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By Derek Egbert, Kevin Baumgartner, Howard Perko

Foundation designs in a bid-build business environment can be challenging as so much depends on the capabilities of the selected contractor.  Owners and governing agencies must be open to value engineering (VE) alternatives.  This paper presents a case history where a foundation VE design was prepared for a county bridge replacement. The existing structure was a two-lane, simply-supported, truss bridge approximately 270 ft long and 30 ft wide.  The new bridge is a three-lane, two-span, continuous steel plate girder bridge approximately 250 ft long and 49 ft wide.  The new bridge was to be founded on two end abutments and one center pier by a total of 173 micropiles. Due to the number of micropiles and the time requirement to install a single micropile, an alternative design was proposed utilizing driven steel piles for support of the abutments and rock-socketed drilled shafts for the center pier. Replacing the micropiles with the proposed alternative was intended to reduce overall construction time and cost. Shallow bedrock and soil scour presented unique challenges for the bridge foundation and required an in-depth investigation to determine the required depth of foundation elements to achieve pile toe fixity. It was determined the sand layer thickness was not sufficient in some places to provide fixity to the VE driven piles and therefore the east abutment had to remain the original micropile design.  Substitution of driven pile and rock-socketed drilled shafts in the other areas still resulted in both time and cost savings.  This case history shows how engineers, contractors, owners, and governing officials can collaborate collectively to develop effective foundation solutions. Keywords: micropile, driven pile, drilled shaft, abutment, center pier        

Oct 7, 2024

By Xue Wang, Callie Babbitt, Chelsea Bailey, Matt Ganter, Gabrielle Gaustad, Brian Landi

"Current trends, motivated by fossil fuel dependence and unprecedented greenhouse gas (GHG) emissions, show lithium-ion batteries (LIBs) emerging as a competitive energy storage technology due to higher power and energy densities compared to Pb-acid and Ni-metal hydride chemistries. These trends may be of concern, however, as environmental impacts are not well understood for either the LIB itself, or for the nanoparticles consumed or released during the battery's production, use, or end-of-life. This study combines economic modeling, dynamic material flow analysis, and fundamental material characterization methods in order to quantify some of the economic and environmental trade-offs for LIBs at their end-of-life. As expected, results show that as chemistries transition from Li-Co based cathodes to Li based Fe, Mn, and S cathodes, LIB recovery value correlates to the value of the raw materials used. These initial results aim to inform collection policies being proposed currently as well as enable future deployment of novel recycling techniques.IntroductionGlobal fossil fuel dependence and unprecedented GHG emissions have led to increasing attention on energy alternatives, for both electricity production and personal transportation. However, development of renewable energy systems is contingent on concurrent technological development of energy storage systems, primarily batteries used for power grid load-leveling, renewable energy storage, and hybrid and battery electric vehicles. In this sector, lithium-ion batteries (LIBs) are emerging as a competitive technology due to higher power and energy densities compared to lead-acid and nickelmetal hydride chemistries[!]. LIBs represent close to 20% of the total rechargeable battery market and 75% of the portable rechargeable battery market, which is the fastest growing segment of the rechargeable battery market, with a 20% global growth in 2008 [2].This surge in production ofLIBs indicates a looming waste problem; total waste from Li-ion batteries has likely grown substantially from the 500 metric tons estimated in 2003 [3]. Figure IA shows the substantial increase in world-wide lithium production that has occurred in the last several decades with batteries making up the largest share of applications (Figure lB). California and New York state legislators have attempted to proactively address this looming waste by issuing diposal bans on rechargeable batteries in their states[4, 5]. However, quantification of the costs involved in collection, transportation, and processing of these materials has not been examined in depth."

Jan 1, 2012

By Muhammad Zaka Emad

ABSTRACT: Sublevel stoping mining methods with delayed backfill employs cemented rockfill (CRF) as a backfill material. It is used in underground mines to achieve ground control and reduce wall slough. In addition CRF serves to reduce development waste and provides a working surface for mining the upper levels. Efforts to optimize CRF practices have been published. This paper presents a detailed review of CRF practices in open stoping mining systems with reference to case studies. A new methodology is suggested in a simple stepwise approach, which can be adopted for site specific conditions. The need of laboratory testing and quality control program is discussed based on the published literature.

