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By Tom Snyder, John Brulia

Part I is the first of a series of articles by the authors on hazardous materials (HM) transportation safety and compliance for shippers and carriers who offer and transport commercial explosives in commerce on public highways in the U.S.

Jan 1, 2014

By A. Tohn, L. May, Adham. K.

The path from process conception to commercial implementation poses significant technical, economic, and sometimes political challenges for every project team. Solving the technical challenges typically distinguishes successful projects from those that fail. Here, the authors provide an outline for technical success based on lessons learned from years of experience in process design and R&D. Challenges faced by new technology developers, with regard to design and definition, are described. Experience-based methods to avoid missteps are shared. Special emphasis is placed on the selection of viable unit operations, definition of known and unknown parameters, experimental screening of options, and piloting for scalable design information. Use of computational models to define, assist, and interpret the pilot operations and results are described. Furthermore, the value of active collaboration amongst the design, research, and owner team is demonstrated.

Jan 1, 2011

By M. Turner-Jones, N. Steenekamp

"The Lonmin Base Metal Refinery treats converter matte from the Lonmin Smelter to produce nickel sulphate crystals, copper cathode as well as a concentrate containing the platinum group (PGM) metals. The original process employed a Sherritt design and utilizes atmospheric and pressure leaches for the dissolution of base metals. This paper describes the original flow sheet and the improvements made to enhance PGM recoveries, product quality and to increase capacity. Changes include the introduction of flash recycle cooling on the autoclave, batch leaches to improve the quality of the PGM concentrate and the implementation of solid-liquid separation with centrifuges. INTRODUCTIONThe Lonmin Base Metal Refinery (BMR) is about 100 km north-west of Johannesburg and treats converter matte from the Lonmin Smelter to produce nickel sulphate crystals, copper cathode and a concentrate containing the PGMs. The plant was commissioned in 1985 based on a Sherritt design to treat 12 tonnes converter matte per day. The original flow sheet consists of a milling circuit, an atmospheric leach and a pressure leach to produce a PGM concentrate which is despatched by helicopter to the Lonmin Platinum refinery in Brakpan, about 40 km east of Johannesburg. The liquor from the atmospheric leach is treated by crystallization to produce a nickel sulphate hexa-hydrate crystal. The leach liquor from the pressure leach is treated by a selenium removal step followed by electro-winning to produce copper cathode. The spent solution from the copper electro-winning is recycled to both the atmospheric and pressure leach steps to provide sulphuric acid for the leaching reactions.Modifications were made to the original circuit to increase the plant capacity, to improve the PGM recoveries and to improve the quality of the PGM concentrate. Capacity increases included all the unit operations, new mill, new first stage, additional autoclaves, additional nickel sulphate crystallizers, new copper electro-winning and new batch leach reactors for upgrading the PGM concentrate. The current circuit is described in this paper and not the detailed history of each plant change."

Jan 1, 2012

By W. B. Coker

A helicopter-mounted lake-sediment and lake-water survey was carried out over Grenville rooks in the Renfrew area (parts of Renfrew and Lanark counties) during four days of October, 1975. In the course of this survey. 1150 square kilometers were covered, with 246 lake-sediment and 276 lake -water samples collected from every body of water on which the helicopter could land. Sample sites, which averaged one per 4.6 square kilometers, included lakes, ponds, beaver ponds, swamps and marshes. Lake-sediment samples were taken using a G.S.C. sampler. Waters were collected directly into polyethylene bottles. At each sample site , surface and bottom-water pH, dissolved oxygen content, conductivity and temperature were measured using a Martel. Water Quality Analyzer. The lake sediments were air dried and then ball milled to pass a minus 80-mesh sieve. Lake sediments were analyzed for U by delayed neutron activation and for Mo, Cu, Zn, Pb, Fe, Mn, Ni and Co by atomic absorption techniques. The organic content of the sediments was determined by loss on ignition at 450 °C. Lake waters were acidified with nitric acid on the day of collection. The U content of the water s was determined by fluorometry; the Cu, Zn, Pb, Fe, Mn , Ni and Co contents of the waters were determined by solvent extraction - atomic absorption techniques. A close relationship was found between bodies of granitic, syenitic and pegmatitic bedrock and elevated U levels in the lake sediments. The Hurd Lake and White Lake granitic intrusive were encompassed by an annulus of higher U activity. Field inspection revealed that the U concentrations occur within a zone which may represent a contact metamorphic aureole. Within these complexes, anomalous concentrations of U appear to be associated with Mo. Information derived from the lake-water data reinforces the geochemical distributions outlined by the lake-sediment survey . This survey was carried out in order to develop optimum sampling and analytical procedures for geochemical reconnaissance of the Grenville Province that may be carried out under the auspices of the Uranium Reconnaissance Program.

