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By S. Afrouz, C. Keles, W. R. Reed, E. Sarver, T. Akinseye, A. Greth, L. Pan, F. Animah

The resurgence of severe lung disease among U.S. coal miners has not only highlighted the need for improved dust controls, but also the need for an improved understanding of dust characteristics and monitoring strategies [1]. Following up on prior work by the National Institute of Occupational Safety and Health (NIOSH) to demonstrate a novel wet dust collection system on a roof bolter [2], the current study explores the effect of that system on dust characteristics and uses interlaboratory comparisons to comment on analytical methods. Results indicate the wet system did not appreciably affect the composition or size of respirable dust in the vicinity of the operating roof bolter. However, the system does appear to have substantial benefits for the operator. NIOSH has already shown it can reduce the respirable dust mass concentration to which the operator is exposed during dustbox cleanout [2,3], which is a frequent maintenance activity that can re-aerosolize dust, and new results here indicate the silica and silicates content in this dust may also be reduced, thereby reducing the overall hazard. Moreover, regarding analytical methods, excellent correlation was demonstrated between measurements of quartz mass, taken first by NIOSH and then by a university laboratory, using direct-on-filter Fourier transform infrared (FTIR) analysis. This method is the basis for envisioned “end of shift” silica monitoring (quartz is the predominant form of crystalline silica in coal mines) [4]. For particle-level analysis by scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX), there was more variability in results generated by two independent university laboratories.

Mar 1, 2024

The Government of New South Wales has granted approval for Hunter Valley Aluminium Pty., Ltd" and Alcan Australia Ltd. to proceed with the building of an aluminum smelter at Lochinvar and the expansion of a smelter at Kurri Kurri. Construction of the smelters is expected to start as soon as the consortium is finalized in early 1982. The smelters are part of a plan to increase Australia's aluminum capacity fivefold to 1.5 million tons by the mid-1980's. CHILE Construction of a $61 million lithium carbonate plant in northern Chile will be started in early 1983 by Sociedad Chilena del Litio Ltdao Production is scheduled to begin in 1984 with an initial capacity of 6,350 tons of lithium carbonate produced from a brine deposit. The firm is owned 55% by Foote Mineral Company, of Exton, Pennsylvania, and 45% by Corporacion de Fomento de la Produccion-CORFO.

Jan 1, 1982

By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022

Two of the most important economies in coal-washing are in the actual washing of the coal and in a proper lay-out to reduce to a minimum the cost of labour for handling and washing. A guarantee is usually required for turning out a washed coal containing not more than 2% of free dirt and a resulting refuse with not more than 2% of free coal; any plant that gives results within such guarantees can he considered economical, provided that there are no other losses during the washing process. Various drainage arrangements and washery lay-outs are illustrated and discussed with respect to drainage, bunkers, sieves, settling tanks and conveyors and two further points considered: siding accommodation, which may become quite important with washeries of large capacity especially when the coal is brought in railway-wagons; and the irregularity with which the coal arrives. (Paper presented at the Manchester Geological and Mining Society's general meeting held in Manchester, April 11th 1916, with Mr. Leonard R. Fletcher, President, in the chair)

Dec 1, 1916

By Earl Gardiner, Michael Grenier, Stephen Hardcastle, John Vergunst

A prototype, self-contained mine refuge station air supply sys- tem was tested in an underground metal mine to verify it's ability to keep oxygen and catbon dioxide levels at acceptable concentrations in an emergency situation. In this test, 25 volunteers were assembled and sealed in a functional underground refuge station for a period of 24 hours, without the benefit of the standard com- pressed air supply. The prototype system was designed to: 1) operate on a self-contained power supply for a period of at least 27 hours; 2) supply oxygen at a metered rate; and 3) remove car- bon dioxide by re-circulating refuge station air through soda lime scrubbing beds. During the test period, the catbon dioxide concentration remained at an average of 2500ppm and oxygen concentration stayed between 20.2% and 20.6%. The volunteers found the prototype easy to use and seemed confident in its ability to provide a safe atmosphere. The test showed that this technology could become part of an underground mine's refuge station emergency equipment.

