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By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013

The processes by which particles and bubbles interact capture many of the central concepts of colloid science and hydrodynamics. This area of research embraces hydrodynamics, interfacial(including capillary) forces, particle and bubble behaviour and solution chemistry. In this review, we discuss collision, attachment and stability efficiencies. We deal with the identification of a flotation ?domain?, the deformation of a bubble surface upon interaction with a solid surface, the kinetics of three phase contact line expansion and the determination of attachment efficiencies through to the direct measurement of bubble-particle interaction forces. We have recently carried out a test of collision theory where the latter embraces both inertial and centrifugal forces. The real challenge is now to quantitatively describe the behaviour of real systems and to incorporate a reliable description of the behaviour of particles in flotation froths. The approach described is very robust when applied to flotation, both from qualitative and quantitative points of view, providing an intellectual foundation for understanding this complex process in separation science and technology.

Jan 1, 1999

By T. Valentine

The SX-EW operation at Morenci includes three electrowinning tankhouses. Stainless cathode blanks require the use of insulating plastic edge strips, which typically have a service life of 1-2 years, therefore, regular replacement of edge strips is a fact of life in tankhouse operations. The largest tankhouse, Central, converted from starter sheets to stainless steel cathode blanks in 1999. During the first year of stainless blank operation at Central Tankhouse, the initial installation edge strips started failing at accelerated rates and there was a sudden need to replace edge strips and repair between 350 and 400 cathode blanks per day. This paper details the design and building of cathode repair shops at the Morenci tankhouses, including choice of equipment and layout design. The objective was to increase efficiency through the use of cathode handling equipment and flow of material.

Jan 1, 2002

By A. Delgado-Jiménez, O. J. Restrepo-Baena, G. Aristazabal

"Mining industry as a source of raw material is essential to society however, it lacks of good reputation due to the type of management historically applied to many of its social and environmental impacts. It is argued that this situation has hampered the obtaining of social license to operate of a lot of mining projects around the world. The last considerations are very common in Latin American countries. As a result, the mining sector has understood that the viability of the business long term is associated with more profit for the shareholders but also with activities that improve the livelihoods of local communities, enhance the capabilities of local governments and preserve the ecosystems around the projects. Nevertheless, recent studios have shown that most of the current advances to incorporate sustainability concepts in mining have been mainly focused on control and the prevention of environmental and social impacts of extractive activities. Thus, contributing to the development of territories around mining projects constitutes a fundamental aspect of the business competitiveness through reducing cost and risks of stopping projects, innovating new ways of relationship with stakeholders, improving the level of reputation of the industry as well as its position in the market. However, this contribution requires formal strategies and models that enable companies understand the different resources in the territories where their mining activities are developed and those resource transformations, in order to establish the best way to articulate the project with the territory, pursuing an effective contribution to its development, truly sustainable over time even after the mine closure. CONTEXT Currently in the world but especially in developing countries such as Latin Americans, different stakeholders are increasingly vigilant of how mining companies carry out their activities in terms of socio-economic and environmental management of territories, not only for its impact on the livelihoods of the communities that inhabit them, but also because many demanders of raw materials -both countries and companies- have set sustainability standards as a prerequisite to establishing business relationships with mining companies, such as the recently declared Sustainable Development Goals by 2030 (UN, 2015). Accordingly, decide underinvest or not to invest in sustainability issues carries risks for mining companies. However, invest much in the wrong way may involve the same risks. Managers are concerned to ensure profits, and therefore they decide carefully how to invest in the areas of production, R & D or marketing. Likewise, they should think strategically about investing in initiatives related to sustainability. This if they really want that those investments in fact help to improve the competitiveness of the company. The mining industry benefits from natural capital that extracts, so it should implement strategies that lead to remunerate such benefit to the territories (Almaguer, 2007). One option is through the transformation of natural capital in other types of non-existent capital or poorly developed in their areas of influence. In this way, the value generated by the extraction of underground resources is shared and additionally contributing to improving the quality of life of the communities. Historically, mining industry has been into several problems to achieve this, which represents one of the aspects that has most influenced the current reputation of mining industry in some regions of Latin America. Many communities, local governments and civil society organizations continue to associate this activity with the destruction of the social fabric and ecosystems in the territories, and their opposition against companies working in the areas has led to affect the operational continuity of many projects (Hamann, 2003; Prno and Scott, 2012; Slack, 2012)."

