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By Hong Peng, James Vaughan

Thermal activation of bauxite has been proposed to enable bauxite dissolution at a reduced digestion temperature and also to reduce the organic content in the liquor. Research has been carried out on phase transformation of its main hydroxide components (gibbsite, boehmite and kaolinite) during calcination. However, there is limited information available on phase bauxite phase transformation during thermal activation. In this study, two bauxite ore samples were heated from 25 to 700 °C at a rate of 50 °C/min while monitoring the phase transformation using Rigaku in situ XRD. Different phase transformation pathways for gibbsite in the bauxite compared with pure gibbsite was observed. Boehmite and kaolinite in bauxite behaved similarly to their pure phases. The temperature of phase transformation depends to some extent on the bauxite sample. Samples were also characterised by scanning electron microscopy (SEM) to reveal changes in the microstructure.

Mar 1, 2018

By W. T. Caneer

Uranium may be in short supply due to the predicted energy needs in the coming years. As a result of this a new surge of uranium exploration is underway. The refinement of numerous exploration techniques has accompanied this surge. One such technique is the monitoring of radon gas in surface soils and rocks as a guide to subsurface uranium deposits. The Colorado School of Mines Research Institute became involved in radon studies in 1967 on a project for the AEC. Since that time the Institute has conducted numerous radon surveys for a large number of companies which have been active in uranium exploration. The objective of this paper is to relate the techniques utilized by the Research Institute and the results of some of the studies performed. Most of the studies performed by the Research Institute were related to roll front, sandstone -type uranium deposits. However, we have performed radon studies in various other types of rock. For those who may not be familiar with the application of radon ?sniffing" in soils and rocks, a brief descriptive background should be given. The following question may be asked -- why use radon as a guide to uranium mineralization? Some of the answers to this question are as follows:

Jan 1, 1974

By M. Fan, R. Letkiewicz, A. Hobert, J. Milbourne

Ultrafine copper, gold and silver minerals flotation has become increasingly important because of the rising demand for processing finely disseminated ores. This paper investigates the improved flotation of ultrafine ores from a Troilus Gold project. Troilus is primarily an Au-Cu deposit but contains minor amounts of Ag, Zn and Pb, as well as traces of Bi, Te, and Mo. As a result of ultrafine Cu-Au-Ag dissemination and associated grinding requirements, Eriez’ column/StackCell and Denver benchtop cells were utilized to optimize their respective flotation responses. Enhanced flotation results were achieved using column and StackCell technologies. KAX 51 and SPRI 206 collectors, Na2SO3, and ZnSO4 depressants were the primary reagents employed. In column/StackCell flotation of three main mineral deposit ore composites, the rougher-scavenger-cleaner circuit Cu, Au and Ag flotation recoveries were 90.4~95.8% at a copper grade of 13.6-17.4%, 87.5-95.1% at a gold grade of 101-145.9 g/t, and 88.6-91.8% at a silver grade of 62.6-251.4 g/t, respectively. The benefits of Eriez Column/StackCell flotation technologies include high flotation selectivity and increased recovery due to unique hydrodynamic designs. Specifically, the StackCell design facilitates high turbulent kinetic energy dissipation rates to improve fine particle recovery and incorporates countercurrent wash water to significantly reduce hydraulic entrainment of the finest size gangue minerals to the froth product.

Feb 1, 2023

By E. J. Onuscheck

Coal mine safety of the past was plagued by disasters that took the lives of thousands of miners. Through the years new mining methods, improved laws, and a commitment from the mining industry has reduced the frequency of such incidents to a minimum. History tells us that coal was mined in the early 1700's in Virginia primarily for use by blacksmiths -- most of that mining was done in the Richmond area. It was in those mines that methane was encountered; as workings became more extensive, methane explosions became more frequent. In the early 1800's the first recorded explosion occurred near Richmond, Virginia -- 40 men were killed.

Jan 1, 1985

By Clinton A. Hollingsworth

The Flotaire Flotation Cell is a simple, efficient hydraulic/pneumatic Flotation Cell that has no moving parts. It is normally used in conjunction with a surfactant (frother) in which case the combination is known as "The Flotaire System". On many ores, metallurgical efficiencies are substantially increased and operating costs reduce. For example, in floating phosphate rock, it is not unusual for BPL recovery to be increased more than 10%, the major increase being due to floating coarse phosphate, up to 14 mesh, and the difficult to float phosphate. Substantial improvements have also been made on coal, mica, vermiculite, kaolin, barite, copper, etc.

