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By F. Boylu

In this study, Ca-bentonite was subjected to a series of systematic hydrocyclone tests with the aim of developing separation procedures and in turn achieving optimum recoveries. In hydrocyclone tests, vortex and apex diameters and also feed pressures were investigated. In each hydrocyclone set, vortex diameter was kept constant while the other two parameters varied to produce bentonites con-centrates of various smectite contents. The separation efficiencies were evaluated based on the cation exchange capacity (CEC), particle size and swelling index. The detailed hydrocyclone tests showed that, upgrading of Ca-bentonites require procedures different from the bentonites reported in the literature. Sodium and mixed bentonites are easy- to-disperse and easy-to-separate whereas calcium types need to be scrubbed rigorously for disintegration. Scrubbing properties of ca-bentonite were investigated as a function of scrubbing time and percent solids by weight (PS). The scrubbing conditions at 700 rpm for 1.5 hours and percent solids of 30 % were found more effective for achieving a better quality bentonite. In addition to the parameters mentioned above, the effect of percent solids on hydrocyclone separation was also studied. Although Ca-bentonites permit studying at higher percent solids, increasing solids content of the pulp deteriorated the quality of the clean products. Application of an appropriate separation scheme enabled the development of a unique separation procedure involving stage wise scrubbing followed by hydrocycloning which yielded calcium bentonite concentrates with CEC of 90 meq/100 g and high swelling indexes of 12 mL from the original bentonite of 65 meq/100 g and 7.0 mL, respectively. These results indicate that upgraded bentonite products can be conveniently used in various diverse industrial applications including bleaching earth, desiccant, cat litter, paper etc.

Jan 1, 2014

By C. Newman

"Over the past decade, as conventional underground deposits have been depleted, mining operations have been forced to produce at greater depths and in more geologically and geometrically challenging conditions. As such, there has been a global increase in the application of cemented paste backfill (CPB) in tabular deposits utilizing open stope mining method with a delayed backfill placement. Despite the extensive use of CPB, many fundamental factors affecting the design of safe and economical fill structures are still not well understood. A critical issue in the design of backfilled stopes is the determination of stress states within the fill material itself as well as the surrounding rock mass. Analytical equations provide a means of quickly evaluating the effectiveness of a given design. However, in developing these equations large assumptions are implemented to simplify the design problem. It is important that one understands these simplifications as well as their effect on the overall design. This paper investigates common analytical equations utilized in the evaluation of single vertical backfilled stopes and their assumptions through comparisons to numerical modeling results. INTRODUCTION AND BACKGROUND As the mining industry continues to produce at greater depths and in more geometrically and geologically complex conditions, cemented paste backfill (CPB) has gained traction as a means of providing localized ground support in modern stope-and-fill mining operations. The application of CPB in stope-and-fill mining as a ground support material has led to the reduction of mine waste costs, while increasing both mine production and stability. In an attempt to achieve total extraction of the mining reserve, stope-and-fill mining operations often employ a primary-secondary excavation-support sequence (see Figure 1). In this practice, primary stopes are initially excavated and then backfilled in a two-stage pour; plug and final pours. During the first stage (plug), a CPB material with increased cementitious content is placed at the bottom of the stope providing a strong base from which to build a backfill structure as well as protect mine works from material breakthrough. Following placement, the backfill plug is allowed to cure to a given strength as designated by the mine design. Upon achieving the required cure strength, a less cementitious CPB material is used to backfill the remaining stope area. This is referred to as the final pour stage. With all primary stopes excavated and supported using backfill, the extraction of the secondary stopes commences as primary stopes are utilized as artificial pillars. While the application of CPB in a primary-secondary extraction-support mining sequence allows for a substantial increase in reserve recovery, it is imperative the mining personnel and planning engineers have a clear understanding of the material’s behavior and stress interaction with the surrounding rock mass to ensure the most efficient, cost-effective, and safe extraction of underground deposits."

