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By Groudeva VI

The biohydrometallurgy of gold is based on different processes which could be grouped into four main groups (Attia, Litchfield and Vaaler, 1985; Karavaiko et al, 1988; Groudev, 1990): 1. bacterial oxidation of gold-bearing sulphide minerals by chemolithotrophic bacteria to facilitate the subsequent chemical extraction of gold; 2. solubilisation of gold from oxide ores by means of heterotrophic bacteria; 3. recovery of gold from solutions by biosorption; and 4. microbial modifications of the surface of gold-bearing sulphide minerals to improve the subsequent gold concentration by physical dressing methods (eg flotation, oil agglomeration).

Jan 1, 1993

By J. J. Reilly

The Vesta Mines of the Jones & Laughlin Steel Corporation operate in the Pittsburgh Seam in Washington County, Pennsylvania. This seam is overlain with a drawslate, 12" to 16" in thickness, which slimes readily when wet. Because of the need for a uniformly good quality metallurgical coal, the amount of reject, together with the top and particle sizes of the raw coal feed, is a serious problem at the Vesta Preparation Plant. The Preparation Plant operates two, seven and one-quarter hour shifts per day and processes 2,100 tons per hour of raw coal feed. The third shift is, used for planned maintenance of equipment. Since the water clarification equipment is so vital in insuring a uniform product, there is no alternative but that it be in operation at all times. To insure this continuous operation,. well-planned maintenance is a necessity. For years, Plant Management has kept performance records of the various units to determine the renewal dates of vital component parts, the length of wear, the various materials used in the manufacture of the equipment, and the labor cost for renewal. These records have been of inestimable help in planning an effective maintenance program to insure continuous operation of the various units.

Jan 1, 1959

By S. T. Wlodek

The surface and subscale oxidation reactions were followed by means of continuous weight-gain and metallographic techniques over the range 1600" to 2200°F (871° to 1204 °C) for up to 400 hr. Full identification of all scale and subscale reaction products was obtained by electron and X-ray diffraction. At or below 1800°F (982°C) a linear rate of reaction (QL = 46.0 kcal per mole) governed the oxidation process, extending for up to 100 hr at 1600°F (871 "C). During linear oxidation the surface scale consisted of an amorphous SiO2 film overgrown with Cr 2O 3 and NiCr204. This initial linear process was followed, and above 1800°F completely replaced, by two successive parabolic rate laws (Qp = 60 and 57 kcal per mole). This parabolic reaction involved the formation of a complex scale consisting of Cr2 O3 and smaller amounts of NiCr2O4. Parabolic oxidation appeared to coincide with the disruplion of the silica film present during linear oxidation and was followed by subscale (internal) oxidation of crystobalite and NiCr2O4. The balance between the subscale and surface oxidation reactions controls the oxidation of this commercial alloy. The amorphous silica film appears to result in the linear rate and diffusion through Cr2O3 is the more likely rate-limiting step during parabolic oxidation. THE oxidation of a multicomponent composition is a complex phenomenon not presently amenable to a rigorous classical interpretation. Nevertheless, even a qualitative understanding of the scaling and subscale reactions that occur in a commercial composition can illuminate the reactions that limit its high-temperature stability in an oxidizing environment. This study of the oxidation of Hastelloy Alloy X presents the first of a series of studies with the above approach in mind. Hastelloy X exhibits one of the best combinations of strength and oxidation resistance available in a wrought, solution-strengthened, nickel-base alloy. Although during long time exposure some precipitation of M6C and M23C8 carbides as well as a complex Laves phase occurs, the amounts are probably small enough to have no appreciable effect on the chemistry of the matrix. Radavich has identified the oxidation products on Hastelloy X oxidized for 5 min to 10 hr at 1115°F as NiO and the NiCr2O4 spinel. Oxidation for 5 to 15 min at 1500°F produced a scale of spinel, NiO, and a rhombohedra1 phase, probably Cr2Os. Sannier et 2. have reported continuous weight-gain data for Hastelloy X at 1650" and 2010°F and internal-oxidation measurements after 150 hr at 2010°F. In addition, much of the data on binary Ni-Cr alloys recently reviewed by Kubaschewski and okins' and Ignatov and Shamgunova4 as well as studies of binary Ni-Mo alloys5 are also pertinent to the oxidation of this composition. EXPERIMENTAL Continuous weight-gain measurements and metallographic measurements of subscale reactions were the main experimental techniques used in this study. X-ray and electron diffraction backed up by a limited amount of electron-microprobe analysis served to characterize the nature of the scale- and subscale-reaction products. Two heats of commercial sheet of the composition given in Table I and identified as A and B were used in the bulk of this study. Internal-oxidation measurements were made on a third heat of material in the form of a 0.5-in.-diam bar. In order to assure homogeneity, all heats were reannealed 4 hr at 2175°F prior to sample preparation. weight-Gain Measurement. All specimens (1.5 by 0.4 by 0.03 in.) were abraded through 600 paper, electropolished, and lightly etched in an alcohol-10 pct HCl solution. An electrolyte of 150 cu cm H,O, 500 cu cm HsPO4 (85 pct conc), and 3 g CrO3 at a current density of 0.9 amp per sq cm or a solution of 10 pct HaW4 in alcohol used at 4 v and 0.3 amp per sq cm was used for electropolishing. The resultant surface exhibited a finish of 3 ± 1 p rms. Continuous weight-gain tests were made at 1600°, 1700°, 1800°, 1900°, 2000", and 2200°F on auer' type balances capable of recording a total weight change of 110 mg with an accuracy of k0.1 mg. All tests were made in air dried to a dew point of -70°F and metered into the 2-in.-diam reaction

