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By G. T. Swanby

Members of AIME, I read to you now a portion of a very fine business letter which we received several years ago. This letter originated in Rangoon, Burma, and reads in part: "Rest assured, if your goodselves see with us eye to eye, sure as certain we should get the business". I don't plan to give anybody "the business" today, but you can rest assured that if some of "you goodselves see with me eye to eye" on what I am about to discuss, I would be most pleased. My talk with you today will discuss the Federal Corporate income tax and its effect on our lives as engineers. In the-engineering-construction business we are faced with all the usual form of taxation which includes such items as sales tax, use tax, school tax, contractor; gross receipt tax, import duties and excise taxes, severance taxes, etc, adinfinutum.

Jan 1, 1965

By C. J. Brown

Controlling the level of impurities in copper refinery electrolytes is essential to achieving acceptable cathode purity. Purge of electrolyte is not an entirely satisfactory solution since the cost of neutralization, waste disposal, and replacement acid can be appreciable. The APU® process utilizes ion exchange resin to sorb sulphuric acid while rejecting metal salt impurities. Extensively employed for recovery of waste pickling and anodizing acids since 1977, the system is now being used at several refineries for removal of contaminants such as antimony, bismuth, iron, and nickel. The purified acid, which is recovered from the resin by water elution, is recycled back to the refinery tank-house, while the metals are typically recovered from the de-acidified by-product solution by precipitation.

Jan 1, 2005

By Yongping Wu

The steeply dipping coal seams in this paper refer to those with the angle of inclination ranging from 35° to 55°. The reserves of the steep coal seams account for approximately 15%~20% of the total coal reserves in China. In the past 12 years, the top-coal caving mining method had been used to mine the steeply dipping thick (11.5-16.4 ft or 3.5-5.0m) coal seams. However, the mining process of top coal caving is complex with low recovery rate and nearly 30% of coal was wasted. Those problems can be solved by using the single pass large mining height (11.5-16.4 ft or 3.5-5.0m) method. But the movement of the overlying strata around the mining face area of large mining height is complex and it is hard to control the stability of ?rock-shield support? system. Therefore, field measurement, numerical simulation and physical (similarity material) simulation methods were used simultaneously to analyze the strata movement, roof structure and rock-shield support interaction characteristics. The results indicate that strata movement, which is the same as mining the steeply dipping seams with conventional mining heights, is asymmetrical about the dipping direction of the face; deformation, failures, and movement of the surrounding rocks are more intense; the roof weighting interval decreases; the weighting intensity increases significantly; and face sloughage occurs frequently. In the gob, the space for sliding and rolling of the roof increases; the broken main roof tends to form an anti-dip pile structure; the backfilling and compactness of broken roof increase at the lower portion of the face, thereby inducing significant unbalance in stress distribution between the upper and lower portions of the face. The overlying strata above the face form a multi-level step structure. The characteristics of contact and loading of roof-shield support system are more complex. The range of shield load variation is larger, and interaction between shield supports occurs frequently. Anti-toppling and anti-sliding devices at the face become more difficult to implement. The research results provide a theoretical basis for the mining practices in the steeply dipping thick seams with a large mining height. The practice in panel 25221 of 2130 coal mine indicates that the accident rates have been greatly reduced and good technical and economic benefits have bee realized.

Jan 1, 2014

Solvent extraction has recently been introduced into Australian hydrometallurgical practice for the production of a high grade uranium concentrate from El Sherana ore by a sulphuric acid leach and solvent extraction process. The solvent is a 5 per cent solution of tri(iso-octyl)amine in kerosene modified with 4 per cent of a long chain alcohol. The stripping reagent is a molar solution of sodium chloride.Preliminary testing for the development of the process showed that the leach liquor was quite amenable to the solvent extraction process and that the equilibrium and rate considerations of both the extraction and stripping steps were very favourable.The industrial plant contains four stages of extraction, three stages of chloride stripping and one stage of secondary carbonate stripping. An internal type of mixer-settler is used for the stagewise contact, the design being based on tests with model equipment.The performance and control of the industrial plant is satisfactory; 99·7 per cent of the uranium is recovered for a loss of 0·3 gallons of kerosene and 0· 4 pounds of amine per 1,000 gallons of liquor treated.INTRODUCTIONThe processing of El Sherana uranium ore from the South Alligator River valley commenced in April, 1959, and thereby introduced into Australian hydrometallurgical practice the unit operation of solvent extraction on an industrial scale. Although there are now some twelve mineral processing plants in the United States and Canada using solvent extraction, its application to the field of primary hydrometallurgy is quite new. Prior to 1956 none of these twelve plants was operating and hydrometallurgical application waslimited to the refining of comparatively high grade uranium compounds and fission products from nitrate and nitric acid solutions.