Jan 1, 2018

By J. Bigu, M. G. Grenier, S. Hardcastle

"This study was undertaken in a belt conveyor drift of an underground hard rock mine. The conveyor transported ore or waste from a crushing operation located upwind from the drift sampling locations. A 250 m section of this drift was selected and several types of measurements were taken. Average respirable concentrations in the drift were 0.43 mg/m3 and 0.19 mg/m3 for total and silica dust, respectively. From the respirable dust concentration profile along the drift, it may be possible to estimate the contribution from extended sources such as dust produced by the belt and return idlers.The airborne dust in the drift had an average mass-median aerodynamic diameter of 4.2 micron. A continuous dust monitor showed that the crushing operation produced fairly high dust concentrations (sometimes greater than 4 mg/m3) over short periods of time.IntroductionAirborne dust in the respirable range is known to be the cause of various forms of lung ailments . In underground mines, respirable dust sources are created at many stages of production. All mining operators are responsible for de signing and establishing means of reducing airborne dust. In some cases, sources of dust are well defined and suppression methods are standard.In the case of interest here, the airborne dust cloud was formed from the contribution from many sources, which may be either discrete or extended. At the experimental site, the discrete or point sources were the crushing operation and the belt conveyor transfer point (tail pulley). These sources may be controlled by proper dust capture and scrubbing systems as well as dilution ventilation. Examples of extended dust sources in the area include dust produced by the re-entrainment of settled particles along the drift. Ventilation air movement and vehicular traffic both contribute to this phenomenon. Dust produced by the conveyor is another example of an extended dust source. Caked deposits on the return strand and idlers as well as the transportation of dry material on the belt, can be major contributors. Proper wetting of roadways and muck as well as proper belt cleaning techniques can help reduce these emissions. The cleaning apparatus, used on the belt where these experiments were conducted, is shown in Figure I. These and other belt cleaning techniques are described in more detail elsewhere."

Jan 1, 1987

By H. S. Chiang, S. S. Peng

"SummaryAir velocity distribution surveys on four mechanized longwall faces are presented and discussed. Although there are discernible patterns in the velocity distribution, there are wide differences in distribution in the cases examined. This can be attributed to differences in mining and face geometry. An important factor is air leakage into the goaf.IntroductionOver the past two years several intensive air velocity surveys have been carried out in West Virginia coal mines as part of a programme aimed at understanding dust transport mechanisms on mechanized longwall faces. These are presented here and some of the patterns of velocity distribution are discussed.Ventilation survey methodologyThe air velocity vector consists of three mutually perpendicular subvectors; the vertical subvector is directed toward the roof, one of the horizontal subvectors is parallel to the coal face and the other pointing to the gob. The air velocity which was measured in this paper is the horizontal subvector parallel to the coal face.To record the velocity distributions at the longwall faces, the surveying stations and the surveying points were established as follows.(1) The first station usually was set at the third support from the headentry T-junction. Within the first few supports, the air coming from the intake airway encounters a sharp right-angle turn at the T-junction, and forms a turbulent region close to the coal face. The intake air in this region is also influenced by the motors that drive the face conveyer. But when the air reaches the different. But for the same face the number was the same. The main air-travelling area was divided into six to 12 equally sized sub-areas, and each surveying point was situated approximately at the centre of the sub-area.The velocity survey was carried out by two persons, one reading the meter and the other taking down the readings. A complete survey at one station took about 5-8 min. Usually, the dimension of the cross-sectional area was measured during that time.A third person used the smoke tubes to observe the following: (I) the air movement patterns at different locations; (2) the extent and the direction of the air leakage; and (3) the machines' influence on the main airflow. At the same time he observed and recorded the roof conditions and the compactness of the roof-caving in the gob."

Mar 1, 1989

Humic acids adsorb on coal and depress coal floatability in the acidic pH range. In alkaline solutions, their effect is not pronounced. In the neutral pH range, a second small addition of kerosene plus MIBC leads to a significant increase in coal yield and better selectivity. Humic acids present on oxidized coal surface were found to be responsible for the inhibited floatability of the? coal. As expected, the flotation of such oxidized coal also strongly depends on the method of pH adjustment.

Jan 1, 1988

By A. H. Cronk

This paper is one of a series being prepared by the United States Bureau of Mines on mining methods and costs in the different mining districts. The mining methods described in this paper are employed by one of the large mines in the Illinois fluorspar district. The mine is located at Rosiclare, Ill., and shipments are made over the Illinois Central Railroad: and by barge on the Ohio River.

