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By H. A. Wilmeth

IN 1955, before planning an accelerated stripping program, Chino Mines Div. began an engineering study to improve data for estimating truck haulage costs for any future haulage layout. The study aimed to develop: 1) significant unit costs, 2) a method of estimating travel time from which truck needs and future stripping rate could be determined, and 3) yardsticks of performance to measure haulage efficiencies. It was suggested that to provide significant unit costs, expense accounts should offer management two types of cost control information-unit cost yardsticks with which monthly unit costs could be compared and unit costs for estimating future expenses for any haulage layout.

Jan 5, 1958

By M. Duclos, A. Sawatzky

A simple model has been developed which describes the steady-state solute distribution in Ti-H type systems above the eutectoid temperature in the presence of a temperature gradient. The solute distribution is dependent on the shape of the phase boundaries. An interesting result, and one that is not observed at steady state in thermal diffusion below the eutectoid temperature, is the existence of a two-phase region. The heat of transport for hydrogen in a titanium, Q*a, over the temperature range 275" to 650.C is determined to be 4500 * 230 cal per mole. The heat of transport for hydrogen in B titanium, QB* over the temperature range 320" to 590.C is found to be 630 ± 200 cal per mole. It is also shown that thermal diffusion provides a method by which phase bounduries above the eutectoid may be determined in Ti-H type systems. IN modern technology materials are being used at constantly increasing temperatures under greater temperature gradients. Thus atomic migration in metal alloys due to a temperature gradient (thermal diffusion) may in some cases occur to an observable extent. The thermal diffusion of hydrogen in zirconium has in recent years received considerable attention1-' because of the use of zirconium alloys in nuclear power reactors. The thermal diffusion kinetics below the eutectoid (547°C) are fairly well understood. At steady state the solid solution, a, and hydride, 6, phases are completely separated with the hydride precipitating at the lower temperatures. No experimental work has been carried out in the a + B region although Droege4 suggested that a complete separation of the two phases, as observed at temperatures below the eutectoid, might not always occur. In the present investigation a simple model has been used to determine the steady-state solute distribution under a temperature gradient in Zr-H type systems heated above the eutectoid temperature. The solute distribution is shown to be dependent on the shape of the phase boundaries in the constitutional diagrams and several typical cases are discussed. The model has been applied to Ti-H. This system was chosen in preference to Zr-H because of its much lower eutectoid temperature (-300°C as compared with 547.C), thereby reducing experimental errors due to oxidation and hydriding. The heats of transport for hydrogen in the a and B phases of titanium also have been determined since they were required to compare the proposed thermal diffusion model with experiment. THEORY In the presence of a temperature gradient the atomic flux in a single-phase region of a two-com-ponent system of which the atoms of only one component are diffusing is given by:' J = - U\dx + RT3 dx) which can be written as: j-D(dn/dt +Q*n/RT2)dt/dx [11 J - -D\dT + RT2)dx [1] where D = diffusion coefficient, n = solute concentration, T = absolute temperature, R = gas constant, dT/dx = temperature gradient, and Q* = heat of transport. At steady state (J = 0) Eq. [I] leads to the solute distribution: n = noexp Q*/RT where no = a constant depending on total solute content. The heat of transport Q* can be experimentally determined from the steady-state distribution. In the present paper we shall determine the solute distribution in systems having the constitutional diagram exemplified by Ti-H shown in Fig. l.' As shown, N,(T) and NB(T) are the equilibrium solute concentrations in the a and 0 phases at temperature T. Lines AA' and CC' define the region of interest to us. The following assumptions are made: 1) Steady-state conditions prevail. 2) In a single-phase region all points on an isotherm have the same thermodynamic potential so that the composition over an isotherm is uniform. If a two-phase region exists, thermodynamic equilibrium is found only at phase interfaces. However, we assume the component of the concentration gradient along an isotherm to be small so that the composition in each phase is approximately the same as at the interface and is given by the constitutional diagram, Fig. 1. 3) There is appreciable diffusion of only one component. 4) We shall consider only the case where Qa*, QB*, and Qg*, the heats of transport for solute diffusion in the a, B, and 6 phases, respectively, are positive. This has been observed for the thermal diffusion of hydrogen in zirconium3 and titanium.10 We will show that the steady-state solute distribution above the eutectoid is primarily determined by the heats of transport and the temperature dependence of Na(T) and Np(T). It may be quite different from the steady-state distribution below the eutectoid. For example, we will see that, under certain conditions,