Jan 1, 1964

By J. Arzuúa, U. Castro-Filgueira, L. R. Alejano, F. Malan

"Pillar design for underground mining is typically done using empirical formulae or numerical modelling. Practical experience and recent literature, nevertheless, illustrate the shortcomings of these design approaches. Ongoing monitoring of pillars is therefore recommended to minimize the risk associated with these designs.In a mine where a large number of pillars are cut, different pillar strengths can be expected owing to variations in rock mass strength from area to area. This problem is compounded by the fact that in mining environments the pillars are not always cut according to the prescribed dimensions. Although the original design using either empirical methods or modelling may predict stable pillars, unstable pillars will be encountered in reality. Very conservative designs with large factors of safety may circumvent this problem, but this approach is uneconomical.A possible solution to localized stability problems may be to enhance the strength of a few unstable pillars. It may even be hypothesized that reinforcing a few critical pillars may prevent ‘pillar runs’ on a much larger scale. Rockbolting, strapping of pillars, and pillar shotcreting have occasionally been used in the past as possible solutions. It appears that these have not been successful in all cases and large collapses have occurred in spite of the pillar remedial work.The authors investigated the strapping of pillars by conducting laboratory tests on cabled rock specimens. The results were qualitatively compared to actual attempts of pillar reinforcement available in the literature, as well as additional observations in an old haematite roomand- pillar mine in Spain. Based on these results, the value of steel cabling and mesh wrapped around pillars to improve stability is demonstrated. Some cases where this approach will not be successful are also discussed."

