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By R. Neumann, O. Gomes, S. Gaydardzhiev

"Phosphorus in iron ores is considered as a deleterious component to iron making reflecting in cold shortness of the produced steel. The present study investigates the phosphorus migration pattern resulting from thermal treatment of an oolitic-type iron concentrate with and without additives. To this end focused mineralogical and microscopic observations were performed. The results have shown that roasting with alkaline additive drives phosphorus outside the hematite hosting mineral, however it remains evenly distributed inside the volume of the oolites. It penetrates inside the newly formed cementing phases of Al- Na-Si-Fe-type and also fills the interstices between the crystals. Other than phosphorus, aluminum, calcium and iron tend also to migrate towards the amorphous-type cementing phase. Finally, the possibilities for P removal by means of magnetic separation and acid leaching of the roasted concentrate were evaluated. The obtained final product presents a standard iron concentrate suitable for steelmaking with its phosphorous being dropped from 0.71% to 0.05% and iron grade of a nearly 66% being reached. INTRODUCTIONSignificant proven reserves of iron ores are still not exploitable due to lack of an economically viable and efficient technology for removal of phosphorus. Among them are the oolitic iron ores with high phosphorus which are estimated to nearly 377 billion tons (Hernandez et al., 2012). Phosphorus is a deleterious component giving a cold shortness to steel and often is penalized if exceeding 0.07%. Most of the high-P iron ores are considered refractory since phosphorus is finely disseminated and is evenly met as phosphate groups inclusions inside the limonite structure. Studies on inclusion of phosphorus in artificially synthesized goethite have shown that it is adsorbed as [HPO4]2- groups bridging the adjacent iron ions (Parfit et al., 1975). The high-phos iron ore originating from Lisakovsk deposit, Kazakhstan presents a similar mineralogical issue because the quantity of P, met as solid solution, is substantially higher than the one in P-containing minerals. A potential reason for that is the ore body formation process from the slow deposition of iron-rich precipitates together with clastic erosional sediments in rivers. There is significant quartz and clays inside and around the oolites. The deposit contains about 1.7 billion tons of measured and indicated reserves at 35–41% iron and 1.1 billion tons of inferred ore have been delineated possessing nearly the same chemical composition (Golubovskaya, 2003; Kokal et al., 2003)."

Jan 1, 2016

ABSTRACTFor the binary system copper-lead two relationsEquation 1andEquation 2have been derived for the activities of copper and lead at compositions and absolute temperatures within the liquid region of the phase diagram.These relations give, with greater accuracy than is given by previously published relations, the activity-composition temperature variations for all regions of the phase diagram of interest to metallurgists.These relations are essentially simple forms of the Margules equations but with linear temperature dependence applied to their coefficients. This has been done in such a manner that a phase diagram obtained from these relations agrees well with the data available for this system. The methods of obtaining the relations and constructing a phase diagram from them are both given in detail. The enthalpies and entropies of mixing are compared with those derived by other methods.

Jan 1, 1971

By H. M. Howe

PART I. INTRODUCTORY. § 24. INTRODUCTION.-This paper discusses the chief existing data as to the temperature, in iron-carbon alloys, of Ae.3, the upper limit of the transformation range when in equilibrium, as distinguished from Ac3, the temperature at which the end of the transformation is noted in heating up, and from Ar3, that at which its beginning is noted in cooling down. The former is in fact carried above Ae3 and the latter below Ae3 by lag. I touch incidentally on the influence of manganese on Ae3 (§ 29, p. 1102). The sections, tables, and illustrations, are numbered consecutively with those in the accompanying papers by Howe and Levy on Determination of, the Position of Ae3 in Carbon-Iron Alloys, and by Burgess, Crowe, and Rawdon on Thermal and Microscopical Examination of Professor Howe's Standard Commercial Steels, to which the present paper forms a sequel. § 25. The contradictoriness of our present evidence is shown by grouping it together in Fig. 14. For instance, both Goerens and Meyer (Series 2) and Meuthen (Series 12) used practically stationary temperature, and thus reduced the influence of lag very greatly; yet Ae3 for 0.32 carbon steel according to the former investigators is 894°, but according to Meuthen it is at or below 770°, a discrepancy of 124° or more. In view of our ability to measure these high temperatures within a few degrees, the existence of such a discrepancy is as unwelcome as it seems needless. I attack the thankless task of bringing some order out of this chaos.