Jan 1, 1970

By Nicholas P. Kripakov

The U.S. Bureau of Mines examined the applicability of existing material models to solve practical geotechnical mining-related problems by solving a yielding pillar stability problem considering confining effects on strength. Numerical difficulties normally encountered with modeling strain softening behavior were eased with a simplified computational procedure using a quasi-elastic approach to account for residual strength after initial failure. Although in agreement with a confined-core pillar design method using actual mine conditions that include mine layout geometry, overburden geology, and rock properties of the deposit and surrounding structure, the results cannot be verified because measured field data are not available at this writing.

Jan 1, 1981

By Richard L. Ranich, Frank F. Aplan, J. B. Hiskey, Robert S. Thompson, B. J. Scheiner

Acidic waters typified by acid mine drainage, copper dump leach solutions and steel pickle liquors will typically contain SO4-2 and cations such as Fe+3, AI+3 and for the pickle liquors, sometimes Cr+3. These acidic waters will often react with limestone, present naturally or introduced for purposes of solution neutralization, to form reaction - inhibiting coatings of gypsum and gelatinous, metal hydroxide precipi¬tates. The coating thickness, as a function of pH, was quantified for both reactive (calcite, limestone) and non-reactive (quartz, barite, fluorite) minerals, and the data were related to the hydroxy species diagrams and to solution turbidity measurements. Coatings were found on the reactive minerals at a lower bulk solution pH than on the non-reactive minerals.

Jan 1, 1993

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations for the smelting and refining of non-ferrous metals, and it is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate. It is also the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y zinc. Since then, production capacity has increased, and at present, it stands at 240,000 t/y zinc. In this paper, the leaching process and particularly the operation of the jarosite circuit is reviewed, specifying process improvements to treat high iron calcines.INTRODUCTIONTwenty years ago the Electrolytic Zinc Plant in Peñoles was treating high quality zinc concentrates with low concentrations of iron (~7.5 wt.%) and silica (1.8 wt.%). Nowadays the quality of zinc concentrates is poor with a typical iron content of around 11 wt.% and silica at 2.0 wt.%. This has created numerous processing problems in our roast-leach-purification- electrolysis sections. In order to meet customer requirements it is necessary to find processing solutions to assure the operational continuity of the plant. These processing solutions are the focal point of this paper.REVIEW OF THE LEACHING PROCESSThe purpose of the leaching process is to recover the metals, mainly zinc, through a series of extraction stages with sulphuric acid solutions, which progressively increases the zinc dissolution. After the series of acidification stages, the solution, which is rich in iron, is sent to the jarosite circuit to separate zinc from iron (Garcia & Valdez, 1996). The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper. Then this solution is sent to the tank house to feed the electrolytic cells."

