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By J. L. Holman

The Bureau of Mines, at its Rolla Metallurgy Research Center, has devised methods for separating and reusing the major portion of waste plastics discarded in urban and industrial refuse. Waste plastic concentrates from a local collection drive, recycling center collections, urban refuse pilot plants, and the secondary metals industry were separated into three major thermoplastic families--polyolefins, styrenes, and vinyls--based on differences in density using a Bureau-designed sink-float-elutriation hydraulic separator. Other separation methods and systems such as air classification, jigging, liquid media, screening, and electrostatics were studied. Vinyl plastics contain up to 50 percent HC1. It was found that over 90 percent of the HC1 in vinyls can be recovered as usable hydrochloric acid by pyrolysis at 350° C. The remaining pyrolysis products which had heats of combustion in excess of 12,000 Btu/lb, could become valuable as a future source of energy. A characterization study conducted on eight chopped wire insulation wastes from secondary copper and aluminum processors showed that most wastes contained 2 to 7 percent residual metal and large percentages of vinyl. The residual metal content of some of these wastes was lowered to 0.1 percent and the vinyl portion segregated using various separation techniques. The research also suggests ways in which reclaimed thermoplastics may be fabricated into useful products.

Jan 1, 1974

By Phil R. Ames, Anil K. Ray, Murali M. Gadde, John A. Rusnak

"Many factors can be responsible for coal mine roof falls including, mining geometry, stress conditions and local geology. In the Illinois Basin coal mines, roof instability is commonly attributed to the low strength of the immediate roof, which is also moisture sensitive. Recently, in order to understand the mechanisms of roof instability, numerical modeling has often been the preferred ground control analysis tool. Since roof materials can exhibit significant spatial variability, such modeling results may not represent every section of the mine. At the same time, it is not feasible to carry out numerical modeling for the full range of geological and mining conditions possible at a mine. Operationally, it is more convenient and highly practical to have a simple map that depicts the expected roof conditions, determined through either complex numerical models or simple empirical analysis throughout the reserve area. In this paper, a case history is presented that shows how a combination of simple empirical analyses of geologic data and past ground control experiences at a mine can be synthesized into a roof stability map, which can then be used to forecast future ground conditions. The usefulness of such a roof stability map will be examined in terms of the predicted and actual ground conditions encountered over a period of more than a year after the map was created.INTRODUCTIONA roof fall, which can result in fatalities and lost work time, is considered to be one of the most severe ground control hazards in underground coal mines. In general, there are many factors responsible for roof falls, including mining geometry, stress conditions and local geology. In the Illinois Basin, roof falls are commonly attributed to the weak nature of immediate roof rocks, and some superficial falls may be initiated due to moisture sensitivity. Some unstable areas also occur when the immediate roof is highly laminated.Numerical modeling is a useful tool used to understand the mechanism of a roof fall by incorporating site-specific parameters. In the past, numerical modeling has been used to explain the mechanism of roof falls as well as simulate· roof falls and cutter behavior, but such work had been strictly site-specific (Gadde and Peng, 2005; Ray, 2009). Because of the restrictions imposed by the input parameters, numerical modeling results cannot represent the entire mine. In the real world, mining conditions vary from place to place, and even in a single panel, modeling results valid at one site may not apply at another nearby site. At the same time, due to the lack of input data pertaining to rock characteristics and in-situ stress variations, it is not practical to carry out numerical modeling for each local area of the entire mine site. In addition to these difficulties, mine operators prefer simple tools to understand the ground conditions at their mine sites. One simple and commonsense based tool is the roof stability map. A stability map not only synthesizes the geologic and stress analysis data empirically, but it can also be used to predict future ground control issues at that mine. Because of this practical appeal, stability maps are more likely to gain mine operators' acceptance and be used in their planning operations. In this paper, a case study is presented on the development of a 'Roof Stability Map' that was principally used for roof fall prediction for a mine in the Illinois Basin."

Jan 1, 2010

By T. P. Clendenin

THE northerly two thirds of Mexico falls into five main physiographic divisions, illustrated on the accompanying map. In form, these divisions are a series of strips, paralleling the northwest-southeast axis of the country.