Jan 1, 2017

By Charles W. Goodale

The ores of the Butte district present a variety of combinations, and their treatment by concentration is an interesting study. They may be classified in general as follows: 1. Copper-silver ores, which are produced by the mines of the Anaconda group, and by the Mountain View, Colusa, Silver Bow and Parrot. The high-grade ores from these properties are roasted and then smelted; but a large proportion of the output is low-grade and siliceous, and hence requires concentration. The copper-bearing minerals are chalcocite, bornite, enargite and chalcopyrite, in varying proportions in the different mines, the gangue, which breaks readily into grains, being quartz and feldspar. 2. Silver-copper ores, of which the Gagnon vein is the largest producer. The grade of the ores from this mine is such that nine-tenths of the output requires concentration. The silver- and copper-bearing minerals of this vein are massive wurtzite, sphalerite, bornite, chalcopyrite, pyrite, tetrahedrite, enargite, tennantite and galenite, with a quartz gangue associated with feldspar and small quantities of barite and fluorite. The gangue is very hard and not at all granular. 3. Silver-ores containing a small amount of gold, embracing the product of the Alice, Magna Charta and Moulton claims, on what is known as the Rainbow lode, and that of the Lexington, Blue Bird, Nettie, Burlington and other mines. The gangue is quartz, carrying pyrite, sphalerite, galenite, tetrahedrite and argentite, with manganese in the form of rhodochrosite and rhodonite. Good results on ores of this class cannot be obtained by concentration, because large percentages of the silver-bearing minerals are disseminated through the gangue in such minute grains that even the finest practicable crushing

Jan 1, 1897

By H. Pearce, A. E. Lewis, A. Ochieng

"Hydrodynamics and mixing are fundamental to the operation of mineral process systems such as flotation cells and metal precipitation reactors. Hydrodynamic conditions influence phase mixing and mass transfer in a multiphase system, and these affect the overall performance of such a system. Detailed information on the effects of the hydrodynamics on the performance of agitated systems is still required for the design and optimal operation of hydrometallurgical systems, which are always multiphase. Computational fluid dynamics (CFD) techniques have been employed to study the hydrodynamics and mixing, most of which have focussed on the performance of axial and radial pumping impellers in agitated tanks. However, very little has been reported on the influence of a draft tube on the flow profile in such systems.CFD simulation of a stirred vessel centres on the way the impeller is modelled. Some of the most recent approaches to modelling an impeller are impeller boundary condition (IBC), snap shot, sliding grid (SG), multiple frame of reference (MFR) and inner outer (IO). The accuracy, with which these models predict experimental results and the corresponding computational demands, form the basis upon which the choice of an approach is made. Most of these approaches (IO, SG and MFR) address the key problem of the stirred tank modelling, namely, the simultaneous meshing of the rotating impellers and the stationary baffles. The MFR is computationally cheap and has been found to give predictions that compare well with experimental data.The CFD technique (code CFX4.4) has been employed in the present work to study the hydrodynamics in a mixing vessel stirred with either a Rushton turbine or a pitched blade impeller. The multiple frame of reference (MFR) approach has been used to model both impellers. A draft tube was used only in the Rushton turbine stirred vessel. The flow profiles for the impellers have been studied in three regions; below the impeller tip, at the middle of the tank, and near the liquid surface. The simulation results were compared with literature data obtained using a laser Doppler velocimetry in the three regions of the vessel, and it was found that the model predictions were better in the impeller region. There was a poor prediction of the experimental results in the region closer to the liquid surface; however, this was improved when the turbulence parameter (C2) in the k-e model was set to a higher value. The value of the impeller clearance at which the Rushton turbine generates an axial impeller type flow has been determined and it has been shown that, at this clearance, a draft tube can be used to enhance axial flow in a Rushton turbine stirred reactor."

Jan 1, 2003

By Clarence Zener

THEORETICAL considerations by one of the authors have led1 to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have veri-fied2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are pre¬sented to test this extended theory. The physical basis for the type of internal friction that is being investi-gated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so like-wise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal cur-rents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,3 and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal cur-rents accompanying transverse vibrations. Of more fundamental impor-tance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adja-cent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