Jan 1, 2017

By Ramanathan Ayothiraman, Anurag Singh

"An experimental program was undertaken to investigate the effects of randomly distributed basalt fibre on the index and engineering properties of Dhanori clay and to compare its performance with the properties of soil reinforced with polypropylene fibre. In the present investigation, 7 groups of soil samples were prepared at four different percentages of basalt fibre and polypropylene fibre content and tests were done for measuring their consistency limits, compaction characteristics, unconfined compression strength and consolidation properties. The test results indicate that the inclusion of basalt fibre in Dhanori clay resulted in significant improvement in properties. The improved properties are not comparable with polypropylene fibres, nevertheless, the improvement by basalt fibres is able to meet the typical design target values and the cost is very much less than synthetic fibres. More importantly, basalt fibres are environment friendly.INTRODUCTIONConstruction of buildings in low lands with engineered filling, flexible and rigid pavements for highways/airfields, and embankments for highways/railways are also part of major infrastructural development in addition to construction of tall buildings, bridges/fly overs, major dams and underground structures. The later projects require different improvement techniques than that is adopted in the former projects. Ground improvement techniques such as use of reinforcement inclusions within soil found as an effective and reliable technique. Especially such modification by fibre reinforcement, is primarily possible in engineered filling, pavements subgrade and embankments, where surface mixing is easier; and may not be feasible when stabilization/modification is required for deeper depths. In comparison with conventional reinforcement using geosynthetics (strips, geotextile, geogrid, etc.), there are some advantages in using randomly distributed fibre as reinforcement. In past few decades, the discrete fibres are simply added and mixed randomly with soil, in much the same way as cement, lime, or other additives.There are several studies (Ziegler et al. 1998; Puppala et al. 2000; Bei-xing et al. 2004; Cai et al. 2006; Tang et al. 2007, 2012, 2016; Abdi et al. 2008; Viswanadham et al. 2009; Le et al. 2015) that investigated the behaviour of polypropylene fibre-reinforced soil and reported that an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. The length of fibres had an insignificant effect on soil characteristics, whereas fibre contents proved more influential and effective. A study on rubber fibre conducted by Hambirao and Rakaraddi (2014) mentions that tensile cracking of clays can be improved with the inclusion of short rubber fibres, optimum fibre content was about 15 % of weight of soil. Several experimental studies (Babu et al. 2008; Chaple and Dhatrak 2013; Vibhakar and Nahta 2014; Soundara and Senthilkumar 2015; Goyal et al. 2015; Jayasree et al. 2014, 2015) were conducted on coir fibre-reinforced soil and concluded that it helped in reducing the swell potential and 1% fibre by weight of the soil almost doubled the CBR value. Martins et al. (2015) found that 4% of sisal fibre by weight of the soil reduced the visibility of cracks. Pillai and Ayothiraman (2012), Ayothiraman et al. (2014) and Sahu et al. (2016) have demonstrated that human hair fibres can be used to improve the properties of both fine grained and coarse grained soils."

Jan 1, 1900

By John S. Berber

Olefin and paraffin mixtures (C10-C16 and C10-C22) were separated from low-temperature lignite tar by urea adduction and sulfated to yield secondary alkyl sulfate detergents. The C10 ?C16 secondary alkyl sulfate showed a 99.3 percent biodegradability, and the C10-C22 fraction showed a 96.8 percent biodegradability, exceeding the required standard of 80 percent for the biodegradability of anionic detergents in washing and cleaning compounds. Chlorination of paraffins yielded a detergent of 93.2 to 93.4 percent biodegradability.