May 1, 2013

By E. Roman E.

A novel anode slime purification process was developed and tested at pilot scale in the Chuquicamata Refinery. The process consists of three main stages: First, an atmospheric alkaline leaching at 90°C, under controlled pH and ORP operation parameters where metalloid impurities are preferentially removed from the anode slimes with high efficiency. In a second stage, alkaline washing of the mud leached with addition of reducing agent, with the intention of reducing the silver of the AgCl to metallic silver releasing the chloride, and finally, copper and other remaining impurities are leached out in mild conditions (60°C, one hour in sulphuric acid). In a side process Se, Te, and Sb are recovery with high efficiency from the alkaline liquor as chemical grade products. The global balance shows a high mass loss yielding a final product with high precious metal and low impurities content showing advantages in both a technical and economic point of view with a clear environmental sustainability. This treatment allows either the direct sale of the purified anode slimes or its pyrometallurgical treatment to obtain metal doré without emissions of Se, Sb and As. Chemical mechanisms for this novel process are also described.

Jan 1, 2007

By Ted DePooter, Mun Wei Leong, Chad Frederick

Downtown Bellevue Tunnel (DBT) is part of Sound Transit’s $3.7 billion, 14-mile light rail transit system from downtown Seattle, across Lake Washington, to the cities of Mercer Island, Bellevue, and Redmond. The tunnel was the first Sound Transit East Link project and posed significant construction risk. This paper discusses implementation of design changes to the soft ground tunneling method, implementation of several technologies such as the use macro-synthetic fiber initial shotcrete lining, use of spray-applied waterproofing, and use of shotcrete for the final tunnel lining. These efforts allowed for significant time and cost savings to the project.

Jun 13, 2021

By James W. Hendrix

A survey of endomycorrhizal fungi occurring on orphan coalmine lands in Western and Eastern Kentucky revealed a great diversity of species present. Thus a large number of fungi are available for isolation and evalution for enhancing revegetation of mined land. Endomycorrhizal fungi isolated from orphan mines stimulated growth of sweetgum seedlings on mine soil at low fertilisation but inhibited growth at high fertilization; this growth inhibition at high fertilization did not occur with plants growing on peat-perlite. Banding of endomycorrbizal inoculum was not advantageous, compared with incorporation of inoculum throughout the growth medium, for production of mycorrhizal sweetgum seedlings. Newly reclaimed mine spoils were nearly nonmycorrhizal, compared with land reclaimed four or eight years earlier. A procedure for isolation of single-spore cultures of endomycorrhizal fungi was developed; this procedure is necessary for studies of ecotypic variability. A practical procedure using container-grown Pisolithus tinctorius-infected shortleaf pine seedlings for production of large numbers of bareroot pine seedlings infected with P. tinctorius for mined land reclamation was demonstrated.

Jan 1, 1982

By E. H. Cho

INTRODUCTION Activated charcoal has been used for several centuries in many capacities including the recovery, isolation and purification of various materials (1). The first use of charcoal in a gold metallurgical system was in the extraction of gold after chlorination (2, 3,4). The gold was dissolved in a chlorine system and subsequently filtered through charcoal. The application of charcoal with cyanide extraction was patented by Johnston (5) in 1894 and adopted commercially in Australia in 1897. The process consisted of dissolving the gold and silver in a potassium cyanide solution and passing it through a series of charcoal filters. The charcoal was subsequently smelted to recover the gold and silver. The interest in the use of charcoal diminished in the first part of the twentieth century as the practice of the use of zinc as a precipitating agent increased. However, in 1916, the Yuanmi Mine in Australia replaced their zinc precipitation plant with a charcoal adsorption plant. In 1926, Scott and Gross (7) of the U. S. Bureau of Mines con- ducted extensive research on the adsorption of gold and silver from cyanide leach solutions. Among their findings was the result that the most important factor in improving the adsorptive power of charcoal was heat treatment with oxidation by air or steam. The work of Zadra (8) in 1952 stimulated renewed interest in the use of activated charcoal in gold and silver recovery with the development of a method of recovery of the gold and silver from the charcoal other than its destruction by burning. The process involved simultaneous desorption