Jan 1, 1961

By C. L. Chaney

Investigations were conducted to develop spectrochemical methods capable of determining 0.01 to 100 micrograms of metals in 50 milliliters of solution. The use of gallium hydroxide (Ga(OH)3) as a carrier-precipitant to concentrate metallic ions is described. A porous-cup graphite electrode is used to collect the precipitate. A specially designed plunger permits the electrode assembly to serve as the sample-containing electrode in the subsequent spec-trographic analysis. Analytical curves are presented for antimony, arsenic, beryllium, and zinc. Sensitivities of detection are given for 13 elements. The techniques were applied to identify impurities separated from tungsten, to determine trace impurities in solutions containing high concentrations of magnesium, cobalt, or nickel, and to identify trace impurities in hydrofluoric acid. Laboratory glassware was a serious source of contamination when low levels of zinc were determined.

Jan 1, 1963

By J. A. S. Tenorio, K. S. Barros, D. C. R. Espinosa

In the last decades, authors have been focused in the development of a cyanide-free bath for the electroplating industry of brass due to the risks that involves the use of cyanide and they have been evaluated the electrodialysis as an alternativemethodforthetreatmentoftheeffluentgeneratedinthistypeofindustry because ofthe limitationscaused bythe chemical precipitation. Hence, thepresent paperaimedtodeterminethelimitingcurrentdensityoftheeffluentgeneratedinthe free-cyanide electrodeposition of copper and zinc using EDTA as chelating agent for the treatment of the effluent by electrodialysis. The synthesized solutions were preparedwith copper sulfate andzinc sulfate indifferent conditionsofpH (10–12) and proportion of cupric ions (30%, 50%, 70%). According to the results, the increase of pH and the cupric ions proportion caused an increase in the limiting current density because of the larger amount of anionic species in solution and the consequent difficult to achieve the concentration polarization phenomenon. (cid:1) (cid:1) (cid:1)

Mar 1, 2018

By Siavash Zamiran, Abdolreza Osouli

"One of the most concerns of room and pillar mining system is subsidence of the ground surface due to coal mining particularly in room and pillar mines. Subsidence of ground surface is a result of floor, pillar, or roof failure of the mine. At the same, due to many difficulties associated with surface disposal facilities of coal refuse, some mining companies are trying to use underground space as a disposal storage place. In this study, stability and subsidence analyses of an underground coal mine located in the Illinois Basin are conducted. This room and pillar mine was abandoned and later on was used as a storage place to accommodate the coal fine refuse with slurry backfilling method. The geological stratigrophy and geomechanical properties of the mine floor and roof were collected. Floor and pillar stability analyses were conducted for areas with various extraction ratios. The stability of the mine was evaluated both prior and after slurry backfilling. The floor and pillar stability analyses results of the mine due to moisture exposure after slurry backfilling are discussed. The subsidence potential due to mine failure is also evaluated.INTRODUCTIONA typical lithology of coal seams in the Illinois Basin consists of weak underclay stratum. The immediate weak underclay causes frequent floor instability problems in Illinois underground coal mines. There are two different stages in assessing floor stability of the mines where slurry backfilling is planned. The first stage is during the mining operation when weak underclay layer squeezes under pillar stress and results in punching or bearing capacity failure. The second stage is after slurry backfilling. During this stage, the slurry material soaks non-durable floor layers and causes strength reduction in floor material. Pillar stability conditions should also be taken into account during both the operational period and after the slurry backfilling."

Jan 1, 2015

By J. V. Scalera

Because of U.S. dependency on imported critical metals, the Bureau of Mines has conducted research to evaluate the possible substitution of nitrided low-alloy steels for higher chromium-containing alloys. The corrosion data for nitrided steels are limited primarily to the Soviet literature. The objective of this study was to determine the corrosion properties of six commercially nitrided low-alloy steels in a 5-wt % NaCl solution at pH 4. Weight-loss tests indicated that, in deaerated test solutions, most of the nitrided steels were less corrosion resist-ant than nontreated steels. However, electrochemical tests indicated that under more oxidizing conditions, nitrided materials are converted to a passive state with a significantly reduced corrosion rate. Elec-trochemical tests performed in an aerated environment confirmed the passivity of the samples in an oxidizing environment.

