generates information about the internal state of the process and helps to identify potential improvements for design, operation and control of the circuit.

Jan 1, 2005

By J. K. Grunig

A process consisting of leach, continuous countercurrent decantation, resin-in-column ion exchange, evaporative crystallization of beryllium sulfate, and decomposition of the sulfate was developed for Spor Mountain, Utah, ores. The process is metallurgically sound, has a minimum of process steps, and is applicable to a wide variety of beryllium ores. The most novel aspect of the process is a resin system of ion exchange which is highly selective for beryllium and which rejects substantially all impurities except for minor amounts of aluminum, magnesium, fluorine, and sulfate in addition to beryllium. The oxide from sulfate decomposition meets specifications of potential users.

Jan 1, 1982

By F. Shigeyoshi

The development of pelletizing during the last ten years has continued, however, self-fluxing pellets have not been regularly and commercially produced for use in blast furnaces, except as Kobe Steel, Ltd., Japan. This paper tells about unique developments for self-fluxing pellets, and their effects when used in Kobe Steel's No. 3 blast furnace at the Nadahama Works (inner volume 1845 Nm3, hearth diameter 9.5 m)., Several phases of the pelletizing process are discussed individually, and also their relation to performance in blast furnace operation. Special emphasis is placed on proper preparation of the limestone added to the raw materials, and indurating at optimum conditions. Means of improving pellet quality by correct control of size distribution of the raw materials used in pelletizing, and indurating temperatures, are also discussed. As basicity (CaO/SiO2) of pellets increased 0. 1, coke consumption decreased 3. 8 to 4. 2 kg per ton of hot metal, when using 70% pellets in the iron burden.

Jan 1, 1969

By K Morrison

Australia’s ageing population means that by 2050 there will be 2.7 people of working age to support each Australian aged 65 years and over compared with five working people per retiree today and compared with 7.5 in 1970 (Swan, 2010). This means that there is going to be a greater demand on social services – for medical and aged care – from a smaller private income base. How will this gap be met? Australia is fortunate in that it has vast resources of mineral wealth; from iron ore, nickel and gas in Western Australia to the giant copper and uranium deposits at Olympic Dam in South Australia.The prospect of a meaningful profit based tax on this vast mineral wealth has been lost through Australian government’s handling of the issue in 2010 and with an industry fiercely opposed to the prospect of a mining tax. Hence, new ways of thinking are required. This paper looks at the issues facing the implementation of a novel scheme whereby Australia leases the mineral resources it extracts and thus derives income over the decades the metals are in-use in pipes, wires and structures with a premium paid for unreturned material or that used in dissipative applications. Applicable minerals could include copper, aluminium, nickel and rare earths. If Australia simply digs up and sells the metals once, the buyer becomes custodian of that resource and they benefit from controlling the future ‘above-ground’ resource stock.A complementary driver for a leasing scheme is the increasing importance of chain-of-custody following initiatives of the Responsible Jewellery Council with gold and diamonds, now with the potential to extend across commodities. The Australian minerals sector could thus position itself as a premium supplier with high social and environmental credentials.Recognising the implementation challenges, this paper includes a review of how such a system could be enforced to ensure that the metal is tracked throughout its life. It concludes with a discussion of the rates and terms should such agreements hold and suggestions for institutional arrangements for enforcing compliance.

Nov 22, 2011

By O. Babak, O. Leuangthong, M. A. Cuba

Integration of data from multiple sources and/or multiple scales is a common, yet challenging aspect of geostatistical resource modeling. Common approaches to data integration are based on a cokriging framework that assumes a consistency of scale in the information that leads to a requirement to composite the data prior to model construction. It is well known that the geostatistical model parameters are scale dependent. In particular, the volume variance of integrating these various scales has a direct impact on the semivariogram that should be used in model construction and/or the assessment of volume-variance relations as it affects resource estimation. This paper reviews and compares two different approaches for semivariogram upscaling. The first approach is the scaling laws. It is an empirically derived approach, involving several simplifying assumptions, one of which is a strict assumption of invariance of the semivariogram shape. The second approach is a theoretically derived direct upscaling of the semivariogram. This approach has been around for a number of years, but is seldom implemented due to software limitations. In this paper, we present a numerical integration approach to facilitate direct semivariogram upscaling. The advantage of direct upscaling over the scaling laws approach is shown by considering a synthetic example and a case study. Further, in the case of multiple codependent random variables, the extension of the direct semivariogram upscaling to the cross semivariograms is derived and an upscaled consistent linear model of coregionalization is presented.

