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By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016

The widely accepted kinetic model for the gaseous reduction of hematite is critically examined. The formation of the wustite layer during internal reduction cannot be explained in terms of solid-state diffusion. Present evidence indicates the existence of a micropore system in the wustite adjacent to the magnetite with the gas/solid type of reaction occurring not only at the iron/wustite interface but also at the wustite/magnetite interface. During the partial reduction of dense hematite pellets, in a controlled atmosphere, porous magnetite and wustite are formed as products. The mean pore size, as measured by mercury injection, increases with time at constant temperature and with temperature increase over the range 6500C to 950°C. The sizes of the pores indicate that Knudsen diffusion is the principal gaseous transport mechanism across thick layers of magnetite or wustite.The kinetics of the gaseous reduction to iron are consistent with a mixed control mechanism involving the interaction of gaseous diffusion effects with a first order reversible chemical reaction at the iron/wustite interface. Because of the larger pore sizes in the iron layers, ordinary molecular gaseous diffusion must be the principal transport mechanism. The usual experimental methods used for establishing the validity of chemical rate ~ontrol are incapable of differentiating between the mixed control- mechanism and exclusive chemical control.Some implications of mixed control kinetics are developed, including a predicted independence of rate on reducing gas pressure at higher pressures.INTRODUCTIONAn extensive literature review of the reduction of iron oxides has been compiled recently by Themelis and Gauvin (1962). From the large number of papers published and the widely divergent opinions of workers in this field, it appears that a simple unified quantitative analysis of reduction kinetics is not possible. The aim of the present paper is to show that a major cause of confusion is due to the attempts of many workers to interpret experimentally observed reaction rates in terms of a single rate controlling mechanism without due regard to other rate processes which must occur simultaneously.Some of the differences in behaviour reported for particles...

Jan 1, 1964

By W. H. Blackburn

This paper describing the milling practice at the Tybo concentrator is one of a series of similar papers being prepared by the United States Bureau of Mines on milling methods and costs at the various mills in the United States. ACKNOWLEDGMENT A large part of this paper way prepared by H. M. Lewers, mill superintendent of the Tybo plant of the Treadwell Yukon Co., Ltd.

Jan 1, 1931

By Shawna Munn, Carol Dounitch, Erika Acton

The EQ Bank Tower, a 24-storey office tower with 4 levels of underground parking, is currently under construction at 25 Ontario Street in the downtown core of Toronto, Canada. The tower geometry required an 18 m (60 ft) deep excavation inside an existing 3-storey 100-year-old façade, to be retained in place throughout construction. This presented a variety of design challenges that required several innovations and a customized monitoring program. In this paper, we will discuss two major challenges, and highlight the innovative and adaptable solutions carried out using performance-based design leveraging the observational method. The first was installation of a shoring system in a 500 mm (20 in) gap between the historical façade and a live gas main. The second involved excavating 10 m (33 ft) into expansive shale bedrock adjacent to a sensitive neighbouring building.

Oct 1, 2022

By J. R. Ross

Techniques for recovering scandium from uranium plant iron sludges and from wolframite concentrates are described. The best procedure found comprised (1) dissolution with sulfuric acid, (2) preliminary concentration by solvent extraction with a primary alkyl amine, (3) further enrichment and purification by a combination of ion exchange, solvent extraction, chemical precipitation, and calcination. Recovery of scandium from these raw materials, which contained 0.058 and 0.14 percent scandium, ranged from 83 to 90 percent in products analyzing 99.6 to 99.9 percent scandium oxide.

Jan 1, 1965

By T. J. Ballard

The Ore Knob mine, in Ashe County, N.C., was one of the largest producers of copper in the eastern states during the 1870's. The ore occurs in a fissure vein, which strikes N. 64° E. and dips nearly vertical. The country rock is granite gneiss. Drilling indicated that the vein structure is approximately 200 feet wide and 1,500 feet long. The vein material shows evidence of replacement of the original gneiss by sulfides. Solution cavities in the vein were noted in some places. The ore minerals and pyrrhotite, chalcopyrite, pyrite, and minor quantities of sphalerite. The gangue contains biotite, magnetite, albite, calcite, and many silicate minerals.