Jan 1, 1984

By K. Soldenhoff, M. Fainerman-Melnikova

The use of strong base resins for uranium recovery is severely affected by the presence of chloride ions in solution. In areas where high-quality process water is not readily available, the use of saline water would extend the potential application for ion exchange in uranium processing. This study presents measurements of uranium uptake, using a wide range of commercially available weak base anionic exchangers, from solutions with chloride concentrations ranging from 2.5 to 22 g/L Cl. Out of 14 weak base anionic resins tested, 3 were identified that were not severely impacted by the presence of chloride and significantly outperformed a gel strong base resin typically used for uranium recovery in high-chloride environments. The uranium loading was sufficiently high for the consideration of development of the application of uranium recovery from uranium ores leached with seawater.

Jan 1, 2012

By Eduardo Dominguez Trindade

Lubricant oils are subjected to reciprocating movement in the piston ring/cylinder tribocouple of automotive engines. In this kind of movement, the relative speed oscillates between zero and a maximum, and therefore the lubrication regime goes from boundary to hydrodynamic. Tribotests are widely used in laboratories to hint at the friction developed in these systems. In the present work, a SRV tribometer was used to evaluate the friction behaviour of lubricant oils under reciprocating movement up to 60 Hz. A high acquisition rate allowed the analysis of data inside each reciprocating cycle. Both a pure base oil and a fully formulated lubricant were used. Changes in the contact pressure, viscosity and speed were seen to influence friction, which was correlated to the relative thickness predicted by Hamrock-Dowson equation. While some observed characteristics were typical consequences of the Stribeck curve, other effects were also observed, such as the occurrence of seizure at high reciprocating frequency. A lower boundary coefficient of friction due to additive package in the formulated oil was also observed. The results allow a better understanding of friction in reciprocating cycles and can be used to evaluate the performance of oils and surfaces in laboratory prior to engine testing.

Jul 31, 2018

By D Hart

In 1944 some ten or so pieces of legislation impacted on the mining industry. Today in excess of 80 in one way or another apply to the Northern Territory miner. This paper will look at the nature of the legislation that has been introduced and the reasons for its introduction. During the Second World War the mining of resources such as iron, tin etc for the war effort set the platform for the subsequent expansion of the industry in the post-war years. Thereafter, the change in attitudes over the years that have resulted from a more conscious public and more responsible governments and developers associated with the recognition of the legal rights of others and the threat of litigation, will be traced. With a major review of the Northern Territory Mining Act currently in progress, this paper will view ANZMEC's foreshadowed preference for a National Code and the NT's intent of drawing some commonalities with other states of Australia to achieve this aim. Finally, the questions of over-regulation and whether existing legislation is complete will be addressed. From this it is foreshadowed how legislation may develop during the lead into the 21st century.

Jan 1, 1994

By M I. Pownceby, M A. Rhamdhani, S Palanisamy, D Fellicia, B Satritama, G A. Brooks, A Ang

Metal production have long been using carbon sources as both reducing agents and energy sources. Consequently, the global extractive metal sector contributes significantly to greenhouse gas emissions, accounting for approximately 9.5 per cent. Hydrogen gas offers as a promising ecofriendly alternative to carbon in metallurgical processes, serving as both a reductant and energy supplier with a by-product being only water vapour. However, the implementation of molecular hydrogen faces certain challenges related to the thermodynamics and kinetics of metal oxide reduction. In addressing these challenges, researchers have explored the application of hydrogen plasma, generated by subjecting molecular hydrogen to high energy to produce atomic, ionic and excited hydrogen species. Hydrogen plasma offers thermodynamic and kinetic advantages over molecular hydrogen and carbon-based reductants, exhibiting lower standard Gibbs free energy of reaction and activation energy. Therefore, hydrogen plasma can produce metal in fewer steps, process any oxide feed and feed size and even be used to refine metals. Despite these advantages, challenges exist in utilising hydrogen plasma in extractive metallurgy, including electricity costs, potential reverse reactions and industrial-scale implementation. This study provides a mini review of prior research on hydrogen plasma for metal oxides reduction, particularly iron oxide, as well as state-of-the-art techniques for its use in extractive metallurgy applications by mentioning several reactor types. Future prospects and scale-up possibilities of the hydrogen plasma in extractive metallurgy will also be presented.

