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By R. W. Vander Laan

Conneaut has a long and illustrious history as a major Great Lakes port for coal and iron ore. The first dock was built in 1892 for unloading iron ore from the Mesabi Range for shipment to the Pittsburgh steel mills via the Shenango & Lake Erie Railroad, later to become the Bessemer & Lake Erie Railroad. The Pittsburgh & Conneaut Dock Company was incorporated in 1893. The world's first Hulett automatic ore unloader was constructed at Conneaut in 1899. Steam operated, it was the model for the giant electric Huletts used today, named after its inventor, George Hulett, who was a Conneaut resident.

Jan 3, 1974

By H. E. Nold

High-volatile coals are most desirable for kiln firing. Low-volatile and even anthracite coals can be used successfully. Most periodic kilns use coal and are hand fired. A few stoker installations have been economically successful. Continuous tunnel kilns reduce fuel consumption 40 to 55 per cent. They are rapidly replacing periodic kilns in the manufacture of the finer wares. They have found great favor in the refractory industry and are successfully used in firing almost all kinds of heavy clay products. Fuel oil has found rather wide application in the Southwest and West. Natural gas is a satisfactory fuel for kiln firing. It is the principal competitor of coal and has largely replaced it for firing the finer wares but cannot compete with it in firing heavy clay products except in regions where cheap gas is available. Figures are given showing the relative thermal efficiency of coal and natural gas as used for firing ceramic ware. The ceramic industry uses from 12,000,000 to 12,500,-000 tons of coal per normal year. The principal use of coal is in firing the heavy clay products. This potential market amounts to about 9,250,000 tons per year. Coal producers could increase sales by furnishing expert firing instruction.

Jan 1, 1934

By D. I. Nicol

An assessment is made of the possible scope for the use of activated charcoal as the solid adsorbent in an upflow fluidized-bed contactor, and a pilot-plant programme for the recovery of low concentrations of dissolved gold in this contactor is described. It was found possible to produce an effluent that contains less than 0,01 p.p.m. of dissolved gold.

Jan 1, 1997

By H. L. Sheakley, D. J. Coolidge

This paper does not deal with all sands used in the glass industry in Missouri; it covers only that used in the plate-glass factory at Crystal City. However, it is probably safe to say that other sands, pro- duced throughout the state for this purpose, are of identical nature. The glass sand used in Missouri is cornrnonly called the St. Peter deposit, which is ascribed to the Ordovician Rock series in the form of sandstone. This St. Peter deposit, aside from a few small outliers, covers a large area of eastern Missouri. It forms, through a broad curve, the northeast margin of the typical Ozark region between Cape Girardeau on the southeast and Mineola, Montgomery County, on the northwest. The belt is extremely irregular, varying from one to ten miles in width; its length is 150 miles in a straight line. The outcrop near the entrance to the Crystal City mine appears in the form of a sandstone bluff approximately 30 ft. high, running along Plattin Creek (Fig. I). Above the sand rock an overburden of Joachim limestone appears, which thickens to nearly 300 ft. and forms the hill commonly called Buck Knob. Test holes where drilled at various points and the drillers' log indicate that the St. Peter deposit ranges in thickness from 63 to 71 feet. Properties of the St. Peter Sand From an analysis of the glass sands of the St. Peter formation in Missouri, the follow-

Jan 1, 1948

By D. J. Coolidge, H. L. Sheakley

This paper does not deal with all sands used in the glass industry in Missouri; it covers only that used in the plate-glass factory at Crystal City. However, it is probably safe to say that other sands, pro- duced throughout the state for this purpose, are of identical nature. The glass sand used in Missouri is cornrnonly called the St. Peter deposit, which is ascribed to the Ordovician Rock series in the form of sandstone. This St. Peter deposit, aside from a few small outliers, covers a large area of eastern Missouri. It forms, through a broad curve, the northeast margin of the typical Ozark region between Cape Girardeau on the southeast and Mineola, Montgomery County, on the northwest. The belt is extremely irregular, varying from one to ten miles in width; its length is 150 miles in a straight line. The outcrop near the entrance to the Crystal City mine appears in the form of a sandstone bluff approximately 30 ft. high, running along Plattin Creek (Fig. I). Above the sand rock an overburden of Joachim limestone appears, which thickens to nearly 300 ft. and forms the hill commonly called Buck Knob. Test holes where drilled at various points and the drillers' log indicate that the St. Peter deposit ranges in thickness from 63 to 71 feet. Properties of the St. Peter Sand From an analysis of the glass sands of the St. Peter formation in Missouri, the follow-