Jan 1, 2016

By H. Linder, W. H. Dennen

The graphitic carbon content of soils may be used to detect and delimit subsurface graphitic zones. Spectrographic measurement of carbon in C horizon soils from several areas in the northeastern United States shows good correlation with known graphitic bodies. Bodies of graphite and sulfides are readily located by electromagnetic prospecting methods, but these methods cannot generally discriminate between them. Usual practice, therefore, requires follow-up work on electrically anomalous areas by trenching, drilling, or soil sampling in order to determine the mineralogical nature of the conductor. The efficiency and cost of such follow-up is consequently an important factor in prospecting. The presence of buried sulfide deposits is often reflected in concentrations of metals in the superincumbent soil. Simple chemical tests for such metal concentrations have been developed and applied with considerable success. Bodies of graphite or mixtures of graphite and sulfides are, however, very common and a means whereby buried graphite could be detected by soil testing should provide valuable additional information in the search for ore sulfide and graphite deposits. Graphite is a notably stable substance and should persist in soil above graphite-rich horizons. Microscopic examination of soil samples high in carbon, however, failed to reveal any recognizable graphite fragments indicating a grain size in the clay range. Presumably such small particles would have some mobility in a soil by a translocation mechanism similar to that proposed for the movement of clay particles in a soil profile. Experimental data supports this idea since the boundary between background and anomalous soils carbon values is quite sharp, but the anomalous zone is slightly broader than the graphitic source rock. A simple spectrochemical technique for the determination of carbon in geological materials has been described by Dennen,1 and may be directly applied to soils. A modification of this technique which employs an arcing chamber through which nitrogen is passed is recommended to decrease contributions from atmospheric carbon dioxide. Tests indicate that soils over graphitic zones may be strongly enriched in carbon. The spectrochemical determination of carbon depends upon the formation of the cyanogen molecule (CN) from carbon in a sample and atmospheric nitrogen, under the high temperatures associated with a dc arc. Samples for analysis are dried, lumps broken, and screened. A small portion of the -100 mesh fraction is packed into a copper electrode and excited as the cathode of a dc arc. The band spectra of cyanogen are recorded photographically and the density of the bandhead CN 3883A is measured. The limit of detection of the method is about 0.01 pct C and its coefficient of variation is about 15 pct. Soils, of course, contain carbon in other forms than graphite, and the amount of interference from such sources was examined. The C horizon of several soils from Massachusetts, Maine, and Pennsylvania were found to have a carbon content of 0.3 to 0.5 pct by weight. This content is chiefly due to the presence of carbonates and vegetable matter in the sample and may be readily eliminated, or at least

Jan 1, 1961

By Samuel B. Rombeger

The behavior of gold in hydrothermal systems is evaluated as a function of pH and oxygen and sulphur activities at temperatures to 250°C. Under conditions of stability of pyrite and argillic alteration as emblages, gold will be transported as bisulphide complexes. In systems containing significant amounts of arsenic, thioarsenide complexes may be important. Oxidation, dilution and reduction in sulphur activity would cause gold deposition from saturated solutions under these conditions. Gold chloride complexes will predominate under oxidized conditions where hematite or other oxides are stable and depo ition would result from increase in pH and/or reduction . Absorption and coprecipitation are po sible mechanisms of deposition for gold in certain low grade depo it . Low concentrations of gold in the transporting solution combined with the ignificant solubility of gold as bisulphide complexes, sugge t hydrothermal solutions rarely may be saturated with gold and coprecipitation with sulphides may be an important initial depositional process. Recrystallization of the sulphides in the presence of the hydrothermal solution would be re ponsible for release of gold to more table ite . Thi mechani m i supported by the close association of gold with pyrite in many hydrothermal gold deposits.

Jan 1, 1986

By San-chuan Tang, Wen Chen, Shun-ming Ning, Kan-ping Yu, Qiang Zhao, Xue-yong Xing

"A new type of desilication agent (PA-2) was selected by experiment based on the analysis of the characters of silica gel, and the influence of desilication type, desilication dosage, pH value, temperature and aging time on the desilicating effect was studied. The test results showed that on the conditions that pH was 2.0, temperature was 20""C, aging time was12 hours and the dosage of desilication agent was 0.23%, the desilication rate was higher than 93% in solution.IntroductionVanadium is an important strategic resources, which applies to steel industry and petrochemical industry. The main materials for vanadium product are steelmaking vanadium slag, stone coal and containing vanadium waste catalyst, etc. And stone coal is a low-grade carbonaceous silicified vanadium resource, which is unique material for vanadium extraction in China. Meanwhile, our stone coal reserves is No.l throughout the world.The silica acid solution containing vanadium is produced by acid leaching of raw stone coal or its roasted ore. The silica content of this solution is mostly high, besides, when pH is higher than 2 , the solution is unstable. Furthermore, it is very easy to generate gel substance with the increasing of pH value and standing time. 'Ibis silica gel is composed of colloidal particles with the size in 0.001 - 0.1 um. As a result, it is very hard even impossible for the following operation of solution."