Jan 10, 1951

By Sebastien Flament

More and more Hot Strip Mills are facing defects on their products that lead to a rejection of complete product batches by their customers. Several of those defects are induced by excessive work roll degradation. This paper is focussed on the understanding of work roll corrosion and oxidation mechanisms in a hot strip mill. Several laboratory trials (Hot rolling simulator, cyclic oxidation) have highlighted important factors influencing corrosion of work rolls as well as helping the understandings of oxidation of a work roll in the roll bite and along the roll circumference in a stand. The attention is focussed on several elements present in water used in HSM for direct roll cooling (e.g. chloride, bactericides, sulphates, phosphates) and their effect on roll surface degradation. The second part of this paper is focused on the understanding of work roll oxidation along the roll circumference. The effects of roll composition, roll temperature, water composition and water temperature have been studied in order to understand the oxidation/corrosion mechanisms in a HSM.

Aug 16, 2017

I find that during the short time I have been in this district, the majority of boilers are, and have been, receiving very bad usage owing to the difficulties which they have to contend against, viz., oil and bad water. Oil on the heating surface of a boiler is of a highly dangerous nature inasmuch as it allows the surface to become overheated, owing to the water not coming into direct contact with the plates, and it naturally follows that when the crown sheets of a flue or firebox become overheated, you lose a considerable amount of the strength of the plate, and the flue or crown comes down. Referring to the oil question, I find that too much care cannot or exercised on the part of engine drivers in order to minimise as much as possible the internal lubrication of the various engines under their control. For I consider that it is here that the most of the trouble is caused. My reasons for stating such to be the case, are:-That the majority of enginedrivers before coming to this field have been used to driving engines that have been exhausting into the atmosphere, and probably they have been taught that it is far better to use a little extra lubrication than to have a hot bearing. So far so good. But one thing that must not be overlooked is that on these fields the conditions are altered in this respect, as the majority of engines in this district are not exhausting into the atmosphere, but are condensing their exhaust steam and using the water so condensed for feed purposes.

Jan 1, 1901

By James W. Halley

' FINE-GRAINED " steels have been standard products for many years. This paper describes an investigation of the effects of some of the more common grain-growth; inhibitors used to produce these steels. The properties, response to heat-treatment, and the deoxidation practice necessary to produce "fine-grained" steels have been the subjects of numerous papers. It has been shown that a substantial quantity of' aluminum is necessary to produce this type of steel, and it has been indicated that titanium and zirconium produce a similar result. For some time there was a lively argument between those who felt that aluminum refined the grain and those who felt that aluminum oxide was the effective agent. This argument subsided with an apparent victory for those promoting aluminum oxide. Most of the work on grain size has divided steels into two broad classifications based upon McQuaid and Ehn's original carburizing test at 1700°F. or some similar test at this temperature. If the steel coarsened at this temperature, it was coarse grained, while if it did not it was fine grained. Quantitative data concerning how much a certain amount of aluminum raised the coarsening temperature and affected the properties, all other factors being constant, are very meager. Similar information regarding titanium and zirconium is practically nonexistent. The published information on aluminum yields some quantitative information. Epstein, Nead and Washburn' gave the first quantitative information on the amount of aluminum necessary to prevent grain growth at 1700°F. They showed that the addition of a pound to a pound and a half of aluminum per ton (0.05 to 0.075 per cent) would assure steel that would not .coarsen during a McQuaid-Ehn test at 1700°F. Herty, McBride and Hough2 reported that a steel containing 0.020 per cent acid-soluble aluminum coarsened between 1742° and 1832°F., while steels containing 0.016 per cent and 0.017 per cent acid-soluble aluminum coarsened between 1652~ and 1742°F. compared with similar aluminum-free steels that started to coarsen at 1580°F. Herty3 also showed a marked improvement in low-temperature notched impact resistance with increasing acid-soluble aluminum up to 0.030 per cent. McQuaid4 compared the coarsening of steels containing 0.011 to 0.204 per cent total aluminum and found a maximum coarsening temperature at 0.098 per cent aluminum. He had no samples between 0.015 and 0.098 per cent aluminum. Houdrement5 found a marked decrease in coarsening temperature with aluminum contents above 0.50 per cent. Kinzel, Crafts and Egan6 found that aluminum and zirconium improved thy low-temperature impact resistance of a low-alloy steel, while titanium was detrimental. Sims7 shows that sulphur increases the coarsening temperature and that the maximum coarsening temperature is between 0.04and 0.06 Per cent added aluminum. The