Jan 1, 1968

By C. Augustus Carlow

THE subject which has been allotted to me is so vast and far-reaching that it is impossible to deal adequately with it in the time available. A complete survey would occupy the spare time of any one man for many years, whereas the time available to me is measured in weeks In the circumstances, I have been fortunate in securing the aid of several willing collaborators, and shall endeavor to re present such information as presently exists in published form, examine the situation critically in the light of present-day conditions, and arrive at certain conclusions' which I shall venture to put forward for your consideration No one who has lived through the past 25 or 30 years, and who has witnessed the amazing achievements of recent scientific research, would venture to deny the possibility that new sources of energy-may yet become available, or to prophesy to what extent these may be harnessed to the service of mankind So far as we can see, however, coal, as a source not only of power and heat but also of that wonderful range of derivatives that form the raw materials of so many industrial processes, must continue to play a vital role in our economic life It is the chief mineral fuel, exceeding all other mineral resources in value, production and demand In value coal overshadows the industrial metals, while of the sources of energy-coal, oil, gas and water power-the first named is the most important Thus, for example, in the United States, coal as a fuel (that is, as a source of heat and power) is still predominant, the figures of percentage of

Jan 1, 1947

By A Weber, L MacNamara, H Schreiber

Design and development of the world?s largest flotation cell was completed in 2002. This was the first 257 m3 flotation cell installed in the mineral industry and represents a major development in the design of larger flotation cells. This cell has a 50% increase in volume over the widely installed 160 m3 WEMCO® Smartcell? flotation machine. In the next few years it is anticipated that 257 m3 flotation cells will be incorporated into rougher-scavenger flotation circuits in many more world class copper sulphide concentrators. The prototype 257 m3 cell, No.250 Smartcell? flotation machine was installed at Minera Los Pelambres in the front of Row 1 in the existing rougher flotation circuit. This cell is followed by nine No. 130 Smartcell? flotation cells. After the successful development phase, this unit has been incorporated as part of a row of No. 250 Smartcell? flotation machines at Minera Los Pelambres. A key to the successful development of the equipment has been the emphasis placed on fundamental hydrodynamic scale-up criteria. Hydrodynamic factors include superficial gas velocity, water (pulp) circulation through the draft tube, and pulp mixing (distribution) characteristics. This paper will review the scale-up criteria of the No. 250 flotation cell, and present a case study of the in-plant equipment testing. The case study will document the metallurgical and hydrodynamic performance of the machine. It will also illustrate the economic benefits derived by incorporating larger flotation cells in a modern copper sulphide concentrator.

Jan 1, 2007

By Samuel Shallcross

THE principal function of the Bell limestone mine, of the American Lime & Stone Co., at Bellefonte, Pa., is to supply raw material to the company's modern rotary kiln plant at Bellefonte. Because mining costs are naturally higher than many open quarries with more favorably lying strata, it cannot compete, except to a limited extent, in the markets for road material and fluxing stone. In the broad sense, mining does have an advantage over the average open quarry when the end products are designed for and controlled by process and final inspection for the exacting demands of the industrial and chemical markets. Approximately 80 per cent of the output of the Bell mine is sold in the industrial and chemical markets. And as higher standards are set each year for construction and agricultural work, the remainder of the mine output goes to these two classes. Mining produces more fines than open quarries, and these fines are difficult to market; on the other hand, owing to absence of contaminating clay and impure rock, a greater percentage of the output of a mine is marketable. Because of the great production of fines, rotary kilns for lime burning are necessary when the stone must be mined. In 1921 the American Lime & Stone Co. operated 19 quarries and 72 lime shaft kilns spread over an area of 40 miles between Bellefonte and Altoona, Pa. At that time the line-production capacity of the 72 kilns amounted to approximately 700 tons per day. After 15 years the company operates three rotary kilns and six shaft kilns, with a combined output of approximately 500 tons of lime per day, concentrated in its single Bellefonte plant (Fig. 1). Its only stone-producing plants are now the limestone mine at Bellefonte and a construction-stone open quarry at Union Furnace, near Tyrone, Pennsylvania.

Jan 1, 1936

Today's conservation thinking is becoming increasingly polarised-a widening gap that could eventually be to the overall detriment of mankind, one way or the other. In one corner, stand the disciples of the untainted wilderness, moral protectors of the natural world who subscribe to the doctrine that the fragile balance of nature is threatened by man's very existence. On the opposite side of the ring, stands the relentless developer, with the megalomaniac notion that nature is purely there to serve humanity and civilisation, under the auspices of 'progress',

Jan 1, 1996

By Gottlieb P, Sutherland D, Jackson R

The QEM'SEM system for automated image analysis of mineral samples is described. Details of the equipment are given together with information on the methods of measurement. Finally some practical applications are described where QEM*SEM has been used for the solution of metallurgical Problems.

