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By Glenn E. Johnson

The Bureau of Mines investigated the production of hydrogen cyanide by reacting powdered coal (minus 300 mesh) with ammonia at 1,250° C in a bench-scale study. Both metallic and ceramic reactors were used. Yields up to 0.7 cu ft of hydrogen cyanide per cubic foot of ammonia consumed r- obtained. The resulting ammonia conversion of about 75 volume-percent approximates conversion obtained commercially in processes utilizing natural gas and platinum catalysts. The coals that had higher volatile-matter contents gave the best yields of hydrogen cyanide. Allowing the coal to adsorb ammonia before reaction resulted in increased yields of hydrogen cyanide. Cost studies for a plant with a 40-million-pound-per-year capacity indi-cate that hydrogen cyanide can be profitably coproduced with carbon black, from coal and ammonia, at the current market price of hydrogen cyanide (11.5 cents/lb). These figures are based on heating the reactor electrically. If a cheaper heating method were devised the economics of the process would be more favorable.

Jan 1, 1967

By Brendan Howard

Rio Tinto has a large globally distributed technical workforce and needs to ensure these employees have the requisite skills to not only manage technical risk and enable safe efficient production, but also ensure they are keeping pace with a fast-changing technological landscape. Traditional approaches to learning struggle for scale and an inability to respond to the extreme diversity of capability development needs. In response, Rio Tinto has successfully introduced innovative approaches to learning and employee engagement via leveraging the power of globally distributed networks for peer-to-peer knowledge transfer and providing mechanisms to recognise, reward and retain the individual technical contributors.

Feb 1, 2024

By Jr. Schnakenberg

The automation (robotization) of coal mining activities at the face offers improvements in worker safety and productivity. The evolutionary introduction of autonomous, intelligent robotic machines to perform the most hazardous tasks may become a reality within the next 10 years. The U.S. Bureau of Mines Robotics and Automation research program is aggressively pursuing the development of the enabling technology necessary to achieve this goal. This program consists of both core and applications research, each focused on the fundamental issues of robotic technology. In the short term, the research is directed specifically to the robotization of present-day underground equipment and is being performed in a manner that can make incremental improvements in safety and productivity. The long-term goal is the development of intelligent autonomous mining systems.

Jan 1, 1990

By ROBERT H. BOOTH

THE happy intra-plant relationships of the Bridgeport Brass Co. are largely attributable to the interest of the management in this important business factor. In furtherance of this development Carl F. Dietz, President of the Company and a member of the Institute, has contributed the novel plan for the objective presentation of business economics, described herein. All of the officers of the corporation are active in its management and they together with many other workers filling both executive and subordinate positions have a substantial financial interest in the enterprise. The viewpoint of this organization is fairly reflected by the following quotation from Roosevelt's "The Foes of Our Own Household."

Jan 1, 1924

By K. C. Hendrick

The paper will review the significant developments in world copper over the past ten years and their impact on the Canadian industry. It will also examine the outlook for the future.

Jan 1, 1971

By Roy F. Abernethy

This publication by the Federal Bureau of Mines contains the free-swelling indexes for 2,812 samples of coal received from January 26, 1948, to July 15, 1957, and the Hardgrove grindability indexes for 2,339 samples of coal received from June 23, 1947, to July 15, 1957. These data consist of the origin of the sample, bed name, and analysis. Summaries show the high, low, and average values for each bed. The free-swelling index is a relative measure of the caking properties of a coal when burned on a grate, and the Hardgrove grindability index is used to estimate the relative ease of grinding coals. Development and standardization of these test procedures were at a much later date than those for the more familiar tests, such as proximate and ultimate analyses and calorific value determinations. The newer tests are valuable in supplying supplemental information, particularly for assisting in evaluating coals used in certain types of combustion processes.4/ Data from such tests are important to designers of burning equipment, operating engineers, and purchasing agents. Data from these newer tests are scarce and scattered through a number of publications. Special projects were started to determine the free-swelling and grindability indexes, in addition to the regular analyses on the tipple samples collected by Bureau engineers. Since the start of these special projects, all the coal fields of commercial importance have been adequately covered in the sampling program.

