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By Peter Fullagar, Adel Vatandoost, Steve Walters, Toni Kojovic

"Traditional comminution tests are a vital component in every mine plant design. Comminution behavior governs both the cost of equipment and its operating efficiency. Most comminution tests are conducted off site on a limited number of samples, owing to the high costs and long lead times involved. Therefore a strong incentive exists to find alternative means for efficiently characterizing comminution behavior for a truly representative suite of samples. The potential for inferring comminution behavior from drill core is investigated in this paper. Our approach involves development of small scale comminution tests on the one hand, and measurement of a wide range of core attributes on the other. Our focus is the relationship between petrophysical properties and comminution behavior.Petrophysical properties of archival diamond drill core from the Ernest Henry Mine (Queensland, Australia) have been measured using a Geotek multi-sensor petrophysical core logger. We have investigated the relationship between the petrophysical properties and the corresponding small scale A*b and estimated Bond mill work index test results for 2m composites of the core. Core samples were petrophysically classified by means of cluster analysis. Comminution behaviour was then modeled for each cluster via multiple regression. The results suggest that prediction of the comminution behavior on the basis of petrophysics is viable at Ernest Henry.INTRODUCTIONMineral processing is the most important downstream operation for mining engineers and metallurgists since most mined materials are subjected to some type of comminution or beneficiation operation (SME, 1992). Comminution or size reduction is typically the first stage of processing. Size reduction steps (crushing and grinding) in any plant consume large amounts of energy, normally more than 50% of total energy (Weiss, 1985). Therefore, it is desirable to obtain laboratory results to design the size reduction equipment appropriately. One of the main factors that control the selection of hard-rock crushing equipment and the design of a crushing circuit is the mechanical character of the ore(s). Work index, density, abrasivity, compressive strength and clay content are essential parameters for ore characterisation (SME, 1992)."

Jan 1, 2009

By S. Kok, D. Delport, J. Calitz

Altering the microstructure in order to improve the tensile properties of bow shackles resulted in inconsistency in the fatigue performance. This raises the question whether the inconsistency in fatigue life can be attributed to microstructural changes along the profile of the shackle or to decarburization at the surface. Bow shackles forged from 080M40 (EN8) material were subjected to different heat treatments in order to alter the microstructure. The shackles were subjected to five different fatigue load cases, which represented typical loads experienced at termination points for an overhead power line with a span length of 400 m, with changes in conductor type, configuration, wind, and ice loading. Although the change in microstructure does improve both the tensile and fatigue performance, we found that the depth of the decarburization layer has a greater effect on the high cycle fatigue life of bow shackles than the non-homogeneous microstructure.

Oct 1, 2021

By Soumendra Basu, Uday Pal, Yang Yu, Srikanth Gopalan, Karl Ludwig, Deniz Cetin, Jacob Davis

"A limiting factor for Solid Oxide Fuel Cell (SOFC) performance is the oxygen reduction reaction (ORR) at the cathode surface. Changes in the surface composition and structure on annealing at 800°C has been studied, since these can influence the ORR. Idealized single crystals of cathode materials La0.8Sr0.2MnO3 (LSM) and La1-xSrxCoyFe1-yO3 (LSCF) were grown as heteroepitaxial thin films on lattice matched single crystal substrates. Changes upon heating the films to operating temperature and pressures were characterized using various synchrotron x-ray techniques. Total Reflection X-ray Fluorescence (TXRF) measurements, which probe compositional changes, were made at high temperature in real time. The LSM surfaces were found to develop manganese enrichment when heated. Highly strontium doped LSCF were found to develop strontium-rich surfaces. HArd X-ray PhotoElectron Spectroscopy (HAXPES) was used to investigate the electronic structure of the materials. Highly strontium doped LSCF precipitates a surface strontium phase that contains both oxide and carbonate contributions.IntroductionSolid oxide fuel cells (SOFCs) are chemical to electrical energy conversion devices that could potentially reshape how energy demands are fulfilled. SOFCs have a potential efficiency over 70%, fuel flexibility, low emissions, and low degradation over long time scales. Commonly, SOFCs are operated at high temperatures (above 800°C). At these temperatures expensive housing is needed to contain an operating stack as well as coatings to contain the oxidation of the metallic interconnects. Lowering the temperature of an operating device would allow for more conventional materials to be used, thus lowering overall cost. Understanding the reaction kinetics of the oxygen reduction reaction at the surface of the cathode is vital to designing a system that will perform well at lower temperatures. A commercialization goal is to reduce operating temperatures without sacrificing performance.In order to exploit the advantages of SOFCs, an understanding is needed of the surface chemical states of cations on the surface of the cathode and how this relates to the oxygen reduction reaction (ORR):"