Jan 1, 1977

By N. Schreithofer

The deposition of octadecylamine (ODA) at the KCI crystal/NaCI-KCI brine interface was investigated using atomic force microscopy (AFM). The AFM images of freshly cleaved KCI specimens immersed in KCI-NaCI saturated brine at room temperature reveal disappearance with time of the atomic steps and formation of cubic NaC1 crystals. These crystals were found to form when the specimen was withdrawn from the saturated solution. Depending on the way of contacting the specimens with the octadecylamine dispersion, the AFM images show huge differences in the deposition patterns of ODA on KCI crystals. Adequate dispersion was found to help the formation of quite even ODA coverage. The coverage was several monolayers thicker when air/brine/solid contact took place, suggesting that in the potash flotation the collector is likely to be carried to the solid surfaces by air bubbles. The presence of methyl-isobutyl carbinol (M IBC) enhanced the dispersion of ODA in brine, thus helping the spreading of the surfactant on the KCI crystal surface.

Jan 1, 2006

By G P. Taylor

Mining Lease SML 57 was registered to Mount Kasi on 5 January, 1995. The Mount Kasi gold mine is located in Vanua Levu, Fiji's second largest island and operated from 1932 to 1946 producing 261,000t of ore at an average grade of 7.5g/t Au. The deposit represents a structurally controlled style of high sulphidation copper gold mineralisation with peripheral low sulphidation mesothermal vein type gold mineralisation. The resource consists of 1,048,000 tonnes of residual soils (eluvium) containing 1.9 g/t Au at 0.5 g/t Au cut off and 1,240,000 tonnes of hard rock at 3.0 g/t Au and 1.0 g/t Au cut. 94 drill holes, 298 auger holes and 85 pits were modelled to outline the resource. 29% of the pits bottomed in mineralisation and it is likely the full thickness of eluvium has been understated. The pit is scheduled to produce 500,000 tonnes of ore per annum to yield 35,000 ounces of gold with an initial 2 years of eluvial ore followed by a further 2 years of hard rock ore. Total capital costs are estimated to be less than 10.0 million dollars with construction planned to commence in 1995. The likelihood of locating further ore is high.

Jan 1, 1995

By M. E. Volin

Reagent control for optimum concentrate yield was studied by laboratory batch flotation tests simulating the Groveland plant flotation circuit in which a rougher concentrate is cleaned twice. The reagents were a fatty acid collector, a sulphonate collector and sulphuric acid. The study included two types of flotation feed representative of the reground and deslimed tailing from the spiral concentration circuit, one when the ore mineral is predominantly specularite and the other when it is magnetite. The factorial design included three levels of fatty acid, five levels of sulphonate and five levels of H2S04, with the two types of ore in nested blocks, making up a total of 75 tests. Similarity of results and reproducibility were established in preliminary tests. The final tests were performed in random order under closely controlled conditions following the established procedure.