Jan 1, 1946

By Alexi J. Neill

"This presentation will showcase two challenging projects with deep excavation support systems in the Atlanta area where state-of-the-art instrumentation and monitoring systems were used to manage risk by confirming design performance requirements / calculations during construction. The instrumentation and monitoring system successfully reduced risk by recording real-time data on a project website while simultaneously sending email alarms to key site personnel when data exceeded pre-determined alarm thresholds. The monitoring data revealed unexpected performance at an early enough stage so that contingency plans could be engaged and remedial efforts devised in order to limit the consequences. Finite element analysis was used to model deformations, analyze the unexpected performance, and prepare theremedial design.INTRODUCTIONConstruction in densely populated urban areas is becoming more common in order to keep up with the increasing infrastructure demands of our growing population. America’s big cities continue to outpace the overall nation in population growth. The city of Atlanta, the nation’s ninth largest city based on metropolitan population, is a prime example of this. The population has grown at a rate of 6.6% between 2010 and 2013, nearly triple the overall growth rate of the United States during the same period (SustainAtlanta, 2015).As a result of increasing infrastructure demands in Atlanta, developers are now constructing larger buildings on smaller properties. In addition, developers are attempting to maximize space on their selected properties, often by designing underground parking garages to accommodate as many cars as possible on these compact sites. In some cases the selected sites are adjacent to buildings, utilities, and other existing structures. The risk associated with construction increases during underground work that requires a support of excavation system, particularly on confined sites adjacent to existing structures. There is a risk posed to people, property, and the environment that the project team should monitor when constructing in these conditions."

Jan 1, 2016

By Keuncheol Choi, Yonghack Lee

"The new lead smelter based on the QSL technology was started operation from May 1992 at Onsan Refinery of Korea Zinc Co., Ltd. The smelter is designed to treat not only various types of lead concentrate but also secondary materials coming from the zinc plant without special pretreatment.Shortly after the start-up of the operation, it has demonstrated that the smelter have a capability to treat wide range of raw materials. Continuous modifications and improvements of the plant are still under way to increase the feed rate and also the ratio of secondary materials to the feed.In this paper, the operating experience and results of QSL smelter, especially the injection of gases and coal to the melt, will be presented with major operation parameters and data.INTRODUCTIONThe QSL lead smelter based on new injection technology was commissioned at the Korea Zinc's Onsan plant from May of 1992. After starting the operation, the QSL lead smelter faced various kinds of mechanical and metallurgical troubles. However, these were gradually worked out by the continuous improvements and efforts.At present, the QSL lead smelter is operated stably at the total feed rate of 57 tonnes per hour with an increased amount of secondary materials."

Jan 1, 1996

By Adam Gray, Emery Gray

State-of-the-art seismographs can be employed to assist the blasting engineer in understanding the propagation of vibration waves generated by blasting. Wave traces and frequency plots are used to adjust shot loading and timing, especially around close or near- field structures. Successful close-in blasting vibration monitoring requires careful consideration of the following: Geophone locations Mounting of geophone both on structures and in the ground Differences between ground motion and structural response This presentation will discuss methods used to control and monitor blast-induced ground and structure motions. Case histories are presented to illustrate seismic monitoring used as a tool to control vibrations and guide the blaster in the design process.

Jan 1, 2005

By Terry L. Muldoon

On July 7, 1971, noise regulations for underground coal mines were implemented under provisions set forth in the Federal Coal Mine Health and Safety Act of 1969. These same regulations now also apply to coal mine surface facilities. In August 1971, in anticipation of these regulations, the Bureau of Mines, through the cooperation of the mine operators, conducted extensive noise surveys in three coal cleaning plants. The survey was conducted in an attempt to identify those occupations where exposures would exceed the proposed regulations.