Jan 1, 1981

Except for uranium search, conventional oil well logging techniques are relatively little-used in mining exploration. The main reasons for this are cost and an apparent lack of awareness of the potential use of the methods in the search for ore. However, relatively inexpensive portable units are currently available for performing the simpler electrical and radiometric logs in diamond drill holes.The emphasis in oil exploration logging programmes is largely on the estimation of porosity. In most mineral work, however, porosity is not very significant, and factors such as mineral conductivity and radioactivity assume an important role.The Bureau of Mineral Resources (BMR) during a programme to explore for uranium and associated base metals in the area east of Rum Jungle, N.T., carried out electrical and radiometric logging of diamond drill holes as a routine part of their investigations. Case histories are described in which the logs were used to aid in defining stratigraphic sequences and transgressive structures in base-metal prospects. Some surface geophysicalanomalies were explained by the logging: induced polarization and electromagnetic anomalies were related to black slate; and self-potential anomalies were related to oxidation of pyrite black slate, or apparent electrokineticeffects in the black slate. The logs provided an objective appraisal of the rock units penetrated and thereby helped to differentiate lithologies.Borehole logging, including newer techniques such as downhole analysis, could be done in geological and geophysical investigations in other areas for a relatively small cost with a considerable potential gain of information.

Jan 1, 1978

By R. M. Reynolds

Engitec Impianti, S?.p.A. of Milan, Italy has successfully designed, constructed and has in operation state-of-the-art battery breaker systems at two European locations. A third facility i:s partially completed in Toronto, Ontario, Canada. The CX system crushes whole batteries, separates the various components and desulfurizes the battery paste. The system also produces sodium sulfate from the sulfuric acid and lead sulfate contained in the batteries. Actual plant operating data indicates that the desulfurized paste contains less than 0. 6 percent sulfur and less than 0. 5 percent antimony. The CX system utilizes mechanical screening and an up-flow hydrodynamic separator to accomplish the component separation. Sodiwn hydroxide or sodium carbonate is used for desulfurization. The sodium sulfate brine is evaporated and crystallized to produce clean anhydrous sodium sulfate suitable for use by detergent or glass manufacturers. Plant data also indicates that an increase in furnace productivity of about 25 to 30 percent is achieved using feed from the CX system. The desulfurized paste is very suitable for electrolytic processing as an alternative to pyrometallurqical processing.

Jan 1, 1990

By Carl Sonnen

Reading the newspapers, you will know that opposition to ratification on economic grounds always points to the view that action will result in major price increases for energy (to both industry and households) with consequent severe losses of energy production and a loss of competitiveness for energy-intensive producers (i.e., in your kinds of industries). You might think of this as the ?carbon tax? fear, and you should note that many of the initial policy development experiments included variations of this theme. Analysis reported in late 2000 and into early 2002 reported reductions in energy production in the long run of between 10% and 20%. At the upper end of that view, these were the kinds of numbers reported in the Industry Canada study ?leaked? to the Press last week. The consequences of this approach included significantly uneven negative effects for some provinces (e.g., Alberta, but also Saskatchewan and Newfoundland). It had been agreed by the First Ministers of Canada, however, that the policy should not yield those results so development in recent months has focused on eliminating sector and therefore provincial ?sore thumbs?. Although an emissions trading system, which represents this type of approach and directly impacts costs of production, continues to be featured in the new or current policy and is applied to the Minerals Industries among others, it is designed to be implemented in such fashion that the costs are more moderate than before. And because the industries covered by permits are almost all price takers, there is no device for moving an increased price signal forward to ?consumers?. What this does do is even out negative effects among sectors in the economy and for provinces, but at the expense of government financial results.

