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By P. Hajiani

Rare earth elements (REEs) are critical materials in many leading-edge technology products. However, REE separation outside China has remained a challenge in addressing environmental concerns of current production. The author has worked on a technique employing the emphasised variability in the electrophoretic mobility (μi) of REE for the purpose of REE separation. In continuation of the results presented in IMPC 2016 [1], this contribution summarizes the progress achieved in 2016 and 2017. The major goal was to increase the REEs concentration by a factor of 1000 and to attenuate the consequent drawbacks, specifically joule heating effect. Amphiprotic hydroxylic solvent was selected to replace water, which has a major impact on the complexation mechanism and buffer requirement. Non-aqueous media result in a significant drop in the specific molar conductivity of the electrolyte, whilst μi reduces several times only. Moreover, a quasi-steady state electrophoretic separation in conjunction with temperature gradient focusing is adapted to improve scalability.

By Boyce WH

Earthquakes are the most frightening and devastating natural phenomena known to mankind. They strike without warning and their consequences can be disastrous in terms of the toll of human life, financial crises related to the damage or destruction of man-made structures and the social and economic effects on a wide spectrum of the affected communities in the aftermath of the event. Such situations can be widely attested to by most areas around the Pacific Rim. Indeed, the threat of earthquakes is always imminent because of the geological-tectonic nature of the region as manifested by past experiences. It is patently obvious that earthquake occurrences are not only a geological hazard but also pose a serious social danger. When one considers the 19 September 1985 Mexico (Michoacan) earthquake (Mitchell at al., 1986), the necessity of continuing research is of paramount importance. An estimation . of earthquake risk encompasses both qualitative and quantitative aspects and demands a multidisciplinary research effort integrating seismology, tectonics, geology, enginering, sociology, economics, insurance and governmental policies (Bolt, 1978; Booth, 1984). These roles in mitigating such a hazard have been aptly discussed by Press (1985). A series of discussion papers based on an intergovernmental conference covering the whole scenario were published by UNESCO (1978). A comprehensive case history was provided through a workshop on the 1886

Jan 1, 1987

Computer applications in mine 'production' planning and control are concerned with the here and now. In production planning and control we are dealing with tactics as opposed to strategy. Our objective is to make the best of the situation in the short term, i.e., in a relatively fixed environment with relatively fixed plant, equipment, and labor. Environmental factors include not only the geology of the deposit but also market factors (such as price) and governmental constraints and regulations. Mine production planning systems are applied at the interface between concept and execution. Mine production control systems are applied at the interface between execution and revised operating practices or a revised concept. Fig. 1 shows the information flow that takes place regardless of whether the planning and control systems are manual or automatic. The feedback that results depends on the feedback mechanism that has been established, and this feedback can be enhanced by careful systems analysis and design. Chronologically, production planning and control activities support the last in the series of line functions that are ordinarily performed by mining companies. The first of these is exploration, the second is evaluation and development, and the third and final function is production.

Jan 1, 1979

By I. Mihajlovic

This paper investigates a potential method for arsenic removal from copper concentrates using hypochlorite leaching. The problems concerning pyrometallurgical processing of copper concentrates with high arsenic contents are discussed. A possible solution to the problem by leaching of natural enargite crystals with sodium hypochlorite under alkaline oxidizing conditions, with enargite converted into crystalline CuO and the soluble arsenic forming AsO43-, was experimentally investigated and results are presented. Kinetic parameters were calculated for enargite leaching, using a model-free approach. Advanced isoconversional methods were used to investigate the dependence of activation energy (Ea) on reaction rate (a). Keywords Enargite, copper concentrate, isoconversional method, kinetics, activation energy.