Aug 21, 2024

By William G. Fricke

MaCROSEGREGATION, as distinct from microseg-regation, is often inverse in nature. That is, the eu-tectic solute elements, which are expected to be con-

Jan 1, 1970

By N. W. Lord

The process of molten-zone refining is analyzed for long ingots and many zone passages. Formulas are derived which give the resultant impurity distribution in terms of finite series. A comparison with the approximate procedure of Hamming is given. HE physical principles and applications of an extremely physicalprinciple efficient form of metallurgical refinement has been described by Pfann. The purpose of the present paper is to describe a method of analyzing exactly the particular program used which enables the segregation effect to be predicted for any number of molten-zone passages in a long ingot. The method is applied to the particular case of refinement of an ingot whose impurity initially is uniformly distributed throughout its length. A number of molten zones of equal length are passed through the ingot effecting a radical redistribution of impurity. Pfann has indicated an approximate method, due to R. W. Hamming, of calculating the resultant concentration after each successive zone pass for a particular value of the segregation constant defined in his paper. Here a solution will be presented in terms of the number of zone passes and the segregation constant. The expression, though cumbersome, is exact and susceptible to ordinary numerical computation procedures. The results of a similar computation using the procedure of Hamming are presented in a table together with the exact results of the present method. The discrepancy in terms of absolute concentrations is tabulated for the first eight zone-lengths. To establish the notation (which follows that of Pfann1 as closely as possible) and physical basis of the analytical equations, the physical model and principal assumptions may be reviewed. An alloy of two elements, where there is formed a continuous range of solid solutions, usually does not melt as a simple compound. Rather, a temperature is reached where the solid solution is in heterogeneous phase equilibrium with a liquid solution of different composition. The temperature dependence of these equilibrium compositions forms part of the phase diagram. For very small concentrations of a solute B in a solvent A, this usually takes the form of Fig. 1. Sometimes the solidus and liquidus slope upward. This corresponds to a segregation constant (defined below) which is greater than unity. The segregation constant is now defined as k = Cn(x)/CnI(x) [1] where C,,(x) is the impurity concentration in the solid ingot at distance x during the nth passing of a molten zone and Cnl (x) is the impurity concentration of the liquid zone from which the solid at dis- tance x is formed (see Fig. 4 of ref. 1.) C (x) remains the same after passage of the zone. The constant k may be either greater or less than unity in general. Purification in the former case is effected only in a finite ingot and in the portion that is melted last. For k less than unity purification is effected even in an infinite ingot. The method which follows gives, in the former case, the successive increases in impurity concentration and, in the latter case, the successive decreases in concentration. The general case of impurity redistribution will be considered first, and purification will be discussed later on. The analysis rests on the following assumption: The movement of the zone is too rapid to allow appreciable atomic rearrangement in the solid sections and too slow to disturb the uniform impurity distribution in the liquid zone characteristic of equilibrium. Hence, the composition in the solid at the left solidifying interface will be determined by Eq. 1 while the impurity concentration of the liquid zone will be uniform throughout its length. The reasoning which follows closely parallels that of Appendix 11 in Pfann&apos;s paper. It is reviewed here for the case of the nth zone pass in order to make clear the meaning of an operator essential to the present method. Fig. 4 of ref. 1 shows the movement of a molten zone of length 1 in an ingot of total length d. Each Cn(x) can be determined from the condition that the amount of solute added to the zone during an incremental advance, dx, is due to the melting in of a solid portion C(x)dx and the freezing out of kCnl(x), that is d I —r- CnL (x) dx = Cn-1 (x+l)- kCnL (x) dx or, in terms of Cn(x) d k k —— C,(x) +—c.(x) =— Cn-1 (x + l). [2] dx l l This, of course, is derived from the main assumption, the fact that 1 is constant, and that the total impurity content previously present up to x + 1 is constant . A correction has to be made for the region (d — nl) < x < d. This is due to the zone length changing during the passage of the solidifying interface beyond x = d — 1. Since the general solution would be too complicated otherwise, only the region 0 < x < d — nl is considered. The general solution of Eq. 2 is

Jan 1, 1954

By D. R. Rice

Separation of valuable constituents from a complex mineral mixture was examined. Nitric acid leaching produced a solution containing copper, zinc, iron and a large proportion of silver. The residue contained antimony, lead, the remaining silver and elemental sulfur. A caustic sodium sulfide leach dissolved the antimony from the residue, producing an insoluble, high-grade silver-lead product and a filtrate for electrolytic recovery of antimony. The pH of the primary filtrate was raised, precipitating the iron and leaving a solution containing the copper, zinc and the soluble portion of the silver, which would be recovered by conventional means.