Jan 1, 1968

By Rangaswamy. K, Naga Sivaji

A stone column is one of the most commonly employed methods of ground improvement techniques. This method used to increase the strength, decrease the compressibility of loose granular and finegrained soils. Also, it accelerates the consolidation in clays and reduces the liquefaction potential of sands and silt soils. In general, the stone column contains 15 to 75mm stone aggregates. In reality, it is not easy to avail the natural stone aggregates due to unavailability in locally nearby places. Present work aims to replace the stones partially or entirely by scrap tyre chips as an alternative material. The utilisation of recycled tyre chips in ground improvement is an environmentally friendly solution and avoid the disposal of tyre chip waste in large pits. Model tests conducted on marine clay with encased end bearing stone columns (ESC) constructed with a mixture of stone aggregate and tyre chips with sizes 4.75 to 10mm. The column diameter is 75 mm, L/d ratio maintained to 5.3. Non-woven geotextile wrapped encased stone column has introduced in the soft marine clay model. Encasement prevents the lateral squeezing of aggregates into the surrounding clay and protects the drainage function of the stone column. A set of load-settlement tests were conducted on both the clay model and clay model treated with the stones-tyre chips column. The model was loaded by the tri-axial loading frame. Shear strength parameters of stones and tyre chips were determined by large size direct shear tests. Model test results are concluding that the load-carrying capacity of the clay is improved significantly after installing the stone column in it. The encasement increases the load-carrying capacity and stiffness of the ordinary stone column. It is also proved that the stone aggregate could be replaced partially by tyre chips up to 60% without a significant reduction in its performance.

Nov 1, 2022

By G Ferguson a, P Carrasco, P P. A Dowd

International codes of practice offer broad definitions with respect to the classification of resources in terms of risk. Specific guidelines and protocols, to analyse sample data, carry out geostatistical appraisals, develop geological models and finally estimate and classify resources, are not addressed. Neither are detailed requirements for engineering mineable reserves from estimated resources. In addition, international codes of practice fail to distinguish between types of deposit, other than in broad terms, as for example, The AusIMM JORC Code (JORC, 1999) which makes reference to diamond and coal deposits. The objective of this paper is therefore to set in motion the process of specifying detailed protocols, acceptable to the international community, for the assessment, reduction and management of risk associated with the development and extraction of mineral deposits. Ordinarily, the main risks and issues encountered during the process of estimating resources and subsequent conversion to reserves, encompass:failure to understand relevant geological controls of mineralisation; validation of grade interpolation; optimism in geotechnical appraisals of dilution and stability and the consequent selection of inappropriate mining methods; metallurgical modelling of minerals and contaminants reporting to concentrates; appraising the hydraulics of heap leaching and the numerous factors that can affect recovery; difficulty of managing metal price cycles and changes in regulations within the constraints of long-term mining plans; and development of better evaluation techniques for mining ventures. Uncertainty is inherent in estimation and engineering work, and its identification, reduction and management should be a fundamental goal of all involved in the mining industry (Figure 1). Variability may be reduced by:following internationally accepted practices for the collection, manipulation and analysis of geoscientific data; and verifying that the procedures actually performed meet the associated standards. Increasing amounts of data will also reduce uncertainty, but only if the procedures used to collect and appraise such data follow the relevant procedures. It is thus the aim of a series of papers in preparation, Beniscelli et al (in prep), to put forward detailed guidelines, for:project sponsors û to provide a global view of the work and documentation needed to support requests for funding various phases of project development and budget approvals; geologists û to indicate a checklist of the requirements and standards for the exploration and estimation of resources; and engineers and economic analysists û the protocols for characterising, modelling, engineering and evaluating the extraction of reserves. It is therefore hoped to encourage the development of consistent standards for declaring reserves within the mining industry. Data from projects and operations will be utilised to illustrate the benefits of adopting a rigorous approach to estimating resources and engineering reserves, Beniscelli et al (in prep).

Jan 1, 2000

By I. Silin, H. Wotruba, A. Liono, I. Volobayev, Y. Rubinstein, D. Gürsel

Old, abandoned or in situ processed and storaged tailings can be a potential source of remained valuable metals and minerals. By reprocessing of tailings, it is possible not only to achieve economical profit from recovery of valuable metals, but also to reduce environmental damage caused by tailings such as generation of acid mine drainage from sulfide minerals, mobilization of heavy metals, soils and groundwater contamination. In addition, storage facilities can be successfully redesigned with modern geotechnical requirements and monitoring to avoid a dam collapse of abandoned tailings. In this case study, the processing of low grade abandoned tailings was investigated. Copper (0.15%), cobalt (0.032%) and gold (0.35 ppm) were determined as main valuable and recoverable metals. Cobalt occurs as cobaltite and cobaltiferrous pyrite, while chalcopyrite represents copper. The fine fraction of tailings below 32 μm is enriched with cobalt and copper. Preliminary test-works with initial tailings sample were aimed to recover copper, cobalt and gold. The previously tested magnetic and gravity separation could not recover the metals in a pre-concentration step. Flotation tests of the tailings sample had shown a suitability for flotation without previous regrinding of the tailings. The valuable minerals are first proposed to be recovered by collective flotation, followed by a selective circuit with production of a low grade copper concentrate and a cobalt bearing pyrite concentrate. Based on various tested collectors, amounts of sulfidisation agents and activators, a suitable reagents regime was determined and used for up-scaling by locked cycled test. Keywords: reprocessing, tailings, copper, cobalt, gold, flotation, cobaltite, cobaltiferrous pyrite