Jan 1, 1948

By John W. Vanderwilt

The fluorescence of scheelite has been an important aid in recent years in the discovery and development of scheelite deposits. The use of fluorescence of synthetic compounds in industry, particularly in advertising, also has expanded greatly during the past decade. As a result, a number of new and convenient units for producing ultraviolet energy have become available, which have led to a greater application of fluorescence in the study of minerals. Studies have shown that the fluorescent color of a mineral may vary: (I) with the kind and quantity of trace elements, and (2) with the particular wave length of ultraviolet energy used. The wave length is dependent first on the type of generating equipment used, and finally on the filter employed to remove the visible light that may be present. A number of so-called ultraviolet lamps are listed and described, together with suitable filters known to be available. Scheelite fluoresces brilliantly with wave lengths of 2200 to about 3000Å., but not with longer wave lengths. The most convenient and efficient sources of ultraviolet for scheelite fluorescence are portable and laboratory units designed particularly for use with scheelite. So-called ultraviolet light globes of the photo-flood type emit wave lengths too long to cause scheelite to fluoresce. Attention is called to the minerals that fluoresce in a manner similar to scheelite, which necessitates a check test by means of characteristic physical properties. Chemical tests are the final authority both for identity and content of tungsten in scheelite ore. Introduction Recent development and extensive use of fluorescent lighting make it unnecessary to explain what fluorescence looks like. The fluorescent light tube is in reality a mercury vapor arc, which generates ultraviolet energy. Coating the inside walls of the tube is a substance, called a phosphor, that converts the ultraviolet rays to visible rays of light. In a like manner, certain minerals will transform ultraviolet energy to visible rays of various colors. The phenomenon of brilliant fluorescent colors cannot be satisfactorily described or reproduced photographically; a display must be seen to be appreciated. Only a few years ago fluorescence was regarded primarily as a source of entertainment, chiefly in spectacular displays of specimens in museums. The brilliant fluorescence of willemite, a zinc ore mineral, at Franklin, New Jersey, was utilized quite early in checking the efficiency of certain milling operations. Fluorescence has been used extensively in exploring for scheelite, as well as in mining this ore, during the past 10 years. The use of fluorescence in detecting scheelite, an important tungsten ore mineral, is well established, and much success has attended this new method; scheelite is a very inconspicuous white to gray mineral in ordinary light, but it

Jan 1, 1949

By John W. Vanderwilt

The fluorescence of scheelite has been an important aid in recent years in the discovery and development of scheelite deposits. The use of fluorescence of synthetic compounds in industry, particularly in advertising, also has expanded greatly during the past decade. As a result, a number of new and convenient units for producing ultraviolet energy have become available, which have led to a greater application of fluorescence in the study of minerals. Studies have shown that the fluorescent color of a mineral may vary: (I) with the kind and quantity of trace elements, and (2) with the particular wave length of ultraviolet energy used. The wave length is dependent first on the type of generating equipment used, and finally on the filter employed to remove the visible light that may be present. A number of so-called ultraviolet lamps are listed and described, together with suitable filters known to be available. Scheelite fluoresces brilliantly with wave lengths of 2200 to about 3000Å., but not with longer wave lengths. The most convenient and efficient sources of ultraviolet for scheelite fluorescence are portable and laboratory units designed particularly for use with scheelite. So-called ultraviolet light globes of the photo-flood type emit wave lengths too long to cause scheelite to fluoresce. Attention is called to the minerals that fluoresce in a manner similar to scheelite, which necessitates a check test by means of characteristic physical properties. Chemical tests are the final authority both for identity and content of tungsten in scheelite ore. Introduction Recent development and extensive use of fluorescent lighting make it unnecessary to explain what fluorescence looks like. The fluorescent light tube is in reality a mercury vapor arc, which generates ultraviolet energy. Coating the inside walls of the tube is a substance, called a phosphor, that converts the ultraviolet rays to visible rays of light. In a like manner, certain minerals will transform ultraviolet energy to visible rays of various colors. The phenomenon of brilliant fluorescent colors cannot be satisfactorily described or reproduced photographically; a display must be seen to be appreciated. Only a few years ago fluorescence was regarded primarily as a source of entertainment, chiefly in spectacular displays of specimens in museums. The brilliant fluorescence of willemite, a zinc ore mineral, at Franklin, New Jersey, was utilized quite early in checking the efficiency of certain milling operations. Fluorescence has been used extensively in exploring for scheelite, as well as in mining this ore, during the past 10 years. The use of fluorescence in detecting scheelite, an important tungsten ore mineral, is well established, and much success has attended this new method; scheelite is a very inconspicuous white to gray mineral in ordinary light, but it