Jan 1, 1965

By Yehia M. Youssef, Nourhan Moukhtar, M. H. Abdel-Aziz, Ibrahim Hassan

Copper was recovered from copper sulfate solution in a batch-recycled galvanic reactor operated under forced convection with the generation of electrical energy during the cementation process. The divided galvanic cell consisted of parallel copper and zinc plates. The mass transfer rate and the amount of electrical energy generated were found to be directly proportional to the solution flow rate and the initial concentration of metallic ions and inversely proportional to the distance between electrodes. The experimental results were expressed in terms of a dimensionless correlation including all parameters. The wastewater treatment presented herein cell can be utilized to recover many soluble heavy metal ions from solution with high efficiency.

Oct 2, 2020

By Neel Gupta, Brijes Mishra

Coal mining activity disturbs the natural equilibrium of in situ stress state such that the induced stresses deform the surrounding rock mass. Although the installation of roof supports typically prevents rock deformation, rock mass failure may still occur in bolted roof. The erratic failure of rock mass after few days to months and years of excavation is the result of time-dependent deformation of roof rock under constant surrounding stresses. In the current research, the triaxial laboratory creep experiments proved that Marcellus shale exhibits time-dependent deformation under constant stress that was smaller than the failure strength. However, unlike conventional experimental results, the time-dependent deformation did not depend on the level of constant stress. The often-neglected initial state of specimens and intrinsic heterogeneity highly influenced the time-dependent failure of Marcellus shale.

Jul 27, 2021

By Jianmin Qin, Raja V. Ramani, Wilson Miola

"The number of underground work entities operating under reduced dust standards in U.S. coal mines has been increasing since the start of the decade of the 80s and is currently approaching 10,000. The concern for controlling the quartz levels in airborne respirable dust in coal mine has manifested itself in several improvements in equipment selection and operation, face ventilation practices, and dust control procedures. At the same time, fundamental studies have been initiated on determining the source-sink relationships of the airborne quartz dust. The P-7 method is the prescribed method for the determination of quartz in the respirable airborne dust samples from coal mines. Questions have been raised on the reliability of the P-7 infrared spectrometry method for quartz analysis in powders. No specific method has been defined for quartz determination in bulk samples from the mine.In a recent study on the relationship between quartz in the airborne dust and that in the materials being mined, both infrared (IR) and x-ray diffraction (XRD) methods were used on a suite of samples from several coal mines. These samples encompassed airborne respirable dust samples, airborne total dust samples, the oversize fraction from the respirable samplers, ROM samples, channel samples, and chip samples from the face, roof, and floor materials. In this paper, the sample preparation and analysis procedures for the samples are discussed. The data, analysis results, and comparisons of the P-7 and XRD results are presented. The quartz percent determined for the same sample by the two methods are different. In 85% of the samples analyzed, the quartz percents determined by the XRD method are higher than those obtained by the P-7 method. However, there is a strong linear relationship between the results from the two methods. Further, the XRD method indicates an average of 20 percent more quartz than that from the P-7 method. The reasons for the differences in the results and the need for additional studies are explored.Since the enactment of the Federal Coal Mine Health and Safety Act of 1969 and the Federal Occupational Safety and Health Act of 1970, the prevalence of free silica as an occupational hazard in dusty work environments has been a matter of increasing concern. In underground coal mining, sometimes, roof, floor, clay veins and other non-coaly material must also be mined along with the coal. Mining these materials may increase the amount of quartz in the airborne dust (Pimentel and Adam, 1985; Taylor et al., 1984; Colinet et al., 1985). The problem of high quartz levels in the respirable airborne dust is widespread in continuous miner sections. In addition to the need for controlling the silica amount in mine atmosphere, a need for a sensitive, easily performed method for the determination of free silica in airborne dust samples was also recognized."