Jan 6, 1913

By AIME AIME

ON THE occasion of the eightieth birthday of Captain Robert W. Hunt, the Iron and Steel Committee of the Institute, desiring to commemorate the great contributions made to the steel industry by Captain Hunt during his long career, conceived the idea of a Hunt Medal to be awarded annually by the Institute for meritorious contributions to the art of making steel. The project was received enthusiastically by all to whom it was proposed, especially by Captain Hunt's partners and employees who considered it their right, and asked for the privilege of -. - raising the necessary funds within their own circle. This was agreed to, and the Institute has received from them $7500 as an endowment fund to provide an annual award, and $1000 for the expenses of providing of medal.

Jan 1, 1920

By Charles B. Carpenter

[The Bureau of Mines selected Anahuac for a petroleum-engineering study because it is one of the notable fields of the Gulf Coast region. It is outstanding because the producing for is very thick; every modern technique of drilling' and development has been applied; complete records of all operations,, including detailed subsurface information have been kept; the field has been developed systematically; and every effort has been made to utilize the reservoir energy efficiently Data and information pertaining to the development anal operation were collected, compiled, and studied by the writers as if the field were under single ownership. The chief aim-of the stud,, was to increase the accuracy of the existing methods of estimating reserves by applying all the data collected during the modern development of an oil-field, These scientific aids include coring; electric logging; micropaleontology determinations of porosity, permeability of oil-bearing sands, and their connate water content; subsurface sampling of the reservoir oil; and depth-pressure measurements. Because the reservoir structure in the Anahuac field is extremely complex, special attention was given to methods of calculating the reservoir volume.]

Jan 1, 1941

By F. Ebbutt

The copper-bearing waters now treated successfully at Britannia for the recovery of their copper content are almost entirely derived from what is known as the Fairview mine; this was the first extensive copper producer of the Britannia ore-bodies, and consisted of a number of almost parallel veins, carrying good copper values, the ore consisting of chalcopyrite and pyrite in a quartz gangue. These veins occur in what is known as the ?Britannia shear zone' (Schofield, S. J., G.S.C. Sum. Rept., 1918, Pt. B), developed for roughly five miles in a roof-pendant in the well-known Coast Range batholith. This .pendant is made up of Palxozoic rocks known as the 'Britannia Formation' (LeRoy, O.E., Portion of Main Coast of B.C. and Adjacent Islands; G.S.C. Memoir No. 996, 1908). These consist of dark carbonaceous slates, quartzites; and tuffs or basic flows, and within them are large quartz porphyry siJls. These Britannia rocks are sheared and altered, the resultant rock being a fissile quartz-sericite or quartz-chlorite schist. The mineralization invariably occurs in this chlorite schist, which in the more productive areas has mottles or blobs of chlorite developed. A narrow, though persistent, band of grey slate forms the footwall of the productive portions of the shear zone.

Jan 1, 1928

By Sadi Medina

As it is characteristic from Custom Smelters, ENAMl Las Ventanas Smelter has to deal with different qualities and quantities of mining products from about 70 suppliers, that contain a variety of impurities that would be harmful for copper production. In order to increase the smelting capacity, an oxygen plant has been running since September of 1990. Moreover, to improve the environmental conditions, a new sulphuric acid plant started up to neutralize the metallurgycal off-gases from the Teniente Converter and partially from the Peirce-Smith converters. Based on the on-line operation among the reverberatory furnace and the Teniente Converter using oxygen enriched air to produce high grade matte, most of the volatilizing impurities, mainly arsenic, are collected as discarding compounds in the gas cleaning system of the acid plant. This paper describes the continuous performance of the Teniente Converter with acid plant, the results attained, the operation problems and how they were solved. The impurities distribution achieved in this process is also included.