Jan 1, 1930

By D. Kruse

Top-down constructed large-diameter (up to 90 m or 300 ft) shaft design and constructability issues present an interesting suite of challenges and opportunities highlighted in this paper. The study covers 2D and 3D finite element models used to analyze various failure modes, evaluate the shaft liner and internal structures' response to seismic loading, assist in segment design and assess final structural design tradeoffs. Efforts to achieve economic advantage over conventional heavy civil practices have prompted innovative solutions for ring and segment design, ring build assembly and annulus backfill grouting. Intended for soft ground conditions, relationships between soil parameters and structure design are also explored. Mining Engineering, 2011, Vol. 63, No. 9, pp. 81-88. Official publication of the Society for Mining, Metallurgy and Exploration, Inc.

Jan 1, 2011

By D. S. Dihalu

A generalization of Gy?s model for the fundamental sampling error introduced the new ?parameter for the dependent selection of particles?, denoted as Cij. This allows for modeling deviations from the ideal situation where the selection of a pair of particles is composed of two independent selections. The generalized model potentially leads to more accurate variance estimates in the case of clustering of particles, differences in densities or sizes of the particles or repulsive inter-particle forces. A straightforward and practically applicable method is needed for the determination of this parameter for miscellaneous mixtures in industrial settings. In this contribution, the feasibility of using digital image analysis to determine this parameter Cij, will be demonstrated. Line transect sampling of a digital image was used to construct a transition probability matrix. A new algorithm to derive quantitative estimates for Cij will be presented and discussed. The applicability was verified by a photograph of zirconium silicate particles of sizes typical for industries dealing with pharmaceutical, food/feed, and environmental applications. Conditions affecting the practical applicability are identified and potential pitfalls will be discussed, including e.g. how a potential unrepresentative surface can affect the quality of the estimate of Cij.

Jan 1, 2010

By C. Alvarez del Villar

"El presente trabajo describe algunos estudios realizados sobre las condiciones ambientales en operaciones de subsuelo, en 30 minas peruanas. Dichos estudios comprenden un período de 10 años (1949-1958) donde se evaluaron los riesgos de contraer silicosis en las zonas mineras, así como aquellos análisis relacionados con las operaciones de subsuelo. La gran mayoría de minas evaluadas están ubicadas en la región de la Sierra (Junin, Pasco, Huancavelica, Cajamarca), mientras que la minoría en Arequipa, Puno, La libertad y Lima, cuyas alturas oscilan entre 1000 y 4800 m.s.n.m. Los resultados de la concentración de monóxido de carbono señalan que de las 20 minas examinadas, solo 8 dieron un 100% de detecciones por debajo del límite permisible. Mientras que del 12 restante, la concentración del gas permanecía luego de un tiempo de dos horas. Por ende, existe una mayoría de centros mineros donde no se concientiza el riesgo de salud sobre estos niveles de monóxido, y tampoco se ejecuta los principios de ventilación por dilución como el mejor medio de evitarlos. Bajo estas circunstancias nace la silicosis, enfermedad producida por la producción de partículas de sílice libre depositada en los pulmones. En 1935, Cummings propuso como primer criterio de riesgo, la relación de la exposición del polvo con la cantidad de sílice libre y a partir de allí, se adoptaron medidas basadas en este primer criterio de ""exposición-respuesta"", encontrándose que el valor máximo del sílice libre está en los minerales de cuarzo, incluso cinco años antes de su exposición. Mientas que la relación alternativa de ""dosis-respuesta"" es más factible en los tres estadíos de la silicosis, tanto en el sentido de sus concentraciones, como en el número de años de exposición."

