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By J. -C. Sztuke, M. Cao

ABSTRACT Wash water and polyethylene oxide (PEO) were used in the flotation of quartz and coal. Wash water decreased entrainment of –15 µm quartz. The optimum superficial wash water rate was 0.05 cm/s. PEO also lowered entrainment. The combination of wash water and PEO led to a slight further reduction in entrainment. For 1:1 mixtures of –15 µm quartz and –300 µm oxidized coal, the combined use of wash water (0.05 cm/s) and PEO increased the separation efficiency from approximately 30% to > 70%, whereas wash water alone at 0.05 cm/s did not lead to a discernible increase.

Jan 1, 2014

By H. E. Wilde

"Zinc has been used for many years as a galvanic coating for the protection of steel. Electrochemical measurements show that zinc actually overprotects steel. The corrosion rate of DQSK (drawing quality semi-killed) steel in air saturated salt water was determined as a Junction of applied cathodic potential. The resulting data indicate that at a critical cathodic over potential of - O. 725 Vsce an acceptably low corrosion rate of less than 1 mpy occurs. Using the developed criterion, alloys of Zn/X and AL/X were produced and evaluated in galvanic contact with steel in a standard laboratory test. The results indicate that Zn /Mn, Zn /Co, AI/Mg/Si and AI/Mg/Ge alloys offer excellent galvanic protection along with (a) no hydrogen evolution, and (b) improved dissolution life over Zn coatings.IntroductionZinc coated (galvanized) steel has been successfully used in applications where bare (or painted non-galvanized) steel would suffer corrosive attack. In general, galvanic coupling to zinc, as either an anode or a coating, is an effective means for combatting steel corrosion. Because of this, the use of galvanized steel has increased markedly, stimulated primarily by automobile manufacurers seeking to extend the corrosion warranties on automobiles(1).Although effective, zinc coatings are not without a number of drawbacks which warrant efforts to improve them. For example, because of the widely differing electrode potentials between zinc and steel ( - 1.05 Vsce and - 0.60 Vscc, respectively, in air saturated NaCl solutions), the zinc corrodes at a rapid rate to protect the steel. This is reflected in the limited lifetimes of galvanized unpainted siding. The basic electrochemistry controlling the situation is shown in Figure 1, for a system controlled by oxygen reduction. The zinc corrodes sacrificially to protect the steel, while cathodically polarizing the steel to a potential near that of zinc's open circuit anode potential."

Jan 1, 1990

By R. Blickensderfer

The sparking and gas-igniting tendency of steels and alloys were evaluated my measuring the radiance of spark showers produced by grinding a sample on an abrasive wheel in air, the time required for a spark shower generated on an abrasive wheel to produce an ignition in an explosive gas mixture, and the energy and speed required for impacts between various materials to ignite an explosive gas mixture. Mixtures of air-methane were found quite resistant to ignition by showers of sparks. A mixture of air-9.S pct hydrogen was used to increase the sensitivity of the tests and to thereby extend the range of materials that could be evaluated. The results of the spark-shower tests indicate that carbon steels and the alloy steels found in coal-cutter tools are among the most sparking and most incendive of any materials tested. Stainless steels, nickel alloys, and tungsten carbide are among the least sparking and least incendive. The brightness of the spark showers depended upon the degree of oxidation of the abraded particles. Impact tests against hard rocks such as solid quartz and sandstone, showed that high-carbon steel was more inc endive in the hydrogen mixture than were the softer steels or the alloy steels found in coal cutters. Ignitions were found much less likely to occur at speeds somewhat lower than the speeds currently in use in continuous mining machines.