Nov 1, 2002

By Leland A. Yerkes

Refining aluminum from crude aluminum alloys by the subhalide reaction was investigated to develop a method of producing aluminum by means other than electrolysis of its oxide. The best materials and design for the apparatus and also optimum operating conditions, including temperature, pressure, vapor flow rate, and composition of alloy charge were studied. In the subhalide process, aluminum-trihalide vapor reacts with aluminum in the alloy under high temperature and low pressure, forming volatile aluminum monohalide which reverts to aluminum metal and aluminum trihalide on cooling. The only halide used in this investigation was aluminum trichloride. The crude aluminum-silicon alloys used as the principal raw material contained from 21.9 to 36 percent aluminum, and significant quantities of iron and titanium. These alloys were produced by direct electric smelting of clays. Graphite tubing that was heated by an induction coil proved to be satisfactory material for the laboratory reactor chamber, Enclosed in an insulated glass or quartz pipe, the reactor was used in both vertical and horizontal positions with various baffle and tray arrangements for directing the trihalide vapor both over and through the alloy. Aluminum trichloride vapor was generated in the sublimer at one end of the glass pipe, passed into the reactor where contact was made with the crude alloy, and aluminum monochloride gas was formed. When the gaseous mixture of aluminum monochloride and unreacted tri-chloride passed out of the reactor and entered the condenser, the gases were cooled to 900° C. or less, causing the monochloride to disproportionate into aluminum and aluminum trichloride vapor. The aluminum was deposited on the condenser walls while the aluminum trichloride vapor was carried out of the condenser and into the opposite end of the glass pipe where it solidified on the cooled copper coils.

Jan 1, 1961

By H. M. Cyr, T. F. Steele, C. W. Siller

The development of a new metallurgical roasting device is described. It consists of a refractory column into which air is injected at various levels, forming several superimposed fluidized beds with no supporting grates. When pelleted zinc sulphide concentrates are charged, the roasted product needs no further sintering before reduction to metal. WHEN a gas such as air is blown upward with increasing velocities through a loose mass of solid particles, marked changes in the physical behavior of the particles are noted. At first, when the velocity of the gas is insufficient to support any of the solid, the mass constitutes a "fixed bed." As the gas velocity increases until the pressure drop through the bed approaches the effective weight of the bed per unit area, the bed expands until the solid particles are supported by the air rather than by the lower particles. Some vibration of the particles becomes apparent, but little mixing occurs. This condition is called a "quiescent fluid bed." A further increase in gas velocity imparts more separation and more motion to the individual particles until a condition of turbulence is reached. This "turbulent fluid bed" resembles a rapidly boiling liquid with the characteristic highly agitated diffuse surface and many small eruptions of the boiling mass. Different degrees of turbulence can be generated and all produce excellent mixing. The final stage occurs when the gas velocity becomes so great as to create a "dispersed suspension." Here no surface of the mass is defined and the gas carries solid particles out of their original positions. These changing conditions of fluidization have been studied carefully and pertinent nomenclature standardized by a committee of the American Institute of Chemical Engineers.' Many mathematical analyses2-3 have been made of the forces acting in a fluid bed. These analyses are invaluable, especially for the design of column sizes and selection of equipment. However, in a metallurgical process involving solids of many sizes with changing densities, varying temperatures, and changing gas compositions within the bed, calculations based on theory become approximate. Optimum operating conditions then are best determined experimentally. Many applications have been made of the principles of fluid-bed action by mechanical, chemical, and metallurgical engineers. Especially when good con- tact between reacting solids and gases is desired, very effective results are obtained from fluid beds. They permit excellent temperature control and uniformity throughout a mass of solids in fluid action. Heat transfer to walls and any coolers is high, and fast reaction rates are attained because the solid surfaces are continuously swept clean. The main disadvantages of fluid-bed operations are the danger of short-circuiting in a single bed, danger of incipient sintering which stops action, the necessity of avoiding large changes in particle size or density during roasting, and dust losses when particles of the charge are carried out with exit gases. In the metallurgical field the roasting of sulphide ores to form oxides and sulphur dioxide appears to combine several operating conditions which can be achieved to advantage in a fluid bed. Roasting involves a solid-gas reaction where a high reaction rate is necessary for high capacity, where good temperature control is important in order to prevent sintering, where good heat transfer is needed, and where the density of the solids, when changing from sulphides to oxides, is not largely changed. Short-circuiting, however, constitutes a major problem when a single fluid bed is used. Because of the turbulence of the bed, an entering particle may be in the region of the discharge before it is roasted. Hence, to attain a satisfactorily low sulphur in the calcine, a long average residence time with correspondingly low capacity is required. The solution to this difficulty is the use of multiple stages, which in the conventional fluid-bed design requires separate hearths with feed and discharge mechanisms for each stage. A further practical difficulty in fluid-bed roasting of flotation zinc concentrates is their fine particle size which makes a true fluid action without excessive carry-over of dust very difficult to attain, especially when the large air volumes necessary for high capacity are used. A New Design After considerable experimentation in the laboratory and on a semipilot-plant scale, a new method and equipment for roasting were devised which provided a unique solution to these problems. A detailed account of this development appears in the patent literature," and many of the variations of this development reported herein are the subject of