Jan 1, 2014

By Walter G. Dupree

When the original version of this study was published in 1972 it was evident that a problem was developing on the energy scene. The ability of the United States to find the energy supplies it needed within its own boundaries--at least in the forms desired--was declining. Production of crude oil in the United States had peaked in 1970 and was declining slowly; environmental restrictions had begun to hamper the production and consumption of high sulfur coal; natural gas reserves were beginning to dwindle; and the development of nuclear power was proceeding more slowly than originally planned. Shortfalls in energy supply were being met through the importation of increasingly larger quantities of petroleum, but supplies were adequate and the price of the imports was below that of domestic production. The energy problem was more prospective than current. In October of 1973 the prospective problem became the "Energy Crisis' when the Arab petroleum exporting countries reduced crude oil production, imposed an embargo on the shipment of crude oil to the United States, and then raised the price of crude oil in a series of large steps. This crisis was a clear demonstration of the dangers of the dependence of the United States on imported petroleum, and of the Nation's vulnerability to the actions of the oil exporting countries. After the embargo was lifted, attention shifted to the immediate hardships resulting from the higher prices for gasoline, fuel, and electricity,

Jan 1, 1975

By Arthur Metcalfe, Edward Thomas, A. J. Barry

"Early in 1947 the Bureau of Mines became interested in adapting suspension roof support to coal mining 5/ as a possible means of reducing the high rate of accidents from falls of roof. For a time the program made little progress be¬cause of the shortage of steel products after the end of World War II, but during the past 8 months this restriction has eased, and as of May 1, 1949, 114 mines had either started experimental work or had ordered materials and equip¬ment in anticipation of trial installations. It is estimated that 30 linear miles of roof in underground passageways have been secured by this method in recent months, and no lost-time roof-fall accident has been reported in these areas up to that date.Many coal-mining companies in widely separated localities have cooperated in making experimental installations. In very few instances are these companies entirely satisfied that they have arrived at the best solution in determining the most efficient adaptation to suit their particular conditions. Moreover, new ideas and modifications of the basic principle are constantly being brought to light and are being tested. Available test data is far from complete, and it is conceivable that some new idea will be developed to alter the present concept of proper technique; therefore, this progress report does not attempt to answer all questions that might arise in connection with this method of roof support; it simply recounts the experience acquired to date. Consequently, few references to costs are made. Up-to-date quotations on material and equipment used in suspension roof-support installations may be obtained from numerous mine-supply companies.The authors gratefully acknowledge the cooperation of mining companies whose personnel made possible collection of the information contained in this circular: Bethlehem Collieries Corp., Barrackville, W. Va.; Berwind-White Coal Mining Co., Windber, Pa.; Consolidation Coal Co., (Ky.); Jenkins, Ky.; Consolidation Coal Co. (W. Va.), Fairmont, W.Va.; Clinchfield Coal Corp., Dante, Va.; Consolidated Coal Co., St. Louis, Mo.; Hanna Coal Co., St. Clairsville, Ohio; Missouri Portland Cement Co., Sugar Creek, Mo.; Pocahontas Fuel Corp., Pocahontas, Va.; Reppert Coal Co., Dola, W. Va.; St. Joseph Lead Co., Bonne Terre, Mo.; and Tennessee Coal, Iron, & Railroad Co., Birmingham, Ala.The fundamental theory of suspension roof supports is not new; in fact, its application in the construction of beams predates mining itself. The basic principle involved is the reinforcement of roof rock with steel rods inserted in the roof and anchored therein at points where the rock is least likely to be affected by stresses resulting from mining. Such roof supports have been used in mines for many years in widely separated localities. The St. Joseph Lead Co., operating in southeastern Missouri, apparently was the first large mining company to prove the practicability of the principle by applying it in a systematic manner for securing roof for more than 20 years (fig. 1)."