Jan 1, 1972

By John T. McDonough

The Climax Mine of AMAX's Climax Molybdenum Division is currently producing approximately 34,000 tons of molybdenum ore per day from two underground levels (see Figure I), and initial design is underway for the next deeper (1200) level. The aim of this report is to present the methods of site evaluation used at Climax for cavability determinations and underground support design. Climax succeeds with its panel caving system of mining (Julin, 1973) (Figure 2) largely because of the presence of pervasive geologic structural discontinuities. The stockwork ore body at Climax was formed by the multiple intrusion of mid-Tertiary rhyolitic magmas into Precambrian granite, schist and gneiss, and the hydrothermal emplacement of molybdenite into the network of fractures that were generated during the forceful upward intrusion of magma. Subsequently, intrusive events that were more deeply seated refractured the overlying, ore- bearing stock and propagated a complex system of axial and radial fractures. Post-ore movement along the Mosquito Fault (Wallace, 1968) and its associated stranded shear zones further fractured the ore body and disordered the existent geologic structure. The result of these structural events is a brittle, crystalline ore body that is transected by a complex pattern of faults, shear zones, and joints that augment cave initiation and enhance comminution of the ore blocks. Generalizations can be made about the structural trends within the ore deposit (King, 1946; Kendorski, 1973), however, the intensity and orientation of geologic structure is by no means uniform throughout the ore body. The relative intensities of silicic and argillic alteration are also highly variable (Vanderwilt and King, 1955). As a consequence, no single rock-mass model suffices as a standard for mine design, and site characterization for cavability and support design is a continuous process.

Jan 1, 1977

By Dongping Duan, Hongliang Han, Li Zhong, Siming Chen, E Zhou

In this study, physical, chemical and microscopic characteristics of Celestine were investigated firstly. Based on which, the thermodynamic analysis of Celestine reduction was discussed. And the experiments of Celestine carbon-containing pellets used in rotary hearth furnace process were studied. The results showed that it is feasible to deal with Celestine by rotary hearth furnace direct reduction process. When the temperature is 1200°C, C/O ratio is 0.8 and holding times is 20min, the conversion rate of SrSO4 in Celestine is above 95%, the utilization rate of Celestine is nearly 100%. This study can provide theoretical and technical basis on economical and rational use of Celestine.

Jan 1, 2016

By R. S. French

The purpose of this paper is to present data that have been obtained during the past two years concerning the effects of prior cold-work and temperature and time of anneal upon the recrystallization and grain growth of 70-30 cartridge brass. It was desirable to study certain of these phases so that an accurate picture of the principles of the subject could be shown. The work is not intended to provide explicit annealing data, but to provide material examples that may help to clarify analogous problems concerning this alloy. Specifications often set limitations upon the grain size of annealed materials because of the importance of grain size upon subsequent manufacturing operations. It was, therefore, worth while to study the variables that affect the recrystallized grain size of this material. C. H. Mathewson and A. Phillips,l W. R, Webster,2 and others have presented annealing characteristic curves of this alloy. A recent typical curve presented by R. S. Pratt3 is shown in Fig. I. The tensile properties and grain sizes are shown as functions of the annealing temperature. Such curves serve as a useful guide in determining the physical properties of annealed material, but as they are made generally under carefully controlled laboratory conditions they do not indicate the performance of metal annealed in a mill muffle, where such conditions as amounts of metal, heating time and temperature may differ. Study of the effect of time and temperature upon grain growth and subscquent recrystallization was made with a coil of metal having the following analysis: 70.04 per cent copper; 0.007 lead; 0.007 iron; 0.00 tin; 0.00 silicon; 0.001 nickel; 0.000 phosphorus; balance zinc. The sample coil was obtained from metal that had been rerolled from hot-rolled mill stock, and was received at 0.228-in. gauge, soft, with a grain size of 0.125 mm. This material was then rolled 43.5 per cent to 0.129-in. gauge and annealed to a 0.053-mm. grain size. In this condition, samples were cut and used in all of the experimental work reported in this paper. Time The first study was of crystal growth at a constant temperature over a moderate length of time. Material was cut from the stock coil at 0.129-in. size and rolled 75 per , cent hard to 0.032-in. gauge. From this piece small samples were cut M by 2 in., suitable for grain-size determina.tions. Twelve samples were placed in an electric furnace uniformly across the width, approximately an inch from the floor. A thermocouple was wired to the center sample, so that the approximate metal temperature could be followed. At various