Jan 1, 2013

By Roger Altman

The solubility of copper in primary spinel crystals encountered in reverberatory slag samples has been determined by electron microprobe analysis. These spinels, which ranged in composition from 22% A12O3 to pure magnetite, contained small quantities of dissolved copper (0-0.4%). Based on literature data it was estimated that the solubility limit of copper in solid magnetite is no greater than about 1% at 1200°C and about 2% at 1250°C. However, it was found that practically every spinel crystal examined contained significant amounts of matte inclusions. Further examination of converter slag revealed large quantities of irregularly shaped precipitated magnetite crystals which contained a large proportion of copper inclusions. Additional experimentation showed that the total copper content in reverberatory slag samples was greater than the sum of the estimated en- trained plus dissolved matte in the slag. This difference is believed to be significant and is due to the presence of matte inclusions in the spinel crystals. In the present reverberatory slag samples these inclusions accounted for about 1/2 of the amount of sulfide directly entrained in the slag.

Jan 1, 1976

By T. Bohmer, L. Auret, N. Pillay, Z. Horn, P. Rambalee, A. Haasbroek

As part of a broader digital technology-enabled transformation programme, a major mining company is systematically implementing Advanced Process Control (APC) solutions and associated instrumentation throughout their operations. This paper highlights the approach and benefits of this holistic approach for a specific instrumentation installation, and APC installation at a South African coal processing plant. For the coal processing plant under consideration, a systematic approach was followed. Process sections/units are considered from upstream to downstream processing. APC solutions are designed for each process section and each process section is interrogated in terms of availability of sufficient process measurements to ensure stable, capable, and ultimately, optimised performance. Where insufficient process measurements are available, instrumentation upgrades are implemented. Finally, APC solutions are implemented, and evaluated in terms of productivity, safety, health, and environmental benefits. For the flotation section, an opportunity was identified to install froth sensors. The installed froth sensors provide measurements on froth velocity, bubble size, height, colour, and stability. The improved visibility that the froth sensors provided on the flotation process resulted in quick gains in terms of productivity: for example, instability in the feed to the flotation section could be quantified. This resulted in targeted process troubleshooting in an upstream thickener, and subsequent improvement of process stability, and reduced feed variance. The measurements from the froth sensors were further integrated in an APC solution. Proportional mass pull contributions per cell and per line can be inferred from the froth sensors, serving as controlled variables, while pulp level set points serve as the manipulated variables. On-off tests indicated that the advanced process control solution provided increases in yield and product quality.

Sep 1, 2021

By N Currey, G W. Wilson, P Ritchie

Kidston Gold Mine in Queensland, Australia has a 310 ha tailings impoundment that has undergone final closure rehabilitation. Kidston Gold Mine evaluated their closure options for this low acid generating tailings impoundment, and due to a lack of cover soils and the cost of importing material, the mine decided to investigate the possibility of direct vegetation onto the tailings impoundment surface. The mine subsequently embarked upon a well planned and detailed research program to determine the feasibility and sustainability of this closure option. The research program included vegetation trials, toxicology studies for metal uptake by vegetation, as well as a comprehensive closure water balance model for the tailings impoundment complex. This paper describes the results of the long-term closure water balance for the tailings impoundment complex for the pre-closure state of the impoundment, as well as predictions towards the impoundment performance once final rehabilitation of the tailings impoundment complex has been achieved. The water balance presented is unique in that it is founded on unsaturated flow principles and accounts in full the impacts of the surface flux boundary conditions. This novel approach enables the prediction of actual infiltration rates into the tailings impoundment surface, which in turn allows for the calculation of how much seepage will exit from the tailings dam toe drains.

Jan 1, 2003

By Michael J. Magyar

The Federal Bureau of Mines has developed a hydrametallurgical method to recover aluminum, aluminum oxide, and fluxing salts from aluminum salt slags. The slag is leached with water at room temperature to produce a saturated brine slurry. Screening of the slurry yields an aluminum-rich fraction that can be returned to the dross furnace. The remaining slurry is vacuum filtered, yielding a clear brine solution and an aluminum oxide filter cake. Evaporation of the clear filtrate produces a high-purity fluxing salt for reuse in the dross furnace. Over 80 pct of the metallic aluminum is recovered in the aluminum-rich oversize fraction, while essentially all the fluxing salts are recovered by evaporation. This report contains the final results of an investigation on a process research unit scale, an economic evaluation of the method, and recommendations to further improve the process.

