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By Carl C. Nesbitt

A process has been developed to recover and recycle metals from wastes of brass foundries which contain copper, zinc and lead in various quantities. Tests were conducted to evaluate several leachants, including sulfuric acid, ammonia, hydrochloric acid, cyanide and acetic acid, and to determine the optimum leaching conditions, such as air flow rate, initial copper ion concentration, temperature, and agitation strength. Sulfuric acid containing copper sulfate with dissolved oxygen is the most successful leachant. More than 99% of the copper and zinc originally present in the waste was dissolved, while only 0.5% of the lead entered the solution after 14 hours of leaching. The leaching mechanisms of copper, zinc, and lead are proposed. The copper and zinc can be recovered from the solution by electrolytic processing. The unleached residue may be converted to a lead carbonate which can be converted to litharge at 400-450°C and to massicot at temperature above 500°C by calcination.

Jan 1, 1995

By Claude Gaspard, Stefan Wahlund, Daniel Cavalier

A point of great importance in the cold rolling process for automotive sheet is the cleanliness of the strip, particularly critical in case of batch annealing with no degreasing line or inefficient cleaning before continuous lines. In this specific cases, pollution of the strip surface could be prohibitive when rolling in the early stands of tandem mill with conventional forged work rolls as ground. The strip cleanliness strongly deteriorates during rolling particularly with high roughness rolls: iron fines are generated at the strip surface due to friction and stick on the sheet. It is well known that chrome plating on ground forged rolls in the early stands improve the strip cleanliness. This paper summarizes the results of 3D surface roughness topography studies on forged work rolls, with and without chrome plating, combined with sheet cleanliness measurement during rolling. It shows that a well determined topography has to be obtained on the work rolls used in early stands in order to roll in the mixed lubrication regime, as described by the Stribeck curve, minimizing the friction coefficient and therefore optimizing the cleanliness of the rolled sheet. The main roll roughness parameters to take into account for that purpose are the roughness level Sa, and even more, the Kurtosis parameters Sk, Spk, Svk and Ssk. The ideal surface morphology promotes deep valleys to the detriment of peaks, leading to a roll surface capable of retaining/trapping oil in the valleys, while peaks are minimized, thus reducing the friction in the roll bite and the amount of iron fines produced. To achieve this objective, new grinding wheel technologies are currently developed, in dialogue with wheel manufacturers, to create such ideal morphology of roughness well adapted to HSS forged rolls.

Oct 1, 2019

By E. R. Bauer

The trend in underground room-and-pillar coal mining is to employ remote-control continuous mining machines and extended cuts, 12 m (40 ft) deep or more. This system of coal extraction, adopted by over 435 mines, can create additional worker-safety hazards. To address the ground control and worker-positioning hazards, a combination of statistical analyses and numerical modeling was conducted. Initially, the reported roof-fall incidents and fatalities were reviewed to delineate the ground-control hazards. Then, the application of the Coal Mine Roof Rating (CMRR) for estimating safe extended-cut depths was evaluated. Finally, computer modeling to predict roof displacements during extended-cut mining was completed. The paper describes the results of these studies and their impact on the safety of extended-cut mining.

Jan 1, 1999

By Bruno Nazário Coelho

O ensaio mecânico de microdureza Vickers consiste em aplicar uma força sobre a superfície de materiais e induzir uma deformação plástica localizada. Por meio da análise das dimensões da impressão gerada em função da carga aplicada, determina-se um parâmetro denominado microdureza. Este ensaio tem sido muito difundido para o desenvolvimento de pesquisas e para análises de controle de qualidade devido às suas diversas aplicações, que incluem a determinação de durezas de fases específicas, a identificação da existência de precipitados, o controle de qualidade de juntas soldadas, a caracterização de tratamentos térmicos superficiais, entre outras. Entretanto, um problema associado a esta técnica é a influência do operador sobre as medidas realizadas. Com o objetivo de eliminar esta dispersão de resultados, este trabalho se propôs a desenvolver um software que, por meio de análise de imagens, identifica automaticamente as impressões na superfície das amostras e determina as suas dimensões. O software foi desenvolvido na linguagem C++, fazendo uso da biblioteca multiplataforma OpenCV. Os dados utilizados para a sua calibração foram provenientes de ensaios em amostras de aços, ferros fundidos, ligas de alumínio e de cobre. Os resultados comprovaram a capacidade do software de realizar medições com boa precisão e excelente reprodutibilidade, mas há a necessidade de melhorar os critérios de identificação das impressões, aplicando, por exemplo, técnicas de aprendizado de máquina.