Jan 1, 1955

By Bolger Witthaus

"High performance production under challenging geological conditions is a product of several parameters. Main factors are the technical equipment and the knowledge in processing. The design and the support system of maingates must also be taken into consideration. The extraction of seams in German underground hard coal mines of RAG in a range of heights between approximately 1.1 and 4.0 m ( 4 and 13 ft) is done by plow and shearer technology. A complete system for quality management of production is required. The process examination of processes begins with procurement of the equipment. Education and training of the engineers and specialists, as well as for the miners are requirements for success as well.This report gives an overview of RAG measures for achieving high performance. Starting with examination of the processes accompanying procurement of equipment, the following important elements are described. Standards in education and training, technical design and elements of automated processing using stateof- the-art in control systems are critical to this system.The application of automation plays a decisive role in modem coal mines. The latest development in German coal mines is the fully-automated shearer system for longwalls. This helps to enhance safety, particularly in difficult ground conditions, by removing the shearer and shield operators from the immediate mining activity.INTRODUCTIONLongwall mining in carboniferous strata in Germany faces various challenges. Different longwall systems are used to mine up to 24 seams, each with a thickness between 1.1 m (3.6 ft) and 4.0 m (13 ft). High stresses due to a depth of up to 1,400 m (4,593 ft) requiring pillars between the panels, require special systems for roadway development, roadway support and reinforcemen.t as well as for longwall advance operations. Two main types of equipment for extraction are shearer and plow systems. While shearers are utilized for seam thicknesses above approximately 1.8 m (6 ft), plow systems can be used for smaller seam thicknesses between 1.8 m (6 ft) and approximately 1.0 m (3 ft)."

Jan 1, 2010

By John G. Payne

The Pebble deposit contains three contiguous zones. In the Pebble West zone, granodiorite stocks intrude gently warped volcanosedimentary rocks that had been intruded by diorite sills and two felsic intrusion breccias. In the Central zone, volcanosedimentary rocks are cut by diorite and granodiorite sills; the latter are genetically associated with the granodiorite stocks. In these zones, widespread potassic alteration consists of brown biotite and K-feldspar, with abundant quartz-carbonate-sulphide vein stockworks. Chalcopyrite/pyrite ratios range from 2/1 to 1/20. Diorite hosts the highest-grade mineralization, with much of it being disseminated. Patchy, later phyllic alteration is moderate and commonly depleted in copper. The Pebble East zone occupies a granodiorite stock and intruded host rocks below an eastwardly thickening wedge of barren Tertiary volcanic and sedimentary rocks up to 600 m thick. Brown biotite alteration and copper mineralization are strong, with chalcopyrite/pyrite ratios commonly over 1/1. The zone extends to a depth of at least 1200 m below surface; some drill holes bottomed in strong mineralization. Later, weak to moderate sericitic alteration removed some chalcopyrite and locally remobilized gold. The Pebble deposit has a Measured/Indicated resource of 3 billion tonnes grading 0.28% Cu, 0.32 g/t Au and 0.015% Mo (= 0.5% copper-equivalent) and an Inferred resource of 1.13 billion tonnes grading 0.30 g/t Au, 0.27% Cu and 0.015% Mo (0.55% copper-equivalent). The Pebble East zone has an Inferred resource of 2.13 billion tonnes grading 0.55% Cu, 0.34 g/t Au, and 0.037% Mo (0.97% copper-equivalent). The Pebble East zone is open to the east and to a lesser extent to the north, south, and to depth.

May 1, 2006

The last decade has seen a very rapid development in TBM tunnelling. Some trends are purely technical or economical and others relate more to preferences of different interests. Power levels have more than doubled and thrust levels too. Shield machines are developed to be able to handle harder rock and the open TBMs are made more feasible for `difficult' rock. What is right and what is wrong is more a matter of opinion, but one thing is certain: TBMs now are a useful tool and no longer an experimental work-shop for the enthusiasts.This paper highlights some recent developments and indicates some probable future ones. A few features that have increased the open TBMs' ability to cope with ever harder rock and also to overcome problems with poor rock are discussed in detail, using the Atlas Copco JARVA Mk 27 -the most powerful TBM built so far - as a reference.

