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By J. W. Evans

ONE of the most important and frequent calculations that the extractive metallurgist is called upon to make is that of the standard free energy change of a reaction (?F°). For many reactions of metallurgical interest, the lengthy arithmetical calculations have been eliminated by the use of free energy-temperature diagrams which have been constructed by Ellingham,1 Richardson and Jeffes,2 Kellogg,3 and Osborn4 (e.g., for oxides, sulphides, halides) from critical surveys of existing data. The speed and simplicity of making calculations with these graphs make them of great practical value and, this should be stressed, in the majority of cases no greater accuracy is obtained by the individual calculations from specific heat data, entropies, and heats of reaction. With the increasing industrial application of vacuum methods to the winning of metals, notably at present magnesium and the alkaline earth metals, it is necessary to calculate low metal vapor pressures above reaction mixtures. The existing free energy diagrams usually give values where the solid and liquid metals are at unit activity. To obtain the free energy change associated with the reaction Metal (solid or liquid) = Metal (gas) it is customary to calculate this from either vapor pressure equations or from the appropriate free energy functions. This paper presents graphically the free energies of vaporization of a number of metals of economic importance which can be used in conjunction with other free energy diagrams. Certain metals have been excluded on the following grounds: titanium, tungsten, molybdenum, and platinum have very high heats of vaporization and boiling points and the uncertainty of these values arising from difficulties of high temperature measurements makes free energy values of doubtful accuracy; the data for cobalt, vanadium, and zirconium are uncertain; finally, arsenic, antimony, and bismuth could not be conveniently included. because of the presence of mixtures of polyatomic and mona-tomic vapors in the temperature range considered. Free Energy Diagram In Fig. 1, the standard free energies of vaporization per mol (?F°T) have been plotted for the temperature range 0" to 2000°C for the reaction M (solid or liquid) = M (gas) The data have been obtained from the free energy functions — (F-H298)/T for the solid, liquid, and gaseous elements and the heats of vaporization at 298°K, i.e., ?H298 (vapor). The values of these functions have been taken without change from the recent critical survey by Brewer;' the bulk of this data is from Kelley7 with adjustments in the light of more recent work. Values of the function — (F-H298) /T at T = 298°, 500°, 1000°, 1500°, and 2000°K were employed. Where possible, a further independent value was obtained by using the boiling point, i.e., where ?F°T = 0. All calculations are based on the assumption that the metal vapors are monatomic and that the boiling points refer to those temperatures at which the partial pressure of the monatomic vapor above the metal is 760 mm. For the alkali metals, e.g., sodium, potassium, and lithium, diatomic gas molecules are present as minor species; details of these are discussed by Brewer." On the basis of the above values and allowing for the change in slope at the melting point, straight line graphs were constructed and extrapolated to 2000°C. The deviation from a straight line did not exceed ±500 cal, which in all cases appears less than the probable error in the ?F°T values.

Jan 1, 1954

By X. Q. Cao

As the second largest phosphate resource in the world, Chinese phosphate ores generally grades with low of P2O5. The presentation of beneficiation test on the low grade of phosphate rock in this paper may be used for a reference for development and utilization of the similar reserves. The ore is a marine sedimentary phosphate rock containing low grade of P2O5 and high content of MgO and R2O3; The banded structure shows its suitability for heavy medium separation. The laboratory heavy liquid testing results indicate that as specific gravity of the heavy liquid is 2.85 g/cm3, a rougher concentrate assaying 28.71% P2O5 could be obtained while the rougher tailings contain only 4.47% P2O5. When the combined process with heavy liquid separation followed by direct & re-verse flotation is employed to treat the feed containing 21.15% P2O5, 3.79% MgO, 1.86% Fe2O3, 3.66% Al2O3, 23.75% A.I, and specific gravity of heavy liquid is 2.84 g/cm3, the optimum mesh of grind is 67.5% minus 200 mesh, a phosphate concentrate contained 32.51% P2O5, 0.48% MgO, 0.81% Fe2O3, 1.69% Al2O3 can be produced at a yield of 55.24%. The concentrate P2O5 recovery is 85% with which quality comply with the Class A specifications for production of phosphate fertilizer.