Aug 7, 2018

By W. E. Howlett, R. L. Slobod

Jan 1, 1965

By Liming Yuan

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Jan 1, 2009

By Peter A. Adcock, Rob Fraser

Interest in monitoring nucleation overpotential in electrometallurgical processes dates back some 40 years or more. Conversely, remarkable progress has been made in recent years on describing in detail the processes involved in the formation of thin films by electrodeposition. The newer body of work underscores a need for greater clarity in speaking about the role of nucleation and in the acquisition and interpretation of nucleation overpotential measurements – the aim of this paper. In electrometallurgy, it is generally desirable to form deposits that remain smooth, compact, and relatively fine-grained while the deposit grows to a thickness on the order of 5-10 mm, about 100 times thicker than technological thin films. Hence, we distinguish two kinds of nucleation that can result in formation of new grains:- (1) initial nucleation (onto the substrate surface) of islands that coalesce into growing deposit, and (2) ongoing nucleation of new grains on the deposit surface long after the substrate has been covered and ceases to have a direct influence. Nucleation overpotential of the first type should be measured on an electrode surface truly representative of a real industrial substrate. The second type requires judicious choice of electrode material – an “ideal foreign substrate”. In general neither the industrial substrate nor native metal to be deposited is suitable for measurement of the second type of nucleation overpotential, because of interference by other processes. For the future, clear terminology is needed to distinguish these two types of nucleation potential. The second is the one for which the type of plot dubbed by Moats and Derrick as an “Adcock plot” and by us as a “Kerby-Adcock plot” was first conceived and correlated with relatively thick zinc electrodeposits. The data of Moats and Derrick showing trends for copper electrodeposition on stainless steel and on copper electrodes are interpreted within this framework.

Jan 1, 2016

By J. Alexis, G. Ye, E. Burström

Over the past twenty years the 3 MW DC arc furnace at MEFOS has been frequently used for development of new processes. These processes include recovery of valuable metals from slag, sludge and dust from steel and other metallurgical industry, treatment of ashes from power plant and incinerators, smelting reduction of minerals and zinc recovery from EAF dust. The process characteristics of the DC arc furnace operation in terms of: ? selective reduction, ? total reduction, ? process stability and flexibility, ? dust carry-over, ? thermodynamic conditions provided in the hot spot area, ? precision in composing slag products These are analysed and described in this paper based on technical results from selected test campaigns over the years and thermodynamic considerations. The electromagnetic properties of DC arcs beneath the electrode have been studied by CFD simulation. The calculated result enables us to understand some interesting technical phenomena observed. The heat balance has also been considered based on data obtained from test campaigns and heat balance calculation.

Jan 1, 2004

By Alessandra Regina Machado Schifino

Neste trabalho foi realizado um estudo comparativo entre as normas utilizadas para validação da solda aluminotérmica em trilhos do tipo Premium – Vignole dos modelos TR, utilizada em reparos de trilhos ferroviários. As normas a serem comparadas são: ABNT (Associação Brasileira de Normas Técnicas), AREMA (American Rail Way Engineering and Maintenance of Way Association) e a Norma Europeia (British Standard – Railway Aplication Track – Auminothermic Welding of Rails). Esta comparação será realizada para avaliar a relevância da variação dos parâmetros utilizados em cada uma das normas e quais fatores devem ser analisados em mais de uma norma para que não haja dúvidas se os trilhos estão aptos para serem colocados em operação. Através da realização dos ensaios mecânicos e metalúrgicos, sugeridos pelas normas, encontra-se defeitos causados por diversos fatores, tais como: processo de fabricação, mau uso dos trilhos, falhas operacionais na soldagem, de preenchimento, de solidificação entre outros. Utilizando-se deste conjunto de informações será possível validar as soldas aluminotérmicas testadas.