Jan 1, 1972

By L Dzinza, K C. Corin, M Tadie

The recycling of process water comes with increased electrolyte concentrations that affect water quality, which may in turn affect the flotation performance of valuable minerals (Hirajima et al, 2016). Electrolytes such as Ca2+, SO4 2- , Mg2+ and S2O3 2- have been surmised to have an impact on the action of flotation reagents such as collectors (Ikumapayi et al, 2012). Xanthate collectors are known to play a significant role in imparting hydrophobicity on mineral surfaces to enhance their flotation. The interaction between minerals and xanthates is well known to be electrochemical in nature. Such redox processes may be elucidated by electrochemical techniques. Since the mechanisms involving the interactions between electrolytes in process water with sulfide minerals and the subsequent adsorption kinetics of collectors are not well understood, this study therefore aims to provide fundamental knowledge to unpack the mechanisms involved when electrolytes interact with Platinum Group Minerals (PGMs) and how these interactions may affect xanthate adsorption. The interaction of sodium iso-butyl xanthate (SIBX) in the presence of electrolytes at increasing ionic strength was investigated by rest potential measurements, to explain the impact of electrolytes on the adsorption of SIBX on PGMs in the flotation process. Rest potential measurements for PdTe2 and PdS were conducted in an air saturated 0.05 M di-sodium tetraborate decahydrate solution, in the absence and presence of SIBX and electrolytes. It was found that the existence of sulfide and telluride on palladium affects the mechanisms in which electrolytes interact with Pd mineral surfaces. An increase in the ionic strength of Na2S2O3, CaCl2 and MgCl2, increased the interaction between the salts and PdS, thus decreasing the extent to which SIBX interacted with PdS. An increase in ionic strength for Na2S2O3 increased the interaction between Na2S2O3 and PdTe2 and therefore decreased the extent to which SIBX interacted with PdTe2. Other salts investigated in this study increased the rate of oxidation of PdTe2 with an increase in ionic strength thereby enhancing the interaction of SIBX and PdTe2. This study has shown that mineral type, electrolyte type and concentration all have an impact on the mechanisms that result in the adsorption of SIBX on PGMs.

Aug 24, 2022

By C. H. Titus

This study consists of four descriptive Sections covering respectively: a state-of-the-art literature survey on ungrounded and grounded power systems, a report on literature pertaining to human threshold limits of electric shock, an analysis of the performance requirements of isolated systems and a section on design and performance specifications for an isolated system the final section includes copies, and translations where applicable, of the most important articles on foreign mining practice as well as some technical publications which could be difficult to obtain elsewhere. Section 2 - Literature Survey In analyzing the available literature on ungrounded systems it became apparent that too strict an interpretation of Section 1.1 of the Contract would limit the survey in both period of time analyzed and in available literature which discussed several types of power systems. Therefore, the survey was expanded to cover approximately the past twenty-year period and to cover literature which addressed itself to both ungrounded and grounded power system operation. Section 2 gives a brief summary of this literature survey and lists the important papers and books which were examined.

Jan 1, 1972

By A. E. Isaacson

Bureau of Mines researchers developed and tested equipment to measure corrosion rates on a commercial scale mill. Bench-scale experiments were designed for duplicating ore grinding conditions closely enough so that realistic rate determinations could be made in laboratory tests. Rates measured in a laboratory system compared favorably with those measured in the field. Cast steel was found to have corrosion rates in a copper mill and laboratory test cell of 22 and 21 mpy, respectively. Corrosion was found to account for less than 5 pct of the total grinding media wear in the operations studied.

Jan 1, 1988

By W. G. Davenport

Chapter 11 determined the combinations of industrial oxygen, oil and blast preheat that will steadily produce 65% Cu matte from pure chalcopyrite concentrate. It showed that the . combinations are described by a flat plane. It also showed that the minimum energy requirement for making 65% Cu matte occurs with maximum oxygen enrichment, zero oil and zero blast preheat. This chapter examines the, effect of matte grade on industrial oxygen, oil and preheat requirements.