Jan 1, 1948

By Henry D. Hibbard

The finishing and casting temperature of steel is a subject concerning which there is so much to learn that some temerity is required to write about it. This paper is, therefore, suggestive rather than dogmatic, though the views expressed seem now to the writer to be correct; nevertheless, they may be modified by future developments or discoveries but until then may be of some utility, particularly to beginners in the making of steel. Consideration is limited to the temperatures of simple steels, also called carbon steels, which are those in which carbon is the only element introduced for the purpose of conferring desired physical properties. Alloy steels will receive attention later. Three things largely determine what a batch of steel really will be; via., composition, casting temperature, and rate of teeming. Each has its advocates as being the most important; but they are so interrelated that each must conform to or be right for the other two. When one is claimed to be the most essential to have right, that, probably, was the one that it was found had to be of a certain description, within narrow limits, to suit the already adopted variations of the other two; that is, it was the last of the three to be brought into line. The term "casting temperature" is rather indefinite as there ale several temperatures to which the term may be applied. Most writers who have mentioned casting temperature of steel have alluded to it in relative terms. The few who have given actual temperatures, including Langmuir, Burgess, Styri, and Bash, do not give full information about them. Their results demonstrate the efficiency of pyrometers used rather than aid the steelmaker. In order to understand and use the temperatures, one should know in each case what the steel was, the stage at which the temperature was taken, whether it was usual or not, and whether or not it was right for that steel at that stage. When these

Jan 1, 1925

By D. Harrington

"The fire boss in coal mining and the shift boss in metal mining, though held responsible to a large extent for safety of underground employees and of the mine, are, it seems to me, not always vested with sufficient authority nor given compensation commensurate with their duties. The metal-mine shift boss, although his position as regards his relations between employer and employee, is frequently an unenviable one, has as a rule much more authority than the fire boss and is not expected to perform the menial tasks required of the latter by many coal-mining companies.In most coal-mining States the coal-mine foreman and the fire boss are re¬quired to possess a certificate of competency obtained by passing an examination. The foreman is legally responsible for the safety of the miners, as in most instances the superintendent is not required to pass an examination. Although the foreman is held legally responsible for the safety of the miners, the law does not, in general, compel the superintendent or other higher officials to delegate sufficient authority to the foreman to enable him to put his wishes or judgment into effect; and this condition has tended in many instances towards perpetuation of unsafe conditions.The fire boss is held legally responsible for conditions in his ""beat"", but he is generally given only such authority as the mine foreman sees fit to delegate, frequently very little, Moreover, the fire boss is generally required to cover his ""beat"" within two hours before the entrance of the underground workers. Only too often his territory is so great that in order to reach all the working faces and chalk the required date at the face, he must travel at a rapid walk or even run. When such haste is necessary to cover the required ground, it is manifestly im¬possible for the fire boss to make a careful inspection or examination of the roof, timbering, wiring, gas, etc., at each place, and doubtless in his hurry many unsafe conditions escape his notice."

Sep 1, 1920

By T. R. Ellis

A number of important international events took place in 2001 in the development and evolution of mineral valuation standards internationally. In Canada, the CIMVal Committee released a draft discussion paper for public and industry comment on principles to guide the development of the planned Canadian mineral property valuation standard. The International Accounting Standards Board (IASB) received comments on its Extractive Industries Issues Paper. IASB will decide whether the financial statements of public mining and petroleum companies will be allowed to provide the value of mineral and petroleum assets on a current value basis instead of an historic cost basis. The author led the Extractive Industries Task Force of the International Valuation Standards Committee (IVSC) in developing its submission to IASB. IVSC intends to develop an extractive industries valuation section for its International Valuation Standards, which could support the planned IASB standard. In Australia, AusIMM has carried out an in-depth review of its highly regarded VALMIN Code. The AusIMM's MICA subdivision organized the VALMIN ‘01 Conference in Sydney, Australia, with a range of international and current issues papers published in the VALMIN ‘01 book. Considerable support for the IVSC initiative was evident at this conference. The results of the review of the extractive industries submissions to the IASB are expected to be released in early 2002. The CMMI Congress in Cairns, Australia in May 2002 is likely to prove to be an important forum for continued discussion of the development and implementation of international standards and qualifications for mineral valuation. The outcomes and implications of these events are discussed.