Jan 1, 1983

By CRO CRO

Elk Valley Coal?s Cheviot Project is located in the Alberta foothills south of the town of Hinton. The mine has been in operation now for the 3 years. The start up and subsequent operation of the Cheviot project has been directly influenced by the Cardinal River Mine. As the Cardinal River Mine was winding down due to reserve depletion in 2004, the price of seaborne traded metallurgical coal jumped to record levels and customers began aggressively seeking new sources of supply. Several months later, the owners of Elk Valley Coal decided to begin mining at the Cheviot mining area, extending the life of the area?s operations by over 25 years. The Cheviot Project had been delayed by low coal prices, ownership changes and a complicated and lengthy regulatory process fueled in large measure by stiff opposition from a number of major environmental organizations. Chief to the startup of the project was the construction of a 23-kilometer-long haul road that would connect the new coal measures to the existing Cardinal River processing and rail facilities. Construction of this road was completed with the first coal truck making its first trip in October 2004. This paper will look at some of original assumptions, the actual mining experiences and the lessons that were learned while moving from the drawing board to the current development as it exists today.

May 1, 2007

By Christopher Van Dyke, Edward L. Petsonk, Knox Van Dyke, Vincent Castranova, Ji-Hee Kang, William Pailes

"INTRODUCTIONPlatelet-activating factor (P AF) has been shown to mediate a broad range of biologic activities (1). Chemical analysis has shown that PAF is a glycerophospholipid with a choline polar head group, an ester-linked acyl chain at the second carbon of the glycerol backbone, and an ether linkage at the first carbon. The alkyl group attached to the first carbon can exist in a variety of chain lengths, with the C16 and C18 forms predominant in humans. The structure of P AF has been identified as 1-0-alkyl-2-acetyl-sn-glycerol-3-phosphorylcholine (2,3).PAF can be released from a variety of cell types, such as basophils, neutrophils, and alveolar macrophages ( 4-6). Stimuli for the release of P AF include calcium ionophore, phorbol esters, chemotactic agents, and zymosan. In addition, endotoxin has been shown to be a potent stimulant of P AF release from alveolar macrophages (7).P AF has been shown to have a number of pulmonary effects. It has been associated with asthma since it can cause contraction of pulmonary tissue (8) and leukotriene secretion from leukocytes (9) and induce airway constriction when inhaled by humans (10). In addition, PAF is a potent chemoattractant and can cause migration ofneutrophils into the airspaces of the lungs (11,12). Endotoxin is a lipopolysaccharide-protein complex derived from the cell walls of gram-negative bacteria. I.PS is the lipopolysaccharide portion of endotoxin. LPS contains four covalently joined subunits: lipid A, 3-deoxyoctonate, a core polysaccharide moiety, and an 0-specific antigenic polysaccharide side chain. Rough LPS contains no 0-antigen side chain. The liP.id A portion of LPS has been associated with most of the biolQgic effects of endotoxin (13). This lipid A subunit consists of a D-glucosamine disaccharide backbone substituted with four fatty acid side chains. Endotoxin is found in a wide variety of occupational settings associated with organic dusts derived from plants or animals, such as cotton, cereal grains, silage, rice, and poultry (14-18). In addition, airborne endotoxin has been found in sewage treatment plants, composting plants, offices with contaminated humidifiers, and showers or saunas (19-22)."

Jan 1, 1990

By J. M. Skeaff

As much as 100% of the gold and 67% of the silver in a sulphur-bearing hydrometallurgical leach residue have been transferred to copper metal at copper smelting temperatures by dissolving the partially calcined residue in an iron-bearing slag maintained in equilibrium with the liquid copper metal and matte phases. The precious metals can then be recovered by conventional refining techniques. Copper can be recycled at least four times without any detrimental effects on gold and silver transfers and recoveries. Apparent copper recovery in the .process can be over 100% because of the copper content of the residue. Based on slag analys.es, the overal1 recovery of gold in the copper metal and matte phases varies from 94% to 100% under all conditions investigated. On the? same basis, silver recovery varies .from 9S% ?to 99% under optimum conditions, but is only 4S% to 73% under other, less attractive conditions. Unaccounted for silver losses of' about 30% make it difficult to determine the major factors affecting ?silver transfer and recovery. A method for implementing the technology on a commercial scale at a Canadian copper/zinc smelter has been proposed. A preliminary economic assessment and comparison of the proposed pyrometallurgical process with conventional cyanidation indicates that either process is economically attractive for recovering gold and silver from leach residues. Although the capital costs are higher, the pyrometallurgical process is simpler, has higher recoveries, lower operating costs and no .potential environmental problems related to cyanide disposal.