Jan 1, 1979

By Luc Morin

What you don't know won't hurt you! This attitude can get you into trouble when considering your process! When trying to extract the most and the best possible performance from a mineral processing circuit this should be reworded to say: What you don't know about your process will hurt your profits! Today, with the popularity of joint ventures, custom milling contracts and process audits by specialists, not knowing is a formula for trouble! Good Sampling Systems are no longer considered a luxury' Not too long ago the practice of grab sampling was considered acceptable and became the norm. Today, it is rare to hear metallurgists say, "All I need is a trend not a good representative sample. so I'll just grab a sample every few hours." Buyers and sellers of quality products have found that grab sampling leads to poor partnerships'

Jan 1, 1999

By J. Menuge, G. Barker

"Liberation (QEM-SCAN) and surface chemical (time of flight secondary ion mass spectrometry -ToF-SIMS) analyses have been undertaken on plant Pb circuit flotation samples with the aim of defining the factors resulting in sub-optimal recovery. Lead flotation circuit feed, cleaner concentrate and tails samples were examined on a size-by-size basis using QEM-SCAN. Sulfide minerals accounted for approximately one third of the flotation feed with pyrite making up 16 wt.%, followed by sphalerite (13 wt.%) and galena (3 wt.%). Non-sulfide gangue minerals comprised calcium carbonates calcite (26 wt.%), dolomite (14 wt.%) with quartz, feldspars and barite all contributing > 5 wt.%. QEM-SCAN analysis indicated that liberation was not the primary cause of the poor flotation response. Principal component analysis was applied to the ToF-SIMS data derived from five samples (as for QEM-SCAN plus rougher concentrate and tails) to enable identification of correlated surface chemical components. Although a significant range of correlations were observed we focus here on those that show a discernible pattern throughout the float circuit. It was found that for the flotation feed the surface of galena were largely obscured but where Pb was observed there was a strong correlation to surface Fe. For the rougher and cleaner concentrates the galena surfaces were relatively clean with no correlation to Fe for the rougher concentrate and minor correlation in the cleaner concentrate. However, in the rougher and cleaner tails the clear correlation of galena with Fe was again apparent. These results suggest, in combination with prior studies of pyrite morphology, that the principal factor effecting grade is the rapid oxidation of the framboidal pyrite resulting in the contamination of the galena surface with a high loading of hydrophilic oxidised Fe species, thus depressing flotation."

Jan 1, 2014

By V. G. Minenko, V. A. Chanturiya, A. L. Samusev

Eudialyte is one of perspective resources of zirconium and other rare earth elements (REEs). Large reserves of eudialyte concentrated in the Murmansk region of the Russian Federation. Usually, technologies of REE treatment include the decomposition of eudialyte concentrate in different acidic, extraction and utilization of all components. The main problems in the leaching of eudialyte include are: the formation of an unfiltered silicon-containing gel; low recovery of REE; difficulty extraction of metals from the productive solution; high aggressiveness of the reagents. One of the promising trends of intensification of the processing of hard-to-degrease rare metal raw materials is the use of energy methods for affecting mineral suspensions. These methods make it possible to increase the efficiency of break up fine-dispersed mineral complexes and extracting micro- and nanoparticles of a valuable component in subsequent deep processing. The purpose of this work is to investigate the effect of energy impacts on the nitric acid leaching of eudialyte concentrate. Experimental studies were carried out in a developed laboratory facility that makes it possible to evaluate the effect of electrochemical, ultrasonic and combined effects on the leaching of zirconium and REE from eudialyte concentrate. The studies carried out on the samples of eudialyte concentrate with the size class of -0.315 + 0.063 mm showed that the use of electrochemical and acoustic effects increases the extraction of ZrO2 in the production solution in 1.6 - 2.5 times, REE in 1.3 - 2.2 times, respectively. An analysis of the microstructure and phase composition of the surface of the eudialyte concentrate showed that the intensification of the leaching process is due to surface cleaning from the silicon-containing gel, as well as the opening of capillary channels and microcracks, which accelerates mass-transfer processes. The results obtained open wide opportunities for creation of modern and effective technology of processing of eudialyte concentrate, producing high-quality zirconium products and REE.

Jan 1, 2018