Jan 1, 1944

By R. S. French

The purpose of this paper is to present data that have been obtained during the past two years concerning the effects of prior cold-work and temperature and time of anneal upon the recrystallization and grain growth of 70-30 cartridge brass. It was desirable to study certain of these phases so that an accurate picture of the principles of the subject could be shown. The work is not intended to provide explicit annealing data, but to provide material examples that may help to clarify analogous problems concerning this alloy. Specifications often set limitations upon the grain size of annealed materials because of the importance of grain size upon subsequent manufacturing operations. It was, therefore, worth while to study the variables that affect the recrystallized grain size of this material. C. H. Mathewson and A. Phillips,l W. R, Webster,2 and others have presented annealing characteristic curves of this alloy. A recent typical curve presented by R. S. Pratt3 is shown in Fig. I. The tensile properties and grain sizes are shown as functions of the annealing temperature. Such curves serve as a useful guide in determining the physical properties of annealed material, but as they are made generally under carefully controlled laboratory conditions they do not indicate the performance of metal annealed in a mill muffle, where such conditions as amounts of metal, heating time and temperature may differ. Study of the effect of time and temperature upon grain growth and subscquent recrystallization was made with a coil of metal having the following analysis: 70.04 per cent copper; 0.007 lead; 0.007 iron; 0.00 tin; 0.00 silicon; 0.001 nickel; 0.000 phosphorus; balance zinc. The sample coil was obtained from metal that had been rerolled from hot-rolled mill stock, and was received at 0.228-in. gauge, soft, with a grain size of 0.125 mm. This material was then rolled 43.5 per cent to 0.129-in. gauge and annealed to a 0.053-mm. grain size. In this condition, samples were cut and used in all of the experimental work reported in this paper. Time The first study was of crystal growth at a constant temperature over a moderate length of time. Material was cut from the stock coil at 0.129-in. size and rolled 75 per , cent hard to 0.032-in. gauge. From this piece small samples were cut M by 2 in., suitable for grain-size determina.tions. Twelve samples were placed in an electric furnace uniformly across the width, approximately an inch from the floor. A thermocouple was wired to the center sample, so that the approximate metal temperature could be followed. At various

Jan 1, 1944

By R. S. French

THE purpose of this paper is to present data that have been obtained during the past two years concerning the effects of prior cold-work and temperature and time of anneal upon the recrystallization and grain growth of 70-30 cartridge brass. It was desirable to study certain of these phases so that an accurate picture of the principles of the subject could be shown. The work is not intended to provide explicit annealing data, but to provide material examples that may help to clarify analogous problems concerning this alloy. Specifications often set limitations upon the grain size of annealed materials because of the importance of grain size upon subsequent manufacturing operations. It was, therefore, worth while to study the variables that affect the recrystallized grain size of this material. C. H. Mathewson and A. Phillips,1 W. R. Webster,2 and others have presented annealing characteristic curves of this alloy. A recent typical curve presented by R. S. Pratt3 is shown in Fig. I. The tensile properties and grain sizes are shown as functions of the annealing temperature. Such curves serve as a useful guide in determining the physical properties of annealed material, but as they are made generally under carefully controlled laboratory conditions they do not indicate the performance of metal annealed in a mill muffle, where conditions are different and the amounts of metal require necessarily longer heating times and temperatures. Study of the effect of time and temperature upon grain growth and subsequent recrystallization was made with a coil of metal having the following analysis: 70.04 per cent copper; 0.007 lead; 0.007 iron; 0.00 tin; 0.00 silicon; 0.001 nickel; 0.000 phosphorus; balance zinc. The sample coil was obtained from metal that had been rerolled from hot-rolled mill stock, and was received at 0.228-in. gauge, soft, with a grain size of 0.125 mm. This material was then rolled 43.5 per cent to 0.125-in. gauge and annealed to a 0.053-mm. grain size. In this condition, samples were cut and used in all of the experimental work reported in this paper. TIME The first study was of crystal growth at a constant temperature over a moderate length of time. Material was cut from the stock coil at 0.129-in. size and rolled 75 per cent hard to 0.032-in. gauge. From this piece small samples were cut ½ by 2 in., suitable for grain-size determinations. Twelve samples were placed in an electric furnace uniformly across the width, approximately an inch from the floor, A thermocouple was wired to the center sample, so that the approximate metal temperature could be followed. At various