Jan 1, 2020

By L. A. Walker

DURING the past twelve years the underground shaft of the United States mine at Bingham has been sunk an additional 2000 ft. with stations and pockets cut every 200 ft. without interrupting the mining of 600 tons of ore per day and the advancing of 1500 ft. of development per month. Following is a brief description of the way the joint work is conducted. The vertical underground shaft is a three-compartment shaft with outside dimensions of 6 ft. 4 in. by 15 ft. 6 in., and inside dimensions for each compartment of 4 ft. 2 in. by 4 ft. 8 in. The manway compartment of the main shaft is used as the hoisting compartment in sinking operations; it is partially lined with 2 by 12-in, lagging and a bucket is used without guides or crosshead. Preparatory work includes the placing of a bulkhead in the manway compartment, 60 ft. above the lowest station or level, the installation of a hoist, a head sheave, a fleet sheave, a-signal system, air and water lines, and a trap door for handling waste.

Jan 1, 1937

By W. Basuki, B. Setyotomo, L. Hakim, R. Hendrajaya

Due to high crack sensitivity of slab product of gas and oil line pipe application, its steel making process and alloy composition were evaluated and then improved to overcome its critical solidification process and reduced surface defects. The study was conducted at Slab Steel Plant Krakatau Steel. The purpose was to improve slab surface quality by reducing surface defects so that the slab surface doesn't need to be totally repaired. The method applied was by performing plant trial process, which the secondary process parameters such as alloying method and the casting parameters such as casting powder selection, metallurgical cooling, mould level control, and superheat were continuously monitored and then adjusted to the surface quality of the product. Based on the calculation of Ferrite potential of the steel, the chemical composition was designed to achieve optimum casting parameters in order to avoid high shrinkage during solidification. The results of the study are decreased surface defect quantity, and smooth casting process. The quantity of crack decreased by almost 90%. The slab surface repairing was significantly reduced from 85. % to less than 10%. These new casting parameters and developed alloy composition are then used and standardized for the mass production of the steel.

Jan 1, 2005

By Martin J. Gavin

During the present study of lubricating oils in the San Francisco laboratory of the Bureau of mines it became desirable to distill oils used in the experimental work at pressures as low as 10 mm., (mercury column) absolute. In the effort to overcome difficulties and eliminate sources of error the apparatus described below was finally developed. The distilling flask is essentially the Hempel flask used by the Bureau of Mines for the analytical distillation of petroleum3. The complete apparatus is shown in Figure 1. As air leakage at connections is an ever present or potential source of difficulty and error in vacuum apparatus, the, mouth of the flask is drawn down to one cm. internal diameter which materially simplifies obtaining an air-tight seal at this point. Before reducing the mouth, the spray screen is inserted and adjusted in position.

Jan 1, 1927

By H. Z. Kuyumcu

Associated with the development of a novel microbiological oxidation process for the conditioning of iron hydroxide slurries from ferrous mine waters, there is a realistic chance to make the contained iron available for a material utilization. The transformation of ferrous into ferric compounds is coupled with the precipitation of iron hydroxisulphate mostly in terms of the mineral Schwert-mannite. The further treatment of the iron hydroxisulphate has to be aimed on the processing for product recovery and product refinement. For many potential applications, e.g. in the ceramic industry, the pigment industry or for metallurgical applications, the removal of sulphate is essential. For the dehydration of the iron hydroxisulphate and the sulphate removal, microwave heating technology is a beneficial method. In contrast to conventional thermal heating processes the supply of energy in microwave application takes place directly within the material through the dissipation of electromagnetic energy, i.e. no heating medium is needed. It is a volumetric heating process regardless of the surface of the material. The rapid and targeted energy supply and the good controllability of microwave heating systems are advantages which have led to a wide variety of applications in industrial processes. Among the diverse use for heating of temperature-sensitive, chemical and pharmaceutical products as well as foodstuffs the number of applications also in mineral and solid processing increases. At the Department for Mechanical Process Engineering and Solids Processing of the Technical University Berlin the use of microwave technology for the treatment of iron hydroxisulphates has been investigated systematically within the framework of a cooperative research project. The paper at hand shows results from material conversion tests subject to a variation of the relevant process parameters. The reaction products are characterized and the process is compared with the conventional heating in a rotary kiln.