Mar 1, 1992

By Raúl Carretero de la Hoz, Leonardo Soares Chaves, João Paulo Soares Toneli, Francisco Felipe da Silva Dantas, Marcos Peres Lopes, Marcus Vinicius da Silva Gonçalves

The mining activity results in environmental impact and thus requires the adoption of techniques to minimize its effects. The rock blasting process is required to break up and move the rock enabling the haulage of the material, however, it might also cause undesirable effects such as flyrock, overbreak, excessive ground vibration or air-blast at the neighboring communities and damage to civil or geological structures located nearby. The Serra Sul mine, commonly referred to as S11D project, has obligations to preserve two natural tropical montane lakes and several maximum relevance natural cavities whose legal preservation radius represents constraints to the mine development and operation. Controlling measures are undertaken to ensure preservation of the cavities, especially during rock blasting stage, with limitations of the maximum instantaneous charge (MIC) and ground vibration control. The demand for high productivity and the large areas with hundreds of blastholes to charge are challenging factors to the charge control. This work presents the development and field application of a map for limiting explosive charges in the rock blasting process at the Serra Sul mine, used for the definition of maximum charges according to the blast location, ensuring the preservation and compliance with the defined ground vibration limits for each cavity. The map is applied at the mine for every blast and when there is a charge constraint, the map helps to define the areas with different charging profiles in the field contributing to higher charging productivity.

Jan 21, 2025

By S Wangchai, D B. Hastie, P W. Wypych, A P. Grima

Industries that handle and process ‘dusty’ ores are facing increasingly difficult challenges to ensure sustainable operation and development. Most existing dust-control measures treat only the symptoms of dust generation and do not deal with the root cause/s of the problem. Many of these methods are also relatively inefficient in terms of controlling dust emissions. This paper summarises the various existing options available for dust control and some of their features, advantages and disadvantages. It then describes some of the new technologies that are being researched, developed and employed to minimise dust emissions by addressing dustability or dustiness and the dust generation mechanisms found in industry. Recent research results and case studies are presented to demonstrate some interesting findings obtained from this work. With improved understanding and modelling of dust generation mechanisms and bulk material dustiness, it is possible to achieve a step-change improvement in the design, troubleshooting and application of more efficient dust-control technologies.CITATION:Wypych, P W, Hastie, D B, Wangchai, S and Grima, A P, 2015. Research and application of new dust control technologies for the iron ore industry, in Proceedings Iron Ore 2015, pp 529–536 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Alessandro Marques

Based on a short overview regarding steel defects in the final product, several refractory approaches to maintain or increase steel cleanliness are reviewed in this publication. By applying a ladle to mold approach, one potential to maintain cleanliness is to reduce the probability of air ingress by selection of a suitable slide gate system. Following this path, also the influence of a special configured impact pot is presented to maintain steel quality. Finally, higher productivity as well as cleanliness can be provided by selection of PROIL as a revolutionary product at the casting machine.

Oct 30, 2017

By L. A. Jordan, D. van Vuuren

A two-dimensional finite difference model has been developed to describe the reduction of kilogram quantities of dehydrated phosphogypsum. The model’s scope has been limited to focus on the heat transfer and reactions that occur within a mass of material contained in a vessel inside a furnace rather than also including the effects of heat transfer to the vessel. Changes in the heat transfer properties (k, ρ, and Cp) are incorporated as the composition of the mass changes as the chemical reactions progress. The model is validated against experimental data, with samples heated to 1000°C at 3°C min−1 while purging with nitrogen gas. A sensitivity analysis of model predictions to the pre-exponential factor of the reaction rate constant of the main chemical reaction and the thermal conductivity of the powder bed indicated that, at the envisaged process conditions, the behaviour of the system depends much more on the rate of heat transfer than on the rate of the chemical reaction. The model demonstrated a significant increase in accuracy when the thermal conductivity was modelled to increase linearly with temperature compared to assuming a constant value.