Jan 1, 2013

By Evan Jamieson

The conditions under which various iron(III) oxy-hydroxides phases precipitate from iron(III) chloride and sulfate solutions at ambient temperatures (<60°C) are reviewed. Many of these precipitates are slow settling and gelatinous but ultimately transform into other more stable or crystalline phases. The phase that forms depends upon the rate of precipitation and pH. A comparison has been made of the iron(III) oxides formed upon the neutralisation of various iron(III) solutions with caustic, slaked lime or slaked magnesia which provide different rates of neutralisation and slowly dissolving solids with localised high pH. Mössbauer spectra of ferrihydrites precipitated under these different conditions are compared and interpreted. Particular attention is paid to the settling rate and settled volume which is likely to relate to industrial thickener and filter performance. It is shown that in pure chloride solutions, poorly settling ferrihydrite is usually produced at 20oC regardless of the choice of base. However in sulfate solutions fast settling precipitates are produced using lime and magnesia but not with caustic. In mixed chloride/sulfate solutions, optimum settling rates occur when the molar ratio of [SO4]2to Fe3+ is about 1:1 and when the sulfate concentration is <0.20 M. It is proposed that ?dense amorphous basic iron sulfate? or well-ordered ferrihydrite is formed on slowly dissolving lime or magnesia surfaces. Implications for industrial liquors are considered.

Jan 1, 2003

By W. Petruk, R. S. Boorman, R. Gilders

Approximately 33% of the silver in the Zn-Pb-Cu-Ag ore of Brunswick Mining and Smelting Corporation Limited is lost to the tailings and an additional 11% to the zinc concentrate for which no payment is received. 38% to 44% of this lost silver is carried by tetrahedrite, 28% by galena and 28% to 34% by a third silver carrier. The silver minerals acanthite and pyrargyrite have been identified in mill products and hence these are suggested as the principal third silver carrier(s) accounting for 13 to 20% of the silver in Brunswick ore. About 24% of this third silver carrier assemblage is lost to the zinc concentrate and 52% to concentrator tailings.

Jan 1, 1984

By E. P. Abrahamson II

The effect of transitiorz element bitzary solid solution additions upon the recrystallization temperature of columbium has been investigated. The elements Mn, Fe, Co, Ni, W, Re, and 0s OWY the yecystallization tempel-aturye, while Ti, V, CY, zr, Mo, Ru, Rh, Pd, Hf, Ta, W, Ir, and Pt mise it. A correlation is kloted between the rate of chatzge of recyystallization tewaperature with atomic hercent solute and the free atom electron configuration of the solute element. The work of Abrahamson and Grant1 has indicated a correlation between the free atom ground-state electron configuration and the change in brittle-ductile transition temperature per atomic percent solute in chromium base alloys. A similar correlation was observed for the change in the recrystallization temperature of iron base alloys by Abrahamson and Blakeney and Abrahamson. It was also observed that the limit of rapid change in recrystallization temperature also Correlated with the electronic configuration of the free solute atom. A further study by Abrahamson4 established the generality of the phenomenon by yielding similar results for vanadium base dilute alloys. It has been inferred that a peri- odicity might be expected with changes in the free atom electron configuration of the solvent element. This study is the third set of transition base metal systems to be studied. It is the object of this and further studies on transitional metal systems to detect any systematic variations in the observed correlation which might contribute to the understanding of the electron interactions which are evidently exhibiting themselves. PROCEDURE All alloys were made using 99.9 pct Cb with 0.030 Ta, 0.016 0, 0.0025 H, 0.003 Mo, 0.021 Fe, 0.005 C, and 0.002 N. The solute elements were 99.9 pct pure. According to the published binary phase diagrams5 and metallographic examinations at X750, all additions were in solid solution. The alloys were arc melted and remelted 6 times in the form of cubic 400-g buttons under an argon atmosphere. They were then hot forged at 1200oC to 0.6-in. diameter, annealed for 3 hr at 1200o under argon, and furnace cooled. The specimens were then machined to 0.400 -in. diameter. Grain size was checked and found to remain essentially constant at 150 i 30 grains per sq mm. The specimens were then cold swaged to 0.187-in. diameter, yielding 46 i 1 pct cold work. All alloys were chemically analyzed for the major solute. Analyses of random samples indicated that the impurity content remained at the values of the starting material. Tungsten contamination was held to 0.007 pet.