Jan 1, 1993

By Hsun Hu, R. S. Cline

A detailed studj) of texture formation in 2 pet Al-Fe single crystals with initial orientations of approximately (111) [112], (112) [111], and (112) [111] was made by examining the textures developed on the surface and at various interior sections of the crystal after rolling to various amounts. Depending' upon the initial orientation of the crystal, the surface and interior textures may differ only in sharpness, or may differ essentially in orientation. The orientation of the (111) [112] crystal does not change upon rolling up to 70 pet, but after rolling more than 90 pet a distinct component of (001) (110] orientation is developed. The texture formed in the two (112) (1111 type crystals consists of (111) (1121 and (001) (1101 components. The latter, however, is largely confined to the surface layers. The textures formed on both sides of the crystal are identical, and the texture composition profile is approximately symmetrical with respect to the central section of the strip thickness. The formation of these texture components is analyzed. DURING the past seven or eight years, deformation and recrystallization textures in rolled Si-Fe single crystals have been extensively studied by various investigators.1-7 From these studies, much knowledge on texture formation in bee crystals of various initial orientations was obtained. However, these results also raised many questions, regarding particularly the correlation between deformation and recrystallization textures, as well as the deformation texture itself of some particular crystals. To take a (111) [112] type crystal as an example, it was shown by Dunn and Koh2, 3 that this orientation does not change during deformation by rolling. This finding is consistent with the conclusion reached by Barrett and Leven-son8 with respect to iron crystals that (111) [112] is one of the stable end orientations. However, different recrystallization textures were observed by Dunn and Koh3 in (111) [112] type crystals of different initial thickness, which widened differently during rolling even though their deformation textures were identical. Another interesting example, also from the results of Dunn and Koh2'3 is that of texture formation in a (112) [111] crystal. This crystal developed a two-component deformation texture of (111) [112] plus (001) [110]. Its recrystallization texture, however, was found to be predominantly (110) [001], which is related to the (111) [112] component by a simple [110] rotation. This crystal, therefore, behaved as if the other deformation texture component, (001) [110], were not present. There are also discrepancies among the results of different investigators, as well as numerous unexplained fine features of the deformation texture of crystals of various initial orientations. In order to have a better understanding of all of these points, a detailed study of deformation textures is greatly needed. One of the obvious things that has been completely overlooked in previous texture studies is the possible effect of surface texture. All past work on the texture of Si-Fe single crystals was conducted in a rather simple manner, i.e., the rolled crystals were etched to a very thin sheet; then their textures were examined by transmission X-ray techniques. For recrystallization texture studies, unless precautions are taken by etching off a sufficient amount of the surface layer before annealing, the texture developed in the interior may be affected by the surface layer, which may well have a different initial texture and which may have undergone recrystallization earlier than the interior of the specimen. Because of this effect, it is now planned to reexamine the texture of various rolled and annealed single crystals at the surface, and at various sections below the surface by using reflection techniques. In some cases, both surfaces of the rolled crystal will be examined. In one of Dunn's early papers,9 he noted that at an early stage of rolling the crystal seems to divide roughly through the middle to become a sample which in effect consists of two layers having some what different orientations. This effect has never been further explored. The investigation described in the present paper constitutes the beginning of a series of thorough investigations of texture formation in deformed bee single crystals designed to clear up some of the uncertainties which have been discussed. We have chosen a high-purity 2 pet Al-Fe alloy for this investigation. It is known that the allotropic transformation of iron is eliminated by alloying with approximately 1petAl. Such an alloy, being very similar to silicon ferrite, can be heated to the solidus temperature without phase transformation. One reason for choosing A1-Fe instead of Si-Fe for the present investigation is that we have been able to make single crystals of a vacuum-melted high-purity A1-Fe alloy by the strain-anneal method without much difficulty, but were not successful in doing so with a vacuum-melted high-purity Si-Fe alloy. For many research purposes,