Jan 1, 1944

By Wilfrid Comeau

This paper deals with the concept of a Quality-Assurance Manual, to the ISO-9001 Level, for quarry blasting in the urban environment. A case history of the incident, which led to its development, is presented in addition to three other case histories. These case histories are related to the potential effectiveness of a well thought-out and applied Quality-Assurance Manual in the conclusions. The basic principle, behind the development of a Q-A manual, is to supply a maximum of quality assurance with a minimum of disturbance to the operation of the quarry. This requires that every intervener in the quarry blasting operations, from management to labourer, be made responsible for the quality of their work. This basic goal can be achieved with a minimum of paper work and added bureaucracy. The manual respects the ISO principle that: Q-A Manuals are not recipe books and should allow for continuing technological developments.

Jan 1, 2003

By Richard A. Allwes

This Bureau of Mines report presents a procedure for the design of an arch canopy for use in rehabilitating a high-roof-fall area. Only dy-namic line loading of an unbackfilled arch canopy at its crown is considered, and the procedure does not account for an asymmetrical loading condition. The evaluation of whether an arch canopy is suitable for a particular installation depends on many variables, including in-mine conditions and the engineering properties of the structure. However, a general evaluation can be based on a comparison of the arch's maximum crown deflection and a prescribed allowable crown deflection. The design procedure is based on the concept that when an arch canopy is sub-jected to impact loading at its crown and deflects from its unloaded state to maximum crown deflection, the structure absorbs strain energy, both elastic and plastic. As a result, this strain energy can be calculated from a static load-displacement diagram for the structure. The significance of this design procedure is that it gives mine personnel an analytical tool to select an arch canopy to meet the dimensional and functional requirements of a mine entry and a prescribed allowable crown deflection.

Jan 1, 1987

By B. H. Kim

The use of a 25.4 mm diameter water-only hydrocyclone for separating fine-size (-150 µm), high-density (>4.5 g/cc) particles from similar-size, lower-density (2.65 glee) particles was investigated. It was found that a single-stage separation recovered nearly 90% of the heavy minerals (7.0 g/cc), while achieving a volume reduction of about 70%. The use of dense medium in a single stage improved volume reductions to 90% at similar heavy mineral recoveries. In addition, computer simulations of a three-stage circuit were performed, which showed that recoveries approaching 97% with volume reductions of 95% were possible.

Jan 1, 1998

By R. L. Stone

None of the currently used methods of testing bentonites as binders for strengthening iron ore pellets is entirely adequate by itself. Since more knowledge was needed about 1) which properties of bentonite most affect pellet strength, and 2) the precise mechanism by which strengthening is produced, attention was paid to possible new techniques for rating bentonites. With the structural nature of bentonites — in particular, the montmorillonite component — the possibility of rating bentonites on the basis of zeta potential was investigated. These bentonites were also rated by conventional tests and measurements, including colloid content, barrel yield, pH, chemical analysis and physical tests on green and dry pellets. A mechanism for pellet bonding based on electro-kinetic forces between the bentonite and the iron ore concentrate appears to be feasible. In pelletizing, from 6 to 18 lbs of bentonite is added per ton of concentrate to give strength to the green and dry pellets. In some operations even more bentonite than is required for strengthening purposes must be added for moisture adsorption to pennit balling of the concentrate. Since bentonite is thus a major item in pelletizing, more knowledge about the way in which bentonites act as binders and better ways of rating this ability would help in the difficult job of selecting the right bentonite for a given concentrate. The fact of the matter is that although several methods are in current use for testing bentonites, none of these methods are consistently foolproof. For example, a given bentonite may rate high by several standard tests yet turn out to be a poor binder, and of course the reverse also occurs. Actually, more knowledge is needed about 1) which properties of bentonite most affect pellet strength, and 2) the precise mechanism by which strengthening is produced. In this study attention is therefore paid to possible new techniques for rating bentonites. With the structural nature of bentonites as a starting point, we investigated the possibility of rating bentonites on the basis of the zeta potential, i.e., the electrokinetic ootential on the montmorillonite colloids — the main component of bentonite binders. The zeta potential technique was applied to a range of commercial bentonites from several areas in the U.S. and abroad. These bentonites were also rated by conventional tests and measurements, including:

