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By Shengli Wu, Jinming Zhu, Wei Huang, Xinliang Liu

The sinter of high basicity would interact with lump ores or acid pellets in the cohesive zone of blast furnace due to the difference of chemical composition and micro structures. The results of this work showed that the softening-melting properties of lump ores and acid pellet would be obviously improved by the high temperature interaction. However, the high temperature interaction index (INI) would be influenced by many factors, such as chemical composition, porosity, interaction interface and so on. The INI between sinter and porous limonite lump ore (L-2) was much higher than that of dense hematite lump ore (L-1) and acid pellet (P-1). In addition, though the softening and melting properties of L-2 were poorest in respective iron ores, the softening and melting properties of integrated burden B (consist of sinter and L-2) were not worse than other integrated burdens due to the strong high temperature interaction.

Jan 1, 2015

Jan 1, 1988

By J. A. Mielczarski

An infrared external reflection spectroscopy (ERS) technique has been developed to study the structure of the adsorbed layer of ethyl xanthate formed on copper and natural chalcocite (Cu2S) electrodes. The infrared technique provides information concerning the identity and the orientation of the adsorbed species at monolayer and submonolayer coverages. X-ray photoelectron spectroscopy (XPS) studies have also been conducted to monitor changes at the surface. The results show that the first oxidation peak on the voltammograms for copper and the first and second oxidation peaks on the voltammograms for chalcocite electrodes are not characteristic of a chemisorbed xanthate species, which is contrary to what has been reported by other investigators previously. As evidenced by the XPS spectra, there was an increase in sulfur relative to copper on the copper and chalcocite surfaces over the potential region where these oxidation processes occur. The spectroscopic results (ERS, XPS) indicate that the second and third (on copper) and the third and fourth (on chalcocite) oxidation processes recorded on the voltammograms are due to cuprous ethyl xanthate adsorption. The orientation of the adsorbed molecules of xanthate was observed to change with increasing surface coverage. Therefore, it has been concluded that xanthate can modify the copper and chalcocite surface in two different ways. At lower potentials, xanthate is a source of sulfur for the formation of a sulfur-rich surface. At higher potentials, an adsorption layer of cuprous ethyl xanthate is formed. Contact angle measurements show that both of these processes of xanthate surface modification lead to an increase in the hydrophobicity of the substrates.

Jan 1, 1990

By R. N. Gow

EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. However, successful application of these diagrams requires several things be kept in mind to prevent what others have termed ?gross errors? in their calculation and use. The aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the thermodynamic equilibrium software, STABCAL. This includes a breakdown of the Gibbs? Phase Rule and how it is employed in STABCAL to modify the diagrams. This methodology was then applied to the aqueous Cu-As-S system and resulting diagrams are compared against examples of those generated using the predominant-ion method. The resulting mass-balanced diagram for enargite (Cu3AsS4) is noted to compare well with spectroelectrochemical measurements using Raman spectroscopy and cyclic voltammetry.

Feb 23, 2014

By I. E. Odom

A study was made of the physical and chemical nature of silica minerals found as natural impurities in bentonites and montmorillonitic Fuller&apos;s earth clay products as well as in <10 micron dust from eight processing plants. The results show that the silica minerals present in these clay materials are totally encapsulated or encased in clay. No "free" silica minerals could be observed in SEM images of either granular or powder products or in dust samples collected for MSHA crystalline silica analysis. Silica minerals, such as quartz, are identifiable by SEM and EDS analysis only after removing the clay coatings by vigorous washing. After washing it can be observed that all crystalline quartz grains also have diagenetic overgrowths of what is probably opaline silica. The clay and opaline silica encapsulation of quartz plus the strongly hydro scopic nature of montmorillonite are believed to be responsible for there not being a single confirmed case of silicosis among workers in the subject plants after more than 65 years of production.