Sep 1, 1949

By Phillip R. Mulligan, Catherine Johnson, Edward Kinzel, Cody Lough, Jason Ho

A shaped charge is an explosive device used to focus detonation energy in a desired direction. Shaped charges have numerous applications in several industries such as oil extraction, weaponry and demolition. The focusing of the detonation energy is the result of the Munroe Effect, which greatly increases the penetration properties of the explosive due to a void in the explosive’s volume. The void in the explosive is lined with a metal substrate that becomes a super-heated projectile when the explosive is detonated. Additive Manufacturing (AM) can allow greater design freedom and geometric complexity for the liner portion of the shaped charge. Specifically, hierarchical structuring and functional grading can potentially provide greater velocity, directionality, and efficiency. By utilizing AM, the conventional use of shaped charges can be greatly expanded upon and may open new possibilities. In this work, selective laser melting (SLM) was used to explore different conical shaped charge (CSC) liners made out of stainless steel 304L. A series of liners were tested that had varying densities and were compared to conventional liners. The CSCs were filled with the high explosive Composition C-4 and detonated to evaluate performance. The blast events were recorded using break wire screens to calculate the velocity of the jet through steel target plates over a standoff of 6 times the charge diameter. A high-speed camera recorded the blast event to calculate the velocity of the jet through the air. The depth of penetration into the steel target plates was also used as a measurement of the effectiveness of the CSCs. The aim of this work is to show the potential for advanced shaped charges produced using SLM.

Jan 1, 2019

By Susanna G. de Jager, Francis W. Petersen

"To enable the prediction of reagents suitable for fine coal flotation, it is necessary to develop a methodology applicable to different South African coal types. Statistical confirmation of the applicability of this methodology is important to avoid recommendation of reagents on a trial and error basis.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements. Flotation tests were used to validate expectations from the characterisation of the coal samples.RESULTSThe flotation data indicated that all of the coal samples were amendable to froth flotation. The best results were obtained with the Witbank seam 2 coal and the poorest flotation with Syferfontein seam 5 coal. The flotation tests showed that the best reagents to float all of the coal samples studied were iso-decanol and dodecene. These reagents produced flotation products that were near to the release curve, which are the optimum flotation results (obtained when using iso-paraffin as collector). Dodecene resulted in low ash products and iso-decanol in high yield products."

Jan 1, 2003

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grindability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions4/ issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor and, if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous .sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1958

By N. I. Um

The coal bottom ash generated from coal-fired power plant accounted for approximately 5 mil-lion tons in Korea. Almost all of coal bottom ash was treated as reclamation of the landfill because of the content of unburned carbon. For recycling of coal bottom ash, effective removal of that is required. So, in this study, the removal of unburned carbon by flotation was studied with respect to adsorption ability in surface of a bubble in order to consider its application to recycle the coal bottom ash. The sample A, B and C were that the coal bottom ash contained 2.73%, 7.01% and 10.49% of the unburned carbon (UC) respectively. The column flotation was carried out for each time as the artificial injection of air at 10.0L/min flow rate and the reagents of 500g/ton kerosene and 80g/ton MIBC were used. The samples per water of 1.3 liters were from 0.5% to 4% (w/w.%). In the result of this study, the kinetic curves of unburned carbon adsorption from injected air bubbles were in-creased rapidly as equilibrium was approached; only 5 sec was needed from the sample A and B and 10 sec was from sample C. And the equilibrium isotherms of unburned carbon adsorbed by the infected air bubble from the sample B and C could appear the BET adsorption isotherm; MT = KMEEO/(EO-E)[EO+(K-1)E](K: adsorption affinity), but not the sample A that was not enough to express the adsorption curve.

Jan 1, 2014

By Jiann-Yang Hwang, Ying Qin, Shu-Jing Zhu

Metallurgical Oil Sludge (MOS) is a byproduct created in the process of steelmaking. More than a million tons of MOS are generated each year throughout the world. The material contains hazardous components such as heavy metals and pathogenic organics, which can cause serious environmental problems and health issues. Landfill, combustion, and pyrolysis have been investigated for the disposal of MOS. However, these methods are unsatisfactory since they are unable to reach the clean environment goal. In this study, we investigate the possibility of using MOS as a reductant in a high temperature metallurgical process. The results are reported and discussed.