Jan 1, 1997

By Joseph E. Pouge

For the purposes of this analysis it is assumed that the petroleum industry has undergone a basic economic change whereby the degree of competition present in its operation is reduced by the collective control of production brought about by statme-directed proration. Formerly freely competitive in all its parts, the industry is now fully competitive only in its marketing, its manufacturing and transportation, its search for new oil supplies, its drilling operations (with some qualifications), and its capital movements. The practical problem before the industry in its new status is the maintenance of equilibrium, with planned control of crude-oil production (proration) substituted for competition and price as the regulatory mechanism at one point in the supply-demand system. It is further assumed that proration has become so firmly established in the legal and operating framework of the business that it may be looked upon as an institution. The purpose of this paper is to call attention to the effect of unregulated drilling upon the orderly functioning of proration. Economic Structure of Petroleum Industry The economic structure of the petroleum industry, under the current form of proration, may be visualized, in simplified form, as shown in Fig. 1. This diagram is designed to indicate the existing mechanism whereby supply and demand are equated. Demand is created largely by conditions external to the oil business, whereas supply is conditioned by a series of stages incidental to the discovery, development and production of a resource. The time elements involved in changes in demand and supply are of an entirely different order, the demand factor being much more flexible and "quicker" than the supply factors. It should be observed, also, that the position of price, formerly between "demand" and "supply," has been moved to a sidewise location where it still affects demand but influences current supply only through its bearing upon proration, drilling and search. Proration has been substituted for price as a throttle at the well head, but at this point only. The mechanism now works in this fashion: a declining price stimulates demand and the

Jan 1, 1936

By Joseph E. Pouge

For the purposes of this analysis it is assumed that the petroleum industry has undergone a basic economic change whereby the degree of competition present in its operation is reduced by the collective control of production brought about by statme-directed proration. Formerly freely competitive in all its parts, the industry is now fully competitive only in its marketing, its manufacturing and transportation, its search for new oil supplies, its drilling operations (with some qualifications), and its capital movements. The practical problem before the industry in its new status is the maintenance of equilibrium, with planned control of crude-oil production (proration) substituted for competition and price as the regulatory mechanism at one point in the supply-demand system. It is further assumed that proration has become so firmly established in the legal and operating framework of the business that it may be looked upon as an institution. The purpose of this paper is to call attention to the effect of unregulated drilling upon the orderly functioning of proration. Economic Structure of Petroleum Industry The economic structure of the petroleum industry, under the current form of proration, may be visualized, in simplified form, as shown in Fig. 1. This diagram is designed to indicate the existing mechanism whereby supply and demand are equated. Demand is created largely by conditions external to the oil business, whereas supply is conditioned by a series of stages incidental to the discovery, development and production of a resource. The time elements involved in changes in demand and supply are of an entirely different order, the demand factor being much more flexible and "quicker" than the supply factors. It should be observed, also, that the position of price, formerly between "demand" and "supply," has been moved to a sidewise location where it still affects demand but influences current supply only through its bearing upon proration, drilling and search. Proration has been substituted for price as a throttle at the well head, but at this point only. The mechanism now works in this fashion: a declining price stimulates demand and the