Jan 1, 1968

THE Joint Committee appointed to consider a Code of Ethics for Engineers recommends, after delib-erate consideration, that each participating Insti-tute or Society adopt the short simple Code of Ethics following this report. The Committee further recommends that the following method of interpreting and administering the Code be adopted by each participating Institute or Society after any necessary provisions have been, made in the Constitution and By-laws of the Organization. The President of each Society or Institute shall appoint a Standing Committee on Professional. Conduct, to administer the Code of Ethics. The duties of such a Committee shall be to interpret the Code and to render opinions on any cases of ques-tionable conduct on the part of members that may be submitted to the Committee. These interpretations shall be reported to the Executive Board of the Institute or Society who may approve these interpretations, or take such other action as may seem just and necessary. The reports of the Committee on Professional Conduct, when approved by the Executive Board, shall be printed in abstract and in anonymous form in the Institute's or Society's monthly journal for the instruction and guidance of fellow members. This Committee on Professional Conduct shall be appointed in each Institute or Society by the President holding office at the time of the adoption of this Code and shall consist of five member one appointed for five years, one for four years, a third for three years, a fourth for two years and a fifth member for one year only. Thereafter, the President then holding office shall appoint one member annually to serve for five years, and shall also fill any vacancies that may occur for the unexpired term of the member who has withdrawn. These appointments shall he made from among the older members of the Institute or. Society, so that advantage may be taken of their mature experi-ence and judgment. The Committee after appointment shall elect its own chairman and secretary. The Committee shall have power to secure evidence or other information in any particular case not only from the organization's own members, but if it should seem desirable, from men in other professions. The Committee may also appoint sub-committees to consider certain cases when deemed necessary.

Jan 3, 1922

By H. W. Gussmann, R. G. Rohrs, E. van der Merwe

Salinity in Effluents carries a high penalty as a result of toxic­ity, corrosion, limited re-use potential, scaling and environmental impact. Although the high TDS, such as Calcium sulfate, other than metals are still being dealt with a low key non issue basis, they are receiving more and more attention from regulators. Traditional solutions to solve these problems are costly and inefficient and create therefore severe constraints on the prof­itability of mining operations and out-price in general the finan­cial resources for environmental clean up operations. Going up the technology versus cost curve the most econom­ic solution to pollution is dilution but which is difficult in a coun­t1y shoti of water. If this can't be done, the second best, at least in sunny areas, is, to pump the whole effluent on a tailings dam for evaporation. Depending on the contaminants, one may have to pond the efflu­ent to avoid re-dissolution and seepage into the ground. The next most common solution to pollution is the addition of lime to remove and concentrate any dissolved metals and then dump the product, hidden in a mass of gypsum in a convenient place. Again ponding may be required to avoid ground pollution. However the treatment costs start to rise steeply if it is not allowed to discharge the limed overflow solution because of its high calcium sulphate content. Further treatment is then required in the form of high cost and high tech membrane process tech­nology such as reverse osmosis or dialysis or even mechanical driven evaporation.

Jan 1, 1998

By M. Guarascio

Microseismic monitoring of mining areas is a developing technique, described here for the Belvedere Spinello Mine, southern Italy, where dissolution cavities in the mining area have proved problematic. The preliminary condition for locating seismic impulses has been found to be a reliable seismic ground model. Ground signals are continuously recorded by means of data from piezometric wells, for sinkhole data, and linked gephones, for microseismic data. A computer system has been implemented to collect, analyse and interpret the incoming signals consequently, identification and classification of hypocentres of activity is facilitated, with advantages in terms of safety, preventing harmful side-effects, including rock bursts, and for environmental conservation.

