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By M Kim, J Park, I-K Suh, E Kim, J Lee

One of the key technologies in developing hydrogen-enriched ironmaking operations is the control of the carburisation, melting, and dripping behaviour of the iron ore burden materials. When a hot compacted iron (HCI) is charged in the blast furnace or the FINEX Melter-Gasifier, iron oxide reduction, the reduced iron’s carburisation, and the melting of iron and slag occur successively. This study investigated the reduction, carburisation, melting and dripping behaviour of HCI under a COH2 gas mixture using the high-temperature X-ray radiographic technique. Under 100 per cent CO gas atmosphere, the dripping temperature was 1410°C. When 5 per cent H2 was introduced, the dripping temperature slightly decreased to 1400°C. Furthermore, the dripping temperature gradually increased as the H2 gas composition increased. As 30 per cent H2 was introduced, the dripping temperature reached 1414°C. The carbon concentration in the drained metal samples gradually increased with increasing H2 composition. It is considered that H2 decreased FeO content in the slag, yielding the increased melting temperature and viscosity of the slag. On the other hand, H2 accelerated the carburisation of the reduced iron by CO gas, enabling the homogenisation of the oxide materials to form a liquid phase. Therefore, it is considered that introducing H2 in the reactor is helpful to increase productivity and energy efficiency by accelerating the liquid phase’s formation.

Aug 21, 2024

As part of the Bureau of Mines subactivity in secondary resource recovery and to expand the Nation's mineral base, the Tuscaloosa Research Center made characterization and preliminary beneficiation studies of the waste residues from various coal-conversion processes: from pilot plant tests of the Synthane process for coal gasification, the Synthoil process for coal liquefaction, and the solvent-refined coal (SRC) process for sulfur removal from coal. Those coal conversion processes selected for this study were based on the availability of pilot plant samples. Physical, chemical, and mineralogical examinations of the wastes made to determine the mineral content prior to physical beneficiation tests indicated that in addition to significant quantities of carbon, some trace elements offer potential for concentration.

Jan 1, 1980

By T. C. Eisele

The separating efficiency of a flotation column is largely limited by the degree of backmixing of tailings into the froth zone, and its recovery is limited by the degree of short-circuiting of feed to the tailings. Current columns are typically made very tall, on the order of 30-40 feet, in order to limit the effects of backmixing and short-circuiting. These effects can also be reduced in a much shorter column, provided that the flow in the column approaches plug-flow. In this work, horizontal baffles were shown to improve the performance of a 6-foot tall laboratory-scale flotation column treating a difficult-to-clean, heavily oxidized coal. Tests with variation in the position of the baffles showed that for the greatest benefit, baffles are needed both above and below the feed inlet. Tracer tests with a fluorescent dye water tracer showed that the addition of the baffles reduced the amount of feed water entrained into the froth at any given coal recovery.

Jan 1, 1994

By Lucas Rosate Leite dos Santos, Erica Marcelino Freitas de Souza Silva, Glaucio Soares da Fonseca

Aços Inoxidáveis Austeníticos (AIA) são largamente utilizados não somente por sua boa resistência à corrosão, mas porque eles são amplamente conformáveis, fabricáveis, duráveis e soldáveis por praticamente todo os processos. À temperatura ambiente, as ligas homogêneas forjadas são, em geral, completamente austeníticas. Entretanto, para muitas aplicações essas ligas necessitam ser submetidas a processos metalúrgicos como a soldagem, que por sua vez pode causar modificações microestruturais. Desta forma, uma liga que antes era completamente austenítica pode apresentar frações de ferrita- δ retida. O presente trabalho investiga a influência do aporte térmico na evolução da microestrutura de solda do AIA 316L submetido à solda similar em dois diferentes aportes térmicos pelo processo TIG Autógeno. A análise microestrutural das amostras soldadas, foi realizada via Microscopia Ótica. Os resultados possibilitaram concluir que o aporte térmico de fato influenciou na microestrutura final do 316L, pois após a soldagem, para ambos aportes aplicados, a microestrutura foi composta de austenita e ferrita-δ e não apenas predominância da austenita como inicialmente apresentava o Metal Base.