Jan 1, 2015

By John Chipman

Published data on the equilibria of carbon in binary Fe-C austenite with H2-CH4 and CO2-CO gas mixtures are used to obtain the constants of an equation repre -senting the activity coefficient of carbon throughout the stable austenite range of temperatutre mid compositiotl. Calculated values for the solubility of graphite are found to be in agreement with the best-published direct observations. Its heat of solution is 10,680 calper g-atom. The free energy of formation of cementite is culculated from the equilibrium compositions of austenite and of gas. Its entropy and heat of formation are also obtained. BASIC knowledge of the high-temperature properties and treatment of steels is contained in the Fe-C diagram and its extensions for the effects of alloying elements. The application of thermodynamics to the Fe-C system, with addition of alloying elements, can serve to simplify and systematize this knowledge. The points of beginning are the binary fee solution, austenite, concerning which our information is reasonably complete, and the binary carbide, cementite. Further studies must include the other phases of the binary system, a and liquid, and for these an accurate knowledge of the ? phase boundaries is essential. These studies should provide a firm base for systematic study of the effects of alloying elements on all phases of the system, their transformations, and precipitation phenomena. With the aid of the simplifying thermodynamic concepts of activity coefficients and interaction parameters it is to be hoped that the results of these studies will be amenable to computer solution thus making the information on multicomponent systems more readily available than would be possible in multidimensional diagrams. Studies of the thermodynamic properties of austenite have utilized equilibrium measurements on the reactions:

Jan 1, 1968

By Robert D. Brown, Charles A. Sorrell

The decade of the 1980's saw "advanced materials" become a key factor among the industrialized nations, with the United States, Japan, and the European Economic Community being the major competitors. All three have identified communications technology, advanced materials, and biotechnology as the keys to future industrial leadership and the closing decade of the 20th Century is expected to be an era of rapid development and restructuring. The progress of EC'92, the effort to develop uniform standards and remove trade barriers in Europe; the determination of Japan to commercialize advanced structural ceramics, alloys, composites, and superconductors; and the emergence of less developed countries as major supplies of commodity materials pose enormous challenges to the position of the United States as an industrial and financial leader. A consensus is developing that the industries that are first to commercialize the large array of new structural materials and electronic, optical, and magnetic materials and devices will be those who determine the structure of national and world economics. Many technical, economic, legal, political, social, and cultural factors are important determinants in the race to commercialize new materials. Millions of words have been written about these factors and their interdependence; yet the sheer complexity of the problems, the rate at which changes are taking place, and the economic risks involved are so great that government policy makers and industrial decision makers find adequate understanding to be very difficult. Of the many factors involved in advanced materials, the Bureau of Mines has the statutory responsibility to provide information on where materials can be found and how they are mined, extracted, purified, combined, and recycled. It is obvious that minerals availability is essential to implementation of any new technology just as there can be no commodity metals industry if the ores are not available. Because "minerals availability" for commercialization of advanced materials and devices is more complex than for commodity materials and a new mix of materials and processes is emerging, the Information and Analysis Directorate of the Bureau of Mines is redirecting resources to provide reliable information for policy and decision making. The Office of Advanced Materials Coordination (OAMC) was established as a staff operation in July 1987 to assist the efforts of the divisions and branches. The key issues and problems were defined and the role of the Bureau was outlined (Sorrell, 1987, 1988). In February 1990, the functions of OAMC were transferred to the new Branch of Advanced Materials, a line organization parallel with the Branches of Ferrous, Nonferrous, and Industrial Minerals, and was given the responsibility for developing new methods to acquire, analyze, and disseminate information about new materials. The purpose of this paper is to provide definitions, a summary of major issues and problems, an overview of minerals and processing availability problems, and a perspective of the ways in which the mining and materials industries can help to ensure domestic availability of raw and processed materials.