Jan 1, 1962

By Charles Wright

AT most mines where large tonnages are handled, "bulldozing" or secondary blasting is an important and costly operation. To reduce the large blocks from primary blasting operations or stoping so that they will be small enough to pass through the chutes into the cars at the haulage level, and not too large for the crushing plant, requires blasting. Often this is done by placing a few sticks of dynamite on top of a block with or without a capping of mud, but to consume less dynamite and to promote safety, most secondary blasting is now done by blockholing, or the drilling of holes 6 to 12 in. long in the blocks, using only a part of a stick of dynamite per hole. Regardless of the method of blasting, however, the term "bulldozing chamber" is applied to the room where this work is done. Bulldozing chambers permit secondary blasting at all times in a safe place without disturbance to the other mining operations. The chambers are usually high above the haulage level and well below the stope level or open-pit floor. In most instances the material is passed through a grizzly in the bulldozing chamber, but sometimes no grizzlies are used. One to four raises extend from the chamber to the stope floor and one or two from the haulage level to the chamber floor. Occasionally large slabs of ore or rock choke the raises above the bull-dozing chamber, and these have to be blasted by attaching a bundle of dynamite sticks on the end of a long pole and placing them up in the raise between the pieces causing the choke. This is called "chute-blasting." To give a picture of the progressive developments in the use of the bulldozing chamber, a few typical mines that show the application of this method to both metal and limestone mines have been selected for description here. Limestone mines have been included because many metal miners do not realize to what extent the nonmetallic, or rock, miners are now applying metal-mining methods successfully in their operations. The bulldozing chamber is the "neck of the bottle" for some mines.

Jan 1, 1935

By H. H. Stout

THE high copper price during the war stimulated the capacity to produce far beyond a possible normal consumption. The curves in Fig. 1 show this. The line YZ indicates, what the world production and consumption of primary copper nor-mally would have been, had not the 3 war upset the rhythm of industry. Granting that the maximum world production of 3,150,000,000 lb. in 1917 was obtained by crowding both the equipment and the grade of ore mined, yet in many instances addi-tional capital was invested, upon which the producer will be driven to earn at least a reasonable interest. During the period of deflation, or C liquidation, which we have entered, the consumption of copper will nat-urally be below the normal. Fig. 1 shows the actual consumption ex-pressed-in per cent. of normal : 1919, 96 per cent.; 1920, 94 per cent.; 1921, 70 per cent. The copper industry, consequently, faces: (1) Potential over-production capacity; I (2) Diminished consumption. To deny the existence of these factors would be illogical. To minimize the menace of this potential producing capacity might lead to regret. All past attempts at artificial control have not proved very successful. Obviously the remedy is to increase, if possible, the consumption of copper to a point where these factors cease to be dangerous. In ultimate analysis, this means: Produce an article so cheap and so good that no one can afford to use substitutes. The problem can be solved by: (1) Re-ducing price; (2) Improving product offered.

Jan 11, 1922

Discussion of the paper of R. H. RICHARDS and BOYD DUDLEY, JR., presented at the New York meeting, February, 1915, and printed in Bulletin No. 97, January, 191.5, pp. 67 to 72. R. H. RICHARDS, Boston, Mass.-I believe that the manner of working for efficiency in almost all lines is to study the conditions of highest efficiency, and then to measure what is being clone. We can then see how near we have approached the highest efficiency. Spigots in practice often use many times the water theoretically needed. There are places where that is necessary for safety reasons. There are, however, places where it is unnecessary, and in these places it seems to me that this work of Mr. Dudley's will be a great help to the mill man to arrive at the greatest economy of water and highest efficiency. ALBERT R. LEDOUX, New York, N. Y.-A good many years ago I received a telegram from that distinguished engineer, Hamilton Smith, which simply said in substance: "I have discovered that liquids will flow faster from a square orifice than from a round orifice of the same area, under the same head." I wondered why he sent me the telegram, but some time afterward he told me that he had been making experiments along that line in Montana; that he thought the discovery was interesting