Jan 1, 2011

Technical graduate wanted for metallurgical. work in experimental laboratory of large New England manufacturing concern. A knowledge of metallography of steel is essential. Practical experience is desirable but not required. No. 305. Man familiar with precipitating with the diamond drill core to act as foreman. No. 311. Competent mining man to develop and take charge of mines in Peru. Property to be developed from start and equipped with thoroughly modern appliances to meet the increased production. Applicant must possess considerable mechanical ability and experience. No. 312. Engineers and assistant engineers in forest production for National Defense work for the duration of war. Laboratory work conducted primarily by experimental and research methods, embracing principally investigations of mechanical and physical properties of wood, processes for the preservation of wood against decay and other destructive agents, practical problems of pulp and paper industry, and other industries utilizing wood by chemical means or otherwise. Assistance in this department of Government is urgently required in order to obtain maximum benefits from the investigation. Salary $1860 to $3000 for engineers; $1200 to $1800 for assistant engineers. No. 313.

Jan 6, 1918

By M. Ide, K. Takemura, S. Taenaka, K. Shinzawa

"The laser characteristic is strongry dependent upon the stoichometry of forsterite (Mg2Si04) and YSO (Y2Si05) single crystals, because of change in the valency and occupied sites of doped Cr in the lattice so that mole ratios of Mg0/Si02 and Y203/Si02 in the above single crystals must be precisely analyzed. In this study ICP-AES was applied for analyzing the mole ratios. Emission intensities corresponding to Si and Mg or Si and Y were measured at the same time with internal standard method. Preparation of sample solutions, measurement conditions of ICP-AES and interferences by coexisting components were discussed, resulting in excellently precise detennination of stoichometry of the above single crystals.IntroductionIn conventional stoichiometric analysis of single crystals, the stoichiometry is detennined by analyzing each component separately with titrimetry and gravimetry techniques. On the other hand, by stoichiometric analyses using ICP-AES, emission intensities corresponding to components are measured at the same time with internal standard method. Consequently erros caused by variation of analytical condition are canceled out.Cr-doped Mg2Si04 and Y2Si05 syngle crystals are known as laser materials. The change of valency and occupied sites of doped Cr affect the characteristic of single crystal as aleser materials. The change of state of doped Cr.Stoichometric composition of Mg2Si04 is constructed by 2mole of MgO and 1mole of Si02, and Y2Si05 is constructed by 1mole of Y203 and 1mole of Si02. In this study, required analytical precision in component mole ratio is within an error of 0.0010 for Mg2Si04 (CV=0.05wt%), and within an error of 0.0030 for Y2Si05 (CV=0.05wt%) (Table I )."

Jan 1, 1998

By P. A. Laxen, P. J. van Staden

Alternative procedures for the recovery of gold from old sand dumps are discussed, with emphasis on the use of heap leaching. The modification of material to improve its permeability prior to heap leaching is not currently receiving much attention in South Africa. The channeling of solutions through heaps and the high consumption of reagents sometimes ascribed to heap leaching can, as shown by the results described in this paper, be lessened by desliming of the sand prior to heap leaching and the treatment of the resulting slimes fraction by agitation leaching and carbon-in-pulp. This combined procedure results in a higher overal recovery of gold. Alternatively, the sand can be heap-leached as it is after agglomeration with lime and cement, which improves the mixing and neutralization of the material, as well as lessening the probability of channeling.

