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By T. Dombrowski

Acid-activated montmorillonite is used worldwide as a catalyst and as a sorbent for the enhancement and purification of petroleum products as well as vegetable and animal-based fats. The solid-acid character of the activated montmorillonite is imparted by the manufacturing process, giving it unique properties that are exploited in these industries. Several international companies and a multitude of local clay producers are focusing on improving the efficiency of their standard and specialized products. This paper will describe the use of acid-activated montmorillonite in traditional sorbent applications, as a solid acid catalyst, and other new uses.

Jan 1, 1997

By Martin Langenderfer, Catherine Johnson, Phillip Mulligan, Kelly Williams

The physical geometry of a charge has a direct correlation to the geometry of the shock wave. This relationship appears strongest within the boundaries of the visible fireball. As the shock wave propagates outward past the limits of the fireball, the theory states that the geometry of the shock wave should even out and become more spherical. This paper investigates pressure vs. time at two distances, one ‘Near Field’ at the extent of the fireball and one ‘Far Field.' The two Fields were instrumented with three free-Field pressure probes from PCB oriented at 0, 45, and 90 degrees to the front face of the charge, in the same horizontal plane as the charge. This orientation allows for the comparison of the shock wave from the face and vertices of the charge. All the pressure sensors were connected to a Data Acquisition System (DAS) recording at 2 million samples per second (2MS/s). Two high-speed cameras, a Phantom and an MREL Ranger II, recorded the detonations for qualitative examination of the fireball, and the shock wave. Three charge geometries were used and compared to the shock propagation of a sphere. The other geometries tested are cylinders, cubes, and tetrahedrons. Charges were made from a PETN based sheet explosive. In the Near Field, a lower pressure is observed along charge vertices with highest pressures from each face. In the Far Field, vertices record a higher pressure, possibly due to the shock waves from the adjacent faces intersecting, indicating that shock pressures do not always even out in the Far Field. This paper will describe the methodology and findings of this experiment and attempt to determine causality for trends in the data gathered.

Jan 1, 2018

By C. Van Dyke, K. Van Dyke, J. Gutierrez, C. Nowack

"Using propidium assay and flow cytometry, we examined how silica exerts its toxicity toward phagocytic cells employing the human neutrophil as a model. This toxicity appears to be associated with calcium bound to silica. Once the silica with calcium is phagocytized, the extra calcium causes the death of the cell. Using ""Ca we found that 6 to 10% of millimolar calcium is bound to milligram amounts of respirable-sized silica (diameter of 5 µ.m or less) at physiological pH. If the silica particles arc coated with an organosilanc (Prosil 28). calcium binding is decreased by 60% as is cell death. Pretreating with INDO IAM (a chelator of intracellular calcium) reduces the cellular death by 80%. Nonfibrogcnic particles- polystyrene beads or coal dust-produced 10% or less cell death in a 4-h period. Silica with no added, external calcium appears to exert toxicity to neutrophils; however, pretreating cells with EDT A decreases cellular death to the level of nonfibrogcnic particles. Chronic toxicity with silica-calcium appears similar to the chronic toxicity in gout where particles cause a cycle of inflammation. c 1993 Academic Press, Inc.Silicosis is an occupational disease caused by the inhalation of fine particles of silica, usually between 0.1 and 5 µ.m in diameter (1). A recent hypothesis explaining silica's toxicity suggested that surface free radicals caused damage to cells (2). This explanation appears doubtful, however, since the addition of silica to water, such as that found in biological systems, quenches free radicals; also, such a hypothesis does not provide basis for a persistent inflammatory pattern that lasts for years. Kane et al. (3) proposed that silica's toxicity resulted from an excessive concentration of calcium ions within the phagocytic cell (macrophages). However, the mechanism that was capable of linking silica to an excess of intracellular, ionic calcium was not explained. The surface of silica is certainly involved because covering the surface with polymers or phospholipids decreases silica's toxicity (4-6).When silica is engulfed by macrophages platelet activating factor and leukotrienes are produced (7, 8). This is the same inflammatory pattern produced by phagocytic cells exposed to the calcium ionophore A23187 and ionic calcium. How could silica be acting like A23187? Perhaps calcium binds to silica extracellulary and then is released intracellulary following phagocytosis; the latter process, in a sense a ""piggy back"" process, would permit activation of inflammation and cell death mechanisms."

