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By Alaina Mallard, Katie Schumacher, Jannette Chorney, Grant C. Wallace, Jerome P. Downey

Commercial ceramic carbide operations require large thermal and mechanical energy inputs in order to produce a powder product. A process that could reduce the energy requirements needed to make these materials would allow for these materials to be implemented in a greater number of industrial applications. In this study, silicon carbide (SiC), tungsten carbide (WC), and molybdenum carbide (Mo2C) were synthesized via the carbothermal reduction of activated carbon loaded with silicate, tungstate, and molybdate anions adsorbed from aqueous solutions. Carburization was carried out under reducing and inert gas atmospheres, at temperatures lower than those utilized by commercial operations. Silicon carbide “whiskers” were synthesized under H2 at 1400 °C, while molybdenum carbide and mixed crystals of WC, W2C, and W were synthesized at temperatures below 1000 °C. X-ray diffraction and scanning electron microscopy were used to characterize the carburization products, and inductively coupled plasma-optical emission spectroscopy (ICP-OES) was used to determine the degree of adsorption onto the activated carbon matrix.

Mar 1, 2018

By Constantine C. Popoff

Several limestone deposits in western Washington were examined by the Bureau of Mines in 1946. This report presents data obtained from the investigation of limestone deposits in the vicinity of Arlington, Snohomish County, Wash. The work consisted of surface surveys and sampling. Samples were taken where complete, or nearly complete, sections of limestone were exposed or where individual beds were exposed at a number of separate .localities. Areas were cleaned by blasting prior to sampling. Channel samples were cut where practical; otherwise chip samples taken. Twenty-one samples were taken. The locations of the samples and the analyses are shown on maps accompanying this report.

Jan 1, 1949

By M. E. Tyrrell, C. W. Houck

Mixtures of zirconium diboride and refractory metals of group VI were resistance sintered to high - density compacts using modified electric welding equipment . To evaluate the use of chromium , molybdenum , or tungsten as binders for zirconium diboride the sintered compacts were examined in polished sections and tested for crushing strength , hardness , microhardness , oxidation rate , and resistance to mechanical shock . Chromium yielded the highest compressive strength , the greatest resistance to mechanical shock and oxidation , and a satisfactory Rockwell hardness . Molybdenum did not yield a satisfactory cermet . Tungsten yielded compacts having high microhardness but very low mechanical strength .

Jan 1, 1964

By Chris Harris, Kamal Adham

The use of HCl acid is gaining momentum among hydrometallurgical processes. However, the issue of environmentally efficient and economically viable ways to regenerate HCl acid (from various metal chloride intermediate products) remains a technology and operational challenge. The authors provide a state-of-technology review based on Hatch’s years of testing, design and commissioning experience with high-temperature units (fluid bed and spray roasters), plus the recent efforts in the area of low-temperature HCl regeneration.

Jan 1, 2014

By James R. Gingery, Byron Foster, Bret Lingwall

While microzonation and setbacks are the typical mitigation for structures exposed to surface fault rupture hazards, lifelines and lifeline facilities are not easily relocated to avoid faulting. In these cases, other remedial measures including ground improvement may be warranted. Deep soil mixing ground improvement was used in this case to mitigate surface fault rupture and liquefaction hazards for a pump station at a wastewater treatment plant with wet wells up to 36-feet (11-m) deep. Paleoseismic field investigations were performed to characterize the site, then deterministic and probabilistic fault rupture displacement estimates were made and used to develop design scenarios. The fault rupture mitigation design consisted of a solid block of DSM encompassing and protecting the pump station and its wet wells. Three dimensional soil-structure interaction numerical modeling of the fault rupture scenarios was performed as part of the design. The analyses showed the fault rupture displacements could be diverted by the DSM and that satisfactory structure performance could be achieved. The design required construction of a large 100 percent replacement ratio block of DSM with a compressive strength of 500 psi. Aspects of construction of this DSM block are discussed.

Sep 8, 2021

By P. James

"INTRODUCTION High sulfate (SO4-2) levels often occur in MIW (mining influenced water) either as the result of oxidation of sulfide minerals exposed by mining activity or by deliberate addition – commonly by sulfuric acid (H2SO4) use in hydrometallurgical leaching activities. Increasing regulation of sulfate discharge is creating new pressure to treat or mitigate sulfate release to prevent its entry into the environment. Current treatments include precipitating as gypsum during lime treatment, filtration separation using membranes such as reverse osmosis and nanofiltration technology, and biological elimination via methods like constructed bioreactors. Blue Planet Strategies (BPS) focuses on improved resource utilization targeting electrolytic treatment and waste conversion into resources and has now demonstrated that its proprietary DEMET™ (Dynamic Electrolytic Metal Effluent Treatment) platform can also remove sulfate from target streams as a byproduct of its usual primary treatment focus points of metal species elimination and/or pH adjustment.[1-6] This powerful new capability can mitigate sulfate contamination and recover the sulfate in a useful and potentially saleable form as a byproduct of improved primary treatments focused on enhancing production or treating waste. This provides a new treatment opportunity and value proposition for lowering overall sulfate consumption/addition or creating new revenue to defray conventional treatment costs. The DEMET Alternative DEMET utilizes a patented electrolytic technology platform employing proprietary dynamic high surface area electrodes in innovative configurations to achieve a variety of novel selective chemistries. DEMET‘s unique elements can yield higher processing rates at practical efficiencies, lower energy consumption, plus improved processing stability and lower maintenance requirements due to enhanced resistance to cell fouling and shorting; while also thwarting cross stream (catholyte vs. anolyte) contamination. Consequently, DEMET can provide a superior, extremely versatile, and cost-effective electrolytic treatment option where a multitude of FEED and PRODUCT stream combinations might be employed in comparison to traditional tankhouse electrolytic cells. Secondary reactions (Figure 1A) which could also occur at the cathode (plating/electrowinning, precipitation/scale formation, etc.) are controlled through process tailoring and operation parameter selection. Additionally, DEMET‘s innovative dynamic system mitigates potential fouling and electrode occlusion or shorting challenges which could occur when process particulars demand some of these secondary side reactions occur."

Jan 1, 2015

By D. B. Dreisinger, M. R. Tavakoli

"Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the pregnant leach solution, and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. This paper reviews the purification of vanadium leaching solution using organophosphorus, solvating, and amine extractants. This review focuses on vanadium separation from iron, molybdenum, and uranium, which are often present in vanadium resources such as primary ores, fly ashes, and spent catalysts.RÉSUMÉ Le vanadium est produit à partir de diverses sources. Ce métal est connu pour permettre des solutions aqueuses de spéciations complexes en fonction de la concentration du vanadium et du pH. En tenant compte de la méthode de lixiviation, des impuretés dans la solution mère de lixiviation et du produit de vanadium planifié, divers agents d’extraction et schémas de traitement peuvent être mis en oeuvre pour purifier la solution. Le présent article étudie la purification de la solution de lixiviation du vanadium au moyen d’extractants organophosphorés, solvants et aminés. L’étude cible la séparation du vanadium du fer, du molybdène et de l’uranium, lesquels sont souvent présents dans les ressources de vanadium telles que les minerais primaires, les cendres volantes et les catalyseurs usés."

Jan 1, 2016

By H. L. Burmeister

These properties were examined by a Bureau of Mines engineer in 1949. During 1950, these mines were studied by the Bureau to determine the possibility of increasing the production and augmenting the supply of fluorspar. As a result of this study, it was decided to core-drill the Knox-Yingling vein to test the continuation of fluorspar to a greater depth than that reached by mine workings. It also was desired to relate the present deposit with the Rosiclare formation. Development work by the Bureau of Mines was performed from February to May inclusive in 1951. Four diamond-drill holes aggregating 2,733 feet were drilled in the hanging wall of the vein.

Jan 1, 1952

By Selim Coskun

In this study, tungsten matrix composites reinforced with 2 wt% TiC particles were mechanically alloyed (MA?d) for 3h, 6h, 12h and 24h. 1 wt% Ni is used as sintering aid which is added before and after mechanical alloying. Microstructural and phase characterizations of composite powders and sintered samples were carried out via SEM and XRD analyses. Furthermore, density and hardness measurements of as-consolidated and sintered samples were carried out. Additionally, DSC experiments were conducted to investigate the sintering behavior of the MA?d powders.

Jan 1, 2009

By S. B. Hildebrand

One of the highest costs associated with insitu leaching of copper is electric power. The ReGeneration Project addressed this cost issue with a research and development project for BHP Copper. The project involved the installation of a reverse pump/turbine for the removal of excessive fluid pressure and the production of useful electric power. The motivation for the project was that a reverse pump/turbine unit could not only remove the excess hydraulic pressure, but when connected to an induction .generator, would produce electric power, which could be easily connected to the local power gird, thus reducing operating costs. The project was successful in removing excess fluid pressure and producing electricity. The unit is operating today, producing useful 2,300 volt power at a rate of approximately 128 kilowatts.

Jan 1, 1998

By Yi Zheng

Under normal circumstances, methane released along a longwall face represents only 10%-20% of the total me- thane emitted from the entire longwall panel. However, there might be a sudden surge of methane at the face which may cause a potential problem because the friction from shearer cutting, support movement, and scraper conveyor dragging can be ready ignition sources. Therefore, to predict the distribution of methane will be critical to prevent possible explosions. In this paper, methane dispersion patterns along a lognwall face are simulated under normal and abnormal conditions. With the simulation of methane released from the face, around shearer drum, and from the broken coal on the conveyor, places with possible high methane content can be identified by different phases of working process and shearer positions. Local ventilation measures are evaluated so precautionary measures can be planned ahead.

Jan 1, 2012

By Alex Joseph

A tertiary amine containing polyamine in its back bone was grafted to exfoliated graphite oxide by means of a series of chemical reactions.The synthesized amine functionalized polyaniline grafted to exfoliated graphite oxide (EGAMPANI) was characterized using various techniques such as, FTIR, TGA, Raman, and X-Ray diffraction.The synthesized EGAMPANI was blended with carbon paste electrode, and used to study the response of Hg2+ in acetate buffer solution.Preliminary analysis showed that the anodic current intensity using the EGAMPANI modified electrode was higher during a potential sweep and 10-4 M concentration of mercury could be detected which could be improved to 10-6 M using anodic stripping voltammetric technique. Keywords: metal sensor, exfoliated graphite oxide, functionalization, polyaniline

Sep 1, 2012

By Howard G. Coopersmith

A resource of low grade good quality diamonds has been discovered through the Diamond Company NL-Moonstone Diamond Corp. Joint Venture. A limited bulk sample diamond test of two large kimberlite pipes on the Kelsey Lake Property, Colorado, has been completed. These kimberlite pipes have petrological and mineralogical indications of the presence of diamond. Small diamonds were recovered from surface samples. Drilling and trenching revealed both pipes were complexes of diatreme facies kimberlite. One pipe contains crater facies kimberlite as well. This is the first reported occurrence of crater facies kimberlite in the Province. Approximately 1000 tonnes of kimberlite rock was excavated and processed through a scrubber -HMS -Sortex -Grease Plant. Significant diamonds were recovered. The diamonds were generally of good color and clarity, with many being in the gem and near gem categories. Grades are considered low however. Additionally, a small potential resource of alluvial diamonds is present.

Jan 1, 1991

By R. L. Montgomery

The heats of formation of lanthanum sulfate and the enneahydrate are -939.8 ± 3.1 and -1,587.1 ± 3.2 kcal. per mole, respectively. The heat of hydration is -32.5 ± 3.5 kca1. per mole. These values were obtained from heat-of-solution measurements of lanthanum oxide and salts. Low rates of solution precluded more accurate determinations of the thermal data. The heat of formation of the chloride was similarly observed to be -256.18 ± 0.28 kcal per mole. Heats of solution and combustion of lanthanum metal yield mutually concordant results, and earlier discrepancies reported in the literature may be ascribed to impurities.