Jan 1, 1961

By Arash Dahi Taleghani, Pooyan Asadollahi

Slurry walls, also known as diaphragm walls, are commonly used as temporary and/ or permanent support of excavation for construction of shafts in soft ground. Through case history, this paper demonstrates economical benefits of disregarding long-term structural contribution of the slurry walls particularly in severe environmental condition. In addition, for temporary slurry wall shaft systems, possibility of using steel fiber, synthetic fiber or additives in lieu of temperature/shrinkage reinforcement is discussed with detailed analysis. Finally, the paper will be concluded by introducing unreinforced slurry wall shaft system using newly developed/patented concrete additive.

Jun 13, 2021

By H. H. Schrenk

[There is a need for method of determining: benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the modification of the Elliott and Dalton6/ procedure. This depends on the nitration of the benzene to reduction to phenylenediamine with all excesses of standard titanous chloride; solution, and titration with e standard ferric ammonium sulphite solution. This method has the disadvantages of being what time consulting: and cumbersome it requires considerable apparatus, and a special modification is necessary in the presence of toluene.]

Jan 1, 1935

By S. P. Lowe

Flotation testing of Flin Flon ore was started in the Denver laboratory of Complex Ores Recoveries Co. in March, 1926. There had been a considerable amount of flotation testing previously which had shown possibilities of success, and it was felt that, with the increased knowledge of flotation and the comparatively new reagents then available, flotation held out the best prospects for a successful commercial treatment of this ore. There remained available for this experimental work a small amount of the rejects from a thorough sampling of the mine and some ore from the mine dump.

Jan 1, 1930

By T. W. Johnson

The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past-several years the flow of natural bas through high--pressure pipe lines.4 This report deals with that part of the study involving the design of pipe-line, systems consisting of lines laid parallel to each other. The lines are deferred to as the original line and the parallel line. The paralleling line may or may not extend the entire length of the original line; however, the parallel line is, connected at its two ends to the original line. As a result of the large expansion of the natural-gas industry almost all markets within economic distance from the developed gas fields have at least one pipe line supplying them with natural gas. Small increases in the consumers' demand for natural gas can be met usually by increasing operating pressures, but any marked increase in demand necessitates paralleling sections of the existing systems. It is believed that to a large extent future

Jan 1, 1934

By Winton J. Gale

The subsidence over a longwall panel at Tahmoor Mine in the Southern Coalfield of NSW, Australia, was found to be approximately twice the size it had been in previous measurements. An investigation into the potential causes was conducted using computer modeling together with hydrological characterization and detailed geotechnical characterization of the strata. The abnormal subsidence was found to be consistent with localized weathering of joint and bedding planes above a depressed water table adjacent to an incised gorge. The study showed that other factors such as variation in stress field, joint zones, variation in rock strength and topographic factors did have sufficient impact to induce the abnormal subsidence. The results have significant implications to subsidence prediction in areas that may be prone to the phenomenon found at Tahmoor. Key indicators of the potential for this form of abnormal subsidence are presented.

Jan 1, 2011

By Z. Yang, M. J. Collins, N. E. Tuffrey, R. J. Kalanchey, I. M. Masters

The high elevation of China Western Mining Company (WMC)' s Ganhe refinery, and the high iron content of concentrates produced by the WMC mines, were key factors in the selection of pressure leaching by WMC for their new zinc refinery. This paper describes the results of pressure leaching test work conducted by Sherritt in Fort Saskatchewan with a sample of WMC concentrate from Qinghai Province in China. Results from batch pressure leach tests and a four-day pilot plant campaign are reported. The pilot plant campaign included continuous operation of a two-stage pressure leach circuit, as well as neutralization and iron removal steps, resulting in the production of iron-free zinc sulphate solution. Greater than 98% zinc extraction was achieved in pressure leaching, while producing solution containing about 9 g/L H2SO4 and 2 g/L Fe. Following neutralization and iron removal, the solution contained about 170 g/L Zn and less than 10 mg/L Fe. Overall recovery of sulphur in the zinc concentrate feed to elemental sulphur byproduct was about 85%, while 75 to 80% of the indium in the feed was recoverable from the neutralization residue. The test results highlighted the technical and economic advantages offered by the Sherritt Zinc Pressure Leach Process and provided the required data for the engineering design.