Nov 1, 1995

By Ramana G. Reddy, Yuxiang Peng

The long-term corrosion behavior of Haynes 230 (H230) alloy in MgCl2–KCl eutectic salt was evaluated at 1273 K for 500 h in Ni crucible in argon gas. The results showed H230 alloy has good corrosion resistance. In addition, corrosion was noted to occur by depletion of Cr, which was deposited on the Ni crucible. Based on the calculation of Gibbs energy of Ni-Cr alloy and exchange current density of Cr in MgCl2–KCl, the Tafel model was constructed to investigate the corrosion potential and rate. The galvanic corrosion can be explained as the predicted results were in agreement with the experimental data.

Mar 1, 2017

By L. E. Salinas-Farran, S. J. Neethling

Key variables in heap leaching include permeability, mechanical stability and mass transport. All of these properties can be manipulated by agglomerating and curing the ore before stacking it into heaps. The chemical and structural evolution of the agglomerates during curing is key to improving agglomerate properties and, ultimately, heap performance. It is possible to image the internal structure of agglomerates using SEM/EDX (e.g. QEMSCAN or MLA), although these methods are destructive and do not represent the 3D structure of the agglomerates. A non-destructive alternative is to image the agglomerates using X-ray Microtomography (XMT). Not only does this provide 3D information, it also allows the same samples to be repeatedly scanned, allowing the time evolution of the agglomerate structure and chemical composition to be tracked. In this paper we compared the behaviour of ores agglomerated using a combination of sulphuric acid and ferric sulphate with ones in which chloride ions are added to the recipe, since chloride leaching is gaining in popularity as a chemical alternative to bioleaching for sulphide ores. We tracked the curing process beyond the typical time scales to see the impact that this has on both the agglomerate structure and the subsequent leaching behaviour. Keywords: Heap leaching, curing extent impact, leaching kinetics, ferric-chloride leaching

Jan 1, 2020

By A. Bhargava, V. Nasri

Traditionally, secant piles have been utilized to provide temporary support during excavation for shafts and cut-and-cover tunnels. As an alternative, the secant piles can be included into the permanent structure, where they serve as the envelope sustaining the lateral loads and gravity of the permanent structure in addition to supporting the excavation during construction. This has several benets, such as shorter building times and lower excavation costs. Recent construction of an approach structure and an underground station as part of Montréal, Canada’s Réseau Express Métropolitain (REM), one of the biggest transit systems in North America, was completed with remarkable success using this. In this paper, a case study based on a project that employed secant piles as the permanent liner is presented. Techniques to guarantee a watertight construction with over a century of service life are described, along with a variety of structural and waterproong methods applied to create an economical design.

Jun 23, 2024

By A. Ennen, R. Wagner, B. Orberger, J. -M. Milazzo, N. Uhlmann, J. Banchet, J. Lucic, N. Wörlein, M. Firsching, J. L. Dubos, C. Bauer

The residues from mining and processing ores can often be considered as secondary raw materials. However, the material is only available in the form of fine particles (< 3 mm). In order to recycle these wastes, it is necessary to agglomerate it for transportation prior to reprocessing. The resulting agglomerates need to mechanically resist the stress of transportation and loading into the furnace. X-ray computed tomography (CT) is an established method for characterisation of internal structures in material science. This non-destructive technique can provide information on size and distribution of particles and grains. However, the information is not limited to the size, but also can yield structural features like orientation and position of cracks and fractures, which are important features indicating potential for deteriorating the agglomerates. Furthermore, deduced features such as contact conditions of inclusions or boundary surfaces can also be calculated. We studied binder-free tablets of manganese-oxyhydroxide, bentonite, kaolinite and slag powder using micro-CT. Inclusions of highly absorbing particles were identified using a watershed transformation with automatic segmentation by Otsu thresholding. Subsequently, the resulting data was analysed regarding their volume percentage, distribution in size and location within the sample. For the slag agglomerates, the volume fraction of iron could be determined. Furthermore, visible cracks were investigated with the goal to determine the long-term durability. It was shown that the data provided by micro-CT is reliable and helpful for the characterisation of industrial waste agglomerates. Keywords: X-ray, computed tomography, micro-CT, agglomerates, manganese fines, slags, kaolinite, bentonite

Jan 1, 2020

By Thomas Boundy, PATRICK TAYLOR

Indium recovery from liquid crystal display (LCD) waste has been the subject of over 50 peer reviewed publications over the last decade; however, the first commercial recycling facilities are just beginning to be built. The low value of indium in the LCD screen material has posed a major challenge to would-be recyclers. Uncommon material combinations and geometries have further challenged development. A review of published literature regarding extraction of indium from LCDs will be presented and themes of advantageous processes will be highlighted. Barriers to rapid expansion of any recycling technology in the form of manufacturin gpractices, environmental regulations, and geographic constraints will be discussed.

