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By Klaus Hasselwander

Fluctuating SO2 gas streams represent a difficult task for designers of SO2 removal systems (with respect to designing the plant), but in spite of the designers great efforts to solve the problems, the operation of such plants requires much care and attention. A fluctuating gas flow usually results from metallurgical smelting processes. Both gas composition and gas flow rate may vary. The first part of this paper outlines some existing technical solutions and presents the Pros and Cons of the different solutions. These solutions outline are: - Sulphuric acid plants operated with a preheater permanent in operation - Sulphuric acid plants with concentration increase of SO2 gas either using regenerative SO2 removal or cryogenic partial condensation of the SO2 - Sulphuric acid plants with additional burning of sulfur to increase SO2 content - Single-stage sulphuric acid plants followed by a tail gas system (which is) designed for periods of low SO2 input In the second part, this paper describes some existing technical solutions for removal of SO2 at low concentrations (i. e. less than 0.1 - 2 %-by volume), which could be used as tail gas treatment system for acid plants. While selecting an appropriate solution, special attention should be given to operating costs, which usually to a large extend depends on the type of absorption agent and the costs for disposal of the sulfur compound produced.

Jan 1, 2009

By D. J. Singleton

Erosion corrosion of 12 alloys in phosphoric acid waste water was studied by the Bureau of Mines. Tests were conducted on oblate spheroids or cylindrical specimens in 12-and 60-cm-diam ball mills by grinding phosphate rock in gypsum pond water with a starting pH of 1.6. For comparison, tests were conducted while grinding phosphate rock in plain water. Static corrosion tests in gypsum pond water also were conducted. For all alloys, the wear by erosion-corrosion (milling with gypsum pond water) was greater than the sum of erosion (milling with water) plus static corrosion. Erosion-corrosion wear was about 1,500 to 3,000 mpy for the alloyed white cast irons, 1,000 to 1,400 mpy for commercial steel ball material and type 316 stainless steel, and 600 to 900 mpy for nickel-base alloys and a high-manganese, nitrided stainless steel. Alloy costs per unit of phosphate rock 'processed favor a low-alloy, high-carbon steel or a high-manganese, nitrided stainless steel.

Jan 1, 1985

By Robert H. Carpenter

Molybdenite mineralization occurs in the hood zone of the Questa mine aplite-porphyry intrusive, one of the three sil ica-rich intrusive5 occurring along the east-west trending Red River Trench that crosses the northerly trending Sangre de Cristo Mountains in north-central New Mexico. The Trench is located immediately north of the circular Gold Hill positive block between the Red River and Cabresto Creek drainages. The aplite-porphyry bodies intruded a mid-Tertiary volcanic section consisting of lower andesites, overlain by latites and rhyolites. They occur largely in the andesites and were emplaced mainly by metasomatism rather than by sloping. Hydrothermal alteration occurs both as blanket propylitization in the volcanics and sericitization and kaolinization in the porphyries and as halo-type alteration outward from veins and shear zones resulting in strong biotization in the volcanics and sericitization and kaolinization in the aplitic rocks. Mineralization consists of: ( 1) molybdenite- quartz veinlets; (2) banded molybdenite, quartz veins frequently with biotite and potash feldspar along the walls and occasionally with minor lead, zinc, and copper sulfides and with fluorite and carbonates when again reopened; ( 3) high grade molybdenite locally along shear zones; and ( 4) molybdenite paint along joint and fracture surfaces. The mineralization was associated with faulting that resulted from numerous periods of gravity adjustment along the Trench and was controlled by the major shear systems that trend northeast, east-west and north-south to northwest. Molybdenite has been well oxidized in nearsurface exposures to ferrimolybdite and the molybdenum-bearing ferric hydroxide, akaganeite. The oxidation of the abundant pyrite within the veins and shear zones and of the alteration pyrite in the volcanics resulted in a low pH environment under which the acid molybdate ion released by oxidation was fixed either in the ferrimolybdite or the akaganeite molecule in the veins and shear zones or in the soils. Little has been lost in the runoff.