Jan 5, 1915

By V. H. Gottschalk, R. S. Dean

In the theoretical study of metallurgical reactions, it is necessary to make certain assumptions concerning the nature of metal-gas systems. The assumption usually made is that the reaction in such systems takes place predominantly with gas that is in "solution" and that the amount of solution follows the rules which have been developed for aqueous solutions; namely, Henry's law. The purpose of this paper is to inquire whether these assumptions are the best ones that present knowledge of gas-metal systems permits us to make. In the first part the extent to which a gas will dissolve in a metal and still follow Henry's law is considered. The conclusion is believed justified that the number of molecules of gas that can dissolve in a metal and have the system follow Henry's law must be small indeed. It is therefore improbable that the first assumption concerning the predominance of these dissolved molecules in reaction is correct. It is suggested that some improvement in the correlation of the probabilities with the assumptions made in the mass law equations would be made by the use of the dp law of Sieverts in place of Henry's law. However, the amount of gas that may be held in a metal so that it follows either Henry's or Sieverts' law is considerably outweighed in most metallurgical reactions by that held in gas-metal systems of entirely different structures and concerning which little experimental evidence is available. Some speculation concerning the nature of these is offered. The conclusion is that attention should be given to the determining of the nature of gas-metal systems and that the really fruitful application of the mass law and its connected calculations will have to await a more complete knowledge of these systems than we now possess. DISCUSSION (Paul D. Merica presiding) P. D. Merica, New York, N. Y. (written discussion).—The solubility relations of gases in metals, in so far as they are known from the pioneer work of Sieverts and others, have from the first presented certain challenging peculiarities. The authors have emphasized the significance of these characteristics and suggest that they point

Jan 1, 1933

By J. H. Zietsman, M. W. Erwee, P. J. A. Bezuidenhout, Q. G. Reynolds

"Pyrometallurgical furnaces are tapped through tap-holes that are opened with drills and oxygen lances. The lance is often used on its own or as the last step of opening the tap-hole. Interaction of oxygen with molten material inside the tap-hole can occur, and is a phenomenon that is not well understood. As part of a study that focuses on the effect of lancing on flow inside and around the furnace tap-hole, a cold-model validation was done. The validation study focuses on validating the MULTIPHASEINTERFOAM multiphase flow solver in OpenFOAM® for the problem involved. The sensitivity of the model to different materials properties (viscosity and density in particular) is presented with both cold models and the results from flow simulations in OpenFOAM®. IntroductionMany pyrometallurgical operations are carried out in furnaces where molten material accumulates continuously. Once enough material has accumulated and is ready to be removed from the furnace, material is tapped through one or more tap-holes in the furnace. Tap-holes differ significantly in both geometry and materials of construction, depending on the process involved – examples of different types of tap-hole configurations can be found in, for example, Nelson and Hundermark (2014). Tapholes all share one common feature: they are high, wear areas of the furnace. Molten material at high temperature flows through these areas, after which the tap-hole is sealed, usually using tap-hole clay. The purpose of the tap-hole clay is to harden inside the tap-hole and seal it until the next tap.Once ready to tap, a pneumatic drill and/or oxygen lance is used to open the tap-hole. The extent of lancing a furnace tap-hole depends strongly on the type of furnace. In, for example, many blast furnace operations lancing is limited as much as possible, and done only if drilling was not effective. In other operations, such as on small-scale pilot furnaces with short tap-holes, only lancing is used to open the tap-hole."

Jun 1, 2019

By Carl-Eric Dr. Nilsson

Energy cost for mine ventilation in Sweden is high, especially during winter time when air must be heated. This paper presents the result from a project entitled ventilation-as-required. The term ventilation-as-required means that the required volume of fresh air should be distributed only to such areas, where mining work is going on and to be reduced to a minimum in the rest of the mine. Ventilation-as-required is a monitoring system that controls the operation and capacity of the fans and measure the air pollutant gases, i.e. carbon monoxide, nitrogen and sulphur dioxide at strategic points. It is an active system that responds when equipment is under operation. MITU proposed in 1991 a project to develop a ventiation-as¬required system and such components as transmitters and receivers for the communication between the equipment and the fans. The mining companies, Boliden Mineral AB, LKAB, Outokumpu and Ammeberg Mining Corporation joined the project and have financed a joint research and development programme supported with a grant from the Swedish Government through NUTEK. MITU proposed a second project in 1992 to the mining companies to develop an improved "intelligent" fan for scope ventilation. Boliden Mineral and LKAB joined the project and have financed a joint research and development project supported by the Swedish Government through NUTEK. The Government even made a commitment to support the investment of the first 50 fans ordered with a grant of 25% of the investment cost. The result from projects show that the target set up in the plans is more than achieved, with an energy reduction that exceeds 30% compared to previous consumption. No environmental influence due to reduced ventilation is observed in the stope when work is under progress. Dilution of exhaust gases from diesel fuel decreased from 6.000 m3/L consumed diesel fuels to 3,600 m3/L. The automatic data processing and sensor system is even increasing the security of the work so that it can be done under safer environmental conditions.

Jan 1, 1995