Jul 20, 1959

By Kristine Bruce Wanderley, Denise Crocce Romano Espinosa, Jorge Alberto Soares Tenorio

Magnesium is present in nickels leach liquor and it is often disposed in waste barriers. However, new technologies with the aim of recuperating magnesium and other metals in the liquor have proven that it is possible to reduce the amount of metal lost during nickel ore processing. In this context, high temperature crystallization removes magnesium, with a concentration of 8 g/L, as MgSO4 H2O from the leach liquor. Kinetic studies of this process are needed to evaluate the thermodynamics of the growth of crystals. Thus, this work aims to study the crystallization kinetics of MgSO4 H2O. Temperatures of 230, 210 and 200 °C were investigated in a batch crystallization system in solutions with pH2. Aliquots were taken at each hour up to 5 h of time residence and analysed by ion chromatography for magnesium concentration. The reaction mechanism as well as rate constant and activation energy for each reaction temperature were obtained

Mar 1, 2018

By Walter W. Kaufman

This report summarizes a study conducted to determine the state of the art of various rock removal systems and their capabilities. The Objective of the study was to determine if currently manufactured equipment can adequately accomplish rock removal in surface mine reclamation applications. Evaluations of state reclamation regulations, with regard to topsoil rock content, were made to determine the rock removal requirements. The major categories of equipment studied are rock pickers and rock rakes. The impact of rock removal implementation on the reclamation operations is discussed in detail.

Jan 1, 1979

By John H. Morris, R. Gwilym Roberts

"The Upper Beaver Mine, Kirkland Lake, Ontario, is a copper-gold deposit in mafic flows and sedimentary rocks. The deposit consists of a number of orebodies of two types: copper- and gold-bearing chalcopyrite-pyrite-magnetite ore; and gold-bearing quartz veins. Chalcopyrite-pyrite-magnetite ore occurs in two structural forms: as cherty interflow material in coarse clastic roks underlying flows; and as veins. Both sedimentary and vein ore occur in each orebody. The goldbearing quartz veins occur in interflow sedimentary units and at the contacts of oligoclase porphyry dykes.The deposit is in a localized, volcanic-sedimentary basin which began to develop during the emplacement of the upper units of the pyroclastic and sedimentary Gauthier Group, and continued to the early mafic flow activity of the overlying Kinojevis Group. The formation of the volcanic-sedimentary basin is ascribed to the D0 deformation. The deformation is significant in terms of the structural configuration in the mine area, and may be significant regionally, but this has not been demonstrated. The early deformation was followed by two tectonic deformations. D 1 is associated with a penetrative mineral foliation, axial planar to upright mesoscopic folds and striking parallel to the trend of regional fold structures. Mesoscopic flexural-slip folds, kink folds and fracture-crenulation cleavage are attributed to the D2 deformation. It is probable that no large-scale fold structures are associated with the D2 deformation. The gold-bearing quartz veins were folded during the D1 deformation.The close spatial relationship of copper-gold, chalcopyritepyrite- magnetite veins with chalcopyrite-pyrite-magnetite in cherty inter flow material is strong evidence for the derivation of the veins from the sedimentary ore by hydrothermal, metamorphogenic processes. By analogy, it is suggested that the gold-bearing quartz veins were formed by similar processes."

Jan 1, 1982

By H. Ewaschuk

"INTRODUCTIONRio Algom's Stanleigh Mill in Elliot Lake began production in June of 1983. The highly instrumented mill treats uranium ore at an average rate of 3900 metric tons per day. To help ensure a good start-up and low operating costs, an extensive training program was undertaken prior to and during start-up. This presentation describes how an unconventional operating crew were combined to form an operating unit with a high efficiency in terms of production and labour utilization. I would like to point out at the outset that the operating philosophy, and the role of the supervisors and the operators as set up at Stanleigh is not unique. Indeed, I have seen the same results at a couple of small plants where efficiency meant survival. However, these situations appeared to be the exception, and it was not readily apparent how similar results could be obtained in a larger plant. A factor that existed at the time was low labour turnover. As in most parts of Canada, jobs were easy to get in the Elliot Lake camp in the late 1970's. This, and other factors, contributed to an unusually high labour turnover. This changed dramatically in the early 1980's. Indeed, Rio's two other operating mills, Quirke and Panel reduced crew sizes at this time to reduce operating costs. As a result all of Stanleigh's operators came from Quirke and Panel with experience varying from 4 to 7 years. The experience that operators had was obviously of benefit and served to reduce the scope of the training program from what would have been required with inexperienced personnel."