Jan 1, 1968

By B. Rai

Processing of dolomitic phosphate ores remains one of the most challenging problems in phosphate ore beneficiation. The beneficiation plant at Jhamarkotra in Rajasthan, India for example is currently using a conventional double stage flotation process which involves first a fatty acids flotation to produce a combined dolomite-apatite concentrate (bulk concentrate) from associated silicate gangue. Dolomite is then separated from this bulk concentrate by flotation with fatty acids collectors and depressing apatite with phosphoric acid and sulphuric acid. This process requires addition of large dosages of reagents (H3PO4 and H2SO4) to depress apatite and to maintain highly acidic pH during flotation. Furthermore several cleaning and scavenging stages are needed to obtain the product of desired quality. We have developed and employed a molecular modelling based methodology of designing selective reagents for apatite-dolomite separation. We have been able to take into ac-count the differences in the distribution of calcium cations on these two surfaces in our design and hence develop novel phosphonic acid based depressants for apatite-dolomite separation with con-ventional fatty acids as flotation collectors. We have demonstrated the utility and power of molecular modelling based reagents design approach through this work on beneficiation of Jhamarkotra dolomitic phosphate ore using our novel phosphonic acids based depressants at pH?s close to natural pH. It was possible to reduce the MgO content of the ore from as high as 13.3 % to 1.5% in a single stage flotation. Our flotation separation results on Jhamarkotra ore with these new phosphonic acids based tailor-made depressants for apatite-dolomite flotation separation are discussed in this paper along with results of corresponding molecular modelling computations on the same system.

Jan 1, 2014

By D Blair, T Scutts, L Fergusson

This paper presents a waste rock treatment and rehabilitation program conducted at a metaliferous mine site in northern New South Wales from 2000–2013. It updates findings from 2005 for Program #1 (which examined acidity, leachable metals and tree growth in a control and three treated areas of waste rock) and includes new results for Program #2 (which examined acidity, plant uptake of metals and trace elements and tree growth in a control and four treated areas compared to undisturbed background levels) and Program?#3 (which examined the treatment and revegetation of submerged mine tailings and an exposed tailings beach).Program #1 showed low soil pH in the control area remained unchanged from years 1–14, and soil pH in the limed and capped areas was initially increased but fell back to starting levels within 12 months and remained low for 14 years. In contrast, soil pH in the Terra B area resulted in soil high pH immediately after treatment and increased in years six and 14 without further treatment. Tree height and density in 2005 and again in 2013 indicated acidity in the control, limed and capped areas suppressed tree height and density; however, in the Terra B area, revegetation in 2013 was comparable to undisturbed forest. Outcomes in the control, biosolids and three Terra B areas in Program #2 were similar to those observed in Program #1.Program #3 showed the submerged and exposed tailings initially had low pH and high concentrations of total and leachable metals before treatment, but these became non-leachable after treatment with Terra B. Revegetation was achieved on the tailings beach, with almost uniform colonisation of bulrush and common reed, along with bottlebrush and golden wattle; a variety of reptiles have also been observed on the revegetated tailings beach, along with migrating ducks, spoonbills and grebes.CITATION:Fergusson, L, Blair, D and Scutts, T, ?2014. Treatment and rehabilitation of acidic waste rock and tailings – a 14-year case study, in Proceedings Life-of-Mine 2014 , pp 247–260 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By Werner Wenzel

Methods to increase the gas penetration through sinter layers. In the field of agglomeration, sintering has gained importance, specially in Europe; in Best-Europe this trend will continue till the year 1980, since it is quite probable that in the blast furnace burdens with 50-60 sinter, 10-20 % pellets and 20-25 % ore lumps will be employed. In order to meet this demand for sinter, new sinter bands with reaction areas between 300-400 m2 will be constructed. Chemical and physical phenomena during the Suction-Draught-sinter process. Iron ore sintering is generally considered as a burning process where the material contains 90-95 % ash i.e. non-combustible ingredients. Sintering represents a heterogeneous exothermic reaction in which the chemical phenomena as combustion, calcination, hydration, reduction and oxydation are superposed by physical phenomena. The physical phenomena are devided into material transport and simultaniously occurring heat transport processes. The velocity of these combined physico-chemical reactions i.e. the change in the reaction site per unit time determine the efficiency of the sinter process. The gas permeability as an important criterion of heat transport during the Suction-Draught sinter process.