Jan 1, 1989

By Grieveson P, Rajakumar V

The reduction of an ilmenite concentrate with coal at 1000, 1050 and 1100¦C was investigated using thermogravimetry and X-ray diffraction, optical microscopy and electron probe microanalysis of the product. The effects of temperature, coal particle size, addition of ferric chloride and preheating of the concentrate in argon on the reduction kinetics and mechanism were determined. The rate of reduction increased significantly with temperature and was enhanced by the addition of the catalyst. The morphology of the iron was primarily determined by the degree of weathering of the particle. Significant coarsening of iron was obtained in the dense particles by the addition of ferric chloride. The sequence of reduction and the enhancement in the rate of reduction by preheating the concentrate in an inert atmosphere are discussed.

Jan 1, 1991

By A. Sutulov

The segregation process, an alternative to benefi-ciation of oxidized and mixed sulfide-oxide copper ores, is studied here with particular emphasis placed on time, temperature, and coke and salt percentage factors. The results show that in a segregated charge, the copper assay of the coarsest fractions normally is of the same order as the copper assay of the tails obtained from grinding and flotation of the same charge. This observation suggests the possibility of limiting or even eliminating the grinding step from the flowsheet of a segregation plant. The segregation process, which offers an alternative to beneficiation of oxidized and mixed sulfide-oxide copper ores, was discovered in 1923 by Moulden and Taplin1,2 who were attempting to apply the Perkins process3'4 to a Chilean ore from the Sagasca mine. After a number of investigations and pilot plant tests,'-' the segregation process became a successful industrial operation.'r9 The process aroused considerable interest in Chile because of the existance of large reserves of oxidized copper minerals which could not be treated by conventional hydrometallurgical methods because of the high consumption and prohibitive cost of sulfuric acid. During the last two years, the Mineral Dressing Dept. of the Institute de Investigaciones Tecnology cas of University of concepci6n (Chile) has carried out a test program on 23 different ore samples representative of the national territory. These tests were carried out on a semi-continuous and batch scale with a rotary, automatically controlled and gas-fired furnace (supplied by Bartlett and Snow, Fig. 1). The results of these tests indicate that out of the 23 samples 20 can be successfully treated by this process with recoveries of copper ranging from 85 to 95%.10,11 The purpose of this paper is to treat some specific problems related to the segregation process. TIME AND TEMPERATURE FACTORS Time and temperature of calcination play an important role in the segregation process. When moderate salt and coke conditions were maintained (each of reagents was added in the quantity of 1 — % wt), systematic testing easily demonstrated the influence of these two factors on segregation and flotation recovery. The pertinent results are summarized in Fig. 2. To determine what specific changes the segregation process made on the ore, the samples, segregated at 700°C for different periods of time and under standard conditions, were granulometrically analysed and