Jan 1, 1993

By John P. Hager

This study investigated the formation of vapor complexes between aluminum chloride and the chlorides of iron, titanium, and silicon. For the A1-Fe-C1 system the proposed gaseous complex species is Al2Fe2C112(g), which is formed according to the reaction 2A1C13(s) + 2FeCl3(s) = Al2Fe2C112(g) The corresponding free energy expression was determined to be ?G° = 38091.49 - 71.45 ? T 400 < T < 600°K The vapor composition above AlC13 melts contaminated with FeC13 was calculated. In the Al-Ti-CI and Al-Si-Cl systems the proposed vapor complex species are Al2Ti2Cl14(g) and Al2Si2Cl14(g) respectively. Free energy expressions were estimated for the formation of the two complex species. Again, the vapor composition above AlCl3 melts contaiminated with TiCl4 or SiCl4 was determined. The results of this study were compared with previous studies on the three systems.

Jan 1, 1980

By Y. Zedan

Cutting fluids play important roles during machining, including the reduction of friction and temperature. Using a cutting fluid, however, degrades the quality of the environment and increases machining costs. The aim of the present research work is to study the effect of cutting fluids and their interactions with cutting parameters on the quality of holes during the drilling of 6061-T6 aluminum alloys. The lubrication types and modes investigated are dry machining, flood lubricant machining and minimum quantity lubrication machining (MQL), while the part quality criteria include the surface finish, the dimensional accuracy, and burr forms and sizes. A scanning electron microscope (SEM) was used to investigate the formation of built-up edges (BUE) in the drill flutes as well as the surface texture of drilled holes. It was found that dry machining and MQL machining can produce parts having quality levels comparable to those obtained in wet machining, when using the optimal cutting conditions.

Jan 1, 2011

By C. A. Schempp

STUDY of the adaptability of Tintic Standard ores to concentration dates back to somewhat before January, 1921, when the chloridizing mill at Harold, Utah, was put into operation. The operation of this mill has been fully covered in the TRANSACTIONS (Vol. 73). The process consisted essentially of a chloridizing roast followed by a percolating leach with a nearly saturated solution of common salt, acidified with sulfuric acid; precipitation of silver on sponge copper, and of copper and lead on tin-plate cuttings. This mill was built to treat the low grade siliceous ores having an average content of

Jan 1, 1933

By Bluhm S. J, Feio L, Ramsden R

A new mining area at the Vaal Reefs gold mine is to have a shaft. system which will extend to a depth of 4 200 m and will require 130 MW of cooling. A novel feature of the proposed cooling system is a large underground air cooling installation in which an ice slurry is sprayed into the ventilation air. The design of the ice slurry bulk air cooler, in the form of counter.flow cooling towers, is discussed. Comparative thermal tests with cold water and ice slurries (with ice mass fractions up to 22 per cent), were carried out in a 5 m high test tower. The presence of the ice in the water spray increases the resistance to heat flow and reduces the overall thermal characteristics of the air cooler by 8 per cent. Notwithstanding this, the use of ice slurries is indeed beneficial in terms of overall costs. It is concluded that a 25 MW air cooler should use 410 kg/s of ice slurry with a 10 per cent ice mass fraction to cool 550 kg/s of air which is 75 per cent of the total air flow rate.

Jan 1, 1988

By lchimura. R. .

Japan Oil, Gas and Metals National Corporation (JOGMEC) and Centro de Investigation Minera y Metalurgica (CIMM) commenced a five year project from 2001 to modify the treatment of the furnace dust from Teniente converter containing harmful elements like arsenic and lead. The project was supported by Japanese and Chilean governments, and a demonstration plant was installed and operated at Las Ventanas Smelter and Refinery (Division Ventanas CODELCO). The basic and detailed engineering was made by Mitsui Mining and Smelting Co., Ltd (MMS) based on the joint study among JOGMEC, CIMM and Division Ventanas CODELCO. Arsenic in flue dust is lixiviated by sulfuric acid and fixed as crystalline ferric arsenate, where leachability of arsenic will be lower enough than the regulation, 5mg/I by TCLP (Toxicity Charactaristic Leaching Procedure) of USEPA. On the other hand, the recovered copper from the dust will be fed to the copper production process at Las Ventanas Smelter and Refinery, while zinc will be recovered as the exportable product. As introducing the crystallization and growing stage, the stable crystalline ferric arsenate formation can be achieved under the normal pressure.

