Search Documents

By María Eugenia Castro, Silvia Galasso, Jorge Duca, Claudia Osuna, Ernesto Esparza

"We present a procedure for treatment of non-active solutions equivalent to the solutions obtained from dissolution of ionic exchange resins used in purification of a nuclear reactor primary cooling system containing Co, Ni, Cs and its isotropic varieties as main radioactivity source. Finally it is immobilized into a ferritic matrix by calcination which avoids its future leaching into environment.In order to achieve the objective of this treatment, a bivalent and a trivalent iron salt is added to the solution. Then, either a base or an acid is added, depending on the initial pH of the treated solution, with a Cs precipitating additive in order to reduce Co and Cs by precipitation, flocculation and adsorption. Controlling the amount of precipitating reactives it is possible to modify the activity/volume rate becoming a medium into a low radioactivity waste.The leaching test result applied over the ferritic sample is lower than the minimum limit established by law. Therefore, it can be kept safely in a interim storage."

Jan 1, 2008

By D. Hong, K. N. Han

The leaching behavior of rhenium in ammonium iodide solutions with iodine as oxidant was studied. Experiments were carried out in an autoclave to investigate the effects of stirring speed, temperature, solution pH, and iodine and iodide concentrations on the dissolution of rhenium. It was found that a high temperature and a high solution pH were essential for the efficient leaching of rhenium. The dissolution rate was found to be dependent upon the concentration of iodine and iodide. It was concluded that the dissolution of rhenium under the conditions studied was controlled by the mass transfer of iodine with an apparent activation energy of 15.8 kJ/mole.

Jan 1, 1999

By H. L. Overton, J. B. Lipson

The concept of sodium single-ion equivalent activity as developed by Gondouin, Tixier and Simard,' was used to determine the filtrate resistivity-activity relationships for 150 laboratory and 49 field drilling muds. With the exception of the native and phosphate high-resistivity muds and the calcium-treated muds, the filtrate resistivity-activity relationships were found to be within 20 per cent of that for pure sodium-chloride solutions. Gondouin, et al,* previously suggested a method of treating the high-resistivity muds in quantitative electrical log analysis. A new treatment is presented which uses the P-alkalinity of the filtrate as a correlating parameter in handling the calcium-treated muds in quantitative electrical log analysis. INTRODUCTION Gondouin, Tixier, and Simard in 1957 introduced new interpretive procedures for analyzing the self-potential curve of electric logging. They re-emphasized the previous work of the Schlumberger brothers, Wyllie and others, and re-defined the activity concept in terms of a number which they termed the effective resistivity. Their procedures are particuarly effective when the connate-water resistivities are less than 0.08 ohm-m or greater than 0.3 ohm-m. For gyp muds where the calcium content is known, a procedure was presented which allows calculation of the connate-water resistivity with improved accuracy. These procedures assume that one of the fluids in the system is a pure sodium-chloride solution, but they are not limited by the assumptions. For the fresh and saline connate waters, for instance, it is assumed that the drilling mud filtrate is a pure sodium-chloride solution. For the gyp mud interpretive procedure, it is assumed that the connate water is a pure sodium-chloride solution. Brown,' on the other hand, has suggested that it would be extremely fortuitous if drilling mud filtrates could all be treated electrochemically as sodium-chloride solutions, and he cites some examples where discrepancies exist. A study has been made of the deviations of sodium single-ion equivalent activities, an of drilling mud filtrates from that of pure sodium-chloride solutions. Drilling fluids in common use on the Texas and Louisiana Gulf Coast and laboratory-controlled muds were investigated. Using a cell patterned after Gondouin, et al, (Fig. I), the equivalent activities were measured. It should be remembered here that the activity measured is merely an index which uses numbers that represent the sodium single-ion equivalent activity a,., of the mud filtrate. The membrane potential developed across the cell was determined with a null-type potentiometer. The resistivities of the solutions were measured by the four-electrode method. The resistivity system was calibrated by using saturated KC1 solution as a standard. Chemical properties of the drilling fluids studied were measured with standard API-approved equipment for the particular property in question. For the activity measurements, two shale discs were chosen to serve as cationic membranes. These two discs were both 1 1/4 in. in diameter and, respectively, 1/4 and 1/8 in. in thickness. The membrane potential, Em, was determined using the shale discs as cationic selective membranes separating two standard sodium-chloride solutions of known mean activity. Then by comparing the constant Km in the following equation, with the theoretical value of — 59 mv at 75OF, the perfection of the membrane was determined. The variation of Km for the two membranes used in this experimental work, as well as one of the many unsuitable membranes, is shown in Fig. 2. The measurement of the activity of mud filtrate involves the balancing of its combined individual activities against a standard solution of known mean activity. At the point where there exists zero potential across the membrane cell, the activity effects may be assumed equal for all practical purposes. The mechanics of making a null reading of this sort requires having a large number of different mean activity solutions. A more practical method involves

By A. Frits van Tol, Rodriaan Spruit, Jan H. van Dalen

"Abstract In recent years, there have been major problems with deep excavations in urban areas supported by diaphragm walls. In some cases, like the fatal Nicoll Highway collapse in Singapore the quality of the D-walls was not the cause. However in other projects, like the problems with the major leak in the walls of the Boston Big Dig and with leakage in a few projects in Belgium and The Netherlands was related to poor D-wall quality. Leakage through the D-walls at the joints in deep excavations led in these cases to very serious settlement behind the walls, in the case of the North- South line in Amsterdam, there was severe damage to historical buildings. This paper describes ongoing research that focusses i on acquiring more knowledge on and improvement of D-wall installation, in particular the flow process prior and during casting ii on the detection of anomalies prior to excavation and iii on the composition of the concrete mixture in view of a better and more sustainable concrete quality of D-walls.INTRODUCTIONIn the case of deep excavations in urban areas close to neighbouring buildings, diaphragm walls are one of the best feasible solutions for the retaining structure. Although the costs of D-walls generally exceed the costs of alternative wall solutions, the advantages are decisive in many situations. The main advantages of D-walls are the limited impact of the installation on the built environment, the high stiffness and bearing capacity and the retention of water, even at considerable depths. This makes Dwalls often the preferred solution for deep excavations Sometimes the D-walls are the temporary support while for the final stage a complete concrete box is constructed in the excavation. In many other cases the D-wall has the permanent function of retaining soil as well as groundwater.In the last ten years, there have been major problems with deep excavations in urban areas supported by diaphragm walls. In some cases, like the fatal Nicoll Highway collapse, 2004 , the quality of the Dwalls was not the cause. In other important failures like the collapse of the Archives in Cologne, 2008 and Dubai Infinity Tower Flooding, 2007 a combination of design and quality issues played a role. However, the major leak in the walls of the Boston Big Dig was related to poor D-wall quality (McNichol, 2000). Van Tol et al, (2010) describe a number of case studies in Belgium and the Netherlands, with leakage through the D-walls at stop end joints. In several cases with deep excavations these leakage caused serious surface settlements behind the walls. In the case of the North-South line in Amsterdam, there was severe damage to historical buildings. All these cases have generated considerable additional costs and delays, and subsequently public and political concern. Van Tol et al. (2010) present several possibilities to improve the quality of D-walls.Other disputes related to D-walls deal with the quality of the concrete and the sustainability of D-walls applied as a permanent wall. In particular the porosity of the concrete cover is sometimes problematic."

Jan 1, 2014

By J. B. Cabezas

The metallurgical processes that are frequently applied today use strong solutions and are of alkaline, acidic, or organic nature. These play a very important part in recovery of values from many ores. These solutions are of such a chemical nature that they are generally corrosive, flammable, and contaminating. In most cases, they are highly dangerous to the environment. Within the extractive metallurgical industry, it is also very common to have to deal with the handling of contaminating solutions with a high content of cyanide, arsenic, mercury, lead, copper kerosene, acid and many other components whose temporary or permanent confinement within the process must be adequate and absolute.

Jan 1, 1986

By D. E. Traut

A fluidized countercurrent ion-exchange system was developed, operated, and evaluated by the U.S. Department of the Interior, Bureau of Mines. The system consisted of integrated multiple-compartment absorption and elution columns in which the solution flows were continuous except for short periods when resin increments were withdrawn. The exchange of uranyl carbonate between a simulated in situ uranium leach liquor and a strong-base ion-exchange resin together with the subsequent elution with an ammonium chloride solution was studied. The effects of the number of sections, section height, amount of resin withdrawal, solution flow rate, and column diameter were investigated. The kinetic and equilibrium relationships for the absorption and elution steps were also examined. The experimental data indicate a strong interdependence between variables. Solution retention time appears to be a major limiting variable in the absorption process, while resin residence time is the determining factor in the elution process. The column was efficient over a range of conditions, but close control was needed for optimum operation.

Jan 1, 1978

By M. Timucin

High-temperature phase relations in the Pb-PbS system were established by the quenching of samples equilibrated in evacuated and sealed silica capsules. The liquid-miscibility gap seen in some previously published phase diagrams was not observed. The thermodynamic activities of PbS in liquid solutions of this system were derived at 1473 K from the isopiestic equilibration of samples belonging to this solution series with Cu2S-PbS melts of known PbS activities. The behaviour of Pb-PbS melts was found to be compatible with a subregular solution model. This model also made it possible to obtain an analytical liquidus for PbS that was in excelent agreement with the experimental determination.