Jan 1, 1996

By Swaminathan Srinivasan, Aaron J. Muck

"When an opportunity arises to combine state-of-the-art concepts with advanced modeling tools, engineers need to take what they know and apply forward thinking to geotechnical solutions to promote the state-ofpractice. Such an opportunity was seized during the design and construction of the Great American Tower in Cincinnati, Ohio. The forty-one story Great American Tower at Queen City Square – currently the tallest building in Cincinnati – has not only changed the downtown skyline, it is also contributing to the advancement of the state-of-the-art use of auger cast-in-place (ACIP) piles as settlement reducers. Predicted settlements of a traditional mat foundation were excessive, and the costs and construction time associated with traditional ACIP piles extending to bedrock were not preferred. A mat supported on a limited number of ACIP piles, with the piles primarily acting as settlement reducers, was evaluated as the preferred foundation type.Promoting the unique soil-structure interaction of the foundation system with confidence required the use of sophisticated numerical modeling tools. Traditional standard penetration test boring data (SPT) was initially used to develop a numerical analysis of the soil-structure interaction using FLAC 3D software. The model was further modified with cone penetration (CPT) and pressuremeter testing (PMT), along with actual load test results on several ACIP pile elements of varying lengths, but all tipping above bedrock. Through a combined design team effort, and detailed numerical modeling analysis, ACIP piles were recommended for reducing mat foundation settlement. Instrumentation during and post-construction confirmed design assumptions and predictions. Integrating sound geotechnical concepts, and using advanced geotechnical analysis and design methods, traditional mat and ACIP pile foundations were successfully integrated into a unique foundation support system.INTRODUCTIONThe Great American Tower at Queen City Square in Cincinnati, Ohio is located within a region dissected by historical geologic deviances associated with the meander of the Ohio River and glacial progression/recession. Combining a challenging geology, with the development of a high-rise office building afforded the design team an opportunity to combine state-of-the-art soil-structure interaction concepts and method with traditional geotechnical engineering concepts. Such a combination required a variety of field tests, collaboration with the design team and owner, and geotechnical-structural modeling during the design phase. During construction, in addition to materials testing and observation, a variety of instrumentation systems were employed. Together, the data was used to corroborate the design model and make adjustments during construction and further substantiate design assumptions following construction."

Jan 1, 2015

By Alan M. Bateman

POSSIBLE postwar trends of the more important world minerals will be determined in part by their present world position and by the acts and forces that have operated during the war period, so it is desirable first to review briefly what has been happening in the foreign field of metals and minerals. When we first entered this war we of the mineral profession were all acutely conscious of our lack of strategic minerals and other materials, which had to be imported in great quantities-minerals such as manganese, chrome, tin, mercury, nickel, and antimony. But we realized also that we had to acquire vast quantities of those minerals of which we had thought we were bountifully supplied. Our assumed domestic abundances turned out to be woefully deficient, and demands also arose for new minerals never before produced in large quantities. Some threescore minerals entered the strategic list of our imports. Ores from new sources had to be sought, developed, and transported. Tonnages in the millions of such bulk materials as zinc, lead, copper, chrome, and manganese flowed to feed our war efforts. Sparsely distributed minerals such as tin, mercury, antimony, tungsten, cobalt, mica, and corundum had to be lured from their rock lairs in greatly increased quantities to feed the hungry maw of war industry, and the rare minerals such as tantalite, columbite, beryl, and quartz crystals had to be developed and procured in quantities never before dreamed of. New uses such as radio and radar created demands for many minerals formerly thought of only as adornments of museum collections and not as pressing industrial minerals. Such minerals were never before mined in quantity.

Jan 1, 1945

By C. O. Hawk

Distillable oils derived from coal were desulfurized and hydrogenated at 2,500 psig in a two-step vapor-phase catalytic operation to give a product rich in saturated cyclic hydrocarbons. The first step was mainly a desulfurization at 400 C, the second a saturation at 300 C. One of the oils used as feed stock was from low-temperature carbonization of a bituminous coal, the other was from the liquid-phase hydrogenation of coal in the Bureau&apos;s pilot plant. The product from the saturation step was distilled to remove the light ends and high-boiling residue and to recover a fraction having acceptable properties with respect to heating value, density, freezing point, viscosity, and boiling range according to specifications suggested by the Air Force for ultra-high-speed aircraft fuel. Quantities of the fuel fraction available were too small for the thermal stability test approved by the Air Force. The experiments, performed on laboratory scale, comprised mostly a study of the effect of varying the oil feed rate (at constant oil-to-hydrogen ratio) on the yield of the desired fuel fraction. The yield of the fuel fraction made from low-temperature carbonization oil was a little more than 1 percent of the weight of coal carbonized; that from coal-hydrogenation oil was about 12 percent of the weight of coal hydrogenated. A few attempts to do both desulfurization and saturation in one operation with sulfur resistant catalysts, developed for vapor-phase hydrogenation or hydroforming, were unsuccessful. By leaving the low-boiling ends in both feed stocks to desulfurization, another product was obtained: a low-sulfur aromatic cut boiling below 200 C. This material would be suitable as a solvent or a chemical raw material.

