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By AIME AIME

REGISTRATION and licensing of engineers is now being given consideration by a special committee of the Institute, authorized at the March meeting of the Board of Directors. The subject is one that has recently been or is now actively before engineering organizations in many of the States of the Union. In Washington, D. C., the Washington Society of Engineers and the local sections of ten national engineering societies, including the A.I.M.E., recently had a joint committee investigate the subject: this committee formulating a proposed law that has been presented to Washington engineers for their consideration. At the same time, the committee has summarized the reasons for and against registration of engineers in Washington, D. C. As many of these reasons are of more than local application, they are here reprinted so that all members of the A.I.M.E. may be informed on the subject. It is expected that some report of the Institute's Committee on Registration, State Councils and Professional Development will he made at some forthcoming meeting of the Board of Directors.

Jan 1, 1932

By Robert E. Wallhagen

This report describes the results of a four year investigation into improved face ventilation systems for underground coal mines. The objective was to experimentally determine configurations for a diffuser fan system and a water spray (spray fan) system which will provide a maximum reduction in face methane concentrations without causing an increase in methane concentrations at the operator's position. The experimental evaluation was performed in full scale mock-up mine entries, simulating continuous mining operations in both a six foot and four foot coal seam complete with normal ventilation, water sprays, and methane emission. A limited study was also performed to assess the effect of scrubber discharge location on methane concentrations in the face area. The results indicated that diffuser fan and spray fan systems that were designed to augment the natural airflow pattern in the entry could provide a factor of 3 to 5 reduction in average methane concentration at the face, compared to a mining machine with just conventional water sprays. The properly designed diffuser and spray fan systems also significantly reduced the total methane present in the entry. A properly designed dust scrubber discharge can reduce face methane levels by a factor of two.

Jan 1, 1977

By M. Hardy

"The structural design of mine headframes is challenging due to the significant differences in the geometry, rigidity, and behaviour of these structures compared to conventional buildings. The differences are related to the main purpose of these structures, which is not human occupancy, but rather the support of hoisting equipment. The main objective of this paper is to present the seismic elastic behaviour of headframe structures in comparison with conventional buildings, which is the base case for the definition of seismic loads. This paper highlights the impact of backlegs on the dynamic behaviour of mine headframes, more specifically the resulting torsional sensitivity. INTRODUCTION The design of industrial structures is often governed by industrial processes rather than by architectural constraints. In ground-mounted hoisting plants, the structural configuration of headframes must allow clearances around conveyances and ropes while resisting the lateral loads associated with the hoisting equipment. Typically, these structures use backlegs to withstand the lateral loads, which leads to highly irregular structures with unconventional dynamic behaviour. The codes and standards applicable to the structural design of mine headframes in Canada are often incomplete or not adapted to the reality of practising engineers. This situation creates confusion, and engineers must look at various guidelines and international standards to support the engineering calculations required for the design of these structures. The loads resulting from the support of hoisting equipment, such as ropes and conveyances, are usually simple to calculate and are determined based on the information from manufacturer and industry related guidelines. Moreover, the loads associated with snow accumulation and wind are calculated applying the same methodology used for conventional buildings, without any major issues. On the other hand, the seismic loads are often difficult to calculate based on the methodology from the National Building Code of Canada due to the significant differences in the dynamic behaviour of the structures. The resulting structures may be either over-designed or worse, under-designed. Hence, there is a lack of uniformity in engineers’ designs. The latest edition of CSA S16-14 “Design of steel structures” includes Annex M (Informative) “Seismic design of industrial steel structures” to help designers close the gap between the requirements of traditional regulations and actual engineering practice."