Oct 7, 2019

By John Naughton

At the General Electric ResearchLabora-tories, we have been interested in the iron-manganese system and the effect of hydrogen on the properties of these alloys. Dr. H. H. Uhlig previously has presented some of these results.' We wish now to offer some other of the data that have a bearing on the subject of this symposium. In the determination of hydrogen in the iron-manganese system by any heating Method we are presented with the problem of the evaporation of volatile manganese and the consequent adsorption of hydrogen by this evaporated metal. It seems wise. therefore, to extract gas at as low a temperature as feasible. Consequently we chose the vacuum or hot extraction method for the analyses of these alloys. The apparatus used is shown in Fig. I. The design is a modification of the apparatus described by Holm and Thompson. To limit loss of hydrogen, samples are stored in a chamber immersed in liquid air. We recommend this procedure whenever there is a question of loss of hydrogen at room temperature. Thence they are moved to the quartz furnace by means of a small magnet, where they are heated by induction to 700' to 800°C. The extracted gas is removed by the circulating pump and placed in the known volume VI (or V2). The circulating pump has been described.3 It is so designed that in spite of the fact that the outlet portion of the pump is part of the known volume, this volume is affected neither by the speed of pumping nor by the pressure of stored gas. The pump also serves to circulate the gases for analysis. The analytical system consists of a

Jan 1, 1945

By W. C. Lilliendahl, H. W. Highriter

THE method developed and used in this laboratory for the production of metallic uranium of such purity that it is ductile and can be cold-worked to fine wire or thin sheet by rolling has already been described1. It consists, briefly, in the electrolysis of potassium uranous fluoride (KUF6) in a molten bath composed of equal parts of sodium and calcium chlorides. The bath is contained in a graphite crucible, electrically heated to about 775° C., the crucible serving as the anode for electrolysis. The uranium deposits in finely divided form mixed with salts upon a molybdenum cathode suspended axially in the crucible. Upon completion of the electrolysis the cathode is removed and cooled, the deposit broken and leached to remove salts. The metal powder is washed with water and dilute acetic acid and dried in vacuo to reduce oxidation. Suitable amounts are then pressed into pellets and heated in vacuo by high-frequency induction, using a thoria crucible. The uranium melts and flows away from the pellet, leaving a shell, which is largely oxide. In general, this method produced a satisfactory metal, although at times the uranium was not ductile. The investigations recorded here were made to find the cause of this embrittlement. It was known that the metal generally contained carbon, derived from disintegration of the graphite crucible in which electrolysis is conducted, in amounts dependent upon the thoroughness of washing the metal powder. Accordingly, analyses of several samples, both ductile and brittle, were made by combustion and absorption of CO2 in Ascarite, using air instead of oxygen to reduce the temperature and rate of oxidation. Several of these metals were made with special precautions to reduce carbon content. The results show no relationship between ductility and carbon content in the range investigated (Table 1).

Jan 1, 1935

By Malcolm Reeves

The heavy oil reservoirs of Alberta and Saskatchewan include sequences of unconeolidated silts and fine sands which respond in an unusual manner when subjected to the high temperature and pore-fluid-pressure associated with steam injection and other thermal enhanced recovery techniques. Apparent transient connections are suddenly established between producers and injectore and there is an associated enhancement in oil (and sand) production. These phenomena have been attributed to local fluidization and piping processes which are known to occur in situations where high pore-fluid-pressures prevent the mobilization of intergranular friction. These breakdown processes may be associated with the penetration of tongues of the heated reservoir fluids with suspended sand into the creep sensitive intact reservoir since the viscosity ratios are sufficiently high for viscous fingering instability of the fluid-fluid interface. A program of laboratory tests has been carried out to measure the strength characteristic of saturated oil sands at a variety of temperatures and fluid pressures. These tests suggest, that in common with the coarser Athabasca sands, the Waseca sands have very little cohesive strength and show the characteristic dilational failure response of dense sands. Some special tests, devised to determine the relative ease with which samples can be fluidized, confirm the expected susceptibility of the fine- sand silts. Both piping and fluidization can be readily induced at in-situ reservoir temperatures and pressures. Analysis of stresses around wellbores suggests that fluid-pressure gradients may be sufficient to initiate piping and that backward erosion along streamlines may link producers and injectors. Such pipes may act as well “adits” gathering oil from the heated reservoir and contributing to enhanced production rates. Mechanical breakdown of the reservoir by drilling, injection and production processes provides a consistent possible explanation for the sand-cut response of production wells.