Jan 1, 1988

By R Wheeler, E Stalenberg, J Lemon, M S. Crowther, D Lunney, K Ross

Gunnedah, in north-western New South Wales (NSW), including the town, the surrounding Liverpool Plains and the Pilliga forests to the west, are currently the subject of intense mining interest for coal and coal seam gas. Achieving positive outcomes for koala conservation on mined landscapes will require a sound grasp of koala ecology; and local knowledge of koala movements, tree choice and associated threats to the continued survival of koalas, particularly roadkill from increased mining infrastructure. This requires a research-oriented approach to testing ideas applicable to the long-term survival of koala populations. Our recent koala research in NSW has shown that, in 2006, Gunnedah had the largest koala population west of the Great Dividing Range, and the only population in NSW that was expanding. That prompted us to instigate a detailed study in 2008 - 2011 to determine, inter alia, whether the koalas were using trees that were planted in the 1990s to cope with rising soil salinity. Our GPS-tracking has shown that regrowth trees as young as ten years old can attract koalas. In 2009, the demise of about a quarter of the local koala population from an intense heatwave gave us a foretaste of how habitat and climate change interrelate at the landscape scale. We are now examining the optimal combinations of tree choice, and patch size and shape, for habitat restoration. This will be relevant to local coal seam gas and coal mine proposals, and ongoing mitigation actions. The Senate enquiry of September 2011 on the koala and demonstrated the intense public interest in the survival of this iconic species. Its subsequent listing for Queensland and NSW under the Commonwealth Environmental Protection and Biodiversity Conservation Act 1999 further raises its profile and obligations for management of koalas and their habitat. It will take considerable effort to manage the Liverpool Plains koala population for the next 50 years in the face of extensive land-use changes from mining, and the attendant threats from road kill, compounded by the new threat of climate change manifesting itself as an increased frequency of heatwaves and more severe droughts. This paper describes the research that underpins these conclusions, identifies some of the research approaches needed, argues for working strategically now, rather than try to patch up matters after the event, and presents a set of guides for environmental plantings. CITATION:Lunney, D, Lemon, J, Crowther, M S, Stalenberg, E, Ross, K and Wheeler, R, 2012. An ecological approach to koala conservation in a mined landscape, in Proceedings Life-of-Mine 2012 , pp 343-352 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By T. M. Gurr

In response to concerns voiced by local, state, and federal agencies and various environmental groups, the Central Florida Phosphate Industry and various governmental agencies have been investigating methods to accelerate the consolidation of waste clays generated during phosphate washing and beneficiation processes. The objectives of research efforts have been to reduce the storage volumes required for clay waste, accelerate reclamation and to return the land to approximate pre-mining topography. Government and industry research to accelerate waste clay consolidation has evolved two general methods: gravity thickening and chemical flocculation. Gardinier, Inc. one of the phosphate mining companies, evaluated the use of synthetic (polyacrylamide) flocculants as an alternate waste clay thickening method in response to mining conditions encountered at their Fort Meade Mine and the proposed North Hardee County extension of the Fort Meade mine (Figure 1). After considerable research and evaluation, the Alsthom-Atlantic Clariflux Super-flocculation method was chosen by Gardinier, Inc. as a method to seriously consider for use at their Fort Meade mine.

Jan 1, 1986

Grey River Gold Mining Limited (GRGML) has constructed and largely completed the commissioning of an alluvial gold dredge designed to recover gold from a low grade gold deposit in the Grey River Valley, New Zealand. The most important resource that GRGML has are the people who are employed by the organisation. The low grade of the deposit necessitates the requirement to operate the dredge at optimum efficiency, which in turn requires the work force to be of high calibre and continually motivated. The primary prerequisite for employment at GRGML is for employees to be receptive to new ideas and have the adaptability to develop new skills and apply those skills to the changing demands of the workplace.   A continually changing organisational structure is utilised to meet the needs of a changing work environment. The adoption of an innovative site employment agreement allowing for flexible working hours has aided the achievement of good employee productivity and attendance.   Employees gain a higher quality of life by working a roster pattern involving twelve hour shifts and a four day on, four day off pattern.   Employees and management are communicating very well and working together to achieve organisational goals which will ultimately benefit the employees, the shareholders, the local community and the mining industry generally.

Jan 1, 1989

By John L. Hill

Cutter roof failure is a specific type of ground control problem which frequently results in massive roof failure. It is a common occurrence in coal mines of the Northern Appalachian Coal Basin, causing delays in production and posing a safety hazard to mine personnel. The Bureau of Mines is conducting research on the causes of cutter roof failure to gain a basis from which to prevent its occurrence and to support such roof when failure does occur. Research conducted in a coal mine of central Pennsylvania has revealed a correlation between the occurrence of clastic dikes and formation of cutter roof failure. In-mine mapping of ground conditions showed an increase in roof failure in areas of high frequencies of clastic dikes. Rock pressure monitoring around clastic dikes registered the greatest amount of roof loading near the intersection of dikes with the rib. Load cells measuring horizontal pressure changes in the roof indicated that the greatest pressure changes were occurring perpendicular to entry headings when clastic dikes were present. Analysis of rock pressure monitoring shows that the roof behaved as two cantilever beams when severed by a clastic dike. Additional roof supports such as trusses and cribbing were found to effectively support the roof in areas of clastic dikes and prevent cutter roof failure. However, these methods were only successful when employed shortly after mining.