Jan 1, 1936

By P. R. Martin, R. B. Kelly

Drilling in Central Texas during 1933 was confined, for the most part, to the search for new serpentine plugs. Bastrop County led in this particular activity, with 50 completions during the 12 months' period, 12 of which were productive. Only one new field was opened in Central Texas during the year, it being known as "Hilbig" (Bastrop County) and was discovered by the Humble Oil & Refining Co. The finding of commercial production in the serpentine at 2500 ft. led to further search in this and surrounding counties, but without success. Bexar County actually provided the greatest amount of drilling but the activity was limited to shallow development from 400 to 2000 ft. The Edwards limestone pay, which has been such a factor in past years, received but slight attention during 1933. Unsuccessful exploration was carried on in Lee and Burleson counties. With the exception of Freestone County, the Woodbine sand area was given even less consideration. This county, because of its close proximity to Anderson and Leon counties, saw a very active leasing campaign and several important tests drilled. In Central Texas, 252 wells were completed in 1933, and of this number 52, or 21 per cent, were productive. Hilbig Field The discovery well, Humble Oil & Refining Company's Annie Hassler No. 1, was completed Feb. 16, 1933, for an initial production of 65 bbl. the first hour, through tubing and 1/2-in. choke. The production was found in serpentine at 2468 ft. and tested 37.2" A.P.I. gravity. Twelve producing wells were drilled during the year and served to indicate that not more than 300 acres would comprise the entire field. Daily production at the end of the year was 775 bbl., although the field potential was 18,240 bbl. daily through 1-in. choke. The field adapts itself to pressure maintenance, and this scientific handling is being undertaken by the Humble Oil & Refining Co. through one injection well. It is the only area in the district where work of this nature is under way. Proration of Oil The more stringent application of proration in 1933 did not affect materially the producing fields in Central Texas. This is accounted for

Jan 1, 1934

By X. Y. Yu, X. A. Wei, A. Zeng

"The flotation behaviors of diaspore and three kinds of silicate minerals - kaolinite, illite and pyrophyllite - using an organosilicon cationic surfactant as collector were investigated as functions of reagent concentration and pulp pH. The results show that the organosilicon cationic collector QAS122 is a suitable collector for the flotation of aluminosilicate minerals but has weak collecting ability with regard to diaspore, enabling the flotation separation of diaspore from silicate minerals using QAS122 as collector. The flotation of a bauxite ore was then studied in detail. Finally, a reverse flotation separation process was used to process a low-grade bauxite ore. It was concluded that use of the organosilicon cationic collector is effective. A concentrate with aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, of 9.67 was obtained from natural bauxite ore with A/S of 6.07 at pH of around 11. The Al2O3 recovery rate was 81.72 percent. IntroductionChina has abundant bauxite ore resources, but more than 98 percent of the bauxite ores are the diasporic type, with the characteristics of complex mineral composition, low aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, and difficulty of processing. The gangue minerals in bauxite ores are mainly kaolinite, pyrophyllite and illite, containing titanium and iron impurities (Zong et al., 2008). It is known that high-grade bauxite ore, with A/S greater than 8, can be processed directly by the Bayer process (Papanastassiou et al., 2002; Ma et al., 1996). However, Chinese diasporic ores have been processed mainly by the sintering process, which is environmentally damaging and energy intensive. Increasing the A/S of the diasporic ores using a flotation method is needed (Xia et al., 2010).Froth flotation is one of the most widely used processes to concentrate valuable minerals in beneficiation ores. It is particularly useful for separating finely ground ores from their associated gangue minerals. For diasporic bauxite ores, flotation is applied to obtain high-quality material for the Bayer process by increasing the A/S. Direct flotation has been shown to be an efficient method for the desilicating of diasporic bauxite ore (Wang et al., 2004; Xu et al., 2004), but reverse flotation has more advantages for this purpose, including less collector consumption, less foaming product and less effect on metallurgy (Liu et al., 2007; Hu et al., 2003; Hu, 2003; Luo et al., 2001)."

Jan 1, 2015

By Shengli Wu, Mingyin Kou, Laixin Wang, Zhe Wang, Xinliang Liu

The sticking behavior of iron ores in the shaft furnace is one of the most important problems in the COREX melting progress, which directly influence the smooth operation and productivity of shaft furnace. Therefore, it is of great importance to study the sticking behavior of pellets in COREX shaft furnace. The results showed that porous metallic iron produced at the interface of pellets samples was the main reason for the sticking of pellets in the COREX shaft furnace. The SI (sticking index) and metallization rate increased with the reduction temperature and gas flow, and decreased with melting rate. However, the SI of pellets in the COREX shaft furnace could be decreased by the proper match of melting rate and reduction temperature, reduction temperature and gas flow, while the metallization rate of pellets were kept at a certain level. Furthermore, the matching of melting rate and reduction temperature was more effective than the matching of reduction temperature and gas flow.