Oct 1, 2022

By Matthias Pulsfort, Hanna Nissen, Markus Herten

An insufficient integrity of cast in-situ bored piles can lead to a reduction of the load bearing capacity and may require cost intensive repairs. Reasons for an insufficient pile integrity are linked to the construction process, mainly to poor concrete quality leading to bleeding and segregation of the fresh concrete. Moreover, the entrapment of soil and an insufficient concrete cover can pose a problem. Knowledge about the time-dependent development of the fresh concrete pressure during the construction process of bored piles is needed for a better understanding of the underlying processes causing these defects. Therefore, pressure measurements were carried out on different construction sites with pressure cells being installed at different depths along the reinforcement cage. The measurements revealed the maximum pressure acting on the surrounding soil. The achievement is a better understanding of the effects of the concrete placement specifically and the construction process in general on the surrounding soil to reduce the risk of pile imperfections.

Sep 8, 2021

By Albert L. Toenges

The Grundy coal field is in process of development, and this circular was written to describe the mining methods and practices in use in the mines now being worked in this field. In lieu of man-hour labor data for individual mines a consolidated sheet of mine costs, which includes expenses for labor, material, and power, is given for all mines. The costs are for a working day only, based on average daily production. Because the demand for coal is seasonal, the costs for idle days, which vary at each mine, have not been estimated. Approximate reserves of coal seams have been estimated from data and maps taken from Bulletin XVIII of the Virginia Geological Survey4/.

Jan 1, 1936

By A Bossilkov

Although environmental and sustainable development reporting has now become widespread in the Australian mining and minerals processing sector, there remains a great deal of diversity in reporting contents and practice. Moreover concerns remain about the effectiveness of reporting for delivering the companyÆs business case for sustainable development as well as for communicating sustainable development performance to a range of external stakeholders. This paper therefore reviews the status of sustainable development reporting in the Australian minerals processing industry. Pertinent international and national developments are briefly captured, leading to a discussion of the framework for integrating sustainable development reporting with sustainable development management (as proposed by the World Business Council for Sustainable Development). This leads to a discussion of the results of a comparative review of sustainable development reports of a cross-section of eight Australian resource companies. Best practice elements are highlighted in regard to reporting on company context, governance, performance and assurance.

Jan 1, 2004

By G. H. Khoe

Although some hydrometallurgical process liquors contain significant amounts of ferrous and arsenate ions, no reliable thermochemical data for the aqueous complexes and the solubility of the ferrous arsenate precipitate are available. The complexation of iron(11) with arsenate has been investigated using the potentiomemc titration method. The results indicated that virtually no complexation of iron(@ with arsenate has been observed. This is in contrast to the significant complexing reported for iron(1n) with arsenate. The solubility product of the precipitate was calculated using the concentrations of appropriate arsenate species pertaining to the observed precipitation pH's. The fit of the observed precipitation points on the solubility curve of the computed stability diagram was used to assess the appropriateness of the equilibrium model.