Jan 1, 1985

Under the Town and Country Planning Act 1977 the Ministry of Works and Development has a responsibility for providing information to local and regional planning authorities on public works and matters of national development and importance, for the exercise of their responsibilities under this Act. One such matter which has recently become a source of concern is the development of South Island lignite. In 1979 the Ministry of' Energy produced a position statement outlining a programme of' research leading to the possible extraction of lignite in Southland or Central Otago for conversion into about 50 per cent of New Zealand's liquid fuel requirements by 1995. Understandably this possibility has caused considerable concern at the local level, expressed particularly by bodies such as Federated Farmers and the local authorities. In the absence of any factual knowledge short of mere conjecture been able to recommend to local authorities is that they limit their planning period to ten years. After this time more information regarding the size, nature, location and certainty of the proposal will permit a more accurate assessment of the implications of the York. While on holiday earlier this year I took the opportunity to visit opencast mining areas in Germany and England to gain an appreciation of the scale of impacts involved and discuss with those concerned the procedures used in planning for such operations. What follows is a brief description of these operations, a comparison with the likely development in this country and the extraction of what may be some relevant principles of' operation for the planning of an environmentally acceptable project. Please note that the views expressed in this paper are mine alone and are not necessarily those of the Ministry of Works and Development.

Jan 1, 1981

By E. L. Smith

The development of larger size flotation machines, which started in the 1950's and 1960's, is still proceeding. The largest mechanical flotation machines avail-able today have unit volumes in the range of 38.2 to 43.9 M3 (1,350 to 1,550 cft). Designs for mechanical flotation cells of unit volumes as large as 70.8 m3 (2500 cft) are available. The development of these "giant" flotation machines has been and continues to be motivated by the increasingly critical forces of higher energy and capital costs, decreasing ore grades, and lower (real) prices for the products. As an expansion of a previous publication, this paper reports the further development of an improved mechanism for these large flotation machines. The starting point in the develop¬ment of a new mechanism was the identification of design and performance features of existing machines where improvements were desirable. The result of this work was a mechanism which s is an improvement over existing designs. This new design is characterized by an efficient overhung stator and a vortex profile rotor. The overhung design of the stator removes unnecessary and undesirable baffling in the lowest parts of the tank, while maintaining a quiescent froth layer. This results in lower power consumption and better pulp circulation and solids suspension. The vortex profile rotor acts as an efficient pump, with higher pulp recirculation rates as evidenced by the increased air dispersion capabilities, good solids suspension, and low power consumption.

Jan 1, 1983

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By V. K. Kollipara

Air flow patterns in the face area of a room-and-pillar mining are critical for understanding the dust dispersion characteristics and for developing engineering controls. SIUC has previously performed a CFD study to analyze the airflow patterns in the face area when continuous miner is making a straight cut. Results from this study identified low air velocity and re-circulation zones in the face area and illustrated the significance of line curtain, and scrubber operation on the air flow patterns. This paper discusses similar analyses when continuous miner is making a right turn cut as it is considered to be the dustiest cut among all the cuts made to advance an entry through a crosscut. This paper presents results for box-cut development for a right hand turn x-cut. This paper also addresses line curtain advance and air leakage through the curtain on the airflow patterns in the face area for such a cut. Low air velocity and recirculation zones were identified by analyzing the velocity vectors.

Jan 1, 2012

By Charles "Chick" Rodgers

"The Key Lake uranium mine is the largest single uranium producer in the world. It is owned 2/3 by Cameco Corporation and 1/3 by Uranerz Exploration and Mining. Cameco is the operator. Current production is fourteen million pounds per year of uranium oxide (U308).The mine's location is 570 kilometres north of Saskatoon on the southern edge of the Athabasca Basin approximately at latitude 57° 11 'north and longitude 105° 34' west. Access to the mine is by an all-weather road and a private airstrip.The mill was commissioned in 1983. A molybdenum plant was constructed in 1989 in response to increasing molybdenum content in the yellowcake or final product. Early test work had showed that the first ore body to be mined, the Gaertner deposit, would present few problems with regards to molybdenum in the product. However, the test work also showed that the higher molybdenum content of the Deilmann ore, the second Key Lake orebody to be mined, would result in increased molