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By John Rudolf

Metropolitan Washington Airport Authority is currently undertaking the first Phase of Metro?s Extension to Northern Virginia. A wide range of tunnel options was considered for the Tysons Corner segment that involves about 20,000 feet of track and four stations. After consideration of many options that involved EPBM single track tunnels, NATM tunnels and large bore tunnel concepts for the entire Tysons alignment, the design now being progressed into construction involves two 520 meter (1,700 feet) long soft ground NATM tunnels with several hundred feet of cut-and-cover construction. The paper discusses the process that led to selection of the short NATM tunnels as the most feasible of the options considered for Tysons.

Jan 1, 2008

By C. R. Tinsley

A strictly limited number of specialist project finance banks exists, with the necessary specialist personnel able to address project cost-competitiveness, cost and commodity forecasting, joint venture negotiations, and completion and sales undertakings. Different techniques of internal bank appraisal are applied, with the usual equity investment project valuation criteria being seldom useful for loan assessment purposes. Company attention paid to the preparation of a sensitivity structured bankable presentation can prove most effective for securing development project finance. Substantial scope is possible for savings of time and money.

Jan 1, 1985

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By Renata Cristina Alves Elias

A análise por microscopia óptica em quase partículas, obtidas após a aglomeração a frio, é de grande importância para o entendimento do processo de sinterização, pois permite determinar aspectos qualitativos e quantitativos da aglomeração, assim como identificar o arranjo microestrutural entre as partículas nucleantes, aderentes, combustíveis e fundentes das misturas a sinterizar. Neste contexto, foi desenvolvida uma metodologia para preparar e analisar ao microscópio amostras da mistura a sinterizar, visando auxiliar na identificação de relações entre as suas características e os parâmetros de produção e de qualidade do sínter. O método desenvolvido permite determinar a porcentagem de quase partículas, de partículas não aglomeradas e de partículas micropelotizadas em cada amostra. Além disso, permite identificar e medir as dimensões do material (minério, sínter, coque, fundente, quartzo) que constitui o núcleo de cada quase partícula e avaliar o material que não aglomera.

Aug 1, 2018

By T. Grammatikopoulos, K. Gibbs, H. De Souza, C. Gunning

The mineralogy of any ore body is a key factor in defining ore zones and predicting minerals/metals behaviour during processing. The determination of forms of gold, defined as the different chemical states in which gold is encountered in ore deposits, is critical. The most commonly known form is that of gold minerals and alloys, while other forms of gold have been collectively described in the literature as submicroscopic gold (i.e., less than 1 µm in diameter). Gold mining operations generally deal with very low-grade ores, in the order of a few g/t, in which gold displays complex mineralogy. These difficulties complicate the mineralogical studies and pose challenges for processing and recovering the gold. A comprehensive understanding of the chemical forms of gold is necessary to define gold mineralization and optimize gold metallurgy. SGS Canada Inc. has been using QEMSCANTM and a Tescan automated SEM that are automated mineralogical techniques that provide vast amounts of data for microscopic Au. The data in conjunction with other physical and chemical methods provide a comprehensive delineation of the ore composition and behaviour.

Jan 1, 2011

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

In order to realize the resource utilization of spent hydrodesulfurization catalyst, a solvent extraction-oxalic acid precipitation process is studied in this paper for efficiently recovering vanadium, nickel, and aluminum from the acid leaching solution of spent hydrodesulfurization catalyst. The process conditions for extracting vanadium with Cyanex 272 and precipitating nickel using oxalic acid as a precipitation agent were explored in detail. The results show that vanadium (IV) in the sulfuric acid medium containing nickel and aluminum was efficiently and selectively extracted by Cyanex 272. After three-stage countercurrent extraction, the extraction efficiency of vanadium was 99.76%, and the co-extraction efficiencies of nickel and aluminum were only 2.47% and 1.87%, respectively. Thermodynamic calculation shows that the extraction of vanadium (IV) from the sulfuric acid medium with Cyanex 272 is an endothermic reaction. The innovative method of oxalic acid precipitation was used to recover nickel from the raffinate, achieving selective extraction of nickel from the solution containing a high concentration of aluminum. The precipitation efficiency of nickel was 98.58%, while that of aluminum was only 0.75% under optimal conditions. The proposed flowsheet for the separation of vanadium, nickel, and aluminum from acid leaching solution may provide a new idea for the comprehensive recovery of valuable metals from spent hydrodesulfurization catalyst.