Jan 1, 1989

The structural design of a mine haul road involves the determination of cover thickness requirements above the in-situ or sub-grade material. The specification of these layerworks is a critical component in the overall road design process. Poor design often leads to premature failure of the road, safety is often compromised and productivity and equipment service-life will certainly decrease. Historically, the California Bearing Ratio (CBR) cover-curve design method has been widely applied to the structural design of mine haul roads. More recently, established mechanistic design principles have superceded the CBR approach to haul road design, using a multi-layer model to represent the various road structural layers. The structural design and associated layer thickness requirements are then determined following a maximum strain criterion. This paper develops a case-study evaluation of the CBR cover-curve and mechanistic design methodologies and through a comparative analysis of layerworks and materials, highlights how improved structural design can be achieved mechanistically.

Jan 1, 2011

By Shaik Jeelani, Esperidiana A. B. Moura, Vijaya K. Rangari, Roberta A. Lima, Rene R. Oliveira

This work present the preparation and characterization of biodegradable nanocomposites based on aliphatic-aromatic copolyester (PBAT)/polylatic acid (PLA) blend reinforced by TiO2 nanoparticle. The biodegradable polymeric nanocomposites were prepared by melting extrusion process using a twin-screw extruder machine. The influence of the TiO2 nanoparticle addition on mechanical and thermal properties of PBAT/PLA blend was investigated by tensile and impact tests, SEM, DSC and XRD analysis and the correlation between properties was discussed.

Jan 1, 2015

By James J. Neate

The augered cast-in-place pile system came into use in the late 1940's where various techniques were tried using pressure grouting methods. In the early development stages some piles were installed using the preplaced aggregate concrete system. As development continued it became more apparent that placement of coarse aggregate was more costly than making a pile out of a cement and sand mixture only. Various techniques were tried consisting of pumping structural grout into an open hole through a pipe left in the bottom of the hole, drilling or driving a pipe in close proximity to the tip elevation of the auger or in working a pipe down adjacent to the auger fluting. For these techniques the pipe was usually withdrawn after grout appeared at the surface. In 1951 a patent was applied for by Raymond Patterson describing the above techniques along with a technique for placement of grout using a hollow stem auger and a removable plug or lead bit at the tip of the auger. The plug or lead bit was removed by grout pressure and this would be an expendable item for each pile placed. The patent was granted in 1956 and patent rights were assigned to Intrusion-Prepakt, Inc. Shortly thereafter other contractors were granted licenses to utilize the system. Patent coverage expired in 1973 and this method now is in the public domain. Today the method is in wide use throughout the world and is particularly well accepted in Japan and England.

Jan 1, 1988

By Michael Moats, Adirek Janwong

The use of cylinder electrowinning cells, such as emew® technology, for the recovery of silver from primary and secondary sources has been growing. In this study, common operating parameters used in silver electrowinning were evaluated for recycling applications. Silver powders were produced from an industrial solution in a laboratory scale emew® cell. A design of experiments was employed to evaluate the effects of HNO3 concentration, iron concentration, current density and solution flow rate on current efficiency, particle size, bulk density, and crystallographic orientation. Current efficiency was affected by each parameter with increasing HNO3 concentration having a strong negative effect, increasing iron concentration and current density having moderate negative effects and increasing flow rate having a positive effect over the ranges examined. Finer particles were produced with increasing current density and decreasing flow rate. Bulk density increased when HNO3 concentration increased. The crystallographic orientation of all powders was dominated by the (111) plane. Increasing flow rate decreased the relative intensity of (200) direction. Based on these observations, silver electrowinning in cylindrical cells can operate at high current efficiency and produce larger powders at low HNO3 concentration, low iron concentration, low current density and high flow rate.