Jan 1, 1991

By P. Greenfield, C. C. Smith, A. M. Taylor

The Mg-Zr alloy ZA and Mg-Mn alloy AM503(S) are shown to have a markedly improved resistance to creep deformation after suitable heat treatments. This improvement makes them suitable for certain stress-bearing fuel element components in nuclear reactors. The extent of strengthening is described and an explanation of the behavior of both materials is given, based on a combination of strain-aging and grain growth. The increase in operating temperatures of fuel element components in Calder Hall type nuclear reactors has necessitated the development of magnesium base alloys with a very high resistance to creep at temperatures up to 500°C. Such alloys are not required for fuel element cans, which require high-creep ductility rather than strength, but for can supporting and stabilizing components, which are needed to support the imposed loads without deforming more than about 1 pct in times of up to 40,000 hr. The amount and type of alloying addition made to magnesium for these parts is limited by the necessity of keeping the cross-section to thermal neutrons as low as possible. The alloys must also possess a high resistance to oxidation in CO2. Alloys which have been developed for this application include ZA, an alloy of magnesium with 0.5 to 0.7 pct Zr and AM503(S), an alloy of magnesium with 0.5 to 0.75 pct Mn. In the as-extruded condition these alloys are very weak and ductile in creep but it has been found that they can be strengthened to a significant extent by heat treatment. This paper describes the method of developing a high-creep resistance in ZA and AM503(S), the extent of the strengthening produced and discusses the probable mechanisms of strengthening. TEST MATERIALS Specimens were taken from typical casts of ZA and AM503(S) alloys extruded into 2 1/4-in.-diam bars, supplied by Magnesium Elektron Ltd. Typical analyses of the bars were as follows: The as-extruded mean grain diameter was 0.001 to 0.002 in. for the ZA alloy and 0.003 in. for the AM503(S) alloy. EXPERIMENTAL METHODS Extruded bars of ZA alloy, 2 1/4 in. in diameter and 9 in. long, were heat treated in electrical resistance furnaces in an atmosphere of flowing CO2 containing 50 to 300 ppm water, thereby reducing the extent of oxidation compared with that which would have occurred in air. Heat treatments were carried out at 600oc for times of 8, 24, 48, 72, and 96 hr and material was subsequently both furnace cooled and water quenched. In order to measure the effect of time of heat treatment, specimens were creep tested at 400°C and 336 psi for about 1000 hr. Subsequently, the behavior of material heat treated for 96 hr at 600°C and furnace cooled was tested at a variety of stresses from 200° to 500°C. Tests were also conducted at 200o and 400°C on material in the as-extruded condition for comparative purposes. With the AM503(S) alloy, only the effect of heat treatment at 565°C for 4 hr was examined. It has been shown1 that such a heat treatment produces marked strengthening in this alloy. Tests on this material were conducted at a variety of stresses at 200°, 300°, and 400oc with comparative tests on as-extruded material at 200o and 400°C. The creep tests were carried out on machines using dead-weight loading and direct micrometer strain measurements on specimens 5 in. long and 0.357 in. diameter. At temperatures of 400° C and below, the creep tests were conducted in air, but at higher temperatures an atmosphere of CO2 was used. Grain size measurements were made on ZA in the extruded and heat treated states and on each specimen after creep testing. This was done by a line count of a minimum of 20 grains in two or three random fields in the longitudinal and transverse directions. The same method was used for measuring the grain size of as-extruded AM503(S), but the grain size of the heat treated material was so large that this method could not be employed. For heat-treated AM503(S) the large grained characteristics (between 0.1 and 1 in.) were confirmed by the measurement of individual grains. In the case of the ZA alloy, specimens taken from various stages in the program were analysed for hydrogen by a combustion method. Material in various states was also analysed for the soluble and insoluble zirconium content by dissolving in dilute hydrochloric acid. This technique has been useda for the determination of amounts of zirconium present

Jan 1, 1962

By R Norris, M Dunne

Substantial efforts by the industry, as well as by process and equipment designers, have resulted in many innovative developments that provide cost effective reductions in water usage. This paper showcases four emerging best practices in industry including examples of recent installations. Belt press filters are a small fraction of the operating and capital cost of alternative ædryÆ tailings technologies. This gives operators who must ædryÆ their tailings a competitive advantage and makes such operations much more sustainable. The new generation of belt filter presses use less energy, produces lower cake moistures and better disposal stacking properties. The need for tailings storage facilities may be eliminated or in some cases high-grade tailings can be dewatered and sold as a low value product. Mining applications include sand tailings, sinter plant waste, coal tailings and power station fly ash. Flip-flow screening machines are proven worldwide in the dry classification of coal and other minerals, reducing the size of beneficiation plants, whilst reducing energy, water demand and media consumption. They also allow the screening of wet/sticky materials not able to be sized using conventional screens. Lamella separators are used for toxic water clarification and/or sludge thickening in many downstream metal industries with the underflow often dewatered in a belt filter press. Such low cost, high capacity thickeners could also be used instead of conventional thickeners at smaller mines. The simple and reliable continuous washing upward flow (CWUF) sand filters have been used for treatment of waste water from coal preparation plants and steel works as well as in the production of potable water. The filtered waste water from mining processes can then either be reused or discharged from site. Other installations include cleaning mine water to prevent the blocking of dust suppression spray nozzles.

Jan 1, 2006