Jan 1, 1962

By J. Jones-Parra, R. S. Reytor

The porosities of fractured limestone reservoirs can be divided into two broad types in accordance with their effects on fluid distribution and fluid flow. In the coarse porosity, gravity segregation lakes place freely and the resistance to fluid flow is very small. In the fine porosity there is no segregation and a high resistance to flow, and it has relative permeability characteristics similar to tight sandstones. By analyzing the affect of the two porosities it is concluded that in some cases to recover the maximum amount of oil it is necessary to remove large quantities of gas from the reservoir by producing at high gas-oil ratios. In this manner the fine porosity is drained of its oil and the gas-oil contact drops slowly permitting higher production rates from the oil leg. Since this conclusion is contrary to widely accepted principles of conservation, a mathematical model (Fig. I) was constructed to duplicate the conditions desired. The behavior of the model indicates that under certain conditions it is possible to recover more oil by producing at high gas-oil ratios than by production at low gas-oil ratios, and that the rate of production is affected more by gas shut-offs than by the decrease in pressure (Figs. 2, 3, 4 and 5). INTRODUCTION It has been noted that certain limestone reservoirs behave in such a way as to indicate that there are two distinct types of porous spaces available for fluid storage and fluid flow. Regardless of the nature of these porous spaces the distinguishing characteristic is that in one type of porous space there is definite gravity segregation between the oil and the gas; while in the other, the gas evolved tends to remain distributed equally throughout the reservoir. For the sake of simplicity the porosity in which gravity segregation takes place at a fast enough rate to affect the behavior will be called "coarse po- rosity", while that in which this is not so will be termed "fine porosity". The behavior of a reservoir of this type would be different than that of a sandstone reservoir, especially if most of the oil is in the fine porosity. It has been observed that fluid flow to the wells takes place mostly through the coarse porosity. The large fractures which