Jan 1, 2014

By Thomas M. Brady

The Spokane Research Laboratory/NIOSH and the University of British Columbia (UBC) geomechanics group are focusing on the development of safe and cost-effective underground design guidelines for weak rock masses having an RMR in the range of 15 to 45. Weak ground conditions, ground support, and mining methods used in several North American underground mines were observed. The RMR values were calculated to update both manned entry span design and non-entry stability graphs, plus a database on underhand mining methods was created to reflect existing North American mining conditions. The immediate rock mass was characterized and analyzed in terms of prevailing type of ground support, potential failure mechanisms, and rock behavior to define how existing design curves must be modified for the existing weak rock mass. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making sound economic decisions that will also ensure a safe working environment.

Jan 1, 2006

By D. G. Hulbert, D. J. Oosthuizen, D. de V. van der Spuy

Expert Online, as a software system, is aimed at providing plant operators in the minerals industry with effective training and on-the-job assistance. It incorporates a number of features to achieve this goal, of which the most important is its ability to explain the dynamics of the plant and control system in simple language, mimicking an informed plant expert who has online access to the inner workings of the plant and control system. This is made possible by a novel form of Artificial Intelligence, called the Interpreting Expert System. Previous implementations of the IES were only capable of explaining controller actions. Expert Online will extend this capability to also perform the more difficult task of explaining process behaviour. Expert Online will implement three main processes, namely the accumulation of data from the controllers and plant models, the interpretation, processing and filtering of that data and lastly communicating the relevant information to the user, both as written messages and in other audio-visual forms. Although Expert Online is aimed at the operator, other plant personnel, like supervisors and plant managers, will also benefit from it. This paper focuses on the structural and functional design of Expert Online for implementation on the latest version of Mintek’s open control platform, PlantStar, highlighting advances and additions since the previous implementations of the Interpreting Expert System and concluding with an example illustrating some of the principles.

Jan 1, 2003

By A. W. Ambrose

The present plans for the Petroleum Division of the American Insti-tute of Mining and Metallurgical Engineers provide for two principal meetings in the year 1928. The first will be at Tulsa, Okla., in September or October, 1928, with the exact date largely dependent upon the date of the .International Petroleum Exposition. The officers wish to hold the meeting at the same time as the Exposition in order that members of the Petroleum Division of the A. I. M. E. may have the advantage of attending both meetings at the same time. It is planned that this meeting will be devoted largely to petroleum production engineering problems. A tentative outline of subjects to be discussed is as follows: 1. Repressuring New Oil Fields, and naturally in conjunction with this falls Repressuring of Old Fields. 2. Air or Gas Lift. 3. Flow Strings in New Wells. 4. Deep Drilling Technique. It is also planned to have at this meeting a general paper relating to Supply and Demand of Petroleum and its Products. The second meeting is planned for February, 1929, in New York at the same time as the annual meeting of the Institute. Special details have not been carried very far on this meeting, although it is expected the program will cover technical problems in relation to production and refining of crude oil, as well as 1928 development in foreign fields and the United States. It is planned during 1928 to cooperate with the Bureau of Mines in an attempt to compile a set of definitions on petroleum engineering. These would be of value to the petroleum engineering profession, in order to better standardize various terms used in discussion of current problems. It has also been suggested that the Petroleum Division study certain problems in which research work is needed by the petroleum industry and outline certain definite programs that could be carried out by the Bureau of Mines and the U. S. Geological Survey, as a follow-up to