Jan 1, 2014

By O. C. Blade, Elizabeth Hughes

Conservation in the utilization of any product is always subject to improvement if the composition and properties of the product are known. Petroleum is no exception, and knowledge of the characteristics of crude oils, even when given on the broad basis of routine type analyses has proved useful to chemists, engineers, and geologists in improving pro- duction and utilization of petroleum. For a quarter of a century the Bureau of Mines has sought to provide such information regarding crude oils and has analyzed many samples of petroleum by its standardized rou- tine method. Most of these analyses have been published, sometimes in special compilations, other times in connection with reports of research on petroleum. This report is a finding index for all analyses published up to January 1, 1948. The routine method used for all these analyses is basically the same as that described by Dean, et al.. Briefly, the procedure consists of testing by standard methods, small samples of a crude oil for gravity, sulfur, color, and viscosity, and of distilling a sample of the crude oil by a standardized procedure and determining certain properties in the sep- arated fractions and residuum. Careful records are made during the proce- dure, and the distillation data obtained are used to calculate the approx- imate amounts of products present in the sample such as percents of gas- oline, kerosine, gas oil, and lubricants. The data obtained are recorded on a standard analytical report form. An analysis of a sample of typical midcontinent crude oil is shown in table 1. Compilation of these analyses, sometimes in tabular form and usually for specific geographic areas, are published from time to time. Analyses are often shown in connection with other studies, such as engineering field reports. This bibliography is a compilation of references to 115 publications, which contain analyses of crude oils by the Bureau of Mines. References may be found to analyses of crude oils from the United States, Canada,

Jun 1, 1948

By AIME AIME

EVERETTE LEE DEGOLYER, past President of the Institute and Anthony F. Lucas Medalist, was presented with the John Fritz Medal at a dinner at the Wal-dorf-Astoria Hotel in New York, Jan. 14. Dr. DeGolyer is the third representative of the Institute in recent years to receive the John Fritz Medal which is awarded jointly by the four Founder Engineering Societies through a board composed of sixteen past presidents. In 1938 Paul D. Merica was given the award "for important contributions to the development of alloys for industrial uses" and in 1933 the distinction was given to D. C. Jackling "for notable industrial achievement in initiating mass production of copper from low-grade ores through application of engineering principles."

Jan 1, 1942

By N. T. Cowper

Slurry viscosity ultimately affects the majority of mineral extraction processes. However, to date its role has been disguised because mineral processing equipment has been conservatively designed to operate at minimal slurry viscosity. With most ores this still meant acceptable solids concentration was achieved. However, with the advent of treatment of weathered ores the resulting higher slurry viscosity (rheology) has meant solids concentration has had to be reduced, often to unacceptable levels. To permit operation at higher solids concentration chemical dispersants are employed. These dispersants are expensive and their addition should be controlled. Slurry Systems Pty Limited (SSPL) has developed an On-Line Viscometer to monitor and control slurry viscosity, whether by controlling water addition or by controlling dispersant addition. Using this instrument the slurry rheology can be controlled at the optimum level, maximizing solids throughput, and minimizing water, reagent, and dispersant addition. This paper discusses rheology of typical mineral slurries, the relationship between slurry rheology and percent solids in a slurry, and the need for rheological control in mineral processing. The effects of rheology on various process steps, and the use of dispersants are reviewed. The paper concludes with summarizing actual case histories and cost impact of Theological control.