Jan 1, 2019

By Robert H. Richards

In the latter part of December a batch of amalgam was retorted and the tin in the retort uncovered while at a low red heat, and allowed to cool slowly to a temperature more suitable for ladling into moulds. It was then ladled and made what appeared to be nice, white, malleable block tin. On February 15th our attention is called to the fact that the tin is brittle, and on examination we find that the molecular condition of the pigs has changed to the extent of one-half its material. The change shows itself by an enlargement appearing on the surface something like crystallization, and comes in spots. The condition of the metal in these spots is very peculiar. It has changed from a malleable metal to a brittle one, with a structure somewhat resembling stibnite, and a color very considerably darker gray than tin. The analyses of the two parts of this tin pig showed the following results: Mercury. Tin. Specific Gravity. Crystalline part,.....2.62 97.24 6.175 Malleable part,.....2.38 97.50 7.387

Jan 1, 1883

By Cody Burcher-Jones

The recovery of rare earth elements (REEs) through heap leach/in situ techniques from so-called ion adsorption clays (IACs) is attractive due to their inherent simplicity. However, the underlying mechanisms of these processes are poorly understood. In this study, the deportment of REEs in a typical IAC material has been investigated and was found to concentrate in the phyllo-layers of the clays, especially hallyosite, and was readily desorbed by various ion-exchange reagents indicating various potential routes to liberate them. Here we are reporting the use of seawater (0.5 M NaCl), spiked with various amounts of (NH4)2SO4, and found better extraction using a reagent mixture than NaCl on its own. Further, the leaching of REEs from a bed of clay material was investigated over time to understand the rate of transport through the stagnant material. Results indicate that REE release is likely to be controlled by diffusion through the clay material, while desorption in agitated systems is rapid. A degree of fractionation between different REEs can be observed during diffusion. Nonetheless, the successful operation of in situ leach operations for this type of material would depend primarily on how easily solution cocktails can be made to flow through the bed material.

By Henry W. Brandt

What is the most practical method for storing a huge quantity of crude oil for a long period of time to assure availability if conditions curtail the source of supply? Underground storage is a logical answer. But can abandoned mines be used for this purpose? That is the proposal Fenix & Scisson International, Inc. submitted to the S.F.F. Association (acting in behalf of the Department of Industries of the Republic of South Africa), Johannesburg, South Africa, in October 1966. This engineering and contracting firm with headquarters in Tulsa, Oklahoma, specializes in underground storage; and based upon previous experiences their engineers were reasonably certain that a mine could be used for storing crude oil. The answer subsequently proved to be "yes." The result was con- version of a coal mine to provide storage for a quantity of crude oil which is the equivalent of a sizeable oil field. The total cost of purchasing, testing, and converting the mine was less than 15 percent of the cost of conventional steel tanks. Operating and maintenance costs are proving to be about 2 percent of those experienced at two large tank farms owned and operated by the Association.

Jan 1, 1973

By D. P. Roberts

This paper reviews the use of crush pillars on mines in the Bushveld Complex and the Witwatersrand Supergroup. Stress measurements were undertaken in order to determine the residual strength of these crush pillars. The results from these stress measurements are compared with previous attempts to determine the residual strength of crush pillars using back analysis. It is concluded that the residual strength of such crush pillars lies in a band between 13 MPa and 25MPa. Using the data from the stress measurements, as well as published and unpublished data, a stress-strain curve for a crush pillar with a width-to-height ratio of 2:1 is proposed. Where further work is required, this is indicated in the text.

Jan 1, 2005

By L. Heber Cole

In making this plea for a better and more sympathetic understanding of the non-metallic industry, I do not for one minute wish to give the impression that I in any way belittle the wonderful strides that have been made in the exploitation of our metallics. We in Canada can be justly proud of our Sudburys, Norandas, Flin Fions, and of the remarkable growth of the Consolidated in British Columbia, and at the same time, without in the !east detracting from these worthy undertakings, be equally as proud of our asbestos, gypsum, salt, and coal deposits, as well as of our building-stone and limestone industries. If, in my remarks, I have occasion to compare the metallic with the non-metallic industry, I do so, not with any idea of dimming the glory which the metallics of Canada have gained- not only in our own country, but in the world at large-but for the purpose? of bringing to your attention the fact, perhaps not very well recognized, that Canada contains deposits of non-metallics well worth y of your serious consideration. In the past 33 years, namely, since 1895, the value of non-metallics produced in Canada has exceeded the value of metallics in 19 of the years, and for the last three years has been increasing rapidly. The war years (1915-1918 inclusive) naturally saw an intensive metallic production, but since that time, with the exception of 1925, when there was a general depression throughout the whole country, the non-metallics have been in the ascendency.