Jan 1, 1949

By M. R. Pickus, C. H. Mathewson

THE study of the plastic deformation and recrystallization of metals has been the subject of many investigations. In regard to the simple deformational processes, such as tension and compression, the early knowledge gained from studies of polycrystalline material has been supplemented by many significant researches on the behavior of single crystals. Unfortunately, this has not been true for more complicated deformational processes. As far back as 1927, G. I. Taylor1 wrote: It is impossible in the present state of knowledge to do more than give a possible reason why (face-centcred cubic) crystals set themselves with a (110) direction in the plane of rolling, and at right angles to the direction of rolling. The explanation of why the orientation of the crystal axes round the transverse direction is what it is, must be left till the distortion of metals, and particularly single crystals of metals in the process of rolling, has been studied in greater detail. That this gap in the systematic study of deformation and recrystallization has not yet been filled was indicated by C. H. Samans,2 who wrote in 1934 that "only four investigations upon cold-rolled single crystals of any of the face-centered cubic metals have been reported in the literature." Of these four studies, only those of S. Tanaka3 and T. Sakao,4 both of whom worked with aluminum crystals, had quantitative significance. The other two, carried out by F. Wever5 and W. G. Burgers," were of a qualitative nature. It is our hope that the present investigation may contribute something to the knowledge necessary for a rationalization of the origin of rolling textures in terms of the known behavior of single crystals, and may add pertinent information concerning the recrystallization characteristics of deformed single crystals.

Jan 1, 1938

By M. Ghiani, P. Massacci, A. Manni, R. Peretti, Center for Mining and Mineralurgical Studies, S. Serranti

"The research study has been devoted to point out the better way to process a colemanite concentrate characterised by a high content of two kind of As sulphides (realgar and orpiment) finely disseminated in the matrix of the boron mineral.Scanning Electron Microscopy analyses have been carried out to determine all the mineralogical constituents and to evaluate their distribution, frequency and mutual relationships.There is a not neglectable part of realgar highly disseminated into the colemanite crystals.The orpiment recurs in small acicular crystals of 20÷30 µm in length and 5 µm in width, very difficult to liberate from the colemanite mineral particles.The colemanite concentrate, in fact, has been addressed to a chemical plant which products were boric acid and gypsum, the contaminated by As. It was unacceptable for further applications and very dangerous if rejected in the environment.Grinding tests under dry and wet conditions have been carried out in order to evaluate the liberation modality of the As sulphide minerals from the colemanite.Some difficulties have been overtaken in order to obtain a selective liberation of the As sulphides from the colemanite even if a certain decreasing in As grade in the higher size classes has been registered.All the comminution products have been analysed by SEM monitoring the liberation degree of the mineralogical constituents.Flotation tests have been carried out after different comminution flow sheet adopting different modulating conditions in order to evaluate the influence of the following parameters:• collector concentration versus contaminants concentration (As minerals) in the froths;• kind and quantity of the frothing agent to maximise the mineral recovery in the froths;• kind and quantity of the modulating agents to maximise the selectivity of the process;• conditioning modalities in order to obtain a suitable dispersion of fines and to avoid segregation of Asbearingparticles together with colemanite ones;• solid/liquid ratio of the pulp to minimise the water flow into the plant."