Jan 1, 1990

By R. Stefaniuk, T. Le, J-Y Huôt, H. Henein

"One of the most important process variables in gas atomization is the gas to metal (G/M) mass ratio as it has a direct effect on the mean particle size of the atomized powder. If this ratio can be controlled during the atomization process, the powder produced would be more uniform and the d50 more predictable. Thus, atomization using a tundish or gravity feed from a crucible would be more stable. In gas atomization, the gas flow rate can be easily monitored; while it is very difficult to determine the molten metal flow rate. This research paper presents a new method of recording the molten metal height with time using a conducting metal height detector. The metal height recorded in real time during atomization was used to characterize using a model the friction losses in the metal delivery system. It is found that the integrity of the metal delivery tube and the cleanliness of the melt play a key role in the maintaining a stable metal feed.IntroductionIn the gas atomization process, molten metal is normally fed to the system either continuously using a tundish or in most cases a certain amount of metal is melted in a crucible and flows into the atomizing chamber under gravity. In the first case, the metal flow rate is believed to be constant during the atomization process despite the presence of slag or dross on the molten metal surface. In the second case, the amount of molten metal is depleted with time and the rate at which the metal flow decreases with time varies from test to test in a seemingly unpredictable fashion.' Furthermore, most atomization systems are confined units and the metal level in the crucible cannot be detected by a visualization method. In industry as well as in laboratories, the metal flow rate is normally calculated on either the mass of input material or the mass of total production divided by the duration of the test. This figure is not accurate enough and obviously cannot be used as a control parameter for the gas to metal ratio as it is only determined after the completion of an atomization run. The need exists for a metal flow rate measurement and control methodology; thereby the d50 of the powder produced may be estimated and controlled in real time. Clearly, the smaller the variation of the G/M ratio during the atomization process the more uniform the powder produced and hence the size of the particles can be predicted."

Jan 1, 1994

By Thomas Deschamps

The main objective of this work was to investigate the effect of binder addition on the geochemical properties of surface paste tailings. Nine leaching columns were prepared following different disposal configurations: non-cemented, non-cemented with cemented layers, and cemented .The proportions of cement by total paste weight were between 0 and 1% for a whole column; the maximum amount of cement in a single layer was 2%. The material used was a sulphide-rich tailings coming from a Canadian hard rock polymetallic mine. The columns have been flushed once a week during 30 weeks. The recovered leachates were analyzed for pH, Eh, conductivity, and a wide range of elements. The drainage rates were monitored during the initial disposal as well as after each column flush. The results show that binder addition can improve the whole environmental performances for some of the studied disposal configurations. The disposal configuration consisting of intercalation of three 2% cement paste layers within non-cemented layers (0.66 wt.% of cement for the whole column), and the configuration with 2% cement added only in the two bottom layers (0,44 wt.% of cement for the whole column), showed the best results in terms of water quality and drainage rates.

May 1, 2007

By J. S. Dunning

Recent developments in energy conversion, mining and minerals processing, pollution control, and chemical equipment have placed in-creased demands on heat-resistant alloys. Higher corrosion rates from oxidation, hot corrosion, and sulfidation have increased consumption of materials that contain critical and strategic minerals and in many cases have limited productivity. The Bureau of Mines is conducting re-search on substitute materials having greater resistance to high-temperature corrosive atmospheres above 6000 C compared to austenitic stainless steels such as AISI 304, 316, and 310, with the goal of conserving critical metals such as Cr and Ni. The substitute materials are based on Fe-Cr-Ni-Al compositions. Aluminum additions to Fe-Cr-Ni alloys significantly improve high-temperature corrosion resistance, particularly sulfidation resistance. In the alloy, devised by Bureau researchers, aluminum additions are held in the form of a second-phase precipitate, 8NiAl. Minor additions of Ti, Mn, and Si improve workability.

Jan 1, 1984

By Manuel R. Lastra

Critical to successful dump and heap leaching for gold, silver, copper and uranium are factors such as permeability, solution delivery to the ore, and solution recovery. This paper deals with possible techniques for successful accomplishment of these three factors. New developments as well as older techniques are discussed, together with rationale for use of some techniques in reference to others. The authors hope to present a checklist so that the ideal application to individual mine situations can be achieved. This involves a discussion of the merits of each different method and the situations for most logical application. It is hoped that such discussion will broaden the geographic areas where dump and heap leaching can be applied to include greater winter cold and tropical regions of large amounts of rainfall.