Oct 30, 2017

By G. X. Du

Improving reaction effectiveness of asbestos tailings and acid is main means to increase the productivity of magnesium hydroxide and amorphous silica and to reduce production costs. In this paper, the process optimization of acid-leaching reaction process of asbestos tailings is reported. Through the orthogonal experiments of four influence factors, such as acid consumption, reaction temperature, reaction time and initial acid concentration in the leaching reaction. The experiment results indicated that the optimal process parameters were as follows: reaction temperature was 95?, reaction time was 1.5h, acid consumption was 218.9g hydrochloric acid(37%) per 100g asbestos tailings and initial acid concentration was about 25%. The influence significance sequence of the four factors was as follows: reaction temperature > reaction time > mass concentration of hydrochloric acid > hydrochloric acid consumption. Under the optimum process conditions, the leaching rate of MgO was 97.3%, total iron 98.15% and Al2O3 57.9%.

Jan 1, 2014

By T. Fraszczak, U. A. Peuker, T. Mütze, O. Ortlepp

Dolomite is a calcium carbonate sedimentary rock that can be found all over the world. In its calcined form it is employed for water treatment or as an additive in iron production. Calcined dolomite is produced at the Wünschendorfer Dolomitwerk GmbH in shaft furnaces (kilns). Because of an expansion of the mined deposit, significantly higher extraction costs were expected. Therefore, the existing upgrading processes for the kiln stone fraction had to be adapted and improved. This paper presents a process optimisation which allows for an increase of the yield of calcined dolomite by 10 % due to a redesign of the crusher circuit and by an additional 5 % due to a comprehensive characterisation of the kiln stone fraction itself. Here the interdependency between the pressure drop in the furnace during calcination and the size distribution of furnace stones was used to increase the amount of fine size fractions in the furnace feed without deterioration of the calcination process. Keywords: Dolomite, crushing circuits, kiln stone production, flowability, calcination

Jan 1, 2020

By Suzzann Nordwick

Over the past decade, significant advances have been made in the development of sulfate-reducing bacteria (SRB) technology to treat acid mine drainage (AMD). Bench-scale testing, field demonstrations, and engineered applications of SRBs for the treatment of AMD will be presented. Designs include an in situ bioreactor installed in the subsurface workings of the Lilly Orphan Boy Mine in 1994, the SRB bioreactors installed at the Calliope Mine from 1998 to 2001, the integrated biological reactors built at the Surething Mine in 2001, and the ongoing development of a replaceable cartridge system. SRB technology benefits include the reduction of dissolved metal ions to insoluble metal sulfides and the neutralization of the AMD resulting from the production of bicarbonate from the oxidation of organic nutrients. This paper will address engineering design criteria including the selection of organic media and system permeability and complete mitigation of AMD. Research was funded under Interagency Agreement No. DW899388-70-01-1 between the US EPA and the US DOE and was conducted by MSE Technology Applications, Inc., through the National Environmental Technology Laboratory (DOE Contract No. DE-AC22-96EW96405) at the Western Environmental Technology Office located in Butte, Montana.

Jan 1, 2003

By Pengfu Tan

NiModel, a thermodynamic model, database and computer program, has been developed to predict the distribution behavior of Ni, Cu, Co, Fe, S, O, As, Sb and Bi, and heat balance in the nickel pyrometallurgical processes such as Outokumpu flash smelting, Outokumpu direct high-grade matte smelting, INCO flash smelting, and Peirce-Smith converting processes. In this model, as much as 16 elements (Ni, Cu, Co, Fe, As, Sb, Bi, S, O, Al, Ca, Mg, Si, N, C and H) are considered. The compositions of matte, slag and gaseous phases, and heat balance are calculated using the thermodynamic data and the activity coefficients of the components derived from the experimental data. The model predictions were compared with the known industrial data from Kalgoorlie Nickel Smelter in Australia, Outokumpu Harjavalta Nickel Smelter in Finland and INCO Metals Company in Canada, and an excellent agreement was obtained. In this paper, the applications of NiModel in the nickel pyrometallurgical industries have been presented. NiModel has been used by Jinchuan Group Limited in China.