Jan 1, 1928

By A B. Christie

Known epithermal deposits in the Coromandel region belong to the low-sulphidation type, represented by three subtypes: (1) andesite-hosted epithermal Au-Ag, (2) rhyolite-hosted epithermal Au-Ag, and (3) andesite-hosted polymetallic veins. Paleo-depths for a range ofdeposits are estimated using various features including: paleo-surface indicators (e.g. sinters), hydrostatic pressures estimated from homogenisation temperature measurements on fluid inclusions, and alteration mineralogy. Paleo-depth estimates to the base of the ore zone for the rhyolite-hosted Coromandel deposits are in the range 200 to 500 m. Andesite-hosted Au-Ag deposits have more variable paleo-depths, and are deeper (up to 950 m) in those deposits with base metals at depth. The majority of Coromandel Au-Ag deposits have limited depth extents (<200 m) of economic grade mineralisation, although Waihi and Karangahake are notable exceptions with depth extents of 575 m and 700 m respectively. Limited depth extents of economic ore are a feature of epithermal systems worldwide and are commonly attributed to gold deposition from boiling fluids. Under hydrostatic conditions in epithermal/geothermal systems, boiling in an up-flowing hydrothermal fluid is controlled by the boiling point for depth (BPD) curve. From fluid inclusion studies of many low-sulphidation epithermal systems, deposition of electrum in economic concentrations appears to be confined to a temperature window of 260 to 180¦C. This means that for dilute, gas-poor fluids that follow the BPD curve, gold deposition is limited to a vertical depth zone of about 400 m, with its upper boundary at about 100 m below the ground surface. The greater depth extent at Waihi and Karangahake, can be explained by mixing of/a deep, hot (300¦C) fluid with cooler (c. 200¦C) heated ground waters. This has the effect of lowering the 260¦C isotherm by up to 300 m, thereby increasing the depth range of economic grade gold deposition within the 260 to 180¦Cwindow of electrum deposition.

Jan 1, 2000

By Sergio Burelli, Darren C. Megaw

"Operational challenges associated with solvent extraction (SX) plants include the effective on-line management of solids introduced from a variety of process streams. Solids are carried over from leaching circuits due to incomplete solid–liquid separation, may be formed as a result of chemical precipitation within the SX circuits, or introduced from downstream electrowinning operations. Solids in SX settlers result in operational challenges that impact plant availability and reduce optimized name-plate design capacity operation. Most available SX crud and bottom solids removal systems are limited in their effectiveness to handle high total suspended solids in SX circuits. Operations are often forced to take settlers off-line for complete removal of contained solids. These cleaning operations are hazardous, high risk, labour-intensive and costly in terms of production down-time and organic extractant and diluent reagent losses. Production pressure results in operations being reluctant to take SX settler units off-line for solids clean-out, resulting in continued operation of the SX, at reduced levels of mass transfer performance. Crud ForxTM is an SX solids removal system, for the on-line removal of interfacial and bottom solids associated with hydrometallurgical SX processes. A case study conducted at Glencore’s Mutanda Mining copper and cobalt operation in the Democratic Republic of Congo demonstrated the effectiveness of the Crud Forx. Benefits identified were an overall improvement in SX fire risk reduction, SX occupational health and safety and an improvement in copper mass transfer. INTRODUCTION Hydrometallurgical copper extraction and purification processes are often associated with ultra-fine solids distribution profiles throughout the process flowsheet (Virnig et al., 1999). The level and impact of the undesired deportment of solids to process streams varies from operation to operation, but the common denominator for all operations that employ solvent extraction (SX) as a copper upgrading and purification step is that, at some stage, they will have to manage solids (crud) within the SX circuit. Available crud removal systems in the industry have had limited success in continuous, effective interfacial crud and bottom solids removal from SX settlers. Most operations use basic removal methodologies which, at best, only result in delaying the requirement for taking the affected SX settler stages off-line for complete clean-out. This operational methodology results in production loss, increased SX organic extractant consumption and adds occupational health and safety risk to SX operations. The integrated Crud ForxTM/Crud FrogzTM SX solids management system assists operations in on-line SX solids management. The system has been proven to significantly reduce the requirement for off-line cleaning of settlers."