Nov 30, 2022

By R. W. Raymond

In a paper on the Divining-Rod (Transactions, xi., 411), presented at the Boston meting, in February, 1883,I suggested, among other signs of which the skilled prospector might consciously or unconsciously avail himself in the search for springs of water or mineral deposits, the presence of particular grasses or shrubs, and the general appearance of the flora. There are not wanting, in the literature of our art, indications that greater attention was paid to such signs in ancient days than at present. It is the tendency of a scientific age to ignore, or regard as superstitious, what cannot be classified or explained. But the acute though unscientific observation of earlier times often, doubtless, accumulated facts which it would be worth our while to re-examine. It is highly probable that the mining prospectors of the sixteenth and seventeenth centuries, to go no further back, were close students of nature, and knew, though they could not explain, and, for reasons of private gain, would not communicate, many curious and significant facts. We can generalize better than they could; but for that very reason we are, perhaps, their inferiors in observation. They let nothing pass, because all things were equally significant to them. We take wider views, and miss more. And, no doubt, there still exists among practical millers, prospectors,, hunters, Indians, etc., an unwritten.

Jan 1, 1887

By Carl E. Williams

During the past two years a computer program called "COPOR," Computerized Open Pit Optimization Routine, has been developed and used for mine planning of several base metal deposits. This routine utilizes a three dimensional computerized block model of an orebody, some economic parameters and operating constraints to locate the mineable or economic limits of the deposit schedule the yearly production from the mine and produce bench by bench ore reserve summaries and maps of the yearly and ultimate pit configurations. The moving cone method is used to perform these functions with a conventional block model. This model is conventional in the sense that each block is assumed to be homogenous; i.e., either ore or waste but not a mixture of the two. Due to the nature of a seam type deposit this approach is not realistic; therefore, revisions have been made to form a new version of the COPOR program. This version has been named "COALOR," Coal Optimization Routine. COALOR contains all of the power of the COPOR program but is equipped to handle the intricacies of coal seam type deposits. The deposit can be composed of a single seam or multiple seams which are horizontal or dipping at any angle. The numerous coal quality values can be incorporated to aid the optimization of the economic pit limits and yearly scheduling.

Jan 1, 1978

By Thomas Wright

No symposium on die casting could be complete without consideration of the methods of formula and impurity control. No consideration of control would be complete without discussion of that new tool of the analytical chemist and inspector, the quartz spectrograph. Just as there is an increased appreciation of the possible applications of the die-casting process and of die castings, so too is there, slowly but surely, of the spectrograph. At present the role of the instrument might well be compared with that of brass or magnesium die castings. Neither is as widely understood or known as they will be. Product specifications are increasing and are getting more explicit and often more rigid. The designer, metallurgist and production engineer or superintendent will be forced to depend more and more on the chemical laboratory. Sampling, as well as analyses, testing and inspection problems will grow. The chemical laboratory must meet its increased responsibility and use of the spectrograph will become more common. Advantages of increased precision, greater speed, lessened labor and often lower costs cannot be ignored. It will be the purpose of this paper in part to outline the respective fields of chemical and spectrographic analyses and to indicate where one may overlap the other and in part to indicate certain possible sources of contamination of zinc-base die-cast alloys in particular.

Jan 1, 1935

By Marius B. Wechsler

A mathematical analysis is developed for the determination of the cases when HP-piles might be replaced by precast concrete piles. The analysis focuses especially on the "integral abutment-bridges" which are used on large scale in the Great Plains of the United States of America, The theoretical considerations are illustrated by a numerical example.

Jan 1, 1992

Thirty mixed cultures of microorganisms from soil, water and mineral samples from the Groote Eylandt Mining Company mine site were approximately three times more effective in biodegrading manganese dioxide (34± 18 mg Mn++/1/day) than sixteen purified strains (11 ± 10 mg Mn++/1/day) isolated from the primary enrichment cultures. Two pure bacterial genera identified as a Pseudomonad and a Bacillus, with an excess MnOz and nutrient, were able to dissolve 106 mg Mn++/litre/day in mixed culture compared with 29 mg Mn++/litre/day when grown separately.