Jan 1, 1959

By I. Nakatsugawa

Chemical conversion coating is a process to create thin oxide/hydroxide film containing several inorganic/organic compounds by way of chemical deposition reaction. In case of the application to Mg mobile electronic housings, the film should possess a good electric conductivity while keeping adequate corrosion resistance and working as a paint base. The use of toxic/hazardous chemicals is strictly prohibited from the environmental aspects. This paper describes the recent trend of conversion coating used for Mg electronic housings and analyzes critically from the point of surface technology. The importance of cleaning process and understanding of surface microstructure are particularly emphasized with several experimental results.

Jan 1, 2006

By José Aparecido Pereira

The innovative methodology developed by the author allows the elaboration of an Angle Roll Pass Design based on the practical observations of the rolling process and applies mathematical criteria, using the Ekelund´s formula supported by Advanced Excel tools (Reach Goal, PROCV-PROCH, Macros) and AutoCad. The first step is the definition of the number of stands, roll dimensions, gear boxes reduction, initial stock, average reductions, spread factors, finishing speed and type of grooves. For each pass are calculated: bite angle, spread, section reduction, lost and gain of temperature, separating force, speed, torque and motor power. After these calculations and checking of the parameters, the program calculates the dimensions of the passes transforming the flat passes into shaped ones. With these dimensions it is possible to draw the grooves using AutoCad and check section reductions. This methodology was already used for the development of a new project and also to check the parameters of existing ones, with comparison of the results and has shown to be reliable in real and tested projects. It is an innovative process that is not available in known literature.

Oct 1, 2019

By Emanuele Catelli, Paolo Vicentini, Manuel Petitat, Paolo Lanfranchi

"More than 800 million tons of material will be excavated during large underground projects such as tunnels, undergrounds and power plants by 2030 in Europe only. The raw material excavated is often classified as waste, which involves environmental impact and transport issues: landfill areas, CO2 emissions and noise. But how can such massive amounts of material be transported, processed and deposited? Using the example of the AlpTransit Ceneri Base Tunnel (15.4 km), we show that suitable excavated materials can be used sustainably as a primary resource for tunnel concrete. This requires careful planning of the installations and storage areas by the client, timely building of the processing plants and other handling facilities outside the tunnel and a continuous evaluation of the raw material quality. 1. INTRODUCTION Spoil management is a central element of large construction projects. The systematic reuse of suitable excavated material not only saves natural resources, reduces transport distances and landfill volume, but can also decrease overall construction costs. Ideally, all of the concrete needed for tunnel lining can be produced with this on-site material. Such a natural resource management concept was applied for the construction of the new Gotthard Base Tunnel (L = 57 km). Spoil management concepts are, how-ever, difficult to implement and call for innovative techniques, sophisticated logistics and organization. In the context of large projects, environmentally friendly transport, processing and storage of millions of tons of excavated loose material represent another logistics challenge (Simmen & Lieb, 2010). This paper shows key factors that led to the successful completion of spoil management at the Ceneri Base Tunnel, which constitutes a part of the AlpTransit Gotthard Project (Figure 1)."

Jan 1, 2016

By M. Rudolph, R. Tolosana-Delgado, E. Schach, M. Buchmanna, G. van den Boogaart, U. Peuker

The multidimensional characterisation of processes based on various particle properties is a key requirement for a detailed prediction on certain process streams. To access the relevant particle properties (e.g. particle size, particle density and mineral content) automated mineralogy (i.e. Mineral Liberation Analyser) is applied. The kernel density estimation is used to transfer the received discrete particle data into continuous distributions without the necessity of binning the information and the related loss of information. From these continuous distributions, multidimensional separation curves are estimated. The uncertainty of these representations is tracked via bootstrap resampling. For the evaluation of the separation efficiency of the multidimensional separation curves, the statistical entropy is calculated. The statistical entropy represents a local (for each property combination) as well as a global (for the investigated property range) measure of separation efficiency and can be weighted with various property distributions (e.g. mass or mineral mass distribution) to allow for a comparison of different parameter settings and processes. With the help of a case study of a dry magnetic separation of a cassiterite bearing skarn ore from the Erzgebirge (Germany), the methodology is presented and the results are discussed in detail. Keywords: Multidimensional, magnetic separation, kernel density estimation, mineral liberation, statistical entropy