Jan 1, 2016

By F. F. Aplan

For the past year, MBD has been engaged in a lively discussion on a name change for the Division. To complicate things, more than one name change has been proposed! There has been much discussion on the subject, as anyone who has attended the Annual MBD Business Meeting or read [jE] knows. The position of many of our members is well known. There is, however, one group that has not been heard from. These are the future members-the present students and those even younger who are yet to elect our profession. As one who has traversed the academic-industrial interface several times, I think I am qualified to speak for this group. Before going further I think it wise to state unequivocally that our Division should adequately represent our profession. The whole profession is just too small to chop into a plethora of pieces: "I'm not a mineral processing engineer, I'm an ore dresser-well, actually, I specialize in comminution, specifically in grinding, mostly in autogeneous grinding-primary autogeneous grinding that is-and my 'thing' is really iron ores, taconites, mind you!" Enough to confuse even those that keep the faith, and certainly we can't build a profession on such narrow pieces. Either an employer can hire a professional who knows the entire profession or he can't. As more and more companies search out opportunities in the mining and metallurgical fields and as environmental considerations bring into question even our technically well proven processes and procedures, there is a greater need than ever be- fore for a well-rounded mineral processing engineer well versed in all of the process possibilities. What is needed is one who can take an ore-or municipal trash for that matter-and produce there from a valuable product by the most appropriate means. It doesn't really matter if this is done physically, chemically or thermally.

Jan 1, 1971

By Noel N. Moebs

The coal wants at the Westland Mine in southwestern Pennsylvania consist chiefly of elongated, sandstone-filled channels with slickensided basal contacts. Tentatively identified as washouts, these channels are about 1,000 feet long and 300 feet wide, are erratic in occurrence and trend, and are difficult to delineate from the customary core drilling pattern. Roof conditions are hazardous adjacent to the washout contact, but roof stability is generally unaffected greater than 30 feet away.

Jan 1, 1981

By André R. Laplante

"This presentation reviews three continuous centrifuge separators, the Falcon-C, Kelsey Jig and Multi-Gravity Separator, two units with possible synergies with centrifuges, the In-Line Pressure Jig and InLine Leach Reactor, and two centrifuge prototypes, the continuous Knelson and the Altair Jig. Typical applications, potential problems, promising synergies and general concentration mechanisms are discussed. A general discussion on the sources of information, the nature of the fluidization water flow, test work for potential centrifuge separations and the early life cycle of new technology, using centrifuge separators as an example, follows. ResumeCette présentation fait le point sur trois appareils de séparation centrifuge, le Falcon-C, bac oscillant Kelsey et Multi-Gravity Separator; deux appareils qui présentent des synergies possibles avec les centrifuges, le bac oscillant In-Line Pressure Jig et le système InLine Leach Reactor; et deux prototypes centrifuges, le Knelson continu et le bac oscillant Altair. On y présente des applications typiques, les problèmes d’opération les plus usuels, les synergies les plus intéressantes. On discute également des sources d’information disponibles pour le minérallurgiste, de l’impact du mode d’ addition de l’eau de fluidisation, de la démarche expérimentale a faire avant d’installer un centrifuge, et du cycle de développement de nouveaux équipements, en utilisant les centrifuges comme exemple.IntroductionGravity separation has undergone a renewal in the past 20 years, much of it attributed to centrifuge units. The semi-batch Knelson Concentrator has probably received the most exposure, but it is rather because of the shear number of units sold than the width and breath of its applicability. It excels at recovery very dense minerals in very small concentrations, and has become a workhorse of the gold industry. Falcon’s Super-Bowl comes a distant second, with very similar applications. A number of copycats are available, and are generically identified as “Knelsons.” This presentation will not address these units explicitly, but as possible synergies."