By P. A. Beck, S. Kohara, M. N. Parthasarathi

IT has been shown1,3 that many observed phenomena related to annealing textures in f.c.c. metals can be adequately accounted for, at least in a qualitative way, by considering the orientation dependence of the boundary mobility, without any hypotheses concerning preferred orientation of nuclei. It was noted1 that this approach is particularly successful in the common cases of primary recrystallization in highly cold-worked polycrys-talline metals, where nuclei occur in great abundance, and that in the other extreme case, where the number of nuclei is very limited, or even only a single crystal is grown, the orientation dependence of boundary mobility has only a small effect, or none at all, on the orientations resulting from annealing. Recently Dunn described examples3-6 where observed secondary recrystallization textures apparently cannot be accounted for on the basis of oriented growth alone, but also require oriented nuclei, or at least the absence of nuclei in certain orientation ranges. In general, the great difficulty in correlating the preferred orientation of recrystallized grains with that of nuclei is inherent in the fact that nuclei are by nature very small, and that they are usually identifiable as "nuclei" only after growth, i.e., after they have already been subject to growth selectivity. An investigation was carried out by Liebmann and Lücke,&apos; and also a very similar one by Graham and Cahn,&apos; to obtain quantitative information on the orientation depend- ence of boundary migration rates in the recrystallization of slightly deformed aluminum single-crystal rods or plates, in which artificially nucleated recrystallized grains of predetermined orientation were grown. Liebmann and Lücke foupd maximum boundary mobility for boundaries across which the misorientation corresponded to a rotation of 40 deg around a common [Ill] axis, in accordance with earlier conclusions.9,1 Also, they confirmed that such an orientation relationship predominates among crystals growing into slightly extended single crystals from presumably random artificial nuclei. On the other hand, Graham and Cahn found no preferred orientation among crystals grown in a similar manner. It is not as yet known how these observations may be reconciled with each other. The view has been expressed in various papers5&apos;10,21 that selective growth based on the orientation dependence of boundary mobility is not in itself sufficient to account for the formation of sharp re-crystallization textures, such as those often observed in highly deformed polycrystalline metals after annealing. The present work was undertaken to ascertain whether or not it is possible to obtain a sharp re-crystallization texture in a case where random nuclei are assuredly present in large numbers. It was previously found1&apos; that high-purity aluminum crystals rolled 80 pct on the (110) plane in the [1T2] direction, when suitable precautions are taken, may be annealed for periods of about 1000 sec at 350°C without recrystallization. It was also found that the reluctance to recrystallize in this case is due to the scarcity of material in sufficiently deviating orientations to serve as nuclei. By using such a matrix,

Jan 1, 1959

By T. R. Ellis

Australia’s mineral valuation code continues to evolve, while mineral valuation standards are also being written for Canada and Southern Africa. The author is leading a task force for writing the extractive industries addition to the International Valuation Standards. Meanwhile, the International Accounting Standards Board is continuing the development of an extractive industries addition to its International Financial Reporting Standards, with an emphasis on valuation reporting. This paper analyzes the need, content and ownership for a U.S. minerals appraisal standard in the context of both these developing international standards and also existing U.S. regulations and appraisal standards. The author provides many questions for research and debate.

Jan 1, 2003

The need to estimate the block size distribution of a jointed rock mass is of great importance in the design of blasting rounds to attain a pre- established fragmentation. Other Geomechanics topics, such as ,hydraulic behavior of rock-masses, as well as the determination of their strength properties, also require the accurate prediction of a rock-mass composition in terms of block size taking in due account the three dimensional interference of joints and other geologic discontinuities. In this paper, a method for computing the block size analysis of a jointed rock mass is described, using as input the common geologic data (dip and strike) of fracture planes existing in a rock bench prior to blasting.

Jan 1, 1977

Solution mining got back in the news recently when Kalium Chemicals, Ltd., a joint subsidiary of Pittsburgh Plate Glass and Armour & Co. announced its plans to go full speed ahead in mining potash by the solution method in its vast holdings 30 miles west of Regina, Saskatchewan. The company is keeping the technical details of this mining technique under wraps for competitive reasons, but company officials insist that the major difficulties in solution mining of potash have been overcome and that the final product will have definite competitive advantages on the open market. Kalium&apos;s holdings in the Regina area total about 500 sq mi. The ore-primarily sylvite mixed with appreciable quantities of halite-occurs in the Prairie Evaporite formation at a depth of 5300 ft. The ore zone averages about 100 ft in thickness. Too deep to be economically mined by conventional underground methods, such as is being done at International Minerals & Chemical Corp.&apos;s Esterhazy mine (depth about 3100 ft), Kalium gambled that it could develop a successful method of solution mining even though earlier attempts in Germany, the U.S., and Canada had failed.

Jan 6, 1964

By Ersin Yazici, Ahmet Bas, Haci Deveci

Pregnant leach solutions from waste of printed circuit boards (WPCB) leaching contain many impurity metals (Fe in particular) at significant levels. These impurities should be reduced to acceptable levels to avoid problems in downstream recovery processes e.g., low current efficiencies in electro-winning of copper from sulfate solutions in the presence of ferric. In this study, removal of iron in the form of goethite from synthetic (30 g/L Cu2+ and 1 M SO42-) and real leach solutions of WPCB was studied in some detail. The influences of initial concentration of iron (1-4.5 g/L Fe3+), pH (2.5-4.0), temperature (80-90°C) and seeding (23.5 g/L) were investigated over a period of 4 h. A significant increase in the iron precipitation was observed (i.e., from 68% to 96% over 4 h) with rising the pH from 2.5 to 4.0. The addition of seeds had also increased the removal rate over 4 h albeit to a limited extent i.e., from 96% to 99%. For the real leach solutions of sulfate (H2SO4-H2O2) and sulfate/chloride leaching (H2SO4-CuSO4-NaCl), precipitation of iron was found to be 63-73% (pH 2.5) and 93-98% (pH 4.0), respectively. The precipitates were further characterised by SEM-EDS analysis which showed the presence of copper (1-25%) in the precipitates indicating significant copper co-precipitation from the solution. These copper losses can be attributed to the formation of copper compounds such as anthlerite and brochantite within the range of pH (2.5-4.0) tested. This study showed that iron can be readily removed from synthetic/real leach solutions of WPCBs to a large extent (=93%) at the expense of high copper losses particularly at pH 4.0.

Jan 1, 2014

By W. Kunda, J P. Warner

SHERRITT GORDON Mines Limited annually produce 300,-000 pounds of pure cobalt by processing a nickel-cobalt-copper-iron sulphide ore which is mined at Lynn Lake, Manitoba. The ore (containing 0.04 per cent Co) is •concentrated to give a concentrate containing l 1-12 per cent nickel, about 2.0 per cent .copper, and 0.25-0.35 per cent cobalt, which is treated at the Refinery in Fort Saskatchewan, Alberta. The concentrate is leached in an ammoniacal solution of ammonium sulphate using compressed air as the oxidant. After filtration the leach solution contains, besides nickel and cobalt, copper ammines, sulpharnates and salts of various thionic acids. The copper is removed by precipitation as sulphide and the sulphur compounds converted to ammonium sulphate by a combined oxidation and hydrolysis treatment. The purified solution •Containing about 45 gpl of nickel and 1 gpl of cobalt is treated with gaseous hydrogen under pressure at 350°F to precipitate metallic nickel powder, the precipitation 'being terminated when the nickel content of the solution is about 0.8-1 gpl. Only about

Jan 1, 1962

By Yuuki Yoshida

Electrolytic manganese dioxide, EMD, is the positive electrode material of primary batteries and the raw material of LMC used as the positive mass of lithium ion batteries and is currently produced by anodic deposition on and harvesting from a titanium anode in acidic manganese sulfate solutions prepared by dissolving high purity of manganese sulfate into sulfuric acid solutions. This paper presents an alternative method of EMD production using a novel anode, Mn2O3 coated titanium, at lower operating temperature than the current process to explore a possibility of manganese recovery from zinc electrowinning solutions. The Mn2O3/ Ti anode prepared by thermal decomposition of a precursor solution containing Mn (II) showed the anodic deposition of MnO2 by constant current electrolysis and the current efficiency was 95% in maximum, while the current efficiency and the crystallographic structure of deposited MnO2 depended on the current density, the electrolysis time, the bath temperature, and the concentration of Mn(II). The deposited MnO2 was successfully harvested from the anode and the recovery rate was 98%.

By R Edwards

Greater efficiency of capture of minus 6 mm to fine micron size particles of free gold is achieved with the Knelson Concentrator. The development, principles of operation and recent innovations relating to this enhanced gravity concentrating device are described by the inventor, followed by a description of application and consequent economic benefits in low grade alluvial gold deposits by a large scale user of Knelson Concentrators in the Northern Territory of Australia.

Jan 1, 1990