Jan 1, 1929

By George F. McIntyre

The subject of this paper is mineral processing chemicals - how they work and where they end up environmentally. First of all, it is necessary to recognize that water is the most universally and widely used chemical used by the mining industry to separate desirable minerals from unwanted wastes, sands, and slimes. Of the total world's water supply, over 97 percent is found in the oceans. Another two percent is tied up in the ice caps, leaving roughly only one percent for us to work with. This one percent is distributed either as ground or surface water and makes up the bulk of all water used industrially. Even with such a small proportion available for immediate use, there appears to be enough fresh water to meet our needs for at least another hundred years. This availability, however, depends heavily on how we handle our waste waters, how we process them, and how we plan for their reuse. Certain governmental agencies have been charged with the task of setting up standards of water quality which must be met prior to environmental discharge. There is even discussion of zero discharge from industrial operations. Due to limited supply and availability, the mining industry has always been forced to reuse its process water or to treat it prior to discharge. Consequently, we are in an enviable position and are presently able to live with the environmentalists demands. To stay on top of the situation, it is necessary to continually concern ourselves with the .effects of changing orebodies and reagents on the final mill effluent. From a process standpoint, it is also important to recognize the impurities of plant recycle water and how they might tend to influence overall operations

Jan 1, 1974

By Y. Maeda

Non-ferrous smelting furnaces generally lnstal1 a gas cooling system for treatment of waste gas containing S02. From the point of view of corrosion resistance and recovery of waste heat, the high pressure boiler system Is the best way to cool gas, however this system requires high Initial investment and relatively higher operating costs. Because the feasibility of this boiler system greatly depends on the smelting process and scale, other lower temperature systems, e.g. water-cooled Jacket system, are more suitable If the smelting process does not produce enough steam nor generate enough electricity to compensate operating cost. In addition, the water-cooled Jacket system Is simple in structure and easy to operate. For those reasons, it is applied widely. A new smelting furnace. was planned tin our factory and It was necessary to install waste gas cooling equipment. In our case, a water-cooled Jacket system was mo11e feasible because of the low gas volume and high dust content. H was also expected to operate without maintenance for ten years. On the other hand, some leakage problems with the water-cool1ed Jacket had been experienced In the past. That is because S02 in the waste gas changed into sulfuric acid which corroded the Jacket material, As the first step, several data from actual usage were reviewed to throw light on the corrosion process, and an appropriate procedure to determine the operating temperature of cooling water was obtained. For the basis of this study, a water-cooled Jacket system was newly designed and tested for three months in a pilot plant. After this system's performance was confirmed, It was installed In a new furnace as a commercial pl.ant. After one year of operation, the initial thickness of carbon steel Jacket remains almost the same.

Jan 1, 1992

By Raimo Vuolio

"Over the past 30 years, the Nordic countries have developed similar practices for estimating damage caused by rock blasting vibrations. However, over the last few years the risk of damage has sometimes been estimated by using international values, which have created unnecessary costs, since they are too conservative. This paper gives a proposal for Finnish blast vibration standards and a calculation model for the extent of the zones for building inspection, risk analysis, and vibration measurements. The international conclusion is that particle velocity is the best descriptor for limiting damage potential for structures. Over 900 000 vibration data recordings from 52971 blasts were collected for this paper during 1970-1989. They show that the most practical description is the vertical component of the peak particle velocity. As rock is a nonhomogeneous medium, it is hard to predict the need and scope of risk analyses, building inspection, and vibration measurements. As a large number of blasts were monitored for the recording of the peak particle velocity in several locations in Finland, and the data combined, it is possible to establish safe scaled distances for the calculation of the need and scope of risk analyses, building inspections, and vibration measurements."