Jan 1, 1987

By S. J. McCarroll

Fig. 1—The belt shown at right carries filter cake to mixing station over calciner. Crude ore conveyors appear in right background. THE Three Kids mine, some six miles east of Henderson, Nev., is in a typical southwest desert area, with high dry summer heat and cool to cold winter seasons. The manganese deposit was located during World War I.' During this period 15,000 to 20,000 tons of ore assaying up to 41 pct manganese were shipped. Interest in the deposit was not revived until the middle thirties, when experiments on the ore were initiated. Test work indicated possible recovery of only 70 pct by flotation, but in 1941 additional work was done at the Boulder City pilot plant of the U. S. Bureau of Mines and also by M. A. Hanna Co. As a result, the Manganese Ore Co. was formed and a plant utilizing the SO2 process was constructed. Numerous operation difficulties ensued, and the plant. was closed when the manganese situation in the country eased. In 1949 Hewitt S. West initiated negotiations to acquire the plant. In 1951 Manganese, Inc., was formed and contract entered into with the General Services Administration to supply 27 million units of metallurgical grade manganese in the form of nodules to the national stockpile. A second contract was made to upgrade 285,000 tons of stockpile ore. Test work was undertaken by the Southwestern Engineering Co. and likewise by the Boulder City pilot plant at the U. S. Bureau of Mines. Results obtained indicated the commercial feasibility of the flotation process. Construction of the plant, which is shown in Figs. 1 and 2, was started in June 1951, and operations on a break-in basis began in September 1952. Apart from the usual starting difficulties two major disasters caused serious setbacks, one a kiln failure in February 1953, and the other a fire that destroyed the flotation building in June of the same year. The nodulizing section of the plant resumed operation in November, and the flotation section in January 1954. The ore minerals are chiefly wad,* with minor amounts of psilomelane, and occur in sedimentary beds of volcanic tuff. The ore is overlain with beds of gypsum which outcrop or may be covered with surface gravel. Intermediate beds of red and white tuff occur frequently with lenses of red and green jasper and stringers of gypsum and calcite. Small amounts of iron are present; lead content averages about 1.0 pct and minute amounts of copper and zinc are found. Barite, celestite, and bentonite are present. Since these are made up of minute asicular crystals, moisture content is very high, averaging about 18 pct. Ore reserves have been estimated at 3 million tons averaging 18 pct Mn2 and up to 5 million tons after grade is dropped to 10 pct Mn. A good part of the orebody was stripped of overburden by the previous operating company . Approximately 50 pct of the ore, representing more than 60 pct of the manganese, can be mined by open-cut methods. A system for underground min- . ing has not yet been decided on. Open-cut mining with benches of 20 ft has proved satisfactory. Although the ore is soft and appears dry and dusty it has a certain resilience, probably due to the porosity and moisture which makes drilling and fragmentation difficult. Wagon drills have been abandoned in favor of the Joy 225-A rotary drill which will put down a 43/4 -in. hole at the rate of 2 ft per min. Holes are spaced in a pattern with 8 to 9-ft centers. Forty percent powder has been used, but better breaking to 2-ft size is obtained with low velocity bag powder of 30 pct strength. Loading is done with one 21/2-yd shovel, and cleanup follows with one D-7 bulldozer. The ore is hauled with Euclid trucks about 1000 ft from the pit to a blending pile, where the daily mine production is spread in layers by bulldozing until approximately one month's mill feed is accumulated. A new pile is then started and mill feed is drawn from the first pile by one 13/4-yd shovel and Euclid trucks, with a haul of approximately 500 ft. Mining is performed by an independent contractor with engineering and supervision by the company staff. Early test work indicated that the manganese could be floated with soap, a wetting agent, and fuel oil to give a recovery of better than 75 pct with a grade of 43 pct Mn. The concentrate when nodulized with coke would upgrade to 46 pct Mn or over, and the lead volatilized to 0.6 pct residual.