Mar 1, 2018

By L. Paulino, C. E. Zangiacomi, J. Yamamoto

"This paper presents the learning from Alcoa Po9os de Caldas Smelter in Brazil, after several energy restrictions resulting from the failures of three rectifier units at its power switchyard. Starting on December 27th, fuses and diodes failed in three rectifier units of Potline #1, causing a long and dangerous power interruption. Even after current was reestablished, amperage was only 70% of the line target leading to a bath freezing process that lasted for around 48 hours. The process engineering team played with several potroom parameters as pot resistance, bath and metal levels, alumina feeding and bath chemistry in an attempt to minimize impact on the potline metal output and energy consumption. As it will be illustrated, the first battle was to keep the pots running on a ""survival"" approach. After that, several changes took place on the procedures used to run at reduced current which were considered rather successful. Finally, some recommendations will be given to foresee and prevent transformers and rectifiers from undesirable failures."

Jan 1, 2006

By R. V. Lundquist

The specific conductance of solutions of sodium hydroxide and of sodium aluminate was directly proportional to the temperature. The specific conductance of sodium aluminate solutions with identical sodium ion concentration and at constant temperature decreased with increase in aluminum concentration. The aluminate ion population in solution was shown to consist of a mixture of monovalent and polyvalent ions. Aluminate ions did not influence the temperature dependence of pH in caustic solutions containing sodium aluminate. The density and viscosity of a solution was inversely proportional to the temperature and directly proportional to the concentrations of sodium and aluminate ions.

Jan 1, 1965

By L. G. Marshall

This report, describing the mining method of the Dresser Trap Rock Co., Dresser, Wis., is one of a series published by the Bureau of Mines on mining methods, performance, and costs at mining operations throughout the United States. SUMMARY Dresser, in Polk County, is 3 miles south of St. Croix Falls, Wis. Company operations are about 1 mile north of the townsite. The mine has been in [peration] since 1914 and under the present ownership since 1949.

Jan 1, 1959

By Dean L. Millar

Measures taken by mining companies around the world to reduce their carbon footprints are becoming increasingly important in the sector securing its social licence to operate. The options for measures reduce to three categories of activity: i) demand reduction by avoiding unnecessary waste of supplied energy, ii) improving the utilization of energy that does have to be consumed and iii) adopting low carbon energy production options?including renewable energy. As well as the environmental imperative, as the prices of electricity, gas and liquid fuels increase, so the economic case for activities i) to iii) gains higher priority, especially in such an energy intensive industry. The specific energy consumption for certain upstream minerals industry operations in Canada is reported to be as follows: underground mining: 99.5 kWh/tonne mined; surface mining: 11.7 kWh/tonne mined; base metal processing: 81.4 kWh/tonne milled; gold processing: 99.6 kWh/tonne milled. Around 508 kWh/tonne (slag) of heat is reported to be available in cooling slag from 1500°C to 25°C; an amount that is simply indicative of the energy intensity of downstream smelting and refining operations. Low carbon, energy saving technology options that are available to mining industry companies lead to projects with return rates that must compete alongside other capital intensive projects considered by mining company boards. Energy projects frequently involve longer payback periods and lower rates of return than those of competing bids for capital, such as those for development of new mineral properties. For energy services companies (ESCOs) that specialize in the financing, construction, and the efficient operation and maintenance of energy projects, the same returns and payback periods may be considered acceptable or even attractive. For the ESCO, the key commercial risk mitigating factor is a securing a long term contract for the supply of energy.

May 1, 2011

By William H. King

The Nevada Massachusetts tungsten deposits (fig. 1) are in the Mill City Mining District in north-central Pershing County, Nev., about 37 miles southwest of Winnemucca. Contact metamorphism of thin limestone beds within a series of metamorphosed sedimentaries formed scheelite-bearing ore bodies. These deposits are distributed over a wide area. A Bureau of Mines development program was started January 11 d was completed on July 25, 1941. This work was centered on the outer and less explored beds in the district and comprised trenching, sampling, and diamond drilling. Exploratory work was done in cooperation with the U.S. Geological Survey. Project work substantially increased the reserve tonnage of marginal ore in three of the areas explored and proved the nonexistence of tungsten in a fourth area. The following pages summarize the history of the district, outline property ownership, and describe physical features and ore deposits. The plan and results of the work performed by the Bureau of Mines are presented along with geologic and topographic maps, assay maps, and diamond drill-hole logs.