Jan 1, 1991

By Paul A. Taylor

MUCH information concerning pegmatites which was thought to be true a few years ago has been proved false, and what is now actually known about some pegmatites is not true of many others. The erratic and seemingly unpredictable structure and variable composition of this class of mineral deposits has been widely emphasized. Even parts of the same pegmatite body exhibit marked differences in texture, mineral composition, width, and attitude. Constructive geological thinking in respect to pegmatites now aims to establish general laws rather than to stress the confusing diversity of features having no special economic significance. Substantial progress has been made in classifying different types of these deposits according to general features, internal structure, mineralogy, and origin. In some cases it has even been possible to block out tonnage reserves in advance of mining. It is still easy, however, to make highly erroneous predictions after a preliminary examination of a pegmatite prospect. Pegmatites are important to the economic well being of the country and to its military security. They furnish virtually all the feldspar, strategic mica, beryl, columbium, tantalum, and caesium utilized in the United States, as well as sundry other minerals and significant amounts of lithium and rare earth minerals and gems. With the exception of vermiculite, occasional ilmenite-rutile, and perhaps soda-lime feldspar and garnet deposits, basic pegmatites are of little economic importance. Consequently in this paper, as in common parlance, the term pegmatite generally relates to coarsegrained acidic rocks or what is aptly called giant granite. Available data indicating the size and importance of the production and trade in specified pegmatite minerals are summarized in Table I. Geological Features Much of the latest thinking on the economic geology of pegmatites is now available in a 115-page monograph' by a group of experts who participated with geologists of the Federal Geological Survey in the widespread wartime investigations. Doubtless the most significant feature of the monograph is indicated by the title, The Internal Structure of Pegmatites, but it also contains a vast amount of other new information and includes the assimilated concepts of many earlier writers, whose works are given in a comprehensive list of references. The shape, size, attitude, and continuity of many pegmatite bodies is controlled by the structure of the older rocks in which they occur. If the older rocks are easily penetrated, e.g., biotite schist, most of the pegmatites in a given district will be found outside the parent granite mass as exterior pegmatites. Marginal pegmatites are more prevalent if the older rocks are massive, unsheared, and sparingly jointed. Networks of pegmatites are abundant in highly-jointed rocks. In strongly foliated schists the bodies are usually lenticular, whereas in highly-folded areas they assume tear drop, pipe or pod-like, bow-shaped, or sinuous forms. Jahns2 recognizes five major shape classes: l—dikes, sills, pipes, and elongate pods; 2— dikes, sills, pipes, and pods with bends, protuberances, or other irregularities; 3-—trough-or scoop-shaped bodies with or without complicating branches; 4—bodies with the form of an inverted trough or scoop; and 5—other bodies, including combinations of the above and miscellaneous shapes. Many pegmatite deposits are scarcely big enough to be recognizable as such. Most of them, in fact, are small tabular deposits less than 4 in. wide and usually without economic concentrations of minerals. On the other hand, some pegmatites are more than a mile long and over 500 ft wide. The ratios of length to breadth range from 1 : 1 to 1 : 100. Although the vertical dimension bears no invariable relationship to strike length, tabular deposits or large lenses are often symmetrical enough to show nearly as much continuity down dip as in their horizontal extension, and some pipes or pods are amazingly persistent in the vertical plane. Small pegmatites often string along a fairly definite trend line; in a given district major bodies may lie roughly parallel, and where only a few of them do not, the erratically disposed bodies generally differ in composition from those conforming to the regular pattern. This does not apply, however, in all districts. Characteristically, pegmatite veins pinch and swell or split into branches. When they pinch out entirely it is often possible to find a new body by prospecting the extension of the strike or dip, but the chances of finding a hidden deposit are ordinarily too uncertain to justify much subsurface prospecting. Diamond drilling may yield valuable information as to the continuity of known deposits whose upper portions are well-exposed. Some deposits, in fact, can be proved up for hundreds of feet by surface trenching and then intersected by drill holes at various depths like any other vein-like deposit. Others twist and branch, apparently defying all efforts to explore them short of actual mining.