Jan 1, 1986

By H. W. Highriter

THE method developed and used in this laboratory for the production of metallic uranium of such purity that it is ductile and can be cold-worked to fine wire or thin sheet by rolling has already been described1. It consists, briefly, in the electrolysis of potassium uranous fluoride (KUF5) in a molten bath composed of equal parts of sodium and calcium chlorides. The bath is contained in a graphite crucible, electrically heated to about 775° C., the crucible serving as the anode for electrolysis. The uranium deposits in finely divided form mixed with salts upon a molybdenum cathode suspended axially in the crucible. Upon com-pletion of the electrolysis the cathode is removed and cooled, the deposit broken and leached to remove salts. The metal powder is washed with water and dilute acetic acid and dried in vacuo to reduce oxidation. Suitable amounts are then pressed into pellets and heated in vacuo by high-frequency induction, using a thoria crucible. The uranium melts and flows away from the pellet, leaving a shell, which is largely oxide. In general, this method produced a satisfactory metal, although at times the uranium was not ductile. The investigations recorded here were made to find the cause of this embrittlement. It was known that the metal generally contained carbon, derived from disintegration of the graphite crucible in which electrolysis is conducted, in amounts dependent upon the thoroughness of washing the metal powder. Accordingly, analyses of several samples, both ductile and brittle, were made by combustion and absorption of C02 in Ascarite, using air instead of oxygen to reduce the temperature and rate of oxida-tion. Several of these metals were made with special precautions to reduce carbon content. The results show no relationship between ductility and carbon content in the range investigated (Table 1).

Jan 1, 1935

By C. A. Hansen

ROASTING FERRUGINOUS ZINC-SULFIDE ORES IN 1912, Mr. J. B. Ideating was developing an electrolytic-zinc process for application to the ores of the Bully Hill mines of the General Electric Co. These ores consist of blende and pyrite so finely crystallized and so intimately mixed that no mechanical separation of the individual minerals had been found possible. The ore was reduced to about 60 mesh and roasted in a hand-rabbled reverberatory furnace preparatory to leaching with sulfuric acid. The extractions obtained were quite irregular, varying from a minimum of about 70 per cent. to a maximum of about 90 per cent. This irregularity led to the construction of a small electrically heated roasting furnace, and to the study of roasting under definitely controllable conditions. From time to time, these studies have been extended to other ores. Several commercial-plant operators profess to have gained useful information from the results of these studies and it is hoped that their usefulness may be extended by this publication. EXPERIMENTAL ELECTRIC ROASTING FURNACE The furnace used for experimental work is shown in Fig. 1. One fire-clay sagger, or pot, was set within another and the space between the two filled with Silox heat insulation. The hearth is a cast-iron plate with an imbedded ribbon of nichrome wire; this wire heater is connected to a potential regulator, which permits a very close voltage control. A mechanically driven arm is fitted with rabble blades so arranged that a uniformly thick ore bed may be maintained indefinitely. This arm is usually driven at about one revolution per minute but its speed of rotation can be varied as desired. Compressed air is led into the furnace through a meter, and it was found necessary to preheat the air in order to secure the definitely isothermal conditions sought.

Jan 8, 1919

By H. Y. Sohn, Y. Mohassab, D. Q. Fan, M. Elzohiery

A flash ironmaking process is being developed at the University of Utah in which iron is produced directly from magnetite concentrate. The kinetics of magnetite reduction by a mixture of H and CO gases was determined in the 2 temperature range 1150–1600 °C. Over 90% reduction degree was achieved at a temperature as low as 1250 °C within 4–6 s which is the typical residence time available in a flash reactor. The kinetics results were applied to experimental data obtained in a laboratory flash reactor in which H and CO gas mixtures were 2 produced from in situ partial oxidation of natural gas with oxygen. CFD was used to simulate the laboratory reactor,and the results were in good agreement with the experimental data.