Jan 1, 1971

By The Staff

"THE property of Red Mountain Mines Limited is located 11/2 miles north and west of the town of Rossland, in southern British Columbia. The mine is situated on the flank of Red mountain, famous in pioneer days as the site of a number of profitable gold-copper producers. Mining and milling commenced in May, 1966, and by the first of July the concentrator was treating close to its average design capacity of 400 tons per day. The following description of the property and its operations is divided into three parts, dealing respectively with geology, mining and milling.GeologyAll the known ore reserves of Red Mountain Mines occur on the Coxey claim, on the west slope of Red mountain. Although there are indications of molybdenite mineralization elsewhere on the Company's property, these have not been developed.The Coxey and adjoining areas are underlain by the Mount Roberts formation of the Rossland volca-nics. This formation consists of an interbedded series of volcanic and sedimentary rocks, mostly brecciated and silicified near the ore zone, and all intruded by igneous rocks which occur in various forms, and vary in composition from basic to acid. The country rock in the vicinity of the mineralization seems to be mostly a volcanic, approximately andesitic in composition, and possibly a surface flow. There is much banding, some of which is undoubtedly due to tuff and agglomerate layers, and some to narrow, siliceous, sedimentary horizons such as the surface exposure of the main ""A"" orebody, much of which was a thin capping of greyish banded rock that looked like quartzite. The drill holes also intersected occasional layers of black, argillaceous quartzite, sometimes altered to a greenish colour. The whole assemblage has been silicified with varied intensity, sometimes to such an extent as to have obscured or obliterated the original characteristics. The mineralized zone has also been strongly brecciated, the fragments varying in size from less than an inch up to large masses, best described as a mega-breccia. Anomalous results obtained in drilling, such as sedimentary sections that do not appear in adjoining holes, may sometimes be due to the presence of these large blocks, no longer in their original position. The whole volcanic unit is thus very complex and confusing. For practical purposes, the ore may be said to occur in a greenstone formation with minor sedimentary interbeds and considerable later igneous material."

Jan 1, 1967

By S. R. B. Cooke, J. Bruce Clemmer, F. P. Diener

"The limestone deposit utilized by one of the plants of the Universal Atlas Cement Co. is covered in part by a stratum of cherty limestone. If this overlying deposit could be utilized by removing the excess of chert economically, quarry costs could be reduced and the amount of rock economically available would be increased greatly. On account of the distribution of flint and limestone, a product fairly free of flint can be obtained until the quarry face is about 50 or 55 feet high. As the face is worked farther back into the hill, the comparatively clean stone is overlain with a constantly increasing amount of high-flint limestone. If this flint remained with the limestone, there would be a prohititively high silica ratio in the finished cement; if the flinty layer were removed as overburden a very large tonnage would be handled and much good stone lost. Consequently it was felt that means should be devised for separating the flint from the limestone after it reaches the plant.The investigation was undertaken by the Mississippi Valley Experiment Station of the United States Bureau of Mines in cooperation with the Universal Atlas Cement Co. and the Missouri School of Mines and Metallurgy, Rolla, Mo.CONSIDERATION OF PROCESSESMany schemes for the separation of Minerals are based on differences in the specific gravities of the minerals to be separated. In this case the flint has a specific gravity of approximately 2.62 while the limestone averages about 2.70. This differential is not large enough to permit separation by any method based on specific gravity. Furthermore, all the limestone particles in any given sample are not alike; usually about 10 percent of them have a specific gravity the same as, or lower than, the flint."