Jan 1, 1954

By A. W. Gauger

IT is with some trepidation that I approach my subject, for I know that I shall at once incur the suspicion of the mechanical engineer, with his concern for boiler tests and efficiencies; of the mining engineer, with his mechanization problems; and of the chemical engineer with his unit processes. Nevertheless, it must be recognized that the technology of fuels, the systematic body of knowledge relating to the production, processing and utilization of mineral fuels, has grown to such proportions and involves so many widely diverse applications of fundamental science and engineering that it behooves us to stop and consider just what its status is in relation to other technologies, as well as in relation to the present and future needs of the social order. The time has come when technologists, applied scientists and engineers must consider the possible effects that their achievements may have 0n Society. The development of a machine to replace several hundred men is a fine achievement when considered solely from the point of view of creative endeavor. But what of the men who are displaced by the machine! Does not the responsibility for the development of this machine embrace as well the consequences of obsolescence and technological unemployment resulting from such development? I believe that it does and that we must recognize this fact in our practice of engineering and technology as well as in the training of future engineers and technologists. MAGNITUDE OF THE FUELS INDUSTRY Fuel technology is the body of knowledge that relates to the mineral fuels. The fuels industry is by far the most important of all our mineral industries. The chart in Fig. I, reprinted from U. S. Bureau of Mines Information Circular No. 6643, indicates the comparative values of metals, fuels and other nonmetallic minerals for the year 1929. Of the grand total of 13 1/4 billions of dollars in value of minerals at the mines, the mineral fuels contributed 48 per cent. Coal, with 34.4 per cent, exceeded the value of any other single mineral. In fact, the value of the production of the Pennsylvania anthracite mines alone annually exceeds the value of the gold production of the entire world. Petroleum and natural gas in 1020 contributed 14.3 per cent and 3.3 per cent, respectively, of the total value of world mineral production. So much for the world picture; let us now look at the situation in the United States. Over the 60-year period 1880 to 1939, $46,409,727,000 of metallic products, S80,788,852,000 of fuels (coal, petroleum, natural gas, natural gasoline) and $27,871,000,000 of nonmetallic minerals other than fuels were produced. The mineral fuels have contributed 52.7 per cent of the entire mineral wealth produced over this period that has seen such tremendous industrial development in our country. As a matter of fact, our present industrial civilization has been made possible through the use of the

Jan 1, 1942

By Ann Lamontagne

Le parc à résidus de l?ancienne mine Dunraine contient des résidus générateurs de drainage minier acide. Le concept proposé pour la restauration du site est d?utiliser le fort potentiel alcalin des boues rouges, résidus d?aluminerie, afin de neutraliser les résidus miniers. En appliquant une certaine quantité de boues rouges à la surface du parc, on provoquera une neutralisation de l?acidité. De plus, les alcalis contenus dans les boues rouges vont provoquer la précipitation de minéraux stables (sulfates tel la jarosite). La précipitation de ces minéraux provoquera la formation d?une couche indurée qui rendra difficile la circulation de l?oxygène et de l?eau. Bien que ce concept ait été vérifié en laboratoire, ce sont là des hypothèses qui restent à vérifier dans des conditions réelles d?exposition. Les principales questions soulevées par l?utilisation des boues rouges, mis à part le contexte géochimique, est le contexte technico-économique. En effet, le transport de quantité importante d?un matériel argileux humide présente un défi économique important. Outre le défi économique, la manipulation et l?épandage de ce produit sur des parcs à résidus constituent également un défi important. Cet article présente les conclusions d?une étude technique sur le transport, la manutention et l?épandage de boues rouges sur un parc à résidus situés en Abitibi : le site de Dunraine.