Jan 1, 1965

By Agne Rustan

This paper is intended to give a summary of the first ten Symposia on Rock Fragmentation by Blasting where the symposia activities were governed by a Steering Committee replaced at Fragblast 2 by an International Organizing Committee (IOC). At Fragblast 9 the name was changed to Fragblast International Organizing Committee (FIOC). Eighty four pages of statistical data about Fragblast 1-10 is documented on the Fragblast Website (ISEE.org).

Jan 1, 2014

By Walter Herd

For the past eight years, No. 2 mine of the Cumberland Railway & Coal Co., Springhill-a subsidiary of the Dominion Coal Co., Ltd.-has had an unenviable reputation for bumps. As the workings extended in certain directions under a greater cover, these bumps increased in severity and it became apparent some change in the system of extraction was necessary if the mine was to continue to operate. In September, 1924, following several fatalities resulting from bumps, the Mines Depart~ of Nova Scotia requested from the U. S. Bureau of Mines the services of George S. Rice, Chief Mining Engineer of the Bureau, to report on the conditions then prevalent in No. 2 mine, Springhill. °This request was promptly and courteously granted. Mr. Rice made a full investigation and a comprehensive and helpful report, which is embodied in the 1924 Annual Report of the Department of Public Works and Mines, Nova Scotia. Prior to 1925, the room-and-pillar method was employed, and in January of that year (there being a cessation of work from March to August due to labour troubles) longwall retreating on the west side, on a limited scale, and in a small section on the east side of the mine, was started. The major portion of the east side was not operated on this system till August, 1926, as there was developed a considerable area ready for pillar extraction between an arbitrary boundary and a point up to which bumps of any consequence had not been experienced. In ?the interval, development work for longwall retreating below the 5,900-foot level was vigorously pushed.

Jan 1, 1929

By William C. Cooley

A review was made of two Russian books and a chapter from a third book dealing with pipeline transport of coal. Emphasis was placed on hydrotransport of coarse coal in underground mines or surface pipelines. The books reviewed were: "Means of Increasing the Effectiveness of Hydrotransport," by V. N. Pokrovskaya (1972), "Parameters and Modes of Hydraulic Transport of Coal" by V. V. Traynis (1970), and the chapter "Calculations of Hydrotransport of Useful Minerals and Waste Rock" from the book "Hydromechanization of Opencast Workings" by G. A. Nurok (1970). All three are unique and useful additions to the world literature on hydrotransport. The Traynis book reveals the development and results of circular wheel stand tests to simulate hydrotransport in horizontal pipes, which is a potentially outstanding contribution to slurry pipeline technology. Graphical data and equations are presented which suggest that headlosses for coarse coal can be predicted with good accuracy for pipe sizes up to 14 inches in diameter. Wheel stands permit tests for pipe wear and lump degradation without recycling coal through pumps. Recommendations are made for wheel stand tests and for correlation of existing data.

Jan 1, 1976

By Norman Paley, Finn Ouchterlony

Detailed fragmentation data for different blast delay timing tests at the Red Dog mine in Alaska are analyzed. This work is a continuation of previous work in which the crusher output was found to be better described by the three-parameter Swebrec function than by the Rosin-Rammler function. For a crusher model, the x50 variable sufficed to describe changing crusher input while b and xmax could be considered fixed. For the crusher output from aggregated stockpile rock, as measured by digital image analysis using Split-Online, the constancy of b was not as apparent. In this paper detailed stockpile data, single Split data series, and sieved belt cuts of crusher product are analyzed using the Swebrec and truncated Rosin-Rammler functions. The variability of b is confirmed. By using specific fraction passing sizes a shortcut is presented that removes the need to do curve fitting to determine the three Swebrec function parameters.