Mar 1, 2017

This is the seventh in a series of reports on properties of commercial motor fuels, made in accordance with a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the United States Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1.935-36.3/ The present report covering 1,87 samples represents the products of 83 companies plus those from the Pacific coast, which were averaged by the Pacific Coast Technical Group before being submitted and are published exactly as they were submitted. For the regular grade 985 samples consisting of 73 different brands are averaged. The premium grade consists of 489 samples of 40 different brands. The third grade has 401 samples averaged from 51 different brands. In this report the districts have been reduced to 21 by combining North and South Texas into one district. El Paso samples are reported with the South Rocky Mountain district, and. Amarillo, Tex., has teen included with the Middle Rocker Mountain district. In the present survey samples from Fort Smith, Ark., have been included in the Tulsa area, Indianapolis has been included in the St. Louis district. Cleveland represents the State of Ohio. Samples from Little Rock, Ark., and North Carolina have been included in the Memphis district. The Pittsburgh district includes samples only from this State and Wheeling, W. Va. The actual sampling points in each area are indicated on table 1.

Jan 1, 1939

By Frank G. Horino

Drill cores from 18 exploratory holes that were drilled into the unleached saline beds were tested for mechanical properties by the Bureau of Mines. Test cores were primarily selected from zones L4B, R4B, L3, and R3A in the Piceance Creek Basin, Rio Blanco County, Colo. Regression analysis techniques were tried in an attempt to relate kerogen yield or apparent specific gravity to the parameters compressive strength, Young's modulus, and Poisson's ratio. Correlation coefficients were very poor, indicating that this type of analysis was not amenable to these data. Analysis of variance techniques were tried using a division of either greater than or less than 10% nahcolite together with the requirement of less than 3% dawsonite. Results showed that a larger percentage of nahcolite tended to lower the compressive strength and to increase Young's modulus. A second analysis was made using a division of less than 3% dawsonite and greater than 3% dawsonite together with the requirement of less than 1% nahcolite. For this analysis, a larger per-centage of dawsonite tended to increase compressive strength, Young's modulus, and Poisson's ratio. Mean compressive strength values were determined for the mining horizons of interest. Average physical properties for design purposes were also determined for the horizons of interest and for a proposed adit based only on logged geologic depths to these horizons. No consideration was given to percentages of nahcolite and dawsonite. Creep data obtained from nahcolite-and dawsonite-rich oil shales provides a best fit to a modified power equation.

Jan 1, 1978

A study was conducted to evaluate the effectiveness of the three types of sample grinders routinely used in the mining industry for the sample preparation of gold ores with particular emphasis placed on testing their capacity to produce a representative assay sample of coarse gold ores. The grinders used in this study are the Labtechnics LM5, the Mixermill 4010 ringmill and the Keegor vertical spindle pulveriser, commonly called a Keegormill. The study was based on the preparation of samples from two sources of known coarse gold ore, the Union Reefs Gold Mine and the Brocks Creek Gold Mine in the Pine Creek region of the Northern Territory of Australia, and a fine gold ore which was from the Macraes Gold Mine in New Zealand. The Union Reefs Mine contains visible coarse gold with 30 per cent to 40 per cent of the gold in the plus 75 μm fraction of milled ore. Discreet particles up to 5 mm have been recorded, Hellsten (1994). Union Reefs Gold Mine recovers 40 per cent of its bullion production through a gravity circuit, Riches (1997). Brocks Creek ore contains visible coarse gold with gravity bullion production fluctuating between 50 per cent and 65 per cent, depending on the mill feed. Average gravity bullion production from the Brocks Creek Mine is 55 per cent, Wilke (1997). The average gold grain size of Macraes Mine ore is 20 μm with 40 per cent of the gold in sub 10 μm particles. No gravity bullion is produced from the Macraes Mine, O'Keefe (1997). The testwork demonstrated conclusively that it is possible to prepare a representative sample for assay, of a coarse gold ore, when a Keegormill is used to pulverise the sample to a nominal 100 μm particle size (90 per cent passing a 100 μm screen by wet sieving). Both the Mixermill and the Labtechnics LM5 failed to prepare a representative sample, even when ground to a nominal 75 μm particle size.