Nov 1, 2002

By Bert Taylor

"The Mining concessions of Quemont Mining Corporation, Limited, are located at 48°16'N latitude, 79°00'W longitude, in Rouyn township, northwestern Quebec. Six hundred and forty acres in area, they lie directly north of, and contiguous to, the Horne mine of Noranda Mines Limited. The north arm of Osisko Lake covers a large area of the southern part of the property. The orebodies lie below the Jake with one body extending through to the bedrock surface.The property was staked in 1922, and was originally known as the Murray Claims. The group attracted interest from numerous exploration companies because of the proximity of the Noranda orebodies.The United Verde Extension Company, of Arizona, optioned the claims in 1926. They sank a shaft to a depth of 235 feet, at a short distance from the Noranda boundary. From a level established at a depth of 215 feet they completed 3000 feet of exploratory driving from which 6000 feet of diamond drilling was done. Only a small body of siliceous gold ore was found before they dropped their ·option.In 1928, The Mining Corporation of Canada purchased a 90 per cent interest in the property. An operating company, later named Quemont Mining Corporation, was formed. An electrical survey was carried out on a portion of the property, followed by deepening of the shaft to 922 feet. Levels were established at 500 and 900 feet, and 4,800 feet of driving and more than 3000 feet of diamond drilling were carried out from them.Geological knowledge at that time recognized that a major break, the Horne Creek fault, lay not far inside the south boundary. Striking north 80 degrees east, the fault dipped south at 85 degrees. The rock on the north side of the fault was massive rhyolite; to the south, meta-diabase and a little rhyolite. A left-handed movement was indicated by a 600-foot offset on a north striking diabase dyke. The small body of siliceous gold ore, referred to previously, was confined to the 215 level."

Jan 1, 1949

By T. W. Lippert

CUBA fancies herself the "pearl of the Antilles" and, by many, Jamaica is called "blessed." But far to the southward lies what is seemingly the Caribbean's most glittering jewel, the sparsely-settled, Spanish-speaking United States of Venezuela, indeed blessed by nature to a lavish degree. Not a large country, Venezuela is leaping from the donkey to the airplane under the impact of its natural wonders. Angel Falls, dwarfing Niagara and seldom seen by man, is hidden in the cold, primitive and unexplored Guiana highlands along the southeast border. A few hundred miles northwest are the low and torrid coastal plains from which gush unlimited black-gold streams of oil. About midway are the Llanos-low-lying, savanna-type grasslands, beneath which large deposits of bauxite are as yet barely touched by the explorer's diamond drill. And jutting starkly upward 2000 ft from a surrounding expanse of savanna is a small mountain (see front cover), 11 miles long and 1 mile wide. It is, or was, La Parida.

Jan 2, 1950

By Joël Kapusta

La pyrométallurgie du cuivre est essentiellement une chaîne de trois étapes successives d’oxydation préférentielle du fer et du soufre et des impuretés moins nobles que le cuivre qui sont contenues dans le concentré de cuivre issu de l’usine de concentration du minerai, aussi appelée concentrateur. La Figure 1 illustre la chaîne complète d’élaboration du cuivre depuis la mine jusqu’au cuivre pur. La voie hydrométallurgique traite le concentré par lixiviation, c.à.d. par dissolution en phase aqueuse à température typiquement inférieure à 100 ou 150⁰C, alors que la voie pyrométallurgique traite le concentré par fusion à température de l’ordre de 1200 à 1300⁰C.

May 2, 2024

By A. S. Gendron

A brief description of Inco's ORC copper refinery tankhouse and the electrowinning tankhouse is followed by a comparison of the requirements for the production of the high-quality copper in both systems. The description will focus on both tankhouses, with emphasis on experience to date in the electrowinning tankhouse. Particular attention will be paid to sensitivities of each tankhouse to process upsets which can. significantly afject the quality of the product cathodes.