Jan 1, 1992

By A. Q. Tool

THE necessity of accurate temperature measurements in the glass-making industries is today being much more widely appreciated than in the past. The introduction of the modern simplified and perfected pyrometric methods in connection with exact regulation of furnace temperatures has caused a marked improvement in the glass product with a quickened rate of production. An example of the processes in which much improvement has been and still can be made is that of annealing or heat-treating the glass. This is one of the most delicate processes in glass manufacture and one that requires a most careful furnace control. The heat treatment is undertaken to decrease the possibility of breakage and, in glass for fine optical instruments, to prevent serious warping of accurately ground and polished surfaces and to make the glass more uniform throughout to the passage of light waves. These objects are accomplished by removing all the harmful stresses that exist in a piece of glass when it has been cooled too quickly or unevenly. Such stresses exist, for example, after it has been pressed, cast, or otherwise worked. Thus the process of annealing consists of heating the glass evenly to the temperature at which it softens just enough to relieve these stresses in a reasonable time and then cooling slowly and uniformly until the glass hardens again. Accordingly, the things that must be investigated and determined in order to anneal glass without loss of time are, the annealing temperature, the time that the glass should be held at this temperature while the stresses relax, and the quickest cooling procedure that will give satisfactory results. After these characteristics of the glass are known the problem is one of pyrometry and temperature control entirely. In cases when it is known that a glass article will be required to withstand some definite type of heat or mechanical shock it is often possible, by a proper heat treatment, to produce such a distribution of the stresses in the glass that it will be enabled to resist these shocks more effectively.

Jan 9, 1919

By G. Walsh, M. T. Wild

In this paper the performance effects of linear shaped charges will be discussed. Different sized charges were tested and reviewed based on their performance used with a typical detonation method vs. detonation with a line wave generator. The goal of the project was to determine if the linear shaped charge had better performance with an ideally linear wave moving through it, verses a swept wave that is currently used. A line wave generator is a flexible sheet explosive formed into a triangular shape with holes placed in strategic places to cause a detonation wave to become linear across the width of the triangle. A standard linear shape charge with a detonator in the side of the charge was be detonated against a witness plate to get a standard depth of penetration. A second standard linear shape charge with a detonator connected to the top of a line wave generator, the line wave generator placed on top of the linear shape charge, was be detonated against a witness plate to get a comparison depth of penetration. All charges had a standoff 1.5 times the width of the cavity, allowing the data to be compared to the control charge. Computer modeling was intended to be used to predict the results from testing these designs in the field. The actual results were compared among themselves.

Jan 1, 2011

By Phil Pennington, D. Jack Adams

Mining and processing of minerals, metals, and fossil fuels can release selenium and arsenic into wastewaters. Both selenium and arsenic are difficult to remove to levels that meet current drinking water and discharge criteria. These metalloids can be used as electron acceptors by microorganisms transforming them back to reduced states, thus removing or stabilizing them. Bioremediation cost effectiveness will be discussed in terms of site information required, microbial populations, co-contaminants, pH, redox, and nutrients. Full-scale, economical ex situ and in situ biotreatments are possible and can produce 1,000’s of times less sludge than conventional precipitation technologies.

Jan 1, 2005

By R. D. Springer, R. L. Wilcox, P. A. PALMARTAN, R. K. Waring, E. A. Anderson

A knowledge of the mutual liquid solubility of zinc and lead is of importance in various phases of zinc metallurgy. The determination of this solubility has been the subject of numerous investigations, but unfortunately the results vary widely, particularly at higher temperatures, and it has been impossible to decide what data are most reliable. It was decided to investigate the matter and in view of the disagreement in the published results, it was felt necessary to take rather unusual precautions to insure the reliability of the data. For this reason determinations were made by four different methods, and the procedures of several of the previous investigators were duplicated. The previously used methods can be divided into two classes: methods involving freezing the entire melt and taking samples of the lead-rich and zine-rich phases in the solid state,l,2 and methods in which the samples are taken while the bath is liquid and at the desired temperature.3,4 Data obtained by methods involving freezing the entire melt show much lower solubility of lead in zinc than methods in which the liquid is sampled at temperature. The latter method was used by Spring and Romanoff5 and by Hass and Jellinek.6 The results of these two investigations are in agreement at temperatures near the melting point but at higher temperatures Hass and Jellinek find a higher mutual solubility. The low-temperature section of the zinc-lead equilibrium diagram is given by Peirce and Anderson.7 The diagram is based on the data of Hodge and Heyer,8 Arnemann,9 and Peirce.10