Jan 1, 2020

By Clara Godoy, Paulo Couceiro, Juan Navarro

The continuous automatization and digitalization of the different stages involved in any underground construction bring new possibilities to optimize the operation. One of the most important requirements for the development of these projects consist of a proper rock mass characterization for optimizing the stages of the drilling, blasting and support cycle. In the last few years the road to digitalization has gone through data science and big data, showing the importance of data gathered to describe the geological and geotechnical environment that surrounds the operations. Since rock characteristics have an important influence in the drilling response, the technological advances in the sensorization of drilling machinery such as the Measurement While Drilling system (MWD) allow to gather the necessary amount of information to be applied in data science processes to evaluate changes in the rock mass with higher resolution than conventional methods. In this paper, Machine Learning techniques have been used to combine data monitored from the drill rigwith scanner profiles of the excavated sections to develop an automatic geotechnical rock mass characterization model able to estimate potential zones of over- or under-break of the remaining rock mass in underground blasting. By comparison of scanner profiles of the excavated sections with the blasthole positions, an Excavated Mean Distance (EMD) between the contour blastholes and the excavated profile has been obtained, which may be considered as damage measure. Considering blasting factors as constant, the model combines the rotary, percussive, hydraulic flushing and the rate of advance of the drilling, and the confinement of the rock mass by depth, to detect zones with different rock properties. This provide an early information of the rock mass condition around the blastholes and the prediction of expected overbreak generated after blasting, being possible to design more efficient bastings, in which each borehole is filled with the right and necessary explosive charge. The analysis comprises data from 57 blasts (around 1700 contour blastholes) and more than 4000 excavated sections.

By L. Frost

"Since the late 1990s, increased prevalence of severe lung disease among US coal miners has been observed, particularly in central Appalachia where thin-seam mining is prevalent. While respirable silica exposures have been implicated in many cases, the available dust monitoring data from mines shows no explanatory trends. One possible factor could be differences in the relative toxicity of silica particles based on their surface condition. Previous research has indicated that particles with occluded surfaces (e.g., by a thin layer of clay) may be less toxic than those with non-occluded surfaces. However, this dust characteristic has not been investigated before now in central Appalachian mines. In the present study, 18 respirable dust samples from seven central Appalachian mines and two northern Appalachian mines were analyzed to assess the relative occurrence of surface-occluded silica. Results showed that the dust from central Appalachian mines actually had higher fractions of occluded silica, which may be due to extraction of large amounts of rock strata along with the coal. However, the central Appalachian mines also more silica particles overall (i.e., occluded + non-occluded) in terms of total number percentage of respirable particles.INTRODUCTIONResurgence of occupational lung disease among US coal miners, especially in the central Appalachian region, has been observed since the late 1990’s (Gibson, 2016; Zosky et al., 2016; Suarthana et al., 2011; Gamble et al., 2011; Antao et al., 2005; Attfield & Sexias, 1995). In addition to increased prevalence of simple Coal Workers’ Pneumoconiosis (CWP, or “black lung”), the prevalence of severe and rapidly progressive disease has risen dramatically (Almberg et al., 2018; Blackley et al., 2018a, 2018b, 2016, 2014; Graber et al., 2017; Cohen et al., 2016). While exposures to respirable silica have long been known to cause or play a role in diseases such as silicosis or progressive massive fibrosis (PMF), which is conventionally considered as the most advanced form of CWP, it is unclear whether silica is the only culprit in the recent outbreak of severe disease. Indeed, as disease rates have risen, both total respirable dust and silica concentrations generally appear to have declined since the late 1980s, based on regulatory monitoring data in the most affected mining districts (i.e., MSHA coal Districts 4, 5 and 12, which cover central WV, eastern KY and southwestern VA, and southern WV, respectively) (Figure 1). Of course, the latency of disease can vary and may be or more 10 years, but many of the most recent cases are likely to have resulted from exposures that occurred since the late 1980s."

Jan 1, 2019