Mar 1, 1935

By R. P. King

"A model of the flotation process can be used effectively for design and control. For design purposes it can be used to predict the performance of a large plant from laboratory and pilot plant data. It can be used for control purposes to assess the utility of any proposed operating modification to an existing plant, and it can also be used to determine optimal control settings for best operating performance.A model has been developed that will allow for variations in feed properties and for variations in fineness of grind. The model can be used to assess the effects of reagent addition rate, aeration rate and pulp level on plant performance and these are the control variables that are used individually or together in all operating flotation plants. The model provides for a distribution in the values for flotation rate constants, particle size and mineral fraction, and, because of its complexity, requires a large computer when it is to be applied to a typical plant configuration. The computational method that is used to apply this model to such configurations is described in this paper, and particular attention is paid to the problem of allowing for feedback of tailings from cleaners and recleaners."

Jan 1, 2014

By William C. Smith

Roof support, an important aspect of ground control, involves maintaining roof competency to ensure a safe and efficient mining environment. Wide variability in rock quality and stress distributions requires a systematic approach to roof support design that satisfies specific goals. The success of past roof sup-port in reducing the incidence of roof falls has been primarily attributed to safer roof bolting practices. However, roof falls continue to be the number one occupational hazard in underground coal mines. This U.S. Bureau of Mines report presents a general overview of roof bolting and other roof support methods used in the United States. Characteristics of bad roof and associated roof failure theories are briefly presented as background to roof support. Methods of detecting and monitoring roof behavior and/or bolt performance provide essential feedback on roof support requirements. A discussion follows on roof bolt design that assimilates roof and support parameters into useful equations or nomographs to help decide what bolt types to use and how they should be installed under different roof conditions.

Jan 1, 1993

By Angelus S. C. Owili-Eger

Although the foundation of a unified treatment of fluid flow in variably saturated porous media was established more than seventy years ago, no serious attempt was made to develop it until the early 1970's. Ever since, a number of unsaturated-saturated numerical models have been reported in the literature. However, none of these models have treated multidimensional, multiphase flow in deforming media, parts of which may undergo extensive secondary fracturing. A situation such as this is not uncommon in coal mining operations in which the longwall method of extraction is employed. The present model has been structured to handle such physical systems. This paper presents the mathematical formulation, the numerical algorithm, and a further validation and evaluation of the modified model. The model treats a multiphase flow in a three- dimensional regime and handles mining excavations of complex and changing configurations.

Jan 1, 1980

By D. B. Dow

This paper on the physical chemistry of oil-field emulsions is the last of a series of three prepared as a result of a study of oil-field emulsions. The first paper3 deals with the factors responsible for the formation of emulsions, find the second4 with methods now utilized for dehydrating oil-field emulsions. A more complete report of the whole investigation is in preparation. The laws governing the formation and resolution of oil-field emulsions fall in that branch of physical chemistry doling with colloids. Much work has been done by the physical chemist on colloids And emulsions, and, although most of this work was on commercial and pharmaceutical emulsions, yet the principles developed apply in a general gray to oil-field emulsions.

Jan 1, 1925

By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

By Jan A. Aune

The paper describes a number of electric furnace equipment modules especially developed or modified for slag furnace applications. Both the resulting design concept for a modern electric sulfide smelter and some of the changes in traditional process-concepts made possible are outlined.

Jan 1, 1983

By D. Fodor

In Romania, there are significant lignite and brown coal reserves hosted by different regions of the country. The most important lignite bearing zone of the country situated in the North ? West part of Oltenia region and which covers a surface area of 2,500 km2 and host a total reserve of 3.0 billion tons of lignite, of which more than 95% can be exploited by open cast method. The paper deals with the existing geological and mining conditions of the zone , the distribution by mining basins and exploitation perimeters, the open cast working technologies and the economic outcomes obtained throughout the time. Years ago, for the improvement of the economic situation as a whole and in each unit, a large production reorganization, technology update and modernization process was started up. There are described the rehabilitation measures of the technological lines and modernization of the equipments of the production flow-sheet, measures developed at present, too and which will still continue in future. There are mentioned the equipments considered, the components under modernization and the economic outcomes obtained so far. At the end of the paper there are presented the future actions for the equipment modernization and perspectives of the lignite deposit exploitation to meet the national economy requirements of solid fuels.