Jan 1, 2003

By C. H. Mathewson, M. R. Pickus

The study of the plastic deformation and recrystallization of metals has been the subject of many investigations. In regard to the simple deformational processes, such as tension and compression, the early knowledge gained from studies of polycrystalline material has been supplemented by many significant researches on the behavior of single crystals. Unfortunately, this has not been true for more complicated deformational processes. As far back as 1927, G. I. Taylor1 wrote: It is impossible in the present state of knowledge to do more than give a possible reason why (face-centered cubic) crystals set themselves with a (110) direction in the plane of rolling, and at right angles to the direction of rolling. The explanation of why the orientation of the crystal axes round the transverse direction is what it is, must be left till the distortion of metals, and particularly single crystals of metals in the process of rolling, has been studied in greater detail. That this gap in the systematic study of deformation and recrystallization has not yet been filled was indicated by C. H. Samans, who wrote in 1934 that "only four investigations upon cold-rolled single crystals of any of the face-centered cubic metals have been reported in the literature." Of these four studies, only those of S. Tanaka3 and T. Sakaoj4 both of whom worked with aluminum crystals, had quantitative significance. The other two, carried out by F. Wever5 and W. G. Burgers16 were of a qualitative nature. It is our hope that the present investigation may contribute something to the knowledge necessary for a rationalization of the origin of rolling textures in terms of the known behavior of single crystals, and may add pertinent information concerning the recrystallization characteristics of deformed single crystals.

Jan 1, 1939

By M. R. Pickus, C. H. Mathewson

The study of the plastic deformation and recrystallization of metals has been the subject of many investigations. In regard to the simple deformational processes, such as tension and compression, the early knowledge gained from studies of polycrystalline material has been supplemented by many significant researches on the behavior of single crystals. Unfortunately, this has not been true for more complicated deformational processes. As far back as 1927, G. I. Taylor1 wrote: It is impossible in the present state of knowledge to do more than give a possible reason why (face-centered cubic) crystals set themselves with a (110) direction in the plane of rolling, and at right angles to the direction of rolling. The explanation of why the orientation of the crystal axes round the transverse direction is what it is, must be left till the distortion of metals, and particularly single crystals of metals in the process of rolling, has been studied in greater detail. That this gap in the systematic study of deformation and recrystallization has not yet been filled was indicated by C. H. Samans, who wrote in 1934 that "only four investigations upon cold-rolled single crystals of any of the face-centered cubic metals have been reported in the literature." Of these four studies, only those of S. Tanaka3 and T. Sakaoj4 both of whom worked with aluminum crystals, had quantitative significance. The other two, carried out by F. Wever5 and W. G. Burgers16 were of a qualitative nature. It is our hope that the present investigation may contribute something to the knowledge necessary for a rationalization of the origin of rolling textures in terms of the known behavior of single crystals, and may add pertinent information concerning the recrystallization characteristics of deformed single crystals.

Jan 1, 1939

By Luis Garay, Felipe Montalvo, Jorge Poma, Jorge Gutierrez

Los sistemas de ventilación auxiliar en minería subterránea proveen de aire fresco a las zonas de producción, preparación y desarrollo. Estos sistemas de ventilación, quizás por su versatilidad, temporalidad y bajo coste de inversión no siempre son objeto de un análisis profundo para su dimensionamiento óptimo. Una muy común mala práctica en minería subterránea es no monitorear y reducir los consumos energéticos relacionados a los sistemas de ventilación auxiliar por considerarse de baja cuantía, sin embargo, existen estudios que demuestran que el coste económico que afrontan las corporaciones mineras en materia de ventilación auxiliar puede variar entre el 60 y 70 % de su consumo energético total de ventilación.

Sep 30, 2022

By José Estela, Yoshiro Chicmana

El presente trabajo, consiste en la implementación de un Sistema Híbrido Solar Fotovoltaico con Baterías para el suministro eléctrico actual y futuro del aeródromo Chagual, de propiedad de Compañía Minera Poderosa S.A. (CMPSA).

Sep 29, 2023

By Douglas Rudenko

Most engineers, mine operators, or contractors acknowledge the importance of having accurate subsurface information in order to plan a project or solve a problem. Conventional methods of exploring the subsurface such as augering, core borings, or test pits can provide information, but it is often costly and sparse. Geophysical methods offer an alternative to help supplement sparse information~ gathered through conventional exploration techniques.