Jan 1, 2007

By Albert Tasias, Daisy Jiménez

La gestión de riesgos mediante barreras, conocida como metodología Bow Tie, permite acompañar el día a día de las operaciones y está adquiriendo mayor relevancia debido a su forma sencilla de describir los peligros a través de un diagrama, en donde se pueden ver las causas y las consecuencias. Asimismo, lo interesante de la metodología son las barreras, que evitan que el peligro o las consecuencias se materialicen, para lo que cuentan con un responsable que debe gestionar y reportar su desempeño. Este trabajo realiza un análisis de la metodología Bow Tie, a través de un glosario de términos, la descripción del proceso, su aplicación actual y las ventajas y desventajas asociadas.

Sep 20, 2019

By Kent Zehr

Suncor Energy Inc. is an integrated producer and refiner of oil and gas headquartered in Calgary, Alberta. The bulk of revenue comes from the Oil Sands Group (OSG) operating in the McMurray formation of the Athabasca Oil Sands. Located some 25 kilometers north of Fort McMurray, Suncor OSG began life in 1967 as Great Canadian Oil Sands, the first operator to successfully enter commercial production of synthetic crude oils from the area. For most of the last decade, dramatic growth has been the standard mode of operation for Suncor OSG. Production of synthetic crude first reached 100,000 barrels per day in 1997 and less than five years later is averaging in excess of 200,000 barrels per day. Within this dynamic organization, Suncor Extraction is the business unit that processes run-of-mine ore into clean diluted bitumen for Upgrader feedstock. Extraction also delivers and places the barren sand and process affected water into tailings storage in one of several ponds from which water is recycled to support the various processes. For reference purposes, Extraction on a typical day currently receives more than 400,000 metric tons of oilsand ore, which is all processed to water based slurry for separation in one of two extraction plants. Separated tailings are disposed of as a slurry and the cleaned bitumen froth is diluted with naphtha and sent to tankage for storage until required by the Upgrading Unit. As a consequence, on a typical day Suncor Extraction pumps more than 1,000,000 tonnes of aggressive slurry into and out of the two extraction plants.

May 1, 2003

By Joseph O. Cook

I know this is, at best, a frustrating period for the coal mining industry. About 20,000 miners have been laid off, mostly in the Appalachian and mid-western areas, and several mines are working less than 5 days a week; however, the industry is experiencing modern growth and, at least, there is the potential for future growth. The coal industry is probably only operating at about 80 percent of its present capacity, and it is certainly capable of helping this country solve its energy problems. Growth, as a rule, does not come easy, and growth in the coal industry is no exception to this rule. Many formidable challenges have to be overcome. As we all know, mining relies very heavily on the earth sciences, which have advanced significantly in the past few years, but we are always working in a changing environment which in most cases is a hostile environment. Large quantities of material are quickly extracted and rapidly moved in, generally speaking, a very confined area. The very nature of the mining business directly and constantly impacts our environment during this period in which the Nation and the world has become increasingly smaller and more concerned about protecting our environment. In addition, growth brings about an expanding work force which is increasingly younger and less experienced.

Jan 1, 1980

By Yongbin Yang

Cathodic reduction of oxygen is a process involved in many fields. As is well known, the mechanism of oxygen reduction usually varies considerably with electrode substrates. In this paper, cathodic reduction of oxygen on gold electrode was studied by linear sweep voltammetry with regards to cyanide leaching of gold. As the results shows, the electron transfer number increases as potential shifted negatively and decreases as pH value increases. Besides, the increment of electron transfer number as a function of potential decreases when pH value increases. When pH increases to 13.0, the volt-ampere curve exhibits a relative flat section with currents approximate to the limit current density of a 2e process. By varying dissolved oxygen concentration, the electron transfer number was calculated for pH11.0 at different potentials, the results being 2.387e, 2.732e, 2.982e, and 3.227e at, -0.35V, -0.40V, -0.45V, and 0.50V, respectively. The calculated current densities are in good conformity with measured results.