Jan 1, 2001

By J. Nutting, D. H. Kirkwood

The oxidation of lead sulfide in air between 200° and 350°C has been investigated by electron diffraction from thick sulfide films and from galena surfnces. It has been demonstrated that sulfate is the stable reaction product up to 570°C. Sulfate is HAGIHARA has investigated' single crystals of galena roasted in air by the reflection electron-diffraction technique, which owing to the very limited penetration of the beam into the crystal gives information of the nature of the surface only. He has shown that up to 280°C the first oxidation product is lead sulfate, followed by lead mono-oxysulfate (PbO . PbS04). At longer times and higher temperatures more complex patterns appeared which could not be analyzed. All of these patterns were of streaks or spots arising from crystals oriented on the galena surface, and it is probable that these crystals are lead compounds whose structures have not been determined, such as the other oxysulfates (2Pb0 • PbS04 and 4Pb0 . PbS04) or a number of oxides. Certain lead sulfide films, formed chemically, give ring patterns in transmission electron diffraction2 because they are polycrystalline, and should also give ring patterns of the products after oxidation. It was thought that a diffraction study would reveal the sequence of phases produced in the reactions at different temperatures, since X-ray powder patterns are available for many lead compounds. PREPARATION OF FILMS The films were prepared by passing H2S over a saturated solution of lead nitrate in water. Once a silvery film had formed on the solution surface, no further thickening was apparent. The films were transferred by a gauze to a bath of distilled water for washing and pieces of film were caught on small discs on which they were dried. The discs were formed initially on galena up to temperatures of 300°C, followed by oxide and oxysulfates in turn at longer times. The appearance of- these phases is believed to result from an inadequate rate of supply of sulfur to the top surface 01. the crystal. standard Siemens mounts, made of platinum alloy, and had seven 20-p apertures drilled through them. The parts of the film which had dried onto the disc surface were light blue in color, which is the interference color of a film about 600A in thickness. A strong pattern of lead sulfide was obtained in transmission electron diffraction through the apertures but slight broadening indicated a crystallite size of around 200A. Tilting a sulfide film in the beam produced arcing of the rings, increasing the intensities of the (Ill), (3111, and (222) rings and reducing (200) and (220). This arises from preferred orientation in the film, a [loo] direction of the crystallites being normal to the plane of the film. These specimens were oxidized in an oven maintained at the required temperature. The reported times include that taken to heat the film to the reaction temperature. STABLE PHASES FORMED IN OXIDATION The conditions in which various oxidation products of lead sulfide are stable have been considered by the authors in a previous paper.3 It was shown that in a normal atmosphere, taken as containing lo-' atm of SOs, lead sulfate would be stable up lo about 570°C. This was confirmed by oxidizing thin films of sulfide for several days, and the analysis of the transmission-diffraction pattern is given in Table 1. The fit with the patt$rn from X-rays is good, except for the missing 3.62A ring. Some disagreement in intensities of reflections given by X-rays and electrons is to be expected. Up to 570°C a spotty pattern of sulfate was still obtained, indicating grain growth, but above this temperature the film disintegrated. Probably this is associated with the decomposition to PbO . PbS04. It needs to be emphasized that the atmosphere

Jan 1, 1965

By F. Twyman, D. M. Smith

THOSE chemists (they are still greatly in the minority) who use the spectroscope, use it very often, and find it almost indispensable. As a means of detecting minute quantities of the metals it is unrivalled. A metal can be readily distinguished in the presence of any other element, compound, or mixture without the necessity of separation. The qualitative analysis of the metallic constituents of a substance, which the spectroscope gives so easily, is a sure basis for planning a chemical analysis. As the determination of each element proceeds the purity of precipitates may be checked as often as desired. If, possessing these advantages, the spectroscope has been neglected in general chemistry, it is not surprising that it was neglected in metallurgical chemistry; for many of the impurities which are of industrial interest, even when they are present in a metal or alloy in small quantities, are not then always easily detected by the examination of their visible spectrum. The history of the development of the art has been given in Bureau of Standards Scientific Paper No. 444.