Jan 1, 2008

By Rui-Qing Li, John G. Peacey, Peter J. Hancock

"Noranda has been investigating a pyrometallurgical process for the direct recovery of zinc from zinc concentrate and zinc and iron containing residues. The process consists of injecting dry zinc concentrate and secondary zinc materials into a molten iron oxysulphide bath, volatilizing metallic zinc into furnace off gas essentially free of sulphur or S02, fixing sulphur contained in the feed materials as iron oxysulphide matte which is disposed, and recovering metallic zinc in an ISP type lead splash condenser. Combustion of petroleum coke with air or oxygen enriched air inside the oxygen containing matte supplies part of the heat, and the products of combustion dilute the zinc-laden gas to a desired level.This paper describes the process concept, thermodynamic background, experimental tests, mass and heat balance calculation for a conceptual flowsheet, environmental stability of the residue and advantages and disadvantages of the process. Experimental tests have successfully proved the process concept and thermodynamic predictions. Direct smelting of zinc concentrate and residues inside an iron oxysulfide bath has a great potential to become a cost effective and flexible zinc smelting process.1. INTRODUCTIONZinc is mainly produced by a roast-leach-electrowinning process route, which accounts for about 80% of the world primary zinc production. This process produces high quality zinc with very high zinc recovery (>95%) but suffers from several major drawbacks such as using high cost electricity as reductant, producing environmentally problematic iron containing leach residue (jarosite or goethite) and the difficulty in treating secondary zinc feed materials containing high impurity levels, such as electric arc furnace dusts from the steel industry, and other complex sources. Also in some areas, markets for sulphuric acid are distant resulting in negative realizations on acid sales.The Imperial Smelting Furnace (ISF) process is the major pyrometallurgical process to treat zinc-lead concentrate. The advantage of this process over the electrolytic zinc process is its flexibility in treating high-lead, bulk concentrates with high recoveries of lead, copper and precious metals. However, this is a two-stage process involving sintering of Zn-Pb concentrates followed by blast furnace reduction. The process requires large amounts of high-quality coke which is a major operation cost, and the sintering process which results in serious environmental problems."

Jan 1, 1996

By H. Golzarpoor

Life Cycle Analysis (LCA) is a methodology for evaluating the environmental impacts associated with a product during its life cycle. LCA is identified as the most reliable method for verifying environmental impacts; however, current LCA-based approaches have certain limitations for environmental analysis of construction products. Integration of the LCA methodology with Discrete Event Simulation (DES) provides a sound framework for modeling and analysing the environmental impacts of construction products. LCA and DES is one possible combination for analysing the cause and effect of various scenarios where time, resources, and randomness of input variables affect the outcome and, therefore, has the potential to address the shortcomings of LCA in construction. Recent studies in disciplines other than construction such as manufacturing systems have revealed positive effects on evaluation of environmental metrics while integrating LCA with DES; however, this integration has not yet been applied for environmental analysis of construction products. By implementing LCA data in a DES model, this research proposes an environmental model of earthmoving operations in a case study. Environmental variables are simultaneously assessed with production variables in the same simulation model and the integration of DES and LCA is discussed.

Aug 1, 2013

By Ashutosh S. Dhar

Cast-in-place piles were examined in this paper from the viewpoints of construction quality, axial capacity, and load-displacement responses. The results of ten 450 mm diameter (18? f) bored piles, installed in a soil deposit of silt to medium dense sand using the method of percussion drilling, were tested under static loads. The results of the pile load tests were used for evaluation of various design methods of calculating pile capacity. The study revealed that the design methods based on the concept of critical depth underestimated the ultimate skin fiction. Thus, the applicability of the critical depth concept for design of bored piles under the soil condition considered may be unreliable. The estimated skin friction factor, ß, was too low in these methods. The Tomlinson method and the Neely method provided the best prediction of the ultimate skin friction. The methods used for calculating end bearing resistance were found to provide a conservative estimate of the resistance. During pile load tests, a settlement of 5 to 6 mm was required for full mobilization of skin friction for the piles in loose sand, while larger settlements (> 10 mm) were required for piles in denser soil. The ultimate skin frictional resistance was observed to be low for piles in loose sand.