Jan 1, 2013

By J. H. Welsh

This Bureau of Mines report presents guidelines to be considered in the design, installation, and operation of environmental mine monitoring systems in underground coal mines so as to enhance safety in the U.S. mining industry. A review of the current status of mine monitoring in the United States is also provided.

Jan 1, 1987

By Alan Bateman

Introduction A few years ago the name Katanga recalled, to those interested in copper, a far-off country in central Africa where deposits of huge size were beginning to pour a stream of copper into the world&apos;s markets. But no one heard of the adjacent part of northern Rhodesia as a potential copper region. It was then a bush-covered wilderness, with a few lonely, widely-spaced villages, and here and there a copper prospect that created but little outside attention. There was also one struggling mine whose development created pessimism. The low-grade carbonate outcrops of Rhodesia did not compare favourably with the rich carbonate ores of Katanga. And, since Katanga was mining only oxidized ores, it was then thought that this adjacent region likewise would contain only oxidized ores. The one mine that had been started, Bwana M&apos;Kubwa, was working on low-grade carbonate ore at a loss. The outlook was not promising. But, a little over three years ago, the aspect changed. The vision of one far-sighted engineer embraced the possibility that here copper sulphides might underlie those low-grade carbonate croppings. His courageous associates furnished the capital; drilling commenced, and the great Roan Antelope mine rapidly emerged. In quick succession, the N&apos;Kana, Mufulira, N&apos;Changa, N&apos;Changa Extension, and Chambishi mines were heard from. Prospecting and development are now proceeding apace, towns are being hewn out of the virgin bush, plants are being reared, and ramifying branch railways are being pushed out from the single line of steel that now connects Rhodesia with the coasts to the south. A great new copper-mining centre is in the making, about which the world will hear much in the future. As with most new mining camps, rumors abound regarding its ore possibilities; some are correct, some are erroneous, and reliable information unfortunately is all too scanty.

Jan 1, 1930

By Patricia R. Devine

This report expands an earlier study by Jack Faucett Associates (OFR #40-88) of the same title. Both reports are based upon an interindustry analysis from 1963 through 1982, during which time U.S. metals consumption and production did not keep pace with economic growth. The report discusses three sources of change: technological change, economic growth, and composition of final demand, as well as the relative importance of the individual components of final demand for metals. The results show investment and personal consumption to be the most metal-intensive components of final demand, and technological change to be the major cause of decline in consumption growth during the study period. Technology change is defined as alterations in production processes resulting in more or less consumption of metal per unit of output, often because of material substitutions and design changes. A trade analysis shows the significance of import growth, particularly indirect imports (metal contained in imported goods) as a factor contributing to the reduced growth rate of domestic metal production. The effect of import growth is partially offset by indirect export growth, suggesting that continued increase of all U.S. exports can have a strong effect in reducing the negative trade balance in metals.

Jan 1, 1988

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25&apos; C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By Victor Dolmage

Introduction Although gold production in British Columbia began in 1859, lode gold was not produced till 1893. Since 1900, the annual production of lode gold has fluctuated between $3,000,000 and $6,000,000. About twenty per cent of this production may be regarded as by-product gold from base metal mining. The remainder comes from a few isolated but important mines, such as the Rossland mines, Nickel Plate, Surf Inlet, Premier, Pioneer, Bralorne, Reno, and Cariboo Gold Quartz, and from several less important mines. All of the above, except Pioneer, Bralorne, Reno, and Cariboo, are approaching or have reached the point of exhaustion, but all are now receiving, under the stimulus of the. present gold-mining boom, drastic resuscitative treatment, with, in some cases, signs of resurrection. Notwithstanding this, however, the main interest at the present time is focussed on the Bridge River and Cariboo fields. Both these fields were discovered in the early &apos;sixties&apos; and, apart from the Cariboo placer production, both have from time to time contributed small amounts of lode gold; but it is only during the last two years that the real possibilities of these areas were discovered. and that they began to assume the appearance of goldfields of major importance. The two fields are sorme three hundred miles distant from one another and contain deposits of distinctly different types, so that the only reason for including them in one article is the fact that they came into prominence more or less simultaneously and at a time coinciding with, but not otherwise related to, the present gold-mining boom.