Aug 1, 2013

By H. S. Price, D. A. T. Donohue

The system of equations describing displacement of a hydrocarbon liquid by a hydrocarbon vapor in a porous medium where mass transfer takes place between the phases is solved numerically for a variety of gas injection processes. Even though the method of solution is quite general, only systems with three hydrocarbon components are considered. Computer simulations of displacement processes wherein mass transfer between phases is both considered and neglected are compared, and it is shown that neglecting mass transfer can give pessimistic displacement efficiencies. INTRODUCTION The role of the gas displacement process in the recovery of petroleum has been subjected to a series of detailed analyses; as a result, a number of predictive models have been published in the literature. However, because of major simplifying assumptions, most of these models do not completely represent the physical system. As a result, the effect of making the simplifying assumptions is unknown. Therefore, a complete representation of this process — one without major simplifying assumptions —should lead to a fuller understanding of the process, and perhaps to methods of improving it. The general method of developing a model for two-phase fluid flow in a porous medium is to solve simultaneously the continuity equation, the energy equations and the equation-of-state for each phase under the prescribed initial and boundary conditions. For an isothermal system, the energy equations reduce to the momentum equation. Darcy's law. However, since natural gas is the vapor state of the reservoir liquid, interphase mass transfer may take place with concomitant changes in both the intensive and extensive thermodynamic properties of each phase. It is this phenomenon that has often been omitted in previous mathematical models. An additional relation, then, which accounts for mass transfer between the phases, must be included with the other equations to specify a complete model. Completely formulating the equations to be solved is not a difficult task1 but obtaining their solution has been intractable up to now. Availability of large-memory, high-speed digital computers now makes an attack on this formidable problem possible. This paper presents a preliminary study of the problem. Since this investigation is intended to be exploratory, it is restricted to the linear, horizontal, isothermal, two-phase viscous flow of oil and gas in an oil reservoir. In the early development of predictive models of this process, the reservoir system was considered as a unit and various forms of the material balance equation were proposed.2-4 Pressure and saturation gradients were then added in the Buckley-Leverett model.5 The Buckley-Leverett formulation considered the fluids to be incompressible; thus, the mathematical model reduces to a steady-state system. In the 1950's, studies incorporating numerical techniques were being published.6-9 These mathematical models differed in the efficiency of finite difference techniques, the inclusion or exclusion of capillarity or the number of space dimensions considered. To solve these nonlinear, partial differential equations, each phase was considered to be homogeneous with time; therefore, mass transfer between phases was neglected. The effect of mass transfer on the gas displacement process was first reported by Attra. 10 He simulated the one-dimension flow system by a series of cells in each of which the fluids were equilibrated during a time step. In addition, the pressure throughout the system during each time step was predetermined and constant-phase velocities were calculated according to the Buckley-Leverett incompressible fluid flow model. Welge et al.11 developed a model for the displacement of oil by an enriched gas where composition is considered to be a dependent variable. Fluid

By Fernando Hernández Polanco

Transportation and handling metals and alloys from mills to consumption factories as well as dosing in conventional processes with ingots and scrap has always been considered a complicated activity with high operating costs. Several manufacturers of ferroalloys willing to solve these problems have chosen an alternative for their products that can be used to secure, during transport and dosage in the processes to making special steels, with more efficient consumption of ferroalloys. The trend for the production and sale of ferroalloys is to provide the product in the form of granules packed in bags or in bulk. In this paper we will show you how the granulation process was developed and rapidly adopted the ferroalloys industry as an effective solution to reduce operating costs, create cleaner and safer working environments.