Jan 1, 1934

Experience, it is said, is the best teacher. Some experiences, however, should be shared so that no one else will ever have to live through them again. The fire at the Sunshine Mine is one such experience. ?Hard-rock mines don?t burn.? The Sunshine Mine near Kellogg, ID, was the nation?s premier silver producer for many years. In 1972, the mine was nearly 6,000 feet deep, contained hundreds of miles of worked-out areas, and employed nearly 500 people. Because of its depth and the type of host rock for the silver (unburnable quartzite), the general thinking of the day was that fires in mines such as the Sunshine were impossible, because ?hard-rock mines don?t burn.? What wasn?t really considered was that timber supports, foam insulation, and mining equipment do burn and that the carbon monoxide gas produced by burning is far more deadly than fire itself. Thus, no one was prepared when, on May 2, 1972, a fire of un-known origin broke out below the 3100 level of the mine. Before long, 173 miners on the day shift were trapped by thick, black smoke. By the time the fire was out, 91 miners had died, and the Sunshine Mine Fire became known as one of the worst mine disasters of the 20th century. It became the catalyst for passage of the Metal/Nonmetal Health and Safety Act of 1977, which applied the same federal safety standards to hard-rock mines as those regulating coal. Mandated safety training, mine inspections, and equipment standards were brought into force.

Aug 1, 2002

By W. E. Keck, Paul Jasberg

TheRe is a considerable tonnage of iron ore in the Menominee Range of Michigan that is unsalable only because it has too large a content of sulphur. Beneficiation of such ore is economically desirable, as a relatively large quantity of finished concentrate would be obtained (deleterious sulphur mineral content being generally less than 5 per cent) and because large blocks of such ore have been developed incidentally during search for low-sulphur ore. Research on the flotation beneficiation of these high-sulphur ores consisted of: (1) a study of the flotative properties of the principal mincrals in a nearly pure state, (2) flotation of synthetic mixtures of these pure minerals and (3) application of this experimental information to samples of the ores. Gypsum in iron ores is extremely deleterious; but when sufficiently free from impurities it is a valuable commodity. In 1934, the United States produced 1,500,000 tons of calcined and uncalcined gypsum valued at $13,700,0001. Of this quantity and value, Michigan produced approximately 19 per cent1. Thus this investigation may also prove to be of interest in connection with the gypsum industry if minerals separation, such as flotation, becomes necessary in the future processing of gypsum. Data on the flotative properties of gypsum would also be of interest to the science of flotation because such information has been extremely limited. The technical literature reveals one reference to the flotation of gypsum, in which was discussed the use of the mineral, with several others, to determine the relation between the floatability of minerals and the pH of the flotation solution2. This investigation necessarily was not comprehensive in regard to gypsum, but it did show that the mineral could be floated with oleic acid under varying pH conditions.

Jan 1, 1938

By W. E. Keck, Paul Jasberg

TheRe is a considerable tonnage of iron ore in the Menominee Range of Michigan that is unsalable only because it has too large a content of sulphur. Beneficiation of such ore is economically desirable, as a relatively large quantity of finished concentrate would be obtained (deleterious sulphur mineral content being generally less than 5 per cent) and because large blocks of such ore have been developed incidentally during search for low-sulphur ore. Research on the flotation beneficiation of these high-sulphur ores consisted of: (1) a study of the flotative properties of the principal mincrals in a nearly pure state, (2) flotation of synthetic mixtures of these pure minerals and (3) application of this experimental information to samples of the ores. Gypsum in iron ores is extremely deleterious; but when sufficiently free from impurities it is a valuable commodity. In 1934, the United States produced 1,500,000 tons of calcined and uncalcined gypsum valued at $13,700,0001. Of this quantity and value, Michigan produced approximately 19 per cent1. Thus this investigation may also prove to be of interest in connection with the gypsum industry if minerals separation, such as flotation, becomes necessary in the future processing of gypsum. Data on the flotative properties of gypsum would also be of interest to the science of flotation because such information has been extremely limited. The technical literature reveals one reference to the flotation of gypsum, in which was discussed the use of the mineral, with several others, to determine the relation between the floatability of minerals and the pH of the flotation solution2. This investigation necessarily was not comprehensive in regard to gypsum, but it did show that the mineral could be floated with oleic acid under varying pH conditions.