Jan 1, 1977

By A. A. Burr, D. Caplan

IN carrying out experiments in metal-gas systems, it is often difficult to estimate how long a reaction period must be allowed for equilibration. This is especially true in systems for which the diffusion coefficient is not known. In an investigation of the Cr-O system, the necessary information was obtained in the way described subsequently. Two pieces of chromium sheet of different thicknesses were packed in mixed powders of chromium and Cr2O3 and sealed into an evacuated metal capsule by welding. Austenitic stainless steel proved suitable as a capsule material up to 1350°C and molybdenum at higher temperatures. The capsule then was heated at a specific temperature for a time sufficient to saturate with oxygen the thinner but not the thicker specimen. The time is readily estimated from a preliminary experiment if a sufficient thickness differential is chosen. Under these experimental conditions, the metal sheet is exposed to a partial pressure of oxygen equal to that of the dissociation pressure of the oxide and hence can become saturated with oxygen without developing any second phase. After cooling, both samples were analyzed for oxygen by the vacuum fusion technique. Assuming that the surface of the specimens is kept saturated with oxygen throughout the experiment, the diffusivity can be calculated by application of the appropriate solution to Fick's second law. This is most conveniently accomplished by use of a plot of mean fractional saturation (Cm-Co) / (Cs-Co) vs (Dt) ½/L as given by Darken,' where t is time, L the half-thickness of the sheet, and D the diffusion coefficient. Cm, the mean concentration at time t, is given by the oxygen percentage in the thicker specimen; Cs, the constant surface concentration, is the oxygen percentage in the thinner specimen; Co is the oxygen content of the original chromium sheet. (Cm-Co) / (Cs-Co) is calculated and the corresponding (Dt) ½/L is read from the graph and D thereby calculated. By performing the experiment at two temperatures and plotting log D vs 1/T, the D for any temperature is established. (The activation energy for diffusion may be obtained from the slope of the line.) Once D is known as a function of temperature, it is a simple matter to estimate the correct reaction time for experiments with single specimens at other temperatures by equating (Dt) ½/L to its value for effective saturation. Darken' points out that this is approximately unity. The solubility of oxygen in chromium, as determined from the thin samples at each temperature, proved to be approximately 0.03 pct at 1350°C and less at lower temperatures. Due to low solubility and to the known difficulties of the vacuum fusion method in this low range, the values obtained for D (5x10-0 sq cm per sec at 1350°C) are estimated to be correct only within an order of magnitude. Nevertheless, the method has proved useful in estimating reaction times. Its usefulness will be greater in metal-gas systems where the solubility is appreciable. A second function of the method is to permit the determination of diffusion coefficients in systems for which the conventional techniques are experimentally difficult or impossible.

Jan 1, 1956

By F. D. Ayhan

The aim of this study was to investigate desulfurization and de-ashing of a mixture of subbituminous coal and gangue minerals by the agglomeration method. For this purpose, experimental studies were conducted on a mixture containing subbituminous coal, pyrite, quartz and calcite. The effects of some parameters that markedly influence the effectiveness of selective oil agglomeration, such as solid concentration, pH, bridging liquid type and concentration, and depressant type and amount, were investigated. Agglomeration results showed that the usage of various depressants (Na2SiO3, FeCI3, corn starch, wheat starch) in the agglomeration medium has a positive effect on the reduction of ash and total sulfur content of agglomerates. It was found that an agglomerate product containing 3.03% total sulfur and 25.01% ash with a total sulfur reduction of 56.71% was obtained from a feed that contained 7% total sulfur and 43.58% ash when FeCI3 was used in the agglomeration medium. Key words: Desulfurization, De-ashing, Agglomeration, Coal, Gangue minerals

Jan 1, 2009