Jan 1, 1969

By Hamidreza Soltanzadeh

The injection of CO2 into a reservoir or aquifer can potentially result in deformation, induced fracturing and fault reactivation in the injection zone and/or the rocks that surround it. This paper reviews the data collection and geomechanical analyses performed to assess these potential hazards for the Heartland Area Redwater Project (HARP), in which CO2 sequestration is being considered in a carbonate (Leduc Formation) reef. A three-dimensional mechanical earth model (3D MEM) was developed using available geophysical log data from several wells. The geomechanical response to CO2 injection was studied using a finite element numerical model based on the 3D MEM and pore pressure distributions predicted using a reservoir simulator. The modeling results suggest that the potential for induced fracturing and fault reactivation is low and the maximum predicted ground surface heave is less than 2 cm. Sensitivity analyses conducted with a 2D geomechanical model that was extracted from the 3D model confirm that this conclusion holds true even when a reasonable measure of uncertainty in rock mechanical properties, ambient pore pressures and horizontal stress magnitudes is accounted for.

Jun 1, 2012

By E. H. Cho, P. K. Dai

An acid mine drainage sludge sample, containing 3.6% Mn, 0.18% Ni, 0.15% Co and 0.39% Zn, was obtained from central West Virginia. The sample was leached at room temperature with a pH 3 sulfuric acid solution. Air was then bubbled through the leach solution at pH 4.5 to precipitate the iron. The leach solution contained 258 ppm Zn, 105 ppm Ni, 90 ppm Co and 2050 ppm Mn. Three solvent extraction studies were performed to selectively extract these metal ions in a sequential operation with DEHPA. Cyanex 272 and Lix 84. The A/O ratio was one, and the extractants were diluted ten times with kerosene. A study of solvent extraction with DEHPA showed that Zn could be extracted without Ni or Co up to a pH of 2.75. A pH of 2.75 is considered to be the optimum pH to maximize the selective separation of Zn from Mn. The separation factor of Co over manganese suggests that the two metal ions should be extracted together by Cyanex 272. The separation factor of Co over Ni indicates that these two metal ions can be separated most effectively around pH 5.3. Also, Ni can be effectively extracted by Lix 84 above pH 5.5.

Jan 1, 1995

By D. Ling, Santos. R. M., T. Van Gerven, M. Guo

The valorization of alkaline waste materials from thermal processes utilizing intensified mineral carbonation routes is investigated. The principal advantages of this approach are the chemical stability and storage safety of mineral carbonates, the opportunities for process integration presented by the technology, and the potential for conversion of low-value materials into useful products. Treatment and disposal of steel slags are a costly burden on steel plants. Sustainable solutions for Argon Oxygen Decarbonisation (AOD) and Continuous Casting (CC) stainless steel slags and Basic Oxygen Furnace (BOF) steel slag are desired. An integrated on-site mineral carbonation approach is envisaged as a favourable solution.

Jan 1, 2011

In 2004, a total of 4,401 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA). Stone mines comprised 30.4% of all mining operations.

Sep 1, 2007

A discussion on simulation tools to aid the development of robotics platforms is presented. The focus of the work is towards mining robotics platforms where operations are typically in unstructured, unpredictable environments and a high degree of dependability in their operations is required. It is argued that a test-based development approach leads to more robust solutions and faster development cycles than traditional single-track field-only development and that the key enabling technology for this development paradigm is the judicious use of simulation tools. The future direction of simulation for use in online applications such as active planning and as a means to assist tele-operation in high latency communication applications is also brief y considered together with the requirements for a useful simulation environment in terms of the simulator architecture. Finally, a case study is presented on the application of the discussed methodologies to an unmanned ground vehicle (UGV) for earth-moving tasks, which is being developed in an accelerated time frame with a transient development team.

Dec 6, 2010