Jan 1, 1998

By James H. Gardner

It is a striking fact in the domestic oil statistics of 1926 that with an increase in production of 13,000,000 bbl., there was nevertheless a lowering of both crude and gasoline stocks. It was the first reduction in the last eight years. In 1918, the last year of the war, stocks of crude and refined products were lowered 16,000,000 bbl., but in the following seven years stocks were increased 350,000,000 bbl., due largely to the phenomenal crop of major pools discovered in 1923. The big pools of that year coming as they did through some curious coincidence unprecedented in the oil industry, not only piled up a sudden increase of stocks at a time of large imports but they continued to add their quota to an increase of storage until 1926. With an increase in crude production, according to the Oil and Gas Journal, from 760,000,000 bbl. in 1925 to 773,000,000 bbl. in 1926, and an increase in cracking facilities of about 30 per cent., there was a draft on storage of 22,300,000 bbl. of crude and 1,000,000 bbl. of refined. Crude and refined changed from a stock surplus of 29,130,000 bbl. in 1925, to a deficit of 23,300,000 bbl. in 1926, or a differential total of 52,430,000 bbl. With a stock reserve of 541,700,000 bbl. of crude and refined oil in 1925, the amount drawn from storage was not large in percentage but it marked an important contrast with previous years. It meant a year of stability in prices and a sound condition in the industry. The indicated domestic demand increased from 695,120,000 in 1925 to 743,360,000 in 1926, (7 per cent.), 1 per cent. of which was due to California fires. Most of the gain in consumption was due to the increased demand for gasoline. There was little comparative change in the combined imports of crude and refined oil. There was an increase in exports of 17,200,000 bbl. (1.5 per cent). A petroleum balance sheet for 1926 and a comparativl sheet for the last two years, production in the United States by major districts and pools, and a list of imports are given in Tables 1 to 5, inclusive.

Jan 1, 1927

By K. Rajani Kanth

Environmental problem is the major concern for any industry and there is a great need to that along green lines. Sangam Dairy being one of the most famous and wide spread Dairies in India, produces wide spectrum of milk products. The BOD levels of effluent water of this industry with MIF treatment were found to be around 100 ppm. Lot of research has been expended in the past to bring down the BOD levels to bare minimum. The main objective of the present study is to minimize the BOD level to the required level stipulated by environmental standards by employing various seeding materials. For this purpose microbes like Bacillus Subtiles, Pseudomonas, Aspergillas, Staphylococcus, and Pencilium have been employed and BOD levels were analyzed. Various Reagents, solutions with different dilution levels have been successfully prepared. Initial and final Dissolved Oxygen levels were determined before and after incubation. From the DO data, BOD was evaluated for all samples and comparison analysis of various seeding material was carried to suggest the efficient seeding material for the ETP plant. In the process, solutions of different dilutions have been prepared using difficult reagents. These samples are treated with above mentioned microbes and BOD levels are estimated. It has been observed that staphylococcus and Pseudomonas proved to be the best seeding materials. When there microbes have employed BOD levels fall to less than 10 and 20 ppm respectively

Jan 1, 2006

By Y. Fautrelle, F. Felten, O. Metais, Y. Du Terrail

"We deal with the prediction of electromagnetically-driven turbulent flows by means of a Large-Eddy- Simulation method (LES). The model is applied in the case of a liquid metal pool submitted to a polyphase linear electromagnetic stirrer. We investigate two cases: (i) the frequency of the magnetic field is equal to 50 Hz; in that case the effects of the pulsating part of the Lorentz forces may be neglected; (ii) the frequency of the magnetic field is low (f= 1 Hz), then the oscillating part of the electromagnetic forces is taken into account. The LES predictions agree well with the mean velocity measurements, as does the standard k-a model. However, as for the turbulent kinetic energy predictions, there is a large discrepancy between the two models. When the oscillating part of the Lorentz forces is taken into account, the computations show that the fluid flow is sensitive to the unsteady part of the forces. We find that the mean velocity is not affected by the fluctuating component of the force. As for the turbulence parameters, the presence of the pulsating part leads to a significant reduction of the turbulent kinetic energy, whilst the turbulence length scale decreases.IntroductionElectromagnetic stirring is commonly used in various metallurgical processes. In continuous casting for example, it may improve the structure of the solidified metal products. Fluid flows generated by electromagnetic stirrers have been extensively investigated (1 ). As for numerical predictions, many works have been published on the subject. In most of the previous works, onepoint closure models have been used. The most used model is the well-known k-i:: model. Those models yield fairly good results as for the mean velocity prediction. However, it has two main drawbacks:(i) the turbulence is not predicted accurately,(ii) it is not well fitted for unstationary flows as well as transitional turbulent motions, where theReynolds number is moderate."