Jan 1, 2015

By M. J. Richards, A. Szirmae, G. R. Speich

The formation of austenite from ferrite, ferrite plus retastable carbide, spheroidite, and pearlite has been studied in a series of irons, Fe-C alloys, and plain-carbon steels using fast heating techniques. In the absence of carbide, austenite nucleates at ferrite/ferrite grain boundaries; nucleation is followed by the rapid growth characteristic of a massive transfornation. The trarnsformation occurs at 950°C at heating rates of 106º C per sec and cannot be suppressed. Metastable carbide dissolves before austenite forms and does not influence the transformation kinetics. For spheroidite structures, austenite nucleates preferentially at the jinction between carbides and ferrite grain boundaries. Growth from these centers proceeds until the carbide is completely enveloped; subsequent growth occurs by carbon diffusion through the austenite envelope. For pearlite structures, austenite nucleates preferentially at pearlite colony intersections. Carbide la)?zellae dissolve at the advancing austenite interface but complete solution of carbide does not occur; the residtial carbide is eventually dissolvled or spheroid-ized depending on the carbon cuntent. The magnitude and temperature dependence of the austenite growth rate into Fe-C pearlite when incomplete carbide dissolution is assumed are satisfactorily explained by an approximate colume diffusion model. The impurities present in plain-carbon steel reduce the growth rate of austenite in comparison to that jound in an Fe-C alloy. The formation of austenite has been studied in much less detail than the decomposition of austenite. This is primarily a result of the importance of harden-ability in determining the mechanical properties of steel. Recently, more interest in the kinetics of austenite formation has resulted from the discovery by Grange1 that rapid heating techniques strengthen steel by refining the austenite grain size. Although the strengthening effect is not large, it is accompanied by no loss in ductility. In addition, interest continues in rapid heat treatment of low-carbon steel sheet for tin plate applications.2,3 Among the few systematic studies of austenite formation are the early work of Roberts and Mehl4 on formation of austenite from pearlite and recent work of Molinder5 and of Judd and paxton6 on formation of austenite from spheroidite. Also, Boedtker and Duwez7 and Haworth and paar8 have recently studied the formation of austenite from ferrite in relatively pure iron, Kidin et al.9,10 have studied the formation of austenite in 8 pct Cr steels, and Paxton has recently discussed various aspects of austenite formation in steels." The present work was undertaken to determine the kinetics of austenite formation for a variety of starting structures including ferrite, ferrite plus metastable carbide, ferrite plus spheroidal cementite, and ferrite plus pearlitic cementite. Emphasis was placed on determining the active sites for austenite nucleation, determining the temperature and time range of austenite formation, and in the case of pearlite a careful study of the growth rate of austenite was made in the absence and presence of impurities. By using a variety of heating techniques including laser-pulse heating, it has been possible to study austenite formation in an isothermal fashion over a wide range of temperatures. EXPERIMENTAL PROCEDURE The alloys studied in the present work are a zone-refined iron with 4 pprn C, an Fe-C alloy with 130 pprn C, 2 Fe-C alloys with 0.77 and 0.96 wt pct C, and a plain carbon steel with 0.96 wt pct C. The zone-refined iron and Fe-C alloys contained 60 pprn and 200 pprn total substitutional impurities, respectively. The plain carbon steel contained 2400 pprn Si, 2000 pprn Mn, and 900 pprn Cr. Various heat treatments were given to these alloys to produce different starting structures of equiaxed ferrite, ferrite plus metastable carbide, fine pearlite, and spheroidite. These heat treatments are given in Table I. A wide range of heating rates were employed in this work because many of the reactions occur so quickly at temperatures in the austenite range that they are completed during the initial heating cycle unless very fast heating rates are used. Essentially the same heating techniques employed by Speich et a1.12 and Speich and Fisher13 were used in this work. For time intervals of 2 sec to 20 hr, simple hand immersion of 0.010-in. thick specimens in a Pb-Bi bath was employed. These specimens were quenched in a 10 pct NaC1, 2 pct NaOH aqueous bath. For time intervals of 100 m-sec to 2 sec, an automatic dunking and quenching device was employed with 0.002-in. thick specimens. Again, liquid Pb-Bi baths were used for a heating medium but now helium gas quenching was employed. For time intervals of 2 to 100 m-sec a laser heating device was employed with 0.002-in. thick specimens; a helium plus fine water-droplet spray was now used for quenching. Additional information on heating times shorter than 2 m-sec was obtained by study of the zones around the centrally heated laser spot. Here diffusion of heat from the centrally heated zone raises the temperature of the specimen locally to all temperatures between ambient and the peak temperature, but for times of the order of microseconds. All the heat-treated specimens were examined by

Jan 1, 1970