Jan 1, 1998

During the past three years Lurgi's Circulating Fluid Bed (CFB) technology has been successfully applied to roasting of refractory gold ores and con- centrates. In comparison with the so-called Stationary Fluid Bed roasting systems, a considerable improvement of gold recovery, to around 95 per cent, has been demonstrated and achieved on many occasions in pilot CFB units and in commercial CFB roasting plants as well. The major reason for such improved gold recoveries is the excellent controllability of the roasting process in the CFB reactor system. Here, temperature, gas atmosphere and solids residence time are more precisely controllable at optimal values during roasting operation in order to achieve the highest possible gold recovery in the subsequent leaching process step. Further dominant benefits of CFB roasting systems are their flexibility with regard to feed material, throughput capacity, dry or slurry feed, almost unlimited oxygen enrichment, direct fuel addition and in situ capture of SO2 in the presence of limestone and dolomite. The system will accept 50 per cent turndown ratio, large variations in feed composition and particle size, as well as a variety of different fuel types. The commercial applications of CFB roasting systems for gold con- centrates have been realized so far at Fimiston, Kalgoorlie/Westem Australia and for whole ores at Cortez, Nevada/USA.

Jan 1, 1991

A field trial of the prompt neutron-gamma SIROLOG technique was undertaken by the CSIRO - Division of Geomechanics at Callide Coalfields during July 1989. The trial investigated whether the sonde could reliably be used for the determination of Ash and Iron Oxide (Fe2O3) in coal seams, which had a highly variable iron content. Ten boreholes were logged, being water filled of a nominal diameter of 120 mm. The logging probe employed a 1.6 ¦g 252Cf neutron source and a 51 x 51 mm BGO detector. The source to detector distance was 15 cm. The results from one exploration borehole at the Dunn Creek Mine are discussed in the paper. The rms deviations for ash and iron determination between the neutron-capture predictions of the geophysical logs and the laboratory - chemical assays were 1.9 per cent Ash and 0.88 per cent Fe respectively. Using existing empirical equations which relate iron oxide concentration in coal ash to Initial Deformation Temperature (reducing conditions) at Callide, it may be possible to indirectly determine ash fusion properties as least as accurately, on a more detailed ply-by-ply basis, and more cost competitively than current laboratory techniques allow.

Jan 1, 1991

By Stephen R. Grano, Jon Glatthaar, Philippe Steinier, Christopher J. Greet

"The importance of the oxygen content of sulphide mineral pulps in determining which reactions occur, and their subsequent influence on flotation behaviour is grossly underestimated in most operating concentrators. While pH is routinely monitored, Eh and dissolved oxygen measurements are obtained infrequently. However, dissolved oxygen measurements in conjunction with other pulp chemical parameters (i.e. pH, Eh, and EDTA extractable metal ion analysis), can provide valuable insight into where and what type of reactions are occurring within a circuit. Unfortunately, these readings yield “instantaneous” measurements of the pulp chemical parameters.What is needed is a means of establishing how reactive a pulp is, and how this reactivity changes as components of the system are manipulated. Oxygen demand provides an opportunity to do this. Several attempts at measuring the oxygen demand of a pulp have been made in the past with varying degrees of success. Most notable among these are Noranda and BOC Gases.Learning from these experiences, Magotteaux have developed the MagO2 ® demand vessel to measure the oxygen demand of mineral pulps. This paper described the apparatus, and through a case study on Broken Hill lead/zinc ore demonstrates how the MagO2 ® demand vessel is used.INTRODUCTIONThe role of oxygen in flotation is complex. While a considerable body of work exists demonstrating the strong involvement of oxygen in the interactions between sulphide minerals and collector (Gaudin and Finkelstein, 1965; Gaudin, 1974; Woods, 1984; Laajalehto, Nowak and Suoninen, 1993), the presence of oxygen can also affect the oxidation state of sulphide and non-sulphide minerals, which can impact on their flotation behaviour. Further, sulphide mineral oxidation is related to their oxygen demand (Spira and Rosenblum, 1994)."