Jan 1, 1950

By S. Mojeddifar, N. Ostadmahdi Aragh, M. Hemmati Chegeni

This work integrated selective principal component analysis (SPCA) with a singularity fractal model to map hydrothermal alterations of argillic, phyllic, and propylitic in the north-west of Kerman city in Iran. SPCA results were provided for short wave infrared (SWIR) bands of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor tomap phyllic and propylitic alterations. Also, the bands 5–7 were applied to map the argillic alteration zone. SPCA results could present useful information for alteration mapping but it does not show the purest pixels of alteration. Therefore, a fractal model of singularity was applied to highlight the different alteration pixels in the Kerman Cenozoic magmatic arc (KCMA). Thus, the singularity index of different hydrothermal alteration zones was produced. Comparing the obtained results with the field data showed that Kader, Serenu,Meiduk, and Abdar deposits were acceptably identified by alteration mapping. Also, it seems that the singularity index could not discriminate the hydrothermal alterations of argillic and phyllic. The same spectral signature of kaolinite and muscovite minerals is the main reason for misclassifications.

Jul 20, 2020

Experimentation was performed on the flotation of apatite and dolomite separately using anionic collectors in the presence of Mycobacterium phlei. Also, the flotation of mixtures of dolomite and apatite in the presence of anionic collectors and in the absence and presence of the bacterium were studied. It was found that M.phlei functions as a depressant for both minerals. However, it functions as a better depressant for dolomite than for apatite. Experimentation was extended to two different Florida dolomitic phosphate rocks. In this investigation a concentrate grade of less than 1.0% MgO was achieved.

Jan 1, 1997

By Anita Wu

"GENERAL BACKGROUND/CONTEXT The £300 million Bond Street Station Upgrade project will provide essential congestion relief and step-free access to an important interchange and destination station in the heart of the London Underground network. In 2010 London Underground (LU) let a design & build contract to Costain Laing O’Rourke (CoLOR), with the works to be completed in early 2017. CoLOR’s lead designer is Halcrow-Atkins JV (HAT). The station upgrade works comprise the following principal elements: •,A new satellite ticket hall on the North side of Oxford Street •,Two additional escalators and stairs providing congestion relief to the Jubilee line platforms •,Four lift shafts to provide step-free access between the different levels of the station •,Additional stairs to Central line platform level •,Tunnelled connection to the Crossrail station immediately to the south •,Connecting passageways, including ten connections to existing station tunnels. To achieve this, an existing property at 354-358 Oxford Street has been purchased and demolished, and the basement deepened to make provision for the new ticket hall. From this basement two circular shafts have been sunk, providing construction access for the tunnelled passages and lift and escalator shafts. The tunneling is principally in the London Clay stratum, which is widely recognized as a favorable tunneling medium, although the deepest parts of the works extend into the Lambeth Group strata which consist principally of stiff clays at this level but also contain water-bearing sands. The majority of tunneling has been carried out using mechanical excavation and sprayed concrete linings but other techniques have been used in areas where SCL is not practicable.A key challenge for design and construction of the works has been spatial constraint, in particular due to: •,The existing underground station layout •,The Limits of Deviation for the works •,The small construction site at 354-358 Oxford Street •,Overlaying Third Party assets including Listed buildings, sewers and water mains."