Jan 1, 1988

By Arthur P. Chaves, John A. Meech, Vanessa M. Torres

Process choice for a refractory gold ore can become a controversial issue, especially at the early stages of a project. This happens since at preliminary stages, a simple economic comparison among the main process options is not possible as the differences are usually smaller than the precision of estimates. This paper presents a methodology to assess the suitability of each available technologies using a heuristic approach, were technical, economic, operational and environmental aspects are taken into account using a neural network methodology. This methodology is embedded in an expert system for gold ore process design, Intelligold, which is in the final stages of development.

Jan 1, 2000

By N. O. Lotter

Evaluation errors and value frequency distribution models of the gold ore bodies in the Witwatersrand and Free State systems are reviewed. It is found that the low-grade sections of the data are prone to the largest evaluation errors, and that an understanding of the shape of the value frequency distribution is essential to the calculation of mean grade. The evaluation of a mineral process for a particular ore requires attention to mil-feed sampling, sample processing, and monitoring. In particular, the calculation of a representative mass of mill-feed sample (Ms) should take account of size-by-size value variance. Alternative Ms models are discussed.

Jan 1, 1995

By K. Valta

This paper presents an approach for developing a Sustainable Development Indicators (SDIs) framework tailored to the Greek Industrial Minerals sector, due to its importance for the national economy. To achieve this goal, an overview of the Greek mining and minerals, and especially the Industrial Minerals sector, from a technological and a financial perspective, is presented. In addition, a brief description of the global initiatives to this direction is given. The proposed indicators are based on those presented in 2006 by the Greek Mining Enterprises Association (GMEA) adjusted for the sector of industrial minerals by taking into account economic, environmental and social issues, known as the Triple Bottom Line (TBL) approach.

Jan 1, 2007

By A. I. Arol, I. Iwasaki

Clay minerals adversely affect the selective flocculation of iron ores. The effect of montmorillonite on a hematite-quartz mixture was studied. Montmorillonite, particularly in the presence of Ca++, caused indiscriminate dispersion of the pulp. Three possible mechanisms were postulated, namely, card-house structure formation, adsorption of dissolved species from montmorillonite, and montmorillonite- hematite interaction. It was determined that hetero- coagulation of montmorillonite on hematite was responsible for the behavior. Flocculation tests, montmorillonite abstraction tests, starch adsorption tests, zeta potential measurements, and surface analysis techniques were used to ascertain the montmorillonite-hematite interaction and to account for the manner in which it affected selective flocculation.

Jan 1, 1987

By J. M. Kane

IN all probability the mining and metallurgical industry as a whole can demonstrate a larger economic return from installation of dust-control equipment than any other major industrial group. This fact has partially accounted for the marked increase of dust-control installations made during the past decade. While the primary objectives for installation of dust-collecting systems are improved working and operating conditions for men and equipment, the fact that an economic return can be anticipated on salvageable materials is an added advantage which shows in partial or complete equipment write-off. The conditions apply to most phases of the mining, milling, and smelting industry, both non-metallic and metallic.

Jan 1, 1953

By David R. Zuchelli, Elio L. . Checca

Two case studies of methane gas explosions and their effect on the operation of underground coal mines are presented. The studies detail the recovery operations and investigations at each mine site. These include the circumstances prior to the explosions and the effects on the surface and underground ventilation control systems. Various ignition sources such as surface and underground electrical power systems, degasification sites, ventilation shafts, test well casings, and lightning activity were investigated. In each case, a lightning report from the National Lightning Detection Network1 was used in conjunction with the physical evidence and eyewitness accounts to confirm lightning strikes as the ignition source for the explosions.

Jan 1, 1995

By E Villaescusa

This paper describes a methodology for the design of mine pillars at the McArthur River Mine. The pillar strength is calculated using a method that accounts for confinement, pillar geometry and intact rock properties. The average pillar stress was calculated using in situ measurements of vertical stresses at shallow depth and the tributary area method in conjunction with numerical modelling. Observations of pillar behaviour indicate that an existing pillar stability graph may be slightly conservative and further adjustments for the local rockmass conditions are needed. The results to-date indicate that all mine pillars are stable for a range of mining geometries at McArthur River Mine.

Jan 1, 1998

By George W. Luxbacher

The inclusion of a new term "planned subsidence" in the Surface Mining and Reclamation Act of 1977 has lead the U.S. coal mining industry into a new aspect of engineering: subsidence planning. Subsidence planning has necessitated the integration of geotechnical, civil, and mining engineering disciplines. Although much of the foundation and application work has been completed, subsidence planning is still a developing area. This paper discusses the application of subsidence planning in several brief case studies (a high voltage transmission tower, a sewage treatment plant, and a slurry impoundment), emphasizing the risk assessment aspects necessary to account for some of the uncertainties that may exist.