Jan 1, 1955

By Guido Deissnann, Jennifer L. Kirkaldy, Stephan Kistinger, Carol M. Pettit

Contaminated mine drainage presents a potential hazard for aquatic ecosystems and groundwater resources. Reliable predictions of long-term developments in seepage quality are necessary to select reasonable decommissioning options and remediation measures for waste-rock heaps during mine closure and/or mining site rehabilitation to minimize future risks and environmental hazards. Extensive geochemical modeling work was used to assess the consequences of various remediation options for waste rock heaps at a former uranium mine in Eastern Germany. The predicted contaminant discharges are used for an assessment of long- term benefits of decommissioning alternatives to derive conclusions for sustainable remediation measures using risk-based cost/benefit analyses.

Jan 1, 2000

By Meifeng Zhi, Yuqing Niu, Xixin Chang, Fengqi Zhao, Weimin Qiu, Hao Wang, Zhenqian Wen, Zujun Shu

An applicable Eluex process was developed for acid in-situ leaching (ISL) uranium mine in Bayanwula. In this process, uranium was adsorbed with strong base anion resin from the pregnant solution, then the loaded resin was eluted by sulfuric acid. After D2EHPA extraction, the concentrated eluate was enriched, and the loaded organic phase was stripped by sodium carbonate. The yellow cake was obtained by sodium hydroxide precipitation at last. The uranium concentration in the loaded strip solution was 52.8 g/L. Parameters of the process were determined, and the impact of the Eluex process in underground leaching was also investigated. In industrial design, 95% of raffinate went back to elution and 5% back to in-situ leaching. No significant effect on uranium leaching or resin adsorption was found.

Jan 1, 2020

By M. Sturzenegger

This paper documents a field survey using long-range terrestrial digital photogrammetry at the Palabora open-pit mine, South Africa, for multi-scale characterization of rock mass discontinuities. Stereomodels covering the entire mine were generated based on photographs taken from a distance of 1600m across the pit, using a series of f=20-400mm lenses. Details on the methodology used and its accuracy are discussed. Preliminary results on discontinuity orientation, persistence and intensity are presented, highlighting the effect of observation scale. The potential uses of long-range terrestrial digital photogrammetry in open-pit mine and large natural rock slope environments is emphasized. The use of an f=400mm lens from distances larger than 1.5km may represent an important step forward in the geotechnical characterization of inaccessible remote rock faces.

May 1, 2009

By K. K. Kelley

"In an earlier consideration of the vapor pressure of iron 3/ it was found necessary to estimate the specific heat of gaseous iron to write satisfactory free-energy-of-vaporization equations for the several forms of iron. That the specific heat of gaseous iron will exceed greatly the classical value of Cp = 4.967 calories per gram-mole per degree is evident from even a cursory Lamination of its spectrum. The two lowest energy states are separated by only 416 cm-1, which is small enough so that the second state is effective, theoretically, at below room temperature. Such phenomena are by no means uncommon, but, while they have been recognized with substances that ordinarily are encountered as gases, classical gaseous specific--heat values still are used, often without question, for the vapors of metals and other elements that are solids under ordinary conditions. The following calculations for iron and copper gases are presented to illustrate the sort of deviations from classical values that are encountered with metal gases.The methods employed in calculating from spectroscopic data of thermodynamic quantities such as specific heat, entropy, and free energy have been described, in detail by Giauque 4/ and others. These will be briefly reviewed here. It is customary to separate the translational energy of a molecule from the rotational, vibrational, and electronic energies. In the case of monatomic gases, only translational and electronic Energies are involved. The classical expression for the specific heat of a mona¬tomic gas, Cp = 4.967, deals only with energy stored in the molecule as translational energy and consequently is valid only in temperature ranges in which no appreciable number of molecules undergoes a change in electronic state."

May 1, 1937