Jan 1, 2016

By S C. Barrie

St BarbaraÆs Marvel Loch operations have successfully used longhole open stoping as the primary mining method for a number of years. A transition to Core and Shell mining was implemented in 2009 to recover substantial ore grade resources remaining in sill and rib pillars. The transition to core and shell for the Exhibition lode required continuous waste filling of created voids and thus the removal of the crown pillar at the base of the Exhibition pit by blasting. Access to the top of pillar was denied as the pit was partially rock filled with waste rock from underground development.Beyond the technical challenges of the blasting project, a simple and transparent risk management process was developed to ensure appropriate controls and mitigating strategies were in place to minimise risk to personnel during the pillar removal process.Although failure of the crown pillar was anticipated but with the actual timing unknown, on 25 December 2011 the crown pillar yielded during normal mine operations. Engineered and isolation controls in place at the time were of a sufficiently high standard to ensure limited exposure of the underground workforce and minimal damage to mine infrastructure. Successful risk management through implementation of appropriate controls during the project lifecycle of two years and three months proved to be fundamental to the safe removal of the crown pillar.CITATION:Barrie, S C, 2012. Successful risk management through project life cycle for removal of the crown pillar at the Marvel Loch Underground Mine, in Proceedings International Mine Management 2012, pp 125-134 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By Wang Jingsong, Ma Tengfei, Feng Fu, She Xuefeng

In this paper the direct reduction melting separation-leaching process is investigated on recovering rare earth from rare earth Bayan Obo complex iron ore (REBOCIO). The REBOCIO was reduced and melting separated to produce iron nugget and rare-earth-rich slag at 1400°C for 12 or 15 min. The RE2O3 is enriched into Ce 4.667(SiO4)O or Ca 3Ce2[(Si,P)3O4]3F, which closely depend on chemical components, especially basic. The optimal acid-leaching parameters of rare earth elements from the rare earth slag are suggested as the hydrochloric acid concentration, the ratio of solid to liquid, leaching temperature, and the leaching time are 1 mol/L, 1:14, 50 °C and 120 min, respectively. The rare earth elements leaching efficiency are more than 95%. Adding of calcium CaCO3 and sodium Na2CO3 in direct reduction process have great in fluence on leaching ef ficiency of thorium.

Mar 1, 2018

By G. W. Reimers

Exothermic oxidation reactions of sulfide minerals can produce self-heating situations in underground mines. If the self-heating is unchecked and the resulting heat is not sufficiently dissipated, the result can be spontaneous combustion fires. This U.S. Bureau of Mines report describes laboratory tests conducted to measure the reactivity of pyrite following treatment with additives to counter its self-heating tendencies. Thermal gravimetric analysis (TGA) and isothermal oxidation procedures were used to obtain information on pyrite ignition and the behavior of pyrite during low-temperature oxidation to ferrous sulfate. The determination of treatment effectiveness was evaluated by adding 5 wt pct of the compound to the pyrite before milling. The resulting samples were then heated in moistened air and after 24 h, the amount of pyrite oxidation determined. Results of these tests indicated that several phosphate compounds reduced the oxidation of pyrite to sulfate to about 50 pct or less compared with the oxidation of untreated sample at 200° C. Cupric sulfate reduced oxidation to about 20 pet untreated sample at 200° C. Sodium, calcium, and potassium chloride reduced pyrite oxidation to levels of approximately 15 pct or less of the untreated sample. Using only 1 pct of sodium or calcium chloride was effective in slowing pyrite oxidation to less than 20 pct of the untreated sample.

Jan 1, 2010

By B. C. Litzinger

Minerações Brasileiras Reunidas S.A. - MBR is a brazilian iron ore mining company geared for the export market. It is controlled by Companhia Auxiliar de Empresas de Minerações - CAEMI through its subsidiary Empreendimentos Brasi leiros de Minerações - EBM which holds 51% in MBR and is formed by CAEMI, the six major japanese steelmills and five japanese trading companies, Universe Tankships, Inc., and Indústria e Comércio de Minérios S.A. - ICOMI. The remaining 49% of MBR&apos;s capital are held by St. John del Rey Mining Company, a subsidiary of The Hanna Mining Company. MBR iron ore reserves exceed 1.5 billion tons of high grade ore distributed in 36 deposits located in the so-called IRON QUADRANGLE in the State of Minas Gerais. The Aguas Claras Mine is the largest presently known and highest grade deposit owned by MBR. Other mines such as Pico, Mutuca and Jangada are in operation at a combined rate of production of about 2 to 2. 5 million tons per year. The project consists of mine, railroad and marine terminal (slide). The Aguas Claras deposit, which is located about six kilometers southeast of Belo Horizonte the Capital of Minas Gerais, was selected for initial development. The Sistema Regional Centro of the Rede Ferroviária Federal, through its 6th Division known as the "Central " is responsible for the transportation of MBR ore, and provided the necessary railway construction to connect Mine and Terminal. The Terminal is located on Guaiba Island near the entrance to Sepetiba Bay, at about 120 kilometers west of Rio de Janeiro.

Jan 1, 1974