Jan 1, 1999

By V. T. McLemore

Petrographic analysis of rocks is traditionally performed with optical microscopy using thin sections and point counting. However, this does not provide accurate mineral proportions for sedimentary, volcanic, and soil-like material, because rock fragments, groundmass, and matrix are not identified as specific minerals. In addition, groundmass phases in volcanic rocks can be too fine to identify individually, and making thin sections of intact soil-like material is difficult because much of the material is not well cemented. ModAn is a normative calculation that estimates modes ??by applying Gaussian elimination and multiple linear regression techniques to simultaneous mass balance equations? (Paktunc, 2001) and allows location-specific mineral compositions to be used. One of the features of ModAn that makes it appropriate for this study is that it can model one of several sulfide minerals. Mineral compositions for Questa minerals were determined from electron microprobe analysis and entered into ModAn. Then by combining and normalizing results, bulk quantitative mineralogy can be determined using ModAn, petrographic observations, electron microprobe analysis, clay mineral analysis, and the whole-rock chemistry of the sample.

Jan 1, 2009

By Sidney A. Hiscock

INTRODUCTION Lead and zinc are today rightly regarded as sister metals. Historically, however, they differ markedly with lead being known and in general use as the metal since 3000 BC in several countries which at that time might have been described as mature economies. Zinc was not isolated and recognised as an industrial metal with distinct and valuable properties until about 1700-1800 AD (although it had, of course, been utilised as a constituent of brass for some 2000 years previously). c were well established as industrial metals by the beginning of the 20th century. The present paper briefly reviews the overall growth in world consumption* and changes in the three main areas which today represent the mature economies or industrialised areas, i. e. ,Europe, the United States and Japan. Trends in overall consumption are determined by the demands for the individual uses for lead and zinc. The changes in patterns of use in the industrialised areas - individually and collectively - and reasons for the changes are also considered. LONG TERM TRENDS - 1900-1984 The World Picture Since the beginning of the 20th century the world consumption of lead (3.9 million tonnes in 1984) has grown almost fourfold and that of zinc (4.7 million tonnes in 1984) is almost eleven times greater than it was in 1900. The long-term trend has been one of continuing expansion for both. metals although the pattern has been severely disturbed at certain periods, for example in the years immediately following the two world wars and at times of marked recessions in industrialised areas. Apart from such major setbacks, new levels of consumption have been established regularly every few years. Recently, however, consumption has not really grown and with only a slow and partial recovery in world industrial activity at present, there is no indication that the peak consumptions of 4.2 million tonnes of lead, set in 1979, and 4.8 million tonnes of zinc (1973) will be exceeded in the near future. The growth in world lead and zinc consumption since 1900 is shown in Figure 1 (which includes changes in copper and aluminium for comparison). Overall growth over the period 1900-1984 has been about two percent a year for lead and about three percent for zinc (annual growth for copper has also been about three percent). Increases in tonnage consumption and growth rates by decade for lead and zinc are summarised in Table I. However, the growth rates by decade sometimes conceal very large individual annual increases and decreases. For example, in 1975 lead consumption fell by 13 percent and zinc consumption by 22 percent compared to 1974. In 1976 consumption of lead and zinc rose by 12 percent and 18 percent respectively. The years when consumption 'landmarks' (ie one, two, three and four million tonnes) were first reached are shown on Table 2. Clearly, the pattern of shorter periods being required to attain each extra million tonnes of consumption was broken in the 1970's. The consumption of zinc overtook that of lead for the first time in 1940, and since 1946 has always been at a higher level. Trends in industrialised areas The two key industrialised areas at the beginning of the 20th century were Europe and the United States which between them accounted for some 95 percent of world lead consumption and 98 percent of zinc consumption. Figures 2 and 3 show the growth in lead and zinc consumption, and Figures 4 and 5 the percentage shares for each area since 1900. Europe has usually been the major user of lead except for some years in the 1920fs, most of the 40's and early 50's when consumption in the United States was larger. In 1900, Europe accounted for about 64 percent of world lead consumption and the United States just over 30 percent. Currently, Europe takes about 40 percent of world consumption and the

Jan 1, 1986

By James Rowland, Marcia Harris, Richard Mainiero, Michael Sapko

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 ?? 10-38 cm6 molecules-2 sec-1 for the rate equation -??d [NO]/dt = K ?? [NO]2 ?? [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

Jan 1, 2006