Jan 1, 1963

By William Bergeson

"BACKGROUND As of December 2015, there are roughly 475 road tunnels within the United States according to the most recent national tunnel inventory data compiled by the Federal Highway Administration (FHWA); whereas, there are more than 615,000 highway bridges on public roads. The FHWA estimates that tunnels represent nearly 100 miles of Interstates, State routes, and local routes. Tunnels are part of the national transportation infrastructure and represent a significant financial investment for the owner and, hence, the tax payers. Tunnels, that are not properly maintained, usually require more extensive repairs and consume more resources. Tunnels must provide safe, reliable, and effective transportation even as these structures age and deteriorate. Furthermore, tunnels generally remain in service for extended periods of time due to their very high construction costs. For example, many tunnels were constructed decades ago during two historic periods of highway system expansion; the first period correlated with the era of public works programs linked to the Great Depression of the 1930-40s; and the second period of expansion occurred with the building of the interstate highway system in the 1950-60s. As such, these tunnels are fast approaching 60 to 80 years old. Congress enacted the Moving Ahead for Progress in the 21st Century Act (MAP-21), which was signed by the President on July 6, 2012. This legislation followed a fatal tunnel incident on July 10, 2006 and a National Transportation Safety Board (NTSB) report1 that noted the importance of conducting regular tunnel inspections. MAP-21 authorized the Federal Highway Administration (FHWA) to develop a mandatory inspection program for all tunnels on all public roadways (Bergeson and Ernst 2015): To help safeguard tunnel users and to ensure reliable levels of service, the FHWA developed the National Tunnel Inspection Program (NTIP), which is comprised of the National Tunnel Inspection Standards (NTIS), the Tunnel Operations Maintenance Inspection and Evaluation (TOMIE) Manual, the Specifications for National Tunnel Inventory (SNTI), and the Manual for Bridge Evaluation (MBE). The data collected from the program will be stored in a National Tunnel Inventory (NTI) database. A comprehensive and refresher training program was also developed to help qualify and certify key tunnel inspection personnel to include the program manager and team leader."

Jan 1, 2016

By George McArthur

GEOLOGY One of the largest copper resources in North America occurs in the Bingham mining district, located 40 km (25 miles) southwest of Salt Lake City, UT. Anaconda's present contribution to the development of this resource is the Carr Fork mine. (Fig. 1, Bingham district plan map.) The Carr Fork story began about 300 million years ago when a thick sequence of sedimentary quartzite and limestone was deposited in the Oquirrh Basin. Subsequent earth stresses formed a series of west-northwest-trending overturned anticlines and synclines that were later offset by northwest-striking thrust faults and northeast-trending normal faults. (Fig. 2, Bingham district cross section.) About 38 million years ago the Bingham stock was intruded into some of the folds, resulting in the formation of porphyry ore in the intrusive, and fissure, replacement, and skarn ore deposits in the sediments. The Carr Fork skarns were formed preferentially in two limestone units, called the Yampa and Highland Boy, which average about 46 m (150 ft) in thickness, separated by about 76 m (250 ft) of quartzite. Copper mineralization consists almost entirely of chalcopyrite associated with pyrite and molybdenite in a gangue of garnet, diopside, magnetite, quartz, and carbonate. Molybdenum, gold, and silver are economic byproducts. (Figs. 3 and 4, indicated ore in plan and section.) EXPLORATION HISTORY The West Mountain mining district, of which Carr Fork is a part, was organized in 1863, after leaf-silver ore was discovered in the Carr Fork of Bingham Canyon. However, it was not until 1873, when the Bingham and Camp Floyd railroad to the town of Bingham was completed, that the mining camp flourished. Many small mining companies in the district were reduced, often through consolidation. By 1937 only the National Tunnel and Mines Co. was active in the Carr Fork area. In 1948 it declared bankruptcy, and was later purchased by The Anaconda Co. Anaconda conducted geologic investigations in the Bingham district until 1968, when a concerted diamond drilling program was initiated to fully evaluate the geologic potential of the Carr Fork area. The exploration program commenced with one diamond drill, but was enlarged to three drills following discovery of the first major ore intercept. Near completion of the exploration effort, large oil well rotary drills were used to drill to depths of 762 to 914 m (2500 to 3000 ft), after which the holes were completed by standard diamond drilling techniques. All holes were collared vertically, but considerable deviation occurred because of structure and rock conditions. Wedging and directional drilling were used to keep the holes on target and to provide multiple ore intercepts in the deeper holes. Geophysical surveys, in-