Jan 1, 1983

By P. J. van Staden

Several differences exist between the columns used for laboratory simulations of heap leaching and commercial heaps. Column walls support part of the weight of the ore and restrict the particle packing arrangements. Columns are typically of a diameter that is smaller than the dripper spacing to be used on the commercial heaps. The stacking practices that cause segregation and stratification on heaps are absent from columns. Intuitively, these physical differences would be expected to be the reasons behind the observed differences between column and heap leaching performance. But how can they be quantified, and what is the magnitude of the differences? Could some of these differences be built into column leaching experiments in order to better simulate commercial-scale heap leaching performance to ease the scale-up calculations from column leaching data? Alternatively, could heap construction practices be improved so that the ideal performance obtained in columns could be emulated on heaps? Data from a few heap leaching cases studies that permit direct comparisons between column and heap leaching performance is analysed, to reveal the extent of the differences in resistance to mass transfer. Discussion is provided on the implications for column and heap leaching practice, and for scale-up design procedures. INTRODUCTION Differences have been known to exist between leaching performance observed in laboratory columns and that of commercial-scale heaps. Both the heap leaching kinetics and finally achievable extent of extraction are generally found to be inferior in heaps compared to that achieved in columns. Heap leaching design engineers extrapolate the anticipated heap leaching performance by multiplying the time-axis of a column-leaching curve by a factor of about 2 and the extraction-axis by a factor of about 0.8, as explained by Jansen and Taylor (2002), Scheffel (2002), John (2011) and Scheffel, Guzmán, and Dreier (2016). The procedure is illustrated in Figure 1 by means of a hypothetical example. The solid line represents the leaching performance observed in a laboratory column, and the dashed line represents the anticipated leaching performance of a heap, extrapolated from the column leaching data using these empirical scale-up factors.

Jan 1, 2019

By T. Mills, M. Evatz

Newmont’s Lone Tree Mine, located in northern Nevada, is an open pit gold operation supported by a standard truck and shovel mine production fleet (Caterpillar 785Bs and Hitachi EXs). Newmont continues to search for ways to decrease capital expenditure and lower operating cost, hence the implementation of the Ultra Light Body (ULW) concept. The fundamental idea associated with the ULWs is the increased payload potential. Economic justification comes from successful achievement of additional payload, within the truck’s rated GVW, without changing its loading and hauling characteristics. The increase in payload capacity allows equivalent tonnage movement using fewer trucks.

Jan 1, 2001

By Luis Toron, Salvador Cortes-Obregon

John D. Price (Colorado Fuel and Iron Corp., Pueblo, Colo)—The paper on the coal fields of the Oaxaca district as prepared by engineers Toron and Cortes-Obregon of the staff of the Bank of Mexico bears witness to the thorough and careful way in which the men associated with this organization perform their work. There is little to be added to their paper in way of discussion other than to confirm and amplify some of their statements. Since the only extensive and well-developed field of coking coal lies in the northeastern section of the country adjacent to Sabinas in the state of Coahuila, it follows that blast furnace plants would be located in that same region. Two such plants are now operating at Monterrey and Monclova, using coke produced at the Sabinas district mines. But the nearer of these two plants is 600 miles from Mexico City and even farther from the center of population. Transportation of products from these mills to the market area is therefore expensive, both because of the distance and the difficulty of the terrain over which it must be carried. The development of an integrated steel industry closer to the center of population has therefore long been a goal toward which the Mexican technicians have been striving. While the presence of coal of some grade has been reported in many of the states, and many ideas have been advanced regarding its possible uses in iron and steel production, deposits of anthracite in Sonora and the various coals of the Oaxaca district as reported on in this paper are the only ones that have been explored in a serious manner. The coking coal from the Mix-tepec zone appears to offer promise of producing a coke which could be used in a standard blast furnace. Several problems are indicated, however: 1—The ash in the coal is high as mined, but indications are that it can be washed to an ash content of 15 pct with a recovery of 70 pct of washed coal. 2—Such washing would increase the volatile content from 17.4 pct to about 20 pct, and in a byproduct oven this should give a coke yield of close to 80 pct with an ash content of coke under 20 pct. 3—A free swelling index of 5 appears low for a good coking coal, and below that of the coals from the Sabinas district, which show between 6 and 9. But washing of the coal should result in an improvement in this regard; in the United States coals from Utah with an index even lower than 5 have made a usable coke. 4—A coal with volatile as low as 17.4 in raw coal and 20 in washed coal would come close to being classed as a low-volatile rather than medium-volatile coal, and low-volatile coals are notorious for their high expansion properties. Several plants in the United States are making coke from straight medium-volatile coal of 26 to 28 volatile content, and one at Rosita,, Mexico, from coal of 25 volatile. But no plants to my knowledge are using coal as low as 20 volatile. Since the Rosita coal appears to be a borderline coal from the angle of its expansion properties the coking of one of the straight lower volatile must be approached with caution. 5—There are few coals possessing any degree of coking properties which cannot be used in coke production by careful attention to its preparation and blending. The fact that coals of other types are available in this same region make improvement through blending very possible. 6—There are other workable methods of reducing iron ore other than the conventional coke-blast-furnace method. These will not be discussed here but it is known that their use has been considered. The technicians of not only Mexico but also of the other Latin American countries are keenly aware of their natural resources and their national needs. This paper emphasizes the fact that the Mexican technicians are working on their problem and attempting to speed the day of self-sufficiency for their country. Salvatore Cortes-Obregon (author's reply)—I wish to thank Mr. Price for his kind remarks. The Mixtepec coal as shown in Table II has 30 pct ash and a free swelling index of 5, but when the same coal is washed to 15 pct ash it has a free swelling index of 8 to 9 and the volatiles increased from 17.4 to 20.7 pct. A satisfactory coke has been produced from blends made in the Mexican laboratory using at least 40 pct of the Mixtepec coking coals with the other Oaxaca non-coking coals. Koppers in Germany report good coke obtained from the Oaxaca coal with a blend of 80 pct Mixtepec coal. Consideration is being given the possibility of using methods other than the conventional blast furnace for the reduction of iron ore near the Oaxaca area; electric furnaces appear promising. The non-coking coals could be used to produce cheap electric energy and the coking coals to make metallurgical coke.