Jan 1, 1938

By C. Y. Wang

Anodic reaction mechanism of complicated antimony-lead concentrate in Slurry Electrolysis has been investigated by the anodic polarization curves determined under various conditions. The main reactions on the anode are the oxidation of FeCln (2-n), though the oxidation of jamesonite particle on the anode can occur during the whole process, it is less. With the help of mineralogy study and relevant tests, the leaching reaction mechanism of jamesonite and gudmundite during Slurry Electroly-sis has been ascertained also. Because of the oxidation reaction of FeCl3 produced by antimony-lead concentrate itself, the non-oxidation complex acid dissolution of jamesonite, the oxidation complex acid dissolution of gudmundite, and the oxidation of air carried by stirring, the leaching ratio of antimony reaches to about 35% when using HCl-NH4Cl solution to leach antimony-lead concentrate directly. So given the theoretical electric quantity, which to oxide antimony in Slurry Electrolysis, all of antimony, lead and iron, which contained in antimony-lead concentrate, are leached.

Jan 1, 2014

By Filippo Vallianatos, Michael Verigakis, Vasili Saltas, Kosta Kaklis, Stelio Mavrigiannakis, Zach Agioutantis

"Development of failure in brittle materials is associated with microcracks, which release energy in the form of elastic waves called acoustic emissions. This paper presents results from acoustic emission measurements obtained during three-point bending tests on Nestos marble under laboratory conditions. Acoustic emission activity was monitored using piezoelectric acoustic emission sensors, and the potential for accurate prediction of rock damage based on acoustic emission data was investigated. Damage localization determined based on acoustic emissions evident in the critically stressed region in the form of scattered events or stresses below and close to the strength of the material.IntroductionNon-destructive testing (NDT) has gained popularity in recent years due to commonly available sensors, devices and software tools. Although the majority of such testing still occurs under laboratory conditions, the ultimate goal is a direct field application, especially in the case of underground mining. NDT, if properly applied, may be used to directly provide material property values and characteristics that can be used to determine rock mass or soil mass behavior, with a direct impact to mine design (Iannacchione et al., 2003).AE is generally defined as the high-frequency transient elastic waves originating from the sudden release of energy at localized points within a loaded material (Nomikos et al., 2010). The field of Acoustic Emissions (AE) due to compressive, tensile or other types of loads is a promising research area due to its wide application. The accurate identification of failure precursors stemming from AE is still an open research topic (Lei et al., 2004).Rock is a typically inhomogeneous and anisotropic material that contains several natural defects with various scales such as grain boundaries, microcracks, pores and joint inclusions (Jing, 2003; Read, 2004). Damage induced by microcracks is an essential mechanism in many brittle rocks subjected to stresses. An applied stress induces microcrack growth and damage is distributed uniformly throughout the sample. Finally, the microcracks coalesce and the damage is localized to a shear band, leading to strain softening and macro-scoping failure (Dragon et al, 2000)."

Jan 1, 2015

By E. Ray Webb

A interest to geologists and to mining and petroleum engineers is a laboratory method for determining the dip and strike of sub- surface structures, as well as the direction of fault planes traversing them. The information is derived by making use of the magnetic properties of borehole cores which must show visible representations of bedding or fault planes. Complete knowledge of these factors aids greatly in the successful exploitation of both ore and petroleum deposits.

Jan 1, 1940

By Duran A, Eggers M. J

It is standard practice in geotechnical studies for mine design to drill a series of inclined oriented boreholes into the proposed pit walls. However, this investigation tool is often used without an adequate understanding of the inherent shortcomings in the method and the many potential sources of error. Of the more commonly used orientation methods in Australia the clay imprint technique is probably the most reliable. Contoured stereographic plots of oriented core data are frequently characterised by diverse pole distributions and low concentration maximums compared with line mapping data. Common sources of error producing these poor results are misinterpretation of orientation marks or imprints, inaccurate marking of the reference line, errors in the structural measurement of the defects, lack of continuity information and blind zones sub-parallel to the borehole direction which correction methods frequently do not fix. Line mapping is the preferred method of structural data collection due to the lower overall cost, availability of continuity information and higher accuracy. The projectability of field mapping data to final wall positions can be assessed with a good understanding of the regional geology and local structural patterns. Where field mapping is not possible due to a thick regolith cover, core orientation should be carried out by experienced personnel to minimise the many potential errors.A series of case studies are presented which compare oriented core with mapping and highlight the inherent problems with the technique.