Jan 1, 2010

By Shoji Taniguchi, Lifeng Zhang, Kaike Cai

"In the present paper, based on the two-phase (Eulerian-Eulerian) model, the 3D fluid flows in gas-stirred systems, i.e., air-stirred water vessel and argon-stirred liquid steel ladle, are simulated. In the Eulerian-Eulerian two-phase model, gas and liquid are considered to be two different continuous fields. The phases are assumed to share space in proportion to their volume fractions. The exchange between the phases is represented by source terms in conversation equations. Turbulence simulated by the k- e model is assumed to be the property of the liquid phase. The following effects of mathematical treatments and operational factors on the fluid flow are discussed, such as interphase drag force, turbulent model, the size of bubble, and gas injection mode.Some interesting results are derived. Except the interphase drag force, the interphase lift force should be taken into accounted in order to exactly simulate the fluid flow in gas-stirred systems. Suitable turbulent model and drag coefficient have effect on the mathematical simulation. Injecting small bubbles can realize a well mixing flow condition. The distance between the two gas-injection nozzles has effect on the fluid flow."

Jan 1, 2000

By Richard C. Barth

Fourteen field plots were established at active coal mines in the Northern Great Plains. A wedge was cut into spoil and backfilled with soil; soil depth ranged from 0 to 152 cm over a linear distance of 15 m. Perennial grasses were planted in each plot, and production was measured from 1978 to 1981. Based on spoil traits and biomass response patterns, plots were grouped into four types. Spoil for Type I plots was near neutral, slightly saline, nonsodic, and clay loam in texture. Perennial grasses reached maximum production with approximately 50 cm of soil depth. Spoil for Type II plots was characterized as sodic and fine textured; soil-depth requirements averaged 83 cm for maximum production. Spoil for Type III plots was characterized as strongly acid, and production increased throughout the soil depth range tested. Spoil for Type IV plots was similar to soil in chemical and physical traits; there was no production response to soil depth. Soil depth requirements were also dependent upon precipitation and species. In general, soil-depth requirements decreased in dry years and with use of introduced species. An appendix contains data evaluations on an individual plot basis.

Jan 1, 1982

By I. R. Jonasson, R. W. Boyle

"Current interest in the distribution of mercury in the natural environment comes from quite different, though not unrelated, sources. Mercury has long been an important metal in many industries and has, therefore, been much sought after by mining interests. The presence of mercury traces in the various media of the natural environment, namely soil, rock, air, water and vegetation, is exploited by geochemists not only to find mercury and polymetallic ore deposits, but also to find most other types of economic metal mineralization. More recently, however, mercury has caught the attention of health authorities and environmental scientists who are becoming increasingly concerned over the hazards of mercury wastes and the danger these present to the environment and to man. It is now apparent that the trace quantities of mercury, considered so important and helpful to exploration geologists, can be concentrated in the biosphere to such levels as to present considerable problems for ecologists. This article summarizes most of the available data on mercury contents in materials of geological interest and presents average normal values for rocks, ores, minerals, soils, sediments, waters and plants. The geoch.emical cycle for mercury in nature is presented and the mechanisms of mercury migration around the cycle are discussed."

Jan 1, 1972

By AIME AIME

LOCAL COMMITTEES. EXECUTIVE.-W. A. Lathrop, Chairman; R. V. Norris, Secretary; S. D. Warriner, Treasurer; Irving A.. Stearns, W. J. Richards, H. S. Drinker, C. D. Simpson. GENERAL RECEPTION.-Irving A. Stearns, Chairman. Archibald, James, Jr., Pottsville. Lawall, E. H., Wilkes-Barre. Ashley, H. H., Wilkes-Barre. Lentz, W. 0., Mauch Chunk. Ayres, WV. S., Hazleton. Lewis, Albert, Bear Creek. Beard, J. T., Scranton. Loomis, W. H., Jeddo. Bridgman, J. C., Wilkes-Barre. Markle, Alvan, Hazleton. Bunting, Douglas, Wilkes-Barre. Markle, John, Jeddo. Chase, F. M., Wilkes-Barre. Neale, J. B., Minersville. Coroner, Eli T., Scranton. Norris, R. V., Wilkes-Barre. Cote, E. B., Jr., Drifton. Oliver, Paul A., Oliver&apos;s Mills. Davies, W. H., Hazleton. Owens, W. D., Pittston. Davis, H. G., Dorranceton. Pardee, 1. P., Hazleton. Dodge, W. F., Wilkes-Barre. Quin, R. A., Wilkes-Barre.

Jul 1, 1911