Jan 1, 2014

By J. Kretschmann, A. Müterthies, T. Rudolph, C. Yang, P. Goerke-Mallet

Catastrophic failures of dams and tailing storage facilities (TSF) have triggered the development of integrated ground monitoring concepts for hazard assessment, risk management and public safety. These concepts are based on knowledge and expertise of persons technically responsible for TSF. The aim is to combine this implicit and explicit knowledge with the data of in-situ- and remote sensors. Risk management for TSF must include a comprehensive monitoring program that integrates data from ground based-, air-borneand satellite-based sensors. Researchers at Technical University Georg Agricola (THGA) in Bochum, and EFTAS, Muenster, Germany, are fusing a variety of sensor data to enhance the capability and performance of TSF monitoring to ensure public safety downstream of TSFs. This paper describes the variety of sensors implemented in numerous research projects. It gives an outlook in terms of planned satellite missions with innovative equipment like hyperspectral sensors. The implementation of the data of these sensors in the analysis will increase the understanding of spatio-temporal impacts of mining activities. Future opportunities are explained by a datacube approach.

Mar 2, 2022

By Sylvie Poirier

This paper focuses on new developments regarding thermal rock fragmentation applications. The technology consists in a strong burner powered by diesel fuel and air. The thermal reaction, which is created, allows for the enlargement of 125-mm to 450-mm holes by breaking the rock in a spalling effect. It has been used for over 30 years in Russian open pit mining. Following an agreement between Dynamitage T.C.G. Inc. and the owner of the technology, major improvements have been brought to this technology, allowing for the fabrication of a prototype suitable for the Canadian industry. In Russia and Ukraine, thermal rock fragmentation is actually used to drill large diameter holes in surface mining. Upon having acquired a better knowledge of this technology, it seems that it presents a great potential for selective mining in narrow-vein operations, for either surface or underground mining. Rocmec International Inc., a subsidiary of Dynamitage T.C.G. Inc., and Natural Resources Canada are technical partners in the evaluation of the operational parameters and environmental aspects, such as gas, heat, dust and fog emissions. Furthermore, Canada Economic Development is a financial partner in this project. This paper presents the technology and its history. It also reports on the changes brought to the equipment to adapt it to North American environments. A summary of the tests realized since 1995 is provided, along with the main conclusions obtained. The anticipated applications for the use of this technology in both surface and underground environments are described, such as open pit mining, bulk sampling and narrow-vein ore extraction. An estimate showing a comparison between the thermal fragmentation mining concept and the long-hole mining method is presented and, finally, the future developments planned are listed.

May 1, 2002

By M. Kowalczyk

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of the (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting pre-concentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gemstones.

Jan 1, 2009

By M Ahmed

Reliable face support pressure is necessary for shield driven tunnels in cohesionless soils to prevent excessive ground movements. This paper presents experimental work on stability of a tunnel face using transparent soil models aiming to obtain magnitude of tunnel face minimum supporting pressure, failure pattern and extension of failed zone. A model tunnel was preinstalled in transparent soil which was supported at the face by means of water pressure. Tests were performed by reducing supporting pressure until collapse occurred. Model tests were sliced optically with laser sheet and images were captured for every decrement in tunnel supporting pressure. Later, these images were analysed by digital image correlation (DIC) and vector fi elds of incremental displacements were obtained. Values of minimum support pressures were given for different cover/diameter (C/D) ratios. Geometry of the failure zones depicted for different (C/D) values and appeared to be of chimney shape with a limited extension front of the face. A minimum support pressure was achieved with support pressures as low as 10 ± 1 per cent of the effective vertical stress at the tunnel axis. The stability of the tunnel face was related to the coefficient of active earth pressure with C/D ratio having a small effect on the magnitude of required pressure at collapse. In general, results of the study were in agreement with current knowledge of full-scale situations.