Jan 1, 1928

By F. Xie

Low gold and silver leaching kinetics has been commonly observed in traditional gold-silver cyanidation process, especially in those heap-leaching operations. The reactivity and availability of oxidant was believed to be the critical limitation for gold and silver dissolution. The occurrence of silver sulfide such as acanthite (Ag2S) in the ore may also result in low overall silver extraction. Leaching of gold and silver sulfide in the ferricyanide-cyanide solution has been investigated through rotating disc tests and the assistant effect of ferricyanide on increasing the dissolution rate of gold and silver was noticed. The potential use of ferricyanide as an auxiliary oxidant in gold/silver cyanidation process was proposed based on the results of leaching of gold-silver ores.

Jan 1, 2014

By H. Salamanca

The electric operation and design features of the 11.000 H.P. variable speed SAG mill gearless drive is presented. The function of the frequency converter, control system drive and lubrication systems are described. An analysis of the harmonic characteristic in the Supply System and Motor is presented, and the dynamic development of the stator current, speed and the magnetic flux in the start-up process of the drive is evaluated. Besides, the most important aspects in the commissioning and maintenance of the drive are analyzed.

Jan 1, 1991

By J. F. Barkley

"In trying various coals at one of the Government power plants, comparison was made of the ash softening temperature of each coal, with the clinkering tendencies of the coal when burned in the furnace. The proximate analyses, ash softening temperature and plant reports as to clinkering were tabulated. It was desired to bring out any correlation that might appear between the ash softening temperature found in the laboratory, and the clinkering of the ash as found in the boiler furnace.Each coal used was sampled and analyzed, and the standard ash fusion test made. The clinkerring of the coal in the furnace was observed by the furnace operator. The furnace equipment consisted of the ""V"" or Murphy type of stoker with the ordinary fire-brick arch roof. With such arrangement very high furnace temperatures are apt to be produced at the ratings carried at this plant.The softening temperature of ash is defined as the temperature at which small cone of the ash, as tested in the laboratory furnace, has fused down to a spherical lump, The softening interval is the difference between the softening temperature and the temperature at which the first rounding, or bending, of the apex of the cone takes piece. The flowing interval is the difference between the softening temperature and the temperature at which the ash has reached a fluid condition as shown by spreading out over the base in a flat layer.While the analyses of the different samples of the some coal did not vary appreciably, the ash softening temperatures were not always so consistent. It will be noted from the following examples that the ash softening temperatures of different samples of the same coal differ as much as 290° F, Hence, in order to judge this property of a coal, many samples ore desirable, taken from many different shipment."

Aug 1, 1924

Operations of the new copper smelter at Mount Isa commenced on the 6th February, 1953. Prior to this date a paper by R. V. Anderson (1953) outlined the smelter layout, proposed operation and expected performance.Nominally a 50-ton per day plant, output is currently at the rate of 85 long tons per day. In the first 3t years, of operation to 30th June, 1956, '71,339 tons of blister copper were produced. Operation has been stabilized' and a number of modifications to plant and operation have been made. This paper reviews the progress made to date.GENERAL LAYOUT AND EQUIPMENTThe general layout and equipment follows well-established practice as study of Figs. 1 to 4, and Appendix II will show. This diagrammatic representation of layout (Fig. 1) and flow sheet (Fig. 2) is intended for the purpose of brevity to take the place of a detailed plant description.Choice of site for the smelter was limited by the necessity for close proximity of the waste heat boilers to the powerhouse.Much excavation was necessary before foundation work commenced, but the plant is compact and further expansion is possible.CHARGE MAKE-UPRoaster charge initially comprised concentrates, purchased ores, revert materials, mine sulphide ore and barren sand. As purchased ore receipts increased and as domestic black rock oxidized ore became available, the latter two fluxes were eliminated from the charge. Fluxes at minus i-in. sizing are trucked from crushing plant or stockpile by motor lorries. Filtered mill concentrates are dropped from an overhead conveyor on to the storage patio floor adj acent to the two concentrate bins.

Jan 1, 1957