Jan 1, 1955

By A B. Christie

REGCHEM is a geochemical database containing stream sediment geochemical analyses compiled from open file mining company exploration reports. The database contains data on over 21 000 samples that have each been analysed for several elements such as gold, silver, arsenic, copper, lead and, zinc.   REGCHEM is supported by GEOEXPL - a custom written computer software application which operates under Microsoft Access. The data can be plotted as maps using a geographic information system (GIS) package called MapInfo, which can incorporate data from other data sets such as mineral deposit sites from the geological resource map database, GERM.

Jan 1, 1994

By John D. Sullivan

The recovery of copper by leaching from relatively low grade ores containing both oxidized and sulphide minerals is rapidly gaining in commercial importance. There is an economic limit below which certain ores can not be treated by concentration methods, and material with values below this limit must be discarded, possibly to be treated later, or the copper must be extracted by wet processes. Heap leaching has been carried out by the Phelps Dodge Corporation, Copper Queen Branch, for several years, and to-day its plant is a large producing unit. The Ohio Copper Coy at Bingham, Utah; has been leaching in place since 1919. Many other leaching operations are also being; carried out in various parts of the United States and in foreign countries. The plant at Rio Tinto, Spain, may be considered the father of heap leaching.

Jan 1, 1931

By Andrew Shabalin, Vladimir Skorohodov, Svetlana Babaeva, ?lga Makovskaya

"At processing of some kinds of wastes (electronic scrap, secondary materials, spent nuclear fuel) in nitric acid solutions, and also in technology of silver refining, the significant amounts of palladium and platinum passes into a solution. The ion-exchange concentration of palladium and platinum in nitric acid solutions (5-500/dm3) are investigated. More than 30 various classes of ionites are tested. The most chemically resistance resins at the given conditions are identified. It is shown, that the maximum sorptive capacity to studied metals at high acidity the complexing, synthetic and inorganic sorbents possess. To definition of platinum metals sorption optimum conditions the kinetics is studied, isotherms of a sorption at various parameters from nitrate solutions are obtained. The conditions of the platinum and a palladium desorption from the pregnant sorbents and its regeneration with the subsequent reuse of materials were defined. The raw materials containing precious metals have very diverse composition and physical properties. Commonly the materials are processed by hydrometallurgical way. If gold or PGMs there are in raw materials to its opening hydrochloric acid solutions are applied. As an oxidizer nitric acid, hydrogen peroxide, gaseous chlorine, etc are used. Nevertheless, at processing of argentiferous materials and preliminary treatment of a waste including the spent nuclear fuel, nitric acid solutions are often used and the specified metals in some extent pass into solution [1]. Therefore selective extraction of PGMs from nitrate solutions is an actual problem. In the present work the ion-exchange concentrations of palladium and platinum in nitric acid solutions (5-500 g/dm3) are investigated. At the testing more than 30 various classes of ionites the most chemically resistance resins at the given conditions are identified. These resins are synthesized on the base of polyacrylate, styrene-divinylbenzene and vinylpyridine. For a selection of the most effective resin among what are made in Russia and overseas, a number of ionites with various functional groups were studied. Influence of functional groups type on a PGM sorption is shown for extraction of a palladium as an example (table 1). The presented data shows, that palladium concentration in a phase of ionites depends on sorbent