Jan 1, 1992

By Don Steffa

Drift mining, according to California mining terminology - and it is distinctly a California development - is the blocking out and extraction (breasting) of the auriferous gravels of an ancient buried stream either through tunnels, inclines, or shafts; it is one of the minor divisions of the larger classification known as placer mining. The contribution of each of these divisions and of lode mining to the gross production of gold in California totals as follows:3 [ ] The total amount of gold recovered from the placers of California from 1848, when Marshall discovered the precious metal in the mill race at Coloma, to 1928, was $1,226,515,404. The same period saw a total gold production from all operations of $1,823,562,360.

Jan 1, 1932

By H. M. Roche

MAGNETITE mining and milling in the Eastern States in 1939 showed considerable improvement over 1938. For the first eight months of the year production of magnetite proceeded at a normal rate but operations were stepped up in the last four months owing to increased domestic demand. In New York, the Republic Steel Corp. operated the Witherbee-Sherman mines at Mineville throughout the year. Chateaugay Ore and Iron Co. operated their low-phosphorus mine at Lyon Mountain for the first seven months, but on Aug. 1, Republic Steel took over this mine -and have since operated it. In Pennsylvania, the Bethlehem Steel Co, operated the Cornwall mine continuously. In New Jersey, Mt. Hops and Scrub Oak were in operation all year. The Washington mine went into production on Nov. 1 and the Richard mine on Dec. 1.

Jan 1, 1940

By W. W. Harvey

The work to be described was part of an exploratory research program directed toward identifying potentially useful but little known reactions in extractive metallurgy. In particular, the major copper sulfide minerals, as a group, have long been considered insoluble in nonoxidizing acids (e.g. Forward and Barren, 1J60; Parsons and Ingraham, 1970; Peters et al. 1972). This generalization was considered to include nonoxidizing conditions in warm aqueous MC1 solutions (Ingraham et al. 1972) and, indeed, was consistent with our own chemical and mineralogical experience. On the other hand, under hydrothermal conditions, copper and sulfide species are carried in solution and deposited as sulfides in mineralized veins. The question that poses itself is: what are the mildest conditions of temperature and fluid composition under which commercially important copper sulfide minerals can be solubilized in the absence of an oxidizing agent? A reference to H2S formation during oxygen-sulfuric acid pressure leaching (Warren, 1958) of chalcopyrite, when the oxygen partial pressure was allowed to fall, provided a clue. In the present study, experimentation with chalcopyrite concentrate in dilute hydrochloric acid, under re flux conditions (in Pyrex flasks) and with an inert purge gas, revealed substantial amounts of H2S production and iron solubilization, cite negligible copper solubilization, after 2 ½ -4 days. Under comparable conditions the extent of reaction with dilute sulfuric, acetic and phosphoric acids was markedly less.

Jan 1, 1976

By G. R. Lane, A. Vermeulen, S. van de Venter, S. Bhoowanpursadh

Over the past two years Anglo Platinum made use of the specialist skills of Cyest Corporation to develop a Mine Optimization Tool (MOT) to enhance the current suite of in house mine planning tools and processes. The application was built in a multidimensional modelling environment developed by Cyest called CarbonL. This has allowed complex modelling that is transparent to the business users and therefore is not prone to the ?black box? approach that generally exists with these types of complex tools. The purpose of the MOT is to have an integrated software tool that can schedule production activities by half level for a shaft complex, while at the same time integrating the economics concomitant with that schedule. The tool allows the user to configure all activities relevant to the selected mining method, define the mine design parameters and geological parameters, define scheduling rules and then schedule all activities. This allows the user to test various production strategies and schedules very quickly and easily in terms of shaft value, costs and revenue profiles, labour complement and production ramp up so as to determine the option that best fits the overall strategy. This allows assessments of multiple scenarios in a relatively short period of time, after which only the best option is taken forward for graphic design and scheduling. This paper discusses briefly the rationale behind the Mine Optimisation Tool and the underlying workings of the modules that comprise the tool. It also covers the life cycle of this tool from the original prototype through to the final Mine Optimisation Tool software and discusses the positioning of the final tool.

Jan 1, 2007