Jan 1, 2000

By B. Holleis, M. Potesser, D. Spoljaric, H. Antrekowitsch, A. Hengelmolen

"During the past only an optimization of metallurgical furnaces were done without attention on the burners. Nevertheless, furnaces without burners are impossible to use in the primary and secondary nonferrous metallurgy in an economic way. Since the energy cost is increasing and the environmental protection is becoming a global issue, the burners are in the focus of several investigations and optimizations. One possible way is the combustion by oxygen. By using oxygen, the flame temperature increases and therefore, fuel accordingly money could be saved by having a low amount of harmful substances like NOx in the off gas. This paper describes a new burner system which combusts fuel with oxygen or air by diluted combustion, hence low pollutants in the off gas. Furthermore the effectiveness of the burner characterized by off gas analyses and simulation in the new development chamber, but also practical tests at an aluminum smelter are described.IntroductionIn 2005, Messer Group established a technology competence centre for metallurgy in Gumpoldskirchen (Austria), with the aim to develop oxygen burners which satisfy today’s and upcoming standards of legislation as well as customer requirements. With the assistance of the Development Sponsorship Fund (FFF) of Austria, cooperation with the University of Leoben was agreed on. With the long term experience of the Gas-Wärme-Institut “GWI” in Essen (Germany) and the University of Leoben, different new burners have been developed."

Jan 1, 2008

By J. R. Parry

Over the past several years, computerized financial models have been an important part of Newmont's strategic planning process. Two applications will be discussed in this paper: a general purpose financial model of Newmont, and a detailed operational/financial model of Magma Copper Company. Newmont?s general purpose financial model was developed using Lotus 1-2-3. It was designed to aid management in assessing the financial consequences of investment and financing decisions associated with long-term strategic planning by simulating the consolidated effect from individual transactions. Not only is the model capable of assessing the sensitivity of specific decisions to changes in the external economic environment (i. e., commodity prices, interest rates, inflation and exchange rates), it can also evaluate the effect from operating and financial decisions, including changing production levels and cost structures at individual operating units as well as simulating several types of transactions, including equity and debt issues, acquisitions and divestitures. The analysis of Magma Copper Company required the development of a detailed operating and financial model of the Company. The model was developed using IFPS in the corporation?s UNISYS (then Burroughs) B7900 mainframe computer and included separate pro forma financial statements for each of San Manuel-Pinto Valley's mines and concentrators, as well as Magma's smelting and refining operations. The outcome of this analysis was the decision to merge Magma Copper and Pinto Valley Copper Corporation, and to recapitalize the new corporation in order to provide funds for a retrofit and expansion of its Arizona smelter and expansions of its refinery and SXEW facilities.

Jan 1, 1989

By K. Shame, H. H. Thiele

South Africa holds approximately 70% of the world’s total chrome reserves. Chromium is an important raw material for the production of stainless steel and ferrochrome alloys. Over the years, China’s ferrochrome market has been dependent on chrome ore imports from South Africa. In 2018, China imported about 75% of its chrome ore from South Africa. With the low platinum price and the rising demand for stainless steel, a growing demand to evaluate new beneficiation technologies for fine chromite was identified. Gravity separation of fine chromite (<75 μm) is inefficient, due to the limitations of the technology to upgrade fine particle size distributions. Potential for the recovery of chromite, specifically fines (<75μm), lost to UG2 PGM flotation tails, but also from MG and LG6 spiral circuit tailings exist. Flotation of podiform chromite ores from India and Kazhkhstan is successful in generating saleable product grade, following acid or alkaline flotation routes. Application to South African stratiform chromite is being evaluated, with the emphasis on evaluating reagent type, optimising dosages and the effect of pH in optimising flotation performance. Flotation can unlock additional value from chromite tailings material. The effect of ore characteristics such as gangue mineralogy, particle size distribution and headgrade are reported. The performance in terms of product quality and yield are evaluated and compared. The impact of this paper will not only prolong life of mine and increase revenue but will also alleviate environmental burdens associated with tailings dams. Keywords: Chromite, flotation, fine material, performance optimisation