Jan 1, 2002

By Allan R. Punkkinen

Safe extraction of the valued ore resource in the deep levels of VALE Creighton Mine has progressed in a pillar-less fashion using vertical retreat, slot-slash and uppers retreat methods since the cessation of ?cut and fill? mining in the late 1980?s. Sequencing of the panel extraction and filling has been the key to successful exploitation of high stress orebodies at depth. In late 2010, discussions between the Operating Department and Creighton Ground Control revealed an opportunity to evaluate a trial primarysecondary sequence in the west end of the 400 Orebody at the 2340m horizon. To manage the trial primarysecondary project, a high level risk analysis and management of change was carried out to mitigate potential danger. As part of the requirements, an instrumentation project was conducted in the hanging wall and footwall bottomsills of the secondary panel and within the secondary panel itself. The extraction sequence was modeled with Map3D® software, confirming high stress levels with the advance of the primary panel. Enhanced ground support was installed based on modelling results. A key objective of the instrumentation project was to verify support system response to mining and to obtain knowledge in regards to the behavior of the stope. This paper describes the first time that this type of new innovative instrumented rockbolt technology had been used in a hard rock mining environment. Understanding of the physical deformation mechanisms of ground support in response to high stress conditions is the basis for an effective ground control strategy. The data played an important role in subsequent enhanced ground support system design at the mine and importantly, established the fact that the secondary pillar had not totally failed. Subsequent cavity monitor results helped establish that fact.

Jun 1, 2012

By Russell H. W. Chadwick

Reviewing events in the minerals industry, in economic geology, and in my own exploration work, I find that the most compelling subject for comment is the increasing ferment in ore deposits theory. New discoveries and continued investigations of bedded deposits of lead and zinc, copper, iron, uranium, etc., coupled with the availability of much new and significant data from sedimentary and metamorphic petrology, geochemistry, and oceanography, has led many economic geologists like myself to become disenchanted with former simplistic notions. Now disenchantment among serious people should presuppose both valid objections to the old, and valid new substitutes. I can sum up my own position and, I believe, what most of the recent writers on ore deposits theory are trying to tell us, by saying that a physico-chemical (bench science) approach to a natural science is neither correct nor useful, and that the obvious cure is a return to the study of the geology of ore deposits. More specifically, ore should be viewed merely as an unusual concentration produced, in stages, by the natural processes inherent in the geochemical cycle. In criticizing the conceptual basis of a science, one is involved simultaneously in the inherent character of the science, its subject matter, and the old and new concepts. I have found it impossible to make a clean separation along those lines. As a result, and as the title suggests, these are not-quite-random reflections on genesis, a matter near and dear to all true treasure hunters since Agricola.

Jan 1, 1967

By D. H. NETLAND

DURING the year 1907 an investigation of the Clinton formation in New York has been carried out under the direction of the State Geologist, and a full account of the results has been prepared for publication.1 The more important economic features of the report are summarized in the present paper. Previous knowledge of this, the type, section of the Clinton has been contributed mostly by Hall and Vanuxem in their reports for the Natural History Survey of New York, which were issued in their final form in 1842-43. Brief accounts of the ore-occurrences have been given by B. T. Putnam,2 J. C. Smock,3 A. H. Chester,4 and E. C. Eckel.5 Prof. C. H. Smyth, Jr.,6has discussed the origin of the Clinton ores in two papers, which, so far as the local occurrences are concerned, have removed all doubt that may have existed on that subject. Distribution of the Clinton Formation. The Clinton strata in New York State are restricted to a single belt, Which extends from the eastern central part to the Niagara river, which it crosses, and thence continues for some distance into the province of Ontario. The New York

Mar 1, 1909

By M. M. Tilman

The purpose of this investigation was to determine the effects of small amounts of cobalt in nickel on the tensile properties and hardness of representative types of austenitic stainless steels . Cobalt substitutions for nickel up to 2 weight - percent were made in types 302 and 309 stainless steels . Data were obtained at room temperature for tensile strength , yield strength , percentage elongation , percentage reduction in area , and hardness . In type 302 steels , tensile strength and hardness increased with increased percentages of cobalt , percentage elongation and reduction in area decreased , and yield strength showed little change . Property changes were largely due to the reduction of nickel content rather than to the addition of cobalt . In type 309 steels , only minor variations were observed for the properties investigated ; the effects of the relatively snall cobalt substitutions and nickel reductions were somewhat reduced by the higher total alloy content .