Jan 1, 1984

In the flotation of a copper ore, entrainment of fine silicate and iron sulfide gangue minerals resulted in poor copper concentrate grade. In the cleaning stage, rejection of these gangue minerals was particularly difficult due to severe mechanical entrainment when the rougher concentrate was ground to 10 µm. To reduce gangue entrainment, polymeric depressants were tested. The rationale being that with the use of such polymeric depressants that also possess flocculation power, not only minerals-to-be-depressed can be made hydrophilic, but their particle size can also be enlarged. In this manner both the "genuine" flotation and the mechanical entrainment can be reduced. An effective polymer to reduce entrainment of silicate gangue mineral in sulfide flotation was identified from bench flotation tests conducted on single minerals. It was then applied to the flotation of a copper-gold ore confirming the beneficial role of the polymeric depressant in the reduction of fine gangue entrainment.

Jan 1, 2007

By L. J. Howell, H. H. Kellogg

AN a previous paper' the phase diagram and vapor pressure of melts in the systems NaC1-ZrCl,, KC1-ZrCl,, and NaC1-KC1 (1:1 molar)-ZrC1, were reported. This note supplements the earlier paper with the results of electrical conductivity measurements on NaC1-ZrC1,and NaC1-KC1 (1:l molar)-ZrC1, melts. The design of the conductivity cell is shown in Fig. 1. Tungsten electrodes, A, were sealed into the Pyrex cell, C. That portion of the electrodes in contact with the melt was covered with a tight-fitting platinum cap. The electrodes were sur-

Jan 1, 1960

By Howard S. Avery

The wear resistance of an alloy in heavy mill liner sections may be quite different from that of the same alloy in small balls and other light sections. This fact was established by means of a well standardized laboratory test that was validated for ball mill service. The salient properties of mill liner alloys, including austenitic manganese steels, medium alloy hardenable steels, and abrasion resistance cast irons are described, critically compared, and quantitatively ranked in terms of mill liner service. Where they are tough enough the high-chromium and other martensitic cast irons (e.g. Ni-Hard) promise maximum economy, but their section sensitivity is a limitation. To overcome this an extensive research program studied over a hundred experimental alloys, ranking them for heavy section abrasion resistance by means of the laboratory test. Computer analysis of the results provided a parabolic formula in terms of composition, the apexes of the parabolas providing optimum wear resistance. From the extensive family of parabolas one apex was selected for intensive study in experimental liners, pilot plant production, development of quality controls, and finally full scale production. This is a 19% chromium iron critically alloyed with nickel and molybdenum and hardened by heat treatment. It has excellent resistance to various types of abrasion, but its chief advantage is in heavy mill liner sections, where it has about 25% better abrasion resistance than the best of the quality controlled chilled Ni-Hards. It is also tougher. After production problems were solved, a number of ball and rod mill tests were arranged on a guaranteed performance basis. Two of these, representing about 138,000 pounds of mill liner castings, have recently confirmed in service the superiority that was predicted by the laboratory tests.

Jan 1, 1969

By G. J. Trezek

The use of polysilicates for treating heavy metals in soils and mining sludges is discussed. Results of the treatment are given for soil contaminated in a metal scrap yard operation and for copper mining processing sludges. The types of metals of concern are arsenic, lead, copper, nickel, cadmium, and zinc. The application of the treatment is predicated on the mixture and relative concentrations of the metals as well as the material matrix. Reductions in soluble concentrations (STLC or TCLP) of one to two orders of magnitude can be achieved with relatively small additions of silicates and cementitious materials.