Jan 1, 2004

By Adam Bezuijen, Tiago Gerheim Souza Dias

"The construction of mechanized tunnels in soft ground has evolved significantly over the last 20 years, especially in the control of the face pressure and the closure of the soil-lining void to reduce the induced settlements. On the other hand, several mechanisms of the TBM excavation cycle are still not taken into account for routine design calculations, such as the increment of water pressures in front of the tunnel face, the flow of excavation fluids around the shield, the dynamic equilibrium between the grout pressures and the excavation convergence, among others. This paper discusses specifically the issue of face pressures and how several mechanisms, which are routinely not considered, can be easily verified and incorporated into the state-of-practice of design. INTRODUCTION The stability of underground excavations is traditionally assessed through analytical solutions based on the lower bound theorem of plasticity (Atkinson and Potts 1977; Mühlhaus 1985) or the limit equilibrium method (Anagnostou and Kovári 1994; Messerli et al. 2010). These methodologies depend on the tunnel geometry, certain ground parameters and the support pressure. When conventional construction methods are used, the internal support pressure is an abstract representation of the combined effects of partial excavation, ground reinforcement, and the different support elements. The use of closed-face tunnel boring machines (TBM) changed this perspective, as the magnitude of pressures acting on the excavation boundary could be controlled in a more direct way. In front of the TBM the ground is excavated as the cutterhead rotates and the cutting tools scrape the ground from the tunnel face while additives are injected to condition the material. Water, polymers, bentonite, and foam can be used as additives under different conditions (Thewes et al. 2012). The loosened ground with additives, herein referred to as the mixture, flows through the openings at the cutterhead and into the excavation chamber. This mixture is kept pressurized to support the face."

Jan 1, 2016

By Steven M. Puricelli

In recent times, smelter off gases treatment plants have become more efficient and environmentally friendly. Where in the past it was acceptable to process only high strength, treatable furnace gases, new smelters must now treat primary gases and abate dust and SO2 from secondary gases: Processing smelter gases can present some interesting challenges. Some equipment can see varying concentrations of sulfuric acid, up to the boiling point, with a periodic table of contaminates thrown in for good measure. Treating weaker secondary gases have, in the past, been cost prohibitive. Nowadays, new technology, like physical absorption or catalytic carbon, show promise for economically treating low strength secondary gases. Modem smelters do a much better job of treating the SO2 laden gases generated by the smelting process but significant challenges remain.

Jan 1, 1998

By Sergio N. Monteiro

Polymeric composites reinforced with natural fibers are increasingly been used in several engineering applications, from automotive parts to building construction elements. In addition to the relatively low cost, the natural fibers are also appraised by their renewable and biodegradable characteristics. Fibers extracted from the crust of coconut fruits, also known as coir fibers have been investigated for a possible use in composite materials. In the present work, the coirfiber/polyester matrix interfacial strength was evaluated by means of pullout tests. The variation of the pullout tensile stress vs. the embedded coir fiber length permitted to determine the critical fiber length and, thus, to calculate the interfacial strength. Observations by SEM complemented the results from pullout tests, indicating that coir fibers have a potential for application aspolymeric composites that could replace conventional materials such as wooden and gypsumpanels.

Jan 1, 2006

By P. E. Fox, R. S. Cameron

"The QR gold deposit lies in the Cariboo plateau region of central British Columbia. The deposit was discovered in 1977 and since then a mineable reserve of 1.3 million tonnes grading 4.7 g/t Au has' been outlined in three separate zones. Soil sampling of glacial tills followed by diamond drilling of favourable host rocks proved to be key exploration techniques.The deposit is situated in the southern Quesnel terrane along the eastern fringe of the Intermontane Belt which here comprises a sequence of basic and intermediate volcanics and a series of stocks of alkaline affinity; generally diorite, monzonite and syenite. Hornfels and epidote-rich ferromagnesian exoskarn and sulphide-rich mantos have developed in a metamorphic aureole formed around a central diorite stock. Gold-rich zones lie along the outer periphery of the aureole where bodies of gold-bearing epidote-rich skarn and auriferous mantos rich in epidote and pyrite have formed in beds of calcareous tuffite lying at the top of a thick basaltic sequence. The deposit is regarded as' a subclass of gold skarn deposits. Diagnostic features are its association with alkalic intrusive rocks in a subvolcanic setting and the presence of oxidized, epidote-rich mineral assemblages.IntroductionThe QR gold deposit lies within the Cariboo plateau region of central British Columbia, 58 km southeast of Quesnel. The deposit, owned by Kinross Gold, was discovered during a regional reconnaissance program by Dome Exploration (Canada) Limited and Newconex Canadian Exploration in 1977. Considerable exploration and development has been done since that time. Mineable reserves of 1.3 million tonnes grading 4.7 g/t Au have been outlined to date in three zones."

Jan 1, 1995