type. If the increasing of solution acidity essentially reduces palladium sorption by sulfonic cation-exchange resins (KU-2×8) than its sorption by strongly basic anionites is approximately equal. Intermediate position is occupied by complexing sorbents. The latter (AN-31, SN-3, ANKB-35, Lewatit TP 207, Purolite S 930) are the most effective for extraction of PGMs from nitrate solutions from the point of view of capacity value. According to [2], solution behavior of Pt (II) and Pd (II) are similar. As is known from coordination chemistry, ligand environment of the metal ions substantially impacts to character of electronic spectra. The figure 1 shows the results of measurements of optical density of platinum bearing solutions with various concentration of nitric acid at ?=400 nanometers"

Jan 1, 2008

By Khaled Morsy

Cementitious seals are made of foamed cements with strength ranging from 100 to 600 psi. These cementitious seals are usually used at locations where the seal will be subjected to some convergence, assuming that this material can absorb entry closure without compromising the structural integrity of the seal. Prior to 2006, Lake Lynn Experimental Mine (LLEM) conducted full-scale tests on various cementitious seals designed to meet or exceed the 20-psi horizontal static load requirements of the old 30 CFR1 75.335. Both hydrostatic and dynamic loading tests were conducted. The structural response (pressure and displacement readings) obtained from these tests were recorded. The stability of the cementitious seal is based on balancing the load applied to the face of the seal from the explosion against the shearing resistance at the seal/rock interface. Therefore, the properties of the seal/rock interface, such as stiffness, cohesion, friction, etc. are critical to determine the stability of a cementitious seal. These properties are usually assumed by the researchers in their models. This paper emphasizes the importance of having the correct properties of seal/rock interface in the numerical modeling. FLAC 3D models were developed to simulate Celuseal2 cementitious seals subjected to both hydrostatic and dynamic loadings. Using the hydrostatic and dynamic loading test data conducted at LLEM, the static and dynamic properties of the seal/rock interface were back calculated. The FLAC 3D models showed good agreement with the test results.

Jan 1, 2009

By Ing. Alois Adamus, Ing. Václav Pošta, Ing. Lubomír Hájek

This paper reviews experiences connected with the use of nitrogen in the Czech coal industry. Special attention is focused on the first use nitrogen In the Czech Republic, it is probably the first case of fighting a mine fire using nitrogen in all the World. Discussion dwells on the present-day use of nitrogen, its sources, consumption, technological equipment, and the theoretical evaluation of nitrogen flushing.

Jan 1, 1995

By Gregg J. Hodges

The Stillwater pt-pd mine and flotation mill are located about 130 km (80 miles) southwest of Billings in Stillwater county, M6ntana~ The pt-pd ore zone stretches about 43 km (27 miles), but varies in thickness from 0 to 6 meters (0 to 20 feet, but generally 3-6 feet) and dips 55-90,degrees from horizontal. The ore is hosted in basic, layered igneous rocks containing about 1% sulfide minerals which include chalcopyrite, pentlandite, pyrrhotite, and minor pyrite. The pt-Pd minerals are intimately associated with these sulfide minerals and are found as precious metal sulfides, tellurides, bismuthnides, and arsenides as well as native Pt metal. Approximately 90 different precious metal minerals have been found, but about 80% of the pd is in solid solution in the pentlandite. The ore assays about 0.1% Cu, 0.1% Ni, 6.2 g Pt/tonne (0.18 Troy ounce Pt/short ton (opt)), 21.3 g Pd/tonne (0.62 opt Pd), 0.21 g Au/tonne (0.006 opt Au), and 0.21 g Rh/tonne (0.006 opt Rh). The ratio of pd to Pt in the Stillwater ore and concentrates is about 3.5.

Jan 1, 1988