Jan 1, 2004

By R. Jacobson

This paper presents comparison of proposed future solution and in-situ mining methods for in-situ leaching and recovery of uranium, gold, silver, and copper. We propose to show that in the future new extraction methods for each metal will eventually evolve for each hydrometallurgical process step, i.e. in-situ leaching, recovery, and concentration; precipitation and reduction; and drying, when required--without generating waste or bleed streams. In the future, to be highly profitable, these forms of mining will develop into an integrated system to eliminate waste streams using safe, powerful lixiviants. This integration will include, with some exceptions, improvements in the following areas of process development: 1. Lixiviant selection and in-situ leaching technique, 2. Target metal recovery and concentration (at a surface hydrometallurgical facility) from the circulating pregnant lixiviant stream, 3. Target metal precipitation or reduction, where decant water from the precipitate dewatering step is reusable for resin or solvent strip liquor (eluant), 4. Final preparation of target metal for sales, i.e. drying, purification, casting, packaging, 5. Restoration where most of the groundwater restoration process is performed at the same rate as multi-wellfield mining.

Jan 1, 1987

By Andy Hudson, Stuart Brashear, David Lilly

Because of greatly increased timing accuracy, electronic detonator systems are a well-known and widely accepted major tool to control and reduce ground vibration. At a Southeastern quarry the authors found that the use of electronic detonators improved the reliability of the well known cubed root scaled distance equation for determining air blast. In addition, the authors noticed significant correlations between selected major peak particle velocity frequencies and air blast magnitudes. The major peak particle velocity frequency alone is a close approximation to air blast magnitudes. This relationship is not as significant or not always evident when standard pyrotechnic initiation systems are used.

Jan 1, 2009

By S. K. Sharma, ANKUSH GALAV, G. S. P. Singh

Providing a suitable protective water barrier pillar (PWBP) is common to reduce inundation hazards in underground coal mines. The imperative factors influencing its performance include the water head acting on the pillar, cover depth, pillar width, strength properties, and permeability characteristics. The mechanical failure of such pillar is a stress-controlled phenomenon, whereas the hydraulic failure is a strain-based phenomenon. A finite-difference numerical modeling approach was developed to study the hydro-mechanical coupled behavior of protective water barrier pillars. The mechanical stability was evaluated in terms of the percentage of failed (ZoF) and intact zones. The influence of the strain-controlled weakening on the permeability of the flow medium was studied through the coupling of the mechanical and hydraulic effects. The coupled steady-state model was used to estimate the outflow rate and its hydraulic stability. The adequacy of the protective pillar was also investigated by assessing mechanical stability and capability to resist hydraulic pressure against the maximum expected water head. A seepage rate-based classification system has also been proposed to evaluate the seepage potential and assess the hydraulic stability. The model has been validated for two case studies at the cover depth of 136–189.5 m and the existing pillar width of 16–42 m against the water head of 25–141 m.

Aug 18, 2022

By Felipe Calizaya, Sekhar Bhattacharyya

Mechanized underground mines suffer from noise overexposure. Noise levels are often above the Permissible Exposure Limit (PEL) where underground fans are used. Sound levels in active workings can reach up to 121 A-weighted decibels (dB(A)), especially when fans are not equipped with silencers. Use of silencers seldom ensures PEL. Overexposure of noise induces permanent hearing loss among mine workers. A NIOSH-funded research project and field studies at six coal and non-coal mines revalidated the findings. The University of Utah undertook laboratory studies to reduce fan noise at the source. A new silencer prototype with varying noise dampening material was designed and tested. The silencer and associated extension can be repacked with different dampening materials. The silencer and the extension were used in various configurations. Attempts were also made to simulate field conditions. The tests demonstrated a maximum sound level attenuation of about 14 dB(A) at the fan discharge. A properly designed silencer offers lesser resistance and thereby better fan performance and lower energy cost. The re-packable silencer is more likely to be maintained properly. Lowering of noise level happens in audible frequencies (4000 to 8000 Hz) which are important in A-weighting.