Jan 1, 1964

By S. D. Michaelson

Open pits and quarries are the major sources of all "hard rock" tonnage mined today. Normally, ore is fractured from the pit face by blasting and then truck-hauled to a primary crusher where pro- cessing begins; overburden (or waste) is generally truck-hauled from the pit to dump areas. Truck haulage of blasted ore and overburden accounts for some 25 to 50% of total mining costs in a typical open pit and commonly is the largest single cost factor. Obviously then, cost reduction efforts should properly focus on improving existing haulage systems and developing new breakthrough techniques for material transport. Continuous flow systems for large tonnages ordinarily will result in a lower cost than batch systems such as truck or rail haulage. Continuous flow with pipelines for liquids and slurries, or conveyors for medium to coarse dry materials (in the -8-in. range) are the economic answers for bulk materials handling over reasonable distances.

Jan 11, 1968

By F. S. Kendorski

This report presents the results of a program to improve, using existing and proven technology, unstable highwall conditions through better blasting practices in Appalachian strip coal mines. Better borehole blasting agent distribution and optimization of burden, spacing, and delay periods allowing satisfactory breakage with minimal backbreak were the objectives. At a selected field site, geologic conditions were closely examined with regard to joint orientation and spacing, and resulting slope stability considerations. A test series of eight blasts was completed and the resultant highwall monitored by repetitive photography. The study of drilling and blasting economics along with equipment performance led to an economic model of blast parameters and the identification of blast design cost benefits. The work demonstrated that small strip mining companies' are able to achieve a more stable highwall excavation utilizing presently available technology, equipment, and explosive products at improved operational cost and safety.

Jan 1, 1981

By J. Jeremy Burden, Bruce S. Brown

A major question in the design and permitting of a tailings storage facility is the quality and quantity of seepage which will occur from the base of the tailings facility into the underlying foundation and groundwater regime. A corollary to this is what liner system, if any, is necessary to protect the groundwater regime from unacceptable contamination. Modern tailings storage facilities are generally designed as drained tailings deposits whereby all free water is removed from the facility by decant, drainage and evaporation. This removes the source of on­going seepage and allows for efficient and timely reclamation of the facilities. Quantifying the residual seepage from the base of the tailings deposit is complicated due to the following factors:

Jan 1, 1992

By Robinson T

The paper describes a spreadsheet system that enables selection of projects and companies that meet the user's corporate exploration and/or acquisition philosophy. A regularly maintained commercially available database has been used as the basis for this system. It provides an easily accessible efficient com- prehensive search method. The technique enables ranking by various criteria, both technical and financial, to provide groups of projects/companies that are of interest. Initially, target size parameters such as reserves, production and mine life are applied together with geological criteria such as age and deposit type; the significance of the targets in the context of the Australian gold industry is addressed.

Jan 1, 1988

By Dave H. Barnett, Brij M. Moudgil

The flotation technique as employed by Florida phosphate producing companies for the beneficiation of fine phosphate particles has been standardized over the years. Lower recoveries of coarse Phosphate rock by froth flotation technique, however, led to the development of new methods based on skin flotation of phosphate agglomerates. Recent developments of floating coarse rock in large flotation machines have not yet convinced the rock Producers of their higher separation efficiency. It is interesting to note that the selection of a particular machine is still bared on equipment preference by an individual company as well as proven performance of a particular machine for upgrading a specific material. Various techniques which have been developed to beneficiate the coarse phosphate rock have been discussed. Performance of the individual techniques is presented.

Jan 3, 1979

By Dave H. Barnett, Brij M. Moudgil

The flotation technique as employed by Florida phosphate producing companies for the beneficiation of fine phosphate particles has been standardized over the years. Lower recoveries of coarse phosphate rock by froth flotation technique, however, led to the development of new methods based on skin flotation of phosphate agglomerates. Recent developments of floating coarse rock in large flotation machines have not yet convinced the rock producers of their higher separation efficiency. It is interesting to note that the selection of a particular machine is still based on equipment preference by an individual company as well as proven performance of a particular machine for upgrading a specific material. Various techniques which have been developed to beneficiate the coarse phosphate rock have been discussed. Performance of the individual techniques is presented.

Jan 1, 1980

By Morrison R

Optimisation has two distinct applications in the concentrator ò the first is in the area of the flowsheet and the operating parameters of the various unit operations ò the second is associated with the higher levels of process control. The Plant Metallurgist is faced with a library of complex theories relating to optimisation. The practical reality of optimisation lies in a combination of steady state simulation to ensure that the process route will permit maximum productivity and an appropriate process control system which will permit achievement of the production and quality objectives.

Jan 1, 1991