Jan 1, 2020

By CH. Liu, H. X. Jiang, X. Xiao

"A study has been conducted to characterize the fatigue life in 7050-T7451 thick plate by the comparison between an experimental alloy and commercial alloy. The fracture origins were specified and their sizes were measured by scanning electron microscope (SEM). Additionally, the size, number density and spatial distribution of porosity in the experimental material and commercial material were characterized and compared, using X-ray Computed Tomography(XCT). The results showed that microporosity was the predominant site for crack nucleation and subsequent failure of the experimental alloy. However, as for the commercial alloy, fatigue cracks were found to originate from constituent particles. The presence of microporosity in 7050-T7451 thick plate reduced fatigue life of an order of magnitude or more compared to the commercial alloy. The relationships between size of origin and fatigue life were proposed. It was showed that the fatigue endurance was reduced when the size of porosity increased.INTRODUCTION 7xxx series aluminum alloys, due to their combination of high strength, high resistance to stress corrosion cracking, and good fracture toughness, are widely used in structural engineering applications where high-strength and low-density characteristics are fundamental design requirements (Williams& Starke, 2003). Every designer is striving to find an optimal combination of properties including strength, corrosion resistance and fatigue resistance (Wanget al., 2016). Based on the design principles of aircraft, a higher fatigue resistance of aluminum alloys are required. Thus, many investigations have been carried out on the microstructures and its effect on fatigue properties of the 7xxx series aluminum alloy (Robson, 2004; Schubbe, 2009).Microporosity, which is a common defect in casting materials, can lead to a significant deterioration of mechanical performance and fatigue resistance, especially in the high alloyed 7xxx aluminum alloys. The actual valid loading area decreases due to microporosity, which results in detrimental effect on the mechanical properties. Many experimental studies have been conducted in this research field. Mayer et al.(2003) investigated the fatigue properties of magnesium alloys produced by high-pressure die-casting. The results show that porosity in magnesium alloys greater than0.18mm diameter may be considered as the most important material defect for high cycle fatigue and fully reversed loading conditions. Nadot et al.(2004) found that the near surface defects are much more dangerous than the internal defects. Wang et al.(2001a) used the Weibull statistics method to analysis the influence of the microporosity, oxides and particles on the A356-T6 alloy fatigue life. The results show that, the porosity is more detrimental to fatigue life than oxide films and particles. With regard to fatigue resistance, although the deleterious effect of microporosity has been generally acknowledged, a quantitative understanding between casting microporosity and fatigue life in 7050-T7451 plate is not well established."