Jan 1, 1934

By Peter K. Strangway

During 1973, a 20,000 net ton (18 100 metric ton) formcoke test was carried out at Inland&apos;s 26.5-foot (8.08-meter) hearth diameter on NO. 5 Blast Furnace. The formcoke briquettes were produced from Elko1 coal by FMC at their pilot plant in Kemmerer, Wyoming. The briquettes were shipped to Inland in open railroad cars and most of them were placed in an outside storage field until a sufficient amount was available for the actual blast furnace test. The test consisted of three phases: an initial four-week base period; the actual 33-day formcoke test period; and a final three-week post-test base period. During the formcoke test period, the regular coke skip loads were gradually replaced with skips of formcoke until, after a three-week period, the replacement ratio reached 80%. The furnace operated smoothly and quality hot metal was produced. The burden remained permeable and it was possible to maintain wind rates 9 of over 100,000 scfm (47 Nm3/s) without significant blast pressure increases. Dusting from the formcoke was not a problem either in the stockhouse or in the top gas. The formcoke briquettes maintained their original shape and density as they descended through the furnace. When the 80 percent replacement level had been reached, the inwall temperatures became higher than normal (about 2000 ºF (1090 ºC)) and followed an unusual steady pattern. In addition, the top gas temperature became higher than normal, and the hot metal analyses and temperatures began to fluctuate unacceptably. In general, it is felt that the high inwall temperatures were a result of channeling of the hot furnace gases along the stack walls. This channeling appears to have been promoted by a change in distribution of the burden in the top of the furnace which, undoubtedly, was caused by the increased increments of formcoke. Since it was felt to be unsafe to operate the furnace for an extended period of time with the inwall temperatures at the high level, a decision was made to remove the formcoke from the furnace. When this was done, the inwall temperatures returned to normal. Once the inwall temperatures had returned to normal, the remaining 3,800 net tons (3450 metric tons) of formcoke were used in the furnace at a nominal 40% replacement level for five continuous days. The furnace operated smoothly during this period, and the results were representative of satisfactory furnace operation with partial replacement of regular coke with formcoke. The test was successful in proving that formcoke can replace up to about 50% of the regular coke in a large furnace operating at high wind rates. However, additional work will be required to develop acceptable charging practices for using higher levels of formcoke replacement.

Jan 1, 1977

By Edward W. Parker

I. INTRODUCTION. AT the Seventy-sixth meeting of the Institute, held in New York, N. Y., February, 1899, I presented a, paper on this subject entitled, Coal-Cutting Machinery,&apos; which has become somewhat out of date, in view of the decade&apos;s development in this feature of the coal-minim industry. It should be explained that the present paper is limited to the use of mining-machines in bituminous mines. Practically all of the anthracite mined is ?shot from the solid," no undercutting being done. Anthracite-mining is therefore not considered in the statistics or other references. The statistical record as compiled by the United States Geological Survey shows that in 1898, the year preceding the presentation of my former paper, there were 32,413,144 short tons of coal undercut by the use of machines. In 1907 the machine-mined coal-product amounted to 138,547,823 short tons. In sympathy with the general decrease in coal-production during 1908, the output of machine-mined coal decreased to 123,183,334 short tons, but the proportion of machine-mined coal to the total output, nevertheless, showed an increase, from 35.1 per cent in 1907 to 37 per cent in 1908. In 1898 only 19.5 per cent. of the total product was undercut by the use of machines. The number of undercutting-machines in use in the bituminous mines of the United States has increased from 2,622 in 1898 to 11,144 in 1907, and to 11,569 in 1908. The total production of bituminous coal in the United States in 1908 was almost exactly double that of 1898, while the machine- * Published by permission of the Director of the U. S. Geological Survey. 1 Trans.. xxix.. 400 to 4,59 (1899).

Sep 1, 1910

By R. D. Berkenkotter

This report describes a weighted method for evaluating the mean and variance of assay data from samples of different length . The method , which produces unbiased estimates from which valid confidence limits can be computed , is appropriate for bedded deposits of variable bed thickness and for vein deposits of variable vein width . Assay data from the bedded Florida phosphate deposit is used to illustrate the procedure .

Jan 1, 1964