Jan 1, 2006

By Bernard Porter

The rate of the heterogeneous reaction between high-purity uranium metal and uranium tetrafluoride in molten lithium fluoride was measured. The apparent heat of activation for the reaction is 16.91 kilocalories per mole of UF4. A surface-controlled mechanism is suggested in which UF4 is adsorbed on the uranium metal surface. Additional UF4 reacts with the adsorbed species and the metal site to form an activated complex that decomposes to the product UF3. The reaction is an important source of metal loss in the electrowinning of uranium metal.

Jan 1, 1966

By Leonard Obert

THIS REPORT presents methods and principles useful in designing underground mine openings and pillars in competent rock formations. Two types of formations are considered: (1) Massive formations, in which openings are generally mined with an arched roof, and (2) bedded formations, in which openings are generally mined with a flat roof. Design principles for openings and pillars in massive formations are obtained by considering the maximum tangential stresses developed around single and multiple openings for stress fields of various types. Design principles for openings and pillars in bedded formations are obtained by considering the average stress in pillars and the maximum stresses in roof layers. Experimental procedures for making stress, strain, and in situ physical-property measurements in underground mines to check design calculations are outlined and the results discussed.

Jan 1, 1960

By J. L. Reuss

The Bureau of Mines derived information on the softening characteristics of both unfired and indurated iron ore pellets as measured by hot compression strength in a laboratory study. A surprisingly high hot strength (240 1b per ½ -inch spheroid) was developed by unfired magnetite pellets near 900° C; lesser maxima were developed by pellets made from hematite and specularite concentrates near 1,000° C. Those from goethite remained weak throughout the pre induration heating. Fully indurated commercial pellets retain a high resistance to softening when heated in air. On the contrary, in a hot reduing atmosphere their high cold crushing strength dissipates rapidly. At 1,000° C, for example, the average compression strength of seven different commercial pellets was 110 lb; at 1,100° C, the hot strength was only 60 lb. After a rather sharp initial drop, the loss of strength with increase of temperature was gradual. There was no sudden collapse, nor any significant difference, in behavior of commercial pellets whether made from magnetite or hematite concentrates.

Jan 1, 1968

By Barbara J. Arnold

A coal's size distribution, clay content and moisture content can affect its handling behavior, but the combined effects of these properties and the effects of other properties are not known. Research underway at CQ Inc.' s (formerly EPRI' S) Coal Quality Development Center (CQOC) and at Iowa State University (ISU) will answer these questions as part of a four-year project to develop a coal handleability index for utilities to use when specifying coals. This paper will present preliminary data from the first year of the project, which focused on obtaining data on the chemical and physical properties of various coals and their measured handling properties. Additionally, size, ash and moisture analyses and shear test data for several coals used at one power plant will be presented along with correlations between these physical and chemical properties and the measured handling properties. These data lead to the conclusion that, while moisture content-is the most important variable, the amount of -325M (-0.044 mm) coal fines is a significant factor in determining coal handling behavior.

Jan 1, 1990

By Clayton M. Rumsey

The U.S. Bureau of Mines investigated prospects and mineralized areas in and adjacent to the Indian Pass and Picacho Peak study areas in 1983 and 1984. The Indian Pass study area contains 33,640 acres and the Picacho Peak study area contains 5,450 acres. The study areas are located in the southeast corner of California and are underlain by Precambrian gneiss, Pre-Tertiary metavolcanic and metasedimentary rocks, and Tertiary volcanic and non-marine clastic rocks. Low-grade gold-silver resources may be present in hydrothermally altered gneiss in the upper plate and altered schist in the lower plate of the Chocolate Mountain thrust fault. The thrust fault is exposed in the study areas for about 3.5 miles west and 5 miles east of Indian Pass. Mineralized zones in the thrust plates were not discovered until 1983. Earlier prospecting explored areas containing minor copper carbonate occurrences in schist and sedimentary and volcanic rocks that are younger than the thrust. Twenty-three mines, prospects, and mineral occurrences inside the study areas and fourteen outs; de were examined for this study. These surficial copper occurrences have been prospected extensively in the study areas; large areas have been scraped, pitted, and trenched by bulldozers. However, they appear to be of limited economic significance. Slightly mineralized zones are in the northwest part of the Indian Pass study area where granite contacts sedimentary and volcanic rocks.

Jan 1, 1986