By R. C. Miranda

Flotation is an operation widely used in mineral processing because of its aptitude to recover minerals of interest very efficiently. Flotation is often responsible for making possible the exploitation of mineral deposits of low concentration. In flotation various processes phenomena occur, some of which have still not been explained scientifically. Due to this fact, there are no models that can be widely applied in flotation control. Thus, in most cases, the control is done by experienced operators who are able to visually classify the types of foam into different categories and each one of them is associated with an operating actuation. In this situation, image analysis is configured as a solution that has already been employed in several ways. In this paper, a control strategy based on the colour of froth on a direct flotation of a nonferrous metal is presented. Moreover, the paper reveals the theoretical basis of the method, the critical points, difficulties and improvements that can be implemented. Data of grade were collected from the mineral of interest and RGB (red, green and blue) data of final concentrate of the froth. The mineral grade was collected and analysed during one month of operation and RGB was obtained using a camera. It was verified that the red colour showed the same trend of the grade curve in the concentrate. Thus, the use of this online data in optimising control was introduced. The laboratory grade is used to calibrate the colour set point. Therefore, it was possible to monitor in real time the trend of enrichment and depletion of a non-ferrous mineral in a flotation. It was possible to establish an online control strategy based on simple data acquisition. The result was an increase of 10% on production.

Sep 1, 2012

'T. C. MERRIMAN, New Haven, Conn. (written discussion *).-This most interesting paper gives much carefully obtained and valuable data. However, there are two points in connection with the commercial application of such data that might possibly be a source of trouble and mis-understanding. In the first place, the examination of thin sections of annealed brass, subjected to standard Brinell test.(500 kg. on a 10-mm. diameter ball) at thicknesses from 0.075 to 0.150 in. (1.9 to 3.8 mm.) indicates that cold work has been performed on the specimen during the application of the load sufficient to extend way through the section, and have the hardness of the metal affected by the backing. If the usual steel support is used, this effect is very evident. If a piece of soft brass is used as a support, there is an indentation in the surface of the support accompanied by a bulge on the under side of the tested specimen opposite the impression made by the 10-mm. ball. The result is that Brinell specifications (governmental or otherwise) on stock for a certain purpose may not be fair in all cases, since manufacturers, owing to differences in equipment, etc., may not all use precisely the thickness and conditions of stock on which the Brinell specifications were based. This would mean that the government Brinell specification might not give them the temper of stock best suited for their manufacturing methods. The concluding paragraph of this paper, stating that "the hardness of cartridge brass may be determined with greater accuracy by the Brinell hardness measurement than by attempting to judge it from the grain size" appears to be in line with the movement of the last year or so among brass manufacturers toward substitution of the Brinell test for microscopic examination as an acceptance test on cartridge brass. The statement may he strictly true that the Brinell test is the best test for hardness, but it is not, as the statement might readily be construed, a sufficient test of suitable condition. For instance, some cartridge brass might accidentally have been overheated to a point where it would be distinctly unsafe to use for the manufacture of small arms cases and then be so rolled (reduction 3 to 5 per cent.) as to pass perfectly proper Brinell specifications. Under such conditions the microscope would reveal its unsuitability where the Brinell test had failed so to do.

Jan 4, 1919

By S Maritsa, E K. Chiw, S M. Masuka, ika, T Chisahwira

The challenges facing the iron and steel industry on a global scale include depletion of resources, excessive energy consumption and CO2 emissions. The demand for iron products in Zimbabwe is increasing due to massive infrastructural development like the expansion and improvement of mines, transportation systems and water reticulation systems. In Zimbabwe, cast iron is mainly produced from recycling scrap metals. However, there is currently a shortage of scrap, which has resulted in the vandalism of state-owned properties such as bus terminals and railway wagons and lines. Nevertheless, Zimbabwe is rich in limonite ores, which are idle, and it is the aim of this research that this ore be effectively used to produce feed for the blast furnace. The Blast furnace is still the dominant route for producing cast iron where sintering and coking processes are the main routes for preparing the Blast furnace feed. Sintering limonite ore fines produce a product of poor grade because of the high value of loss on ignition that has a negative impact on Blast furnace efficiency. Furthermore, the sinter plant and the coke making plant are a source of huge environmental pollutants. Since low-grade Zimbabwean coal fines are also available in abundance, they were used in the preparation of the composite materials ensuring maximum utilisation of this resource. Results showed that the limonite ore-carbon composite pellets sample with the binary basicity ratio (CaO/SiO2) of about 0.27 and coal addition of 2.5 wt per cent achieved above the minimum physical quality requirements for pellet of drop number of at least 4, a dry compression strength greater than 2.2 kg/pellet and an indurated compression strength greater than 250 kg/pellet. Limestone was used as the binder avoiding the addition of more impurities from bentonite since the limonite ore has a high SiO2 content of about 8.78 wt per cent.

Sep 18, 2023