Oct 30, 2017

By Y. Buro

The Bachelor Lake gold deposit occupies an ESE-trending, SW-dipping, silicified shear zone with hematitic alteration. It transects NE-trending, steeply dipping Archean volcanic formations and the O'Brien granite. Major W-SW and N- NE-trending faults have affected the ore zone and the emplacement of the granite intrusions. Movements along the WSW set may have opened the fractures filled by the mineralization. Gold is generally associated with pyrite. Its source, whether a granitic pluton or a volcanic sequence, is undetermined, but the granite probably provided the concentrating mechanisms through heat and hydrothermal solutions.

Jan 1, 1984

By W. A. Padgham, H. Helmstaedt

Field evidence for current hypothe e about age and kinematic ignificance of gold-bearing hear zones in the Archean Yellowkni fe greenstone belt is reviewed , and it is concluded that major disagreements between previous workers are a direct result of differences in stratigraphic and tructural in terpretations of the Yellowknife Supergroup. Although goldbearing hear zone appear to be confined to the mafic volcanic pile of the Kam Group. it can be shown that shearing affected all supracru tal rocks, including the Jackson Lake Formation. now con idered to represent the youngest unit of the Yellowknife Supergroup. tructural ob ervations are incompatible with the hypothe is that the hear zones represent loci of ynvolcanic gravity sliding but are consistent with earlier conclu ions that shear zone development commenced with rotation of the volcanic pile and continued as re ult of lateral shortening broadly overlapping with the emplacement of granitoid batholiths. Shear Zones are common throughout the entire green tone belt. yet productive zone are confined to the Yellowknife Bay Formation of the Kam Group and localized where flow abut with a high angle again t the contact of the We tern Plutonic complex. However. no obvious tructural and lithological features have been recognized that are more favorable for gold deposition and distinguish the shear zones and flows of the area around the mines from those of other parts of the greenstone belt. The model that gold wa transported by metamorphic solutions and that hear zones were the firs t-order control for gold deposition provides no explanation for the trong localization of the depo it . As porphyries with elevated gold contents are present in and near ome of the mines. the possibility that gold was deposited from hydrothermal system around fel ic intrusion representing early phases of the Western Plutonic complex should be given erious consideration.

Jan 1, 1986

By D. Krawczykowski, D. Saramak, T. Gawenda

"Annual world zinc consumption is as high as nearly 14 millions of tonnes. Approximately 50% share of zinc is used for corrosion protection in processes of continuous galvanization and the hot dip processes. In the latter, two zinc containing residues are produced: zinc ash and hard zinc, which constitute around 10% each. Paper concerns the method of possible separation of metallic zinc from the non-metallic zinc compounds from the zinc ashes – the waste product of hot dip galvanization process. The investigative programme covered the comminution tests of the feed (zinc ash) in selected crushers: jaw crusher, roller crusher and impactor. Results of investigations show that application of individual crushing device results in various breakage of the feed sample. Impact force caused the highest increase in finest particles size fractions of the product, while metallic and non-metallic fractions were comminuted differently. The compression force, in turn, caused the selective comminution, i.e. the breakage of metallic zinc was observed in a higher degree. The presented approach appears to be an economical supplementary method of initial recovery of metallic zinc from metallurgical zinc waste. For the high demands for the zinc in the world and the need of corrosion protection, the method presented in the paper helps in more effective zinc recovery and environmental protection.INTRODUCTION AND METHODOLOGY World production of metallic zinc during last decade shows a slight increase and in recent years its consumptions reach 14 millions of tonnes. Figure 1 shows world production of zinc in the time period 2009 – 2016. Main directions of zinc utilization include: - Galvanization - Production of zinc alloys - Brass and bronze production - Semi-manufactures of zinc - Chemicals The major share in global zinc consumption constitute galvanization process (Bright 2007). Two main types of zinc galvanization are: hot-dip galvanizing (HDG) and electro-galvanizing."

Jan 1, 2018