Mar 8, 2011

By J. O. Marsden

The Candelaria copper-gold mine is located approximately 25 km south and east of Copiapo in Region III, Chile. The original concentrator was designed to treat 28,000 t/d (30,800 stpd) of chalcopyrite-bearing ore through a circuit consisting of a single 11.0 m (36 ft) diameter SAG mill, two ball mills, conventional rougher and scavenger flotation, column cell cleaner flotation, and ceramic disc filtration. The plant was commissioned in August 1994 and quickly reached capacity and expected levels of metallurgical performance. In May 1996, a decision was made to double the capacity of the concentrator by the addition of a second line of equipment. The expanded facilities were commissioned in October 1997, less than 18 months after the decision to proceed, and well within the budget. The original concentrator facilities were replicated or duplicated as much as possible, however, a number of important equipment changes were made to take advantage of industry developments since the original concentrator was designed. These included the use of Eimco 120 m3 (4,200 ft3) cells for rougher and scavenger flotation and the installation of a Svedala VTM -800 Vertimill for regrinding. This paper describes the rationale behind these changes and explores the reasons for the success of the project.

Jan 1, 1999

By W. G. Pariseau

This paper is concerned with the problem of calculating ground movement that occurs as a consequence of mining. Solution to this problem is straight forward in principle but rather complex in practice. The complexities of the problem arise from the ever present constraints of technology and economics. However, the identity of these constraints is often obscured by a faulty understanding of the fundamentals of the problem and a lack of appreciation of current computational capabilities and costs. As a consequence much time and effort are sometimes wasted on gathering information that is of little direct value to ground control programs while important input data are neglected. This paper therefore reviews the essentials of the process of formulating the ground movement problem. Emphasis is upon application to longwall mining, although much of the discussion applies to other mining methods as well. In many instances, the hardrock term stope could be substituted for longwall panel because the fundamentals of the problem are independent of the excavation dimensions and numerical values of rock properties. The latter affect the outcome of a calculation, of course, but not the underlying formulation. Only the major features of the problem are discussed in this brief review. The objective of the discussion is the generation of a reliable basis for developing a technically sound ground control strategy. Any rational ground control strategy must be consistent with basic physical laws. For example, under static conditions, equations of equilibrium must be satisfied. Operational, that is, tactical, details may vary widely with local conditions, but the basic approach must be based on physical laws. The alternative empirical route is intrinsically unreliable and unnecessary as well. Empirical descriptions of ground motion caused by mining including recent statistical curve fits to specialized data sets (for example, surface subsidence data) as well as antiquated "theories" of ground pressure and so forth, however dignified with mathematical formulas, are hardly worthy of the label "theory". Extrapolation of statistical data is always accompanied by rapidly diverging confidence limits, while empirical equations simply lack predictive capability under circumstances even slightly different from those of the original development. For example, applications of surface subsidence curves generated empirically in the United Kingdom to coal mines in the United States generally result in considerably greater subsidence and wider subsidence troughs than actually observed. Locally, empirical criteria for specific ground control actions may be made practical through trial and error, but such tactics are no basis for the development of a general ground control strategy. In this regard, it is worthwhile to recall the traditional scientific distinctions between speculation, hypothesis and law, between the empirical and the proven.

Jan 1, 1982

By F. R. Cattoir

The Federal Bureau of Mines refined chromium from an aqueous electrolytic process in molten sodium chloride-chromium chloride electrolytes. Oxygen and nitrogen contents were reduced by a factor of 10 to 40, but most other impurities were little changed. The product usually contained a little more iron than the feed. Since iron was entering the bath from the iron pot and the graphite liner at a nearly constant rate, contamination of the chromium deposits by it was more serious at low currents and deposition rates. A few runs in an iron cell with a nickel liner yielded chromium containing one half as much iron as the feed, but up to 1.5 pct. nickel. In all cases the anode feed lay in the bottom of the container, which itself was used as the anode connection. With a 12-in. cell, variations in applied voltage from 0.05 to 1.5, in current from less than 10 to over 100 a., and in initial cathode current densities from less than 100 to over 2,000 a./sq.ft. had little or no effect upon the analysis of the metal produced) except for iron content. Changes in bath analysis from 3 to 11 pct. chromium were also without effect. These changes did bring about large differences in the physical forms of the crystals obtained. The thick heavy crystals produced at low voltage and current contained voids which made them difficult to leach free of chlorides. Easiest to leach were the thin leaf-like crystals obtained at around 1 v.

Jan 1, 1960