Jan 1, 1992

During underground mining, rock mass changes can occur as a function of the mining sequence and excavation processes. Mining-induced rock mass damage can occur due to redistribution of static stresses and the application of dynamic stresses from blasting and seismic activity. These rock mass changes can result in a degradation of strength of the bulk rock mass and the remaining rock surrounding existing excavations. Rock mass damage near existing excavations which lead to excavation-scale instabilities such as rock fall, excavation closure, or visible rock mass fracturing can detrimentally affect the safety and profitability of mining operations.The focus of the current work was the prediction and assessment of damage to mine infrastructure occurring in relation to the blasting of a sublevel open stope. The study case involved a 60kt stope located in a highly-competent rock mass at a large Australian sublevel open stoping mine. The mine infrastructure of interest for investigation included local stope access development, critical access and haulage development crossing a regional-scale fault, an explosives storage magazine and a ventilation return air raise. The methods used to predict or assess the blast-induced damage to each infrastructure element in response to stope extraction were:- intact rock strength testing,- discontinuity mapping,- linear-elastic static stress modelling,- blast-damage mapping,- near-field blast vibration monitoring and analysis,- geophysical assessment using inferred stiffness and wave velocity methods, and- post-extraction void assessment.The results of the detailed blast damage prediction and assessment program at the mine site have been discussed by the primary author elsewhere (Fleetwood, 2010). The current work will address blast-induced damage to mine infrastructure as a result of extraneous blasting vibrations from stope production blasting. A method for predicting the amplification of excavation surface motions from reflecting body waves will be discussed as well as the results of damage mapping around the study stope. The results of the damage mapping program identified blast-induced damage that occurred to the surface of the explosives storage magazine and local stope access development. No damage was observed at the main fault crossing or return air raise where higher vibration amplitudes were measured or predicted.

Dec 6, 2010

By M. L. F. Paullo, S. Cristian Mejia, D. Roehl

"Rock fracture simulation most often presents non-linear behaviour due to loss of material integrity and strain concentration in the fracture zone. These strains generate local instabilities that propagate to the global system of equilibrium equations, generating convergence problems of the numerical solution. Often, in such cases, analyses in the post-critical regime are unfeasible. To overcome the numerical difficulties associated with problems of stiffness loss in the post-critical regime control methods, also called continuation methods, are employed. Among them are the arc-length method, the energy control method and the indirect displacement control method. These methods are employed in conjunction with a Newton- Raphson scheme for the solution of non-linear systems of equations. However, depending on the system instability, convergence in not guaranteed even with very small increments. In the present work these control techniques are investigated in combination with cohesive elements to simulate rock fracture. The constitutive model employed with the cohesive elements represents stiffness degradation through a damage law, which leads to serious convergence difficulties as reported in the literature. Here the continuation methods mentioned are applied to a Mode I rock fracture problem and to hydraulic fracture simulations. The effectiveness of the different continuation methods is compared.INTRODUCTIONThe process of rock fracture induced by the fluid pressure is called hydraulic fracturing. The propagation of a hydraulic fracture is a complex process, which is basically defined by the mechanical deformation of the rock, the fluid flow within the fracture and the fracture propagation itself (Mokryakov, 2011). In the works of Bendezu et al. (2013), Chen (2012) and Carrier et al. (2012), vertical hydraulic fracture propagation is modeled by cohesive elements with traction-separation law. The softening behavior of rock in post-critical regime is demonstrated by experimental testing and is characterized mainly by high strains and low stresses (Crowder and Bawden, 2004). This nonlinear behaviour can arise due to material nonlinearity, such as micro-cracking and damage, leading to softening behaviour (Chandrakant, S.D., 2012). The cohesive fracture model considers in its formulation the softening behaviour that most rocks present in post-critical regime with propagation criteria."

Jan 1, 2015

By Y. Gordon

ABSTRACT A methodology based on a two-stage approach was developed for process technology selection. The first stage includes evaluation of available technologies, followed by shortlisting the best technologies based on mass and energy balance modelling, financial analysis, and risk analysis. The second stage involves detailed analysis using refined input data, mass and energy balance modelling, and capital and operating cost estimation, as well as a more detailed financial analysis. A case study covering the selection of ironmaking technologies for a company in the Russian Federation is presented to illustrate the critical elements of the methodology and the analysis process.