Jan 1, 1982

By N. J. Grant, C. F. Flo, F. B. Cuff

An investigation of the Ti-Cr system has shown the presence of a complete series of solid solutions in the ß phase, with a minimum in the solid us near 50 pct Cr. An intermetallic compound, TiCr2, forms during cooling from the ß solid solution. There is a eutectoid reaction at the low chromium side of the system. IN view of the recognition of the potentialities of titanium and its alloys as important structural materials there has arisen a need for a systematic investigation of various titanium binary diagrams. Of these, the Ti-Cr system was of particular interest because of the improved properties imparted to titanium by small chromium additions. A literature survey disclosed a partial constitution diagram that had been suggested by Vogel and Wenderott,¹ This diagram, shown in Fig. 1, is the result of work done on the Fe-Cr-Ti ternary system. Alloys containing less than 43 pct Cr were not investigated. In addition to this, a study of alloys in the Ti-Cr system was reported by McPherson and Fontana.² Adenstedt3 furnished a number of dilato-meter curves obtained from specimens containing 5, 10, and 15 pct Cr. Very recently, McQuillan4 submitted a proposed diagram covering the complete range of compositions between titanium and chromium. This diagram was in general agreement with the one described here. Experimental Procedure Sponge titanium (99.7 pct) and electrolytic chromium (Bureau of Mines analysis: 99.03 pct Cr, 0.40 pct Fe, 0.53 pct O2) were used for the initial determination of the system. Subsequent refinement of points, particularly for the low chromium side of the diagram, was accomplished by using iodide titanium and high purity chromium (National Research Corp. analysis: 0.050 pct C, 0.045 pct O2). The Ti-Cr alloys were prepared by melting 25 g charges in an enclosed, water-cooled copper crucible using a movable tungsten electrode. The atmosphere was helium, prepurified by first passing it through a drying agent and then through sponge titanium heated to 850°C. Particular care was taken to avoid any large scale segregation resulting from insufficient mixing of the components. Each charge was melted and kept molten for approximately 1 min, allowed to cool, inverted, remelted, and kept molten for an additional minute. In order to ascertain the amount of impurity pickup (oxygen and nitrogen) during the melting procedure, three iodide titanium specimens were melted in sequence and then checked for increased hardness. The specimens in the as-cast condition showed a relatively large hardness increase over the hardness of the as-received iodide titanium. The scattering on these readings was large. However, after the specimens had been homogenized at 840 °C for 2 hr and slowly cooled, the measured increase in hardness over the as-received titanium was small with a corresponding decrease in scatter. The reason for this hardness change is that in heat treating these specimens below the transformation temperature (885°C) there was a conversion from the as-cast structure to the more nearly equilibrium structure of the annealed specimen. The alloys were analyzed for chromium content and although the actual percentage was invariably low the deviation from the nominal composition never exceeded 0.6 pct Cr.

Jan 1, 1953

By George Burgess

1. Introduction.-THE methods of production of sound steel ingots have been described in several papers read recently before this Institute. It was thought by Director Stratton, of the U. S. Bureau of Standards, and ourselves to be of sufficient interest and importance, as a further contribution to this subject, to compare the properties of rails rolled in one mill according to American practice, from several types of ingot of substantially the same chemical composition but cast by several processes; and to compare in considerable detail the properties of an ingot manufactured by the Hadfield special-feeding process and one of the usual type for rolling into rails. We are greatly indebted to F. W. Wood, President of the Maryland Steel Co., who made this investigation possible by kindly placing his rail mill at our disposal; and he and his associates at Sparrows Point did everything possible to make the experiment a success, including the execution of several of the tests and analyses. 2. Classification and Manufacture of Ingots.-Of the ingots used in this investigation, eight were made in Sheffield and furnished by Sir Robert Hadfield, and one was made and furnished by an American steel company,' as a comparison ingot, and was supposed to represent the usual type of ingot from which rails are made.

Jan 2, 1915

By M. Liu

In-situ soil washing using surfactants shows great potential to remove hydrophobic organics from subsurface environment. Lab scale soil washing experiment were performed using Sodium Dodecylsulfate (SDS), an anionic surfactant, and anthracene, a highly hydrophobic compound. The results of this research show that solubility of anthracene increases linearly with an increase in SDS concentration above the critical micelle concentration. Furthermore, SDS can be effective in removing anthracene from contaminated sand.

Jan 1, 1992