Jan 1, 2018

By G. L. F. Powell

g samples of Cu-20 wt pct Ag alloy have been mdercooled to a maximum of 197°C by melting under a slag of commercial soda-lime glass in a vitreous silica crucible. No grain refinement of the primary copper was observed in samples undercooled to the maximum of 197°C. When the samples contained a small amount of oxygen, the copper dendrites were partially recrystallized at undercoolings greater than 97°C. In previous papers&apos;-3 reporting the grain structure of undercooled silver and copper, it was observed that grain refinement was dependent on both undercooling and oxygen content. Grain refinement occurred in undercooled silver when the degree of undercooling exceeded the range 153" to 175"C, while in Ag-0 alloys (0.12 wt pct) fine equiaxed grains were exhibited when undercooling was greater than 50°C. Similarly, copper samples undercooled as much as 208°C displayed fan-shaped growth from a single nucleation site, while the grain structure of Cu-O alloys (0.08 wt pct) was fine and equiaxed at undercoolings larger than 150°C. Thus the presence of oxygen greatly reduced the undercooling at which grain refinement occurred. It was also observed that the change in grain size resulted from recrystallization and was not due to an enhanced nucleation rate in the liquid-solid transformation. It is possible that the influence of oxygen on recrystallization is due primarily to its presence as a solute element. walker4,&apos; reported that, although a grain size change did not occur in pure nickel until the undercooling exceeded 150°C, small grains were observed in samples of Ni-Cu alloy solidified at small and large degrees of undercooling. Jackson et al.6 suggested that the fine grained structure of the Ni-Cu alloy resulted from the melting off of dendrite arms during recalescence. This remelting process may occur in alloys as a result of segregation during freezing which causes a variation in liquidus temperature from point to point within a dendrite. It was therefore decided to undercool copper with a metallic alloying element to ascertain whether the presence of a metallic solute would have a similar effect to oxygen in inducing grain refinement. A Cu-Ag alloy was chosen, since both metals had been shown to behave similarly on undercooling. The alloy Cu-20 wt pct Ag was selected since the eutectic constituent outlines the initial growth form of the primary copper, so that the as-frozen grain structure is not obscured if subsequent recrystallization occurs. This paper describes the results of undercooling experiments carried out with Cu-20 pct Ag samples undercooled to a maximum of 197°C and the effect of oxygen content on the grain structure of the undercooled samples. EXPERIMENTAL Melting was carried out in a small cylindrical resistance furnace using "fine" silver granulate and oxygen-free high conductivity copper. The procedure adopted was to melt the required quantity of silver in air in a clean vitreous silica crucible for approximately 15 min, freeze, and add granulated commercial soda-lime glass to form a complete surface slag cover, after which the sample was melted and frozen several times to reduce the oxygen content. The glass slag cover was approximately 3 in. thick. Pieces of copper (=50 g) were added to the crucible until the required quantity to make 350-g samples of alloy had been charged. Each piece was added quickly to the crucible which was held at a temperature slightly above the melting point of silver. The piece was quickly pushed beneath the glass to minimize oxidation and any oxide coating usually decomposed before the piece had settled down into the silver. After the full quantity of copper had been added, the melt was stirred with a silica rod to hasten homogenization and a Pt/Pt 13 pct Rh thermocouple enclosed in a vitreous silica sheath inserted for temperature measurement. Heating and cooling curves were recorded on a potentiometric chart recorder fitted with a zero suppression unit. The milli-voltage range of the recorder was adjusted so that temperatures could be read to 1°C. Heating and cooling curves were taken every hour until three consecutive readings gave the same solidus-liquidus range, consistent with the solidus-liquidus range for this alloy composition by reference to Hansen and Anderko.7 Metallographic examination of samples frozen at this stage, failed to show any variation in composition from bottom to top of the ingot. Consequently, it was considered that the melt was homogeneous at this stage and undercooling experiments were then car-

Jan 1, 1970

By John Capers

•The IME is the Safety and Security Association of the commercial explosives industry in the United States and Canada. •Founded in 1913 •Board of Governors •5 Standing committees- 1. Technical 2. Environmental Affairs 3. Legal Affairs 4. Safety & Health 5. Transportation & Distribution

Jan 1, 2006

By Raphael Banda

1 Initiating Systems ? a definition An initiation system is a combination of explosive devices and component accessories specifically designed to convey a signal and initiate an explosive charge from a safe distance. In the use of explosives, the initiating system performs the functions of transmission and control of the firing signal to each explosive charge. As functional groups, initiating systems may be considered as: Starters Those which provide the initial signal to start the blasting process. Surface systems Products which provide transmission of the starter signal and delay timing (if any) across the surface of the blast outside the blast hole. In-hole systems Products which provide the signal transmission, delay timing (if any) and the initial explosives energy in the blast hole.1 2 Different types of Initiating Systems The initiation systems commonly used in Sub Saharan Africa are: ? Detonating cord and detonating relay systems ? Capped fuse and igniter cord systems ? Shock tube non electric systems ? Electric systems ? Electronic detonators 3 Overview of Electronic Delay Detonator Technology Conventional detonators use pyrotechnic delay elements and the variation of the actual delay periods is at best approximately 1% the nominal delay. The lack of guaranteed precision common to all pyrotechnic systems enhances the likelihood of negative environmental blasting effects.3 For example, take a 500 ms in hole delay. In conventional detonators this means that 95 % of shots fire within 10 ms of the mean. i.e. a window of 20 ms. Taking a fixed interval between shots of 25 ms, with a range of ± 3 ms, a very ragged firing pattern could be expected which in practice would result in non uniform fragmentation.

Jan 1, 2005