Jan 1, 2014

By G. Ansell, J. Weertman

G. Ansell and J. Weertman (Rensselaer Polytechnic Institute and Northwestern University, respectively) —The great increase in creep strength that you found in your indium-glass composites is quite striking. You ruled out a decrease in the dislocation source density as an explanation of the reduced creep rates. Could you tell in greater detail why you feel this is an inadequate explanation of the phenomenon. It appears to us that it is a reasonable one. Consider the spacing between the glass spheres in your composites. It is of the order of 10-3 cm. The spacing between dislocations in a (single-phase) annealed metal with a dislocation density of the order of 106 to 107 cm per cm3 also is of the order of 10-3 cm. Therefore it is not reasonable to expect that the arrangement of the dislocation lines is the same in the composite material as it is in pure indium. If the dislocation arrangements are different the density of the dislocation sources likewise will be different. Another way of saying the same thing is the following. The presence of the glass spheres reduces one of the dimensions of the metal phase to 10-3 cm. Thus the metal phase, in effect, is equivalent to a metal whisker or a thin metal film. These are strong because they have so few dislocation sources within them. T. D. Gulden and J. C. Shyne (authors' reply)—It is to be expected that the arrangement of dislocations in the indium-glass composites would be quite different than that observed in annealed pure metals. The dislocations probably exist primarily as segments connecting the dispersed particles. These segments and discontinuities at the very large area of particle-metal interface could act as dislocation sources. For this reason it was considered unlikely that the very high observed creep strengths were due to a low density of dislocation sources. A more likely explanation is that the distance a dislocation can glide is limited by the interparticle spacing. The particles averaged about twenty in diam and were less than 10 µ apart in the 40 pet composite. It seems reasonable to assume that a dislocation loop in a volume of metal surrounded by these relatively large particles would not bow out around them but would be restricted to the region between particles. A general expression for creep rate is given by the product of the dislocation source density, the average rate at which loops are generated from a source, and the average area swept out by a loop times the Burgers vector magnitude. Assuming that the area swept out is limited by the interparticle spacing and the rate of generation of loops is controlled by the rate of climb of loops over second-phase particles, as suggested by Ansel and Weert-men,9 a calculation of the dislocation source density may be made from the experimentally observed creep rates. The result comes out 10" to 10" per cm3 which seems reasonable in view of the assumptions involved. Thus it is concluded that the anomalously low creep rates that were observed were due not to a low dislocation source density but rather to a limitation on the area swept out by each dislocation loop.

Jan 1, 1964

By Alexander Malahoff

The most exciting frontier in Ocean Technology is represented by a new class of Marine Bioproducts, the source of which lies in marine microorganisms. The microorganisms include microalgae, bacteria and archaea. These organisms represent very diverse, adaptive life forms and in their metabolic processes use carotenoids, polyunsaturated fatty acids, ultraviolet blockers, as well as a wide range of enzymes that are pivotal in the production of new pharmaceuticals and nutraceutical products. These organisms cover a wide spectrum of ocean environments, from the shallow to the deep, from the normal to the extreme. The technological challenge is in the identification of candidate organisms, in the screening for valuable enzymes, and in the industrial production. A whole new range of collecting strategies involving submersibles, ROVs and in situ ocean floor instrumentation is emerging. New non-polluting industrial chemical processes involving the use of photobioreactors and extremophile bioreactors for breeding and monitoring these organisms in neo-farming technology is emerging. The commercial value of these candidate products is immense, as is the range of potential organisms. The dimension of this new industry is global. The Marine Bioproducts Engineering Center (MarBEC), funded by the National Science Foundation (NSF), has been established at the University of Hawaii. The vision of MarBEC is to develop a seamless research system stretching from undergraduate education to industry for the purposes of producing valuable marine bioproducts outside of the normal chemical factory production. MarBEC is uniquely and strategically placed in the Pacific to explore, find, and adapt highly bioactive marine micro-organisms found in the tropical ocean. We have watched the increasing need by the ever-

Jan 1, 2000