Jan 1, 1984

By Betânia Mendes Sena

Neste trabalho é apresentada a influência de diferentes processos de tratamentos térmicos sobre as microestruturas e propriedades mecânicas resultantes em tubos de um aço sem costura do tipo API 5L. Após tratamentos térmicos, o material foi estudado em três condições diferentes: apenas laminado, normalizado e temperado e revenido, objetivando obter os graus X42R, X42N e X70Q, respectivamente. Ensaios de tração, dureza e impacto foram utilizados para caracterizar o comportamento mecânico dos diferentes graus do aço. Técnicas de microscopia eletrônica de varredura foram utilizadas para caracterizar as microestruturas resultantes dos tratamentos térmicos e as fractografias dos corpos de prova de tração e impacto. Os resultados mostram que tubos de aço sem costura do tipo API 5L não precisam ser de graus tão elevados quanto os tubos soldados, pois graus intermediários relativos aos tubos sem costura possuem propriedades mecânicas similares aos elevados graus de aço relativos aos tubos soldados, o que evidencia a vantagem da rota de fabricação de tubos sem costura.

Aug 17, 2017

By Pilon CG, Deakin RC

It is proposed that a waste rock dump be constructed on slopes consisting of soft colluvium and weathered Chim Formation mudstone at the Porgera Gold Mine, in Enga Province, Papua New Guinea (PNG). Geolog- ical, geomorphological and geophysical investigations were conducted in support of geotechnical studies to assess the physical character of the 6km2 site. Geomorphological studies focused on the extent and nature of colluvium cover and landslide activity. Detailed ground traverse mapping resulted in classification and delineation of eight terrains and seven material types. Seismic refraction and resistivity profiling, combined with drilling, provided subsurface data. Results were presented as standard profiles, coloured contoured sections and plans. Subsurface features, including deep colluvial channels, buried cliffs, slump blocks and buried alluvial channels, were identified. Results of the combined investigations allowed designers to model the colluvium/ bedrock surface and identify critical areas of deep, mobile colluvium and weak bedrock. A design approach was developed which accounted for the morphology of landslide systems and distribution of colluvium types.

Jan 1, 1991

By M. N. Qureshy, D. D. Sarma, B. K. Verma

Kolar Gold Fields are one of the best known gold deposits in South India where gold occurs in quartz reefs in Archaean hornblende schists and shows large variation in grade. The history of mining goes back to 18th century. The workings at Nundydroog Mines, chosen for Operations Research studies, have entered a depth of 2150 meters. The gold values in these mines were thought to be erratically distributed. However, by using 10540 samples from 49 blocks of ore, it is established that the gold value properties in inch- pennyweight units follow a two parameter log-normal distribution. Emperical relationships between arithmetic means and estimates based on peripheral and internal block values have been worked out using the estimator suggested by Krige (1951) instead of 't' estimator suggested by Sichel (1952). These relations can be used in arriving at block estimates with respective standard errors. There is no significant emperical relationship between depth and the grade of ore.

Jan 1, 1969

By John L. Shafer

A process for the conversion of stibnite (Sb2Sj) concentrates, crude antimony oxide, or metal to a pure cubic antimonous oxide (senarmontite) has been developed on a laboratory scale. The conversion of stibnite to senarmontite has been piloted. The high purity of the final product is the result of forming antimony trichloride as a low temperature distillable intermediate. To obtain the antimony trichloride the stibnite, or crude oxide is slurried in molten antimony trichloride and reacted with gaseous hydrogen chloride. Antimony metal is oxidized to the trichloride with chlorine. The hydrogen sulfide produced from the hydro- chlorination of stibnite can be upgraded to a strength of 95% or greater for further treatment. The crude antimony trichloride is separated from the gangue by a preliminary evaporation and then is fractionally distilled and the trichloride distillate has less than 50ppm of arsenic and lead combined (the most troublesome impurities in antimony processing). The purified antimony trichloride is then hydrolyzed with sodium or ammonium hydroxide to produce the cubic form of antimonous oxide (senarmontite) to the exclusion of the rhombic form (valentinite) which is photosensitive. The advantage of this process is the ability to treat a wide range of antimony ores, concentrates, and metal to yield a high purity oxide in a controllable range of particle sizes.

Jan 1, 1975