Jan 1, 1986

By B. V. Driga

The paper presents the evaluation method of the thermal power potential of the salt lakes developed in collapsed salt mines in Romania. It is well-known that the hydro-chemical stratification of these lakes favors warmer internal layers. The degree of heat varies during the year, but, taking into account the large number of genetic lakes of this type, it can be used as a local utilizable power source. The authors analyze the correlations between the physico-chemical parameters of the water and the degree of heat stored as a function of the morphological parameters of the lakes, as well as the technical parameters for capitalizing on this power.

Jan 1, 2008

By Jin C, Shi X

The electrochemistry of leaching gold with thiosulphate has been studied systematically by using electrochemical techniques. Results show that the current peak of anodic dissolution of gold occurs at about 50 mV(SCE) and there is passivation in the polarisation curve in the thiosulphate solution in the absence of ammonia. Ammonia markedly improves the anodic dissolution rate of gold and reduces the passivation as well as making the current peak shift negatively. Results also show that there is no current peak for a cathodic process in the range of 0 -900 mV(SCE) in the thiosulphate solution in the presence of oxygen but absence of cupric ions and ammonia. In the solution containing 0. 1 mol/L cupric-ammonia ions, the peak occurs at about -400 mV (SCE) and the cathodic process is characteristic of a catalytic reaction. Oxygen presents a predominate effect on the cathodic process. Based on the electrochemical investigation, the following mechanism of leaching gold with ammoniacal thiosulphate has been proposed. Ammonia reacts primarily with gold ions on th anodic surface of gold and the formed A (NH3)2+ rea~s then with S2O 3 in solution to form the stabler Au(S203) 2 . Cu (NHS) 4 gains electrons on the cathodic surface and is reduced to CU(N) ? which is then oxidised by oxygen and regenerated into Cu(NH3) 4 after entering the solution.

Jan 1, 1993

By M. J. Nicol

This paper ,examines the kinetics of the extraction of uranium from acid sulphate solutions by strongbase anionexchange resins. Parameters such as the concentration of uranium in solution. the agitation of the resin beads in solution. the size of the resin beads. and the degree of cross-linking within the resin matrix were varied. and the effec ts on the kinetics are reported. The applicability, of various empirical kinetic models to the description of the data is assessed, and an attempt is made at the modelling of the rate data in terms of established theories about the diffusion of ions through films of stagnant liquid and through spherical beads of resin.

Jan 1, 1980

By Fathi Habashi

Precipitation of a metal from an aqueous solution of its salts by another metal is known as cementation, because the precipitated metal is usually cemented on the added metal. This phenomena was once described by the alchemists as "transmutation," when they dipped a piece of iron in a solution of copper sulfate and the iron was coated with a layer of metallic copper. The process can be predicted in terms of electrode potentials. The metal with the more positive (oxidation) potential, as given in Table 13-1 of the electromotive series, will pass into solution and displace a metal with a less positive potential.

Jan 1, 1970

By C. Klutke

This paper outlines a simple methodology for mineral characterization, developed as part of the Australian Mineral Industry Research Association (AMIRA) managed research project P777 ?The Development of Heavy Suspension Techniques for High Density Separations (Replacement of Clerici?s Solution)?. The project was sponsored by De Beers, Rio Tinto and Iluka Resources. Heavy mineral characterization of samples arising from exploration, mining or metallurgical processes is frequently conducted using laboratory heavy liquid analysis. Unfortunately, there are only a limited number of high density (?heavy?) liquids and these tend to be more toxic as their density increases. Low-toxicity inorganic solutions, based on tungsten compounds, have been developed that can be utilized at relative densities (RD) up to 3.0. Beyond this value organic liquids can be used; however, this presents significant health and safety hazards. Diiodomethane (methylene iodide) having a relative density of 3.31 is commonly used. Mixtures of thallium formate and thallium malonate were found in the early 1900s by Clerici to provide liquids having specific gravities between 4.0 and 5.0. For the characterization of the heavy components of mineral sand deposits (e.g. anatase RD 3.9, rutile RD 4.2, ilmenite RD 4.4?4.7 and zircon RD4.6?4.8) there is currently no heavy liquid alternative to Clerici?s solution. Clerici?s solution is highly toxic and testing is now conducted by few laboratories worldwide, with costs reflecting the chemical costs, infrastructure costs and health and safety regimes (e.g. blood testing of exposed staff). A simple laboratory technique of density fractionation has been developed, employing suspensions of fine tungsten carbide particles in lithium heteropolytungstates solutions, that can replace Clerici?s solution in the evaluation of fine mineral sands samples (e.g. -250 +150microns). The developing methodology that can achieve low-cost, low-toxic separations at relative densities above 4.0 is outlined and the comparison of results with Clerici?s solution presented. In addition, preliminary work on density fractionation of zircon samples is presented. Zircon fractionation relates to their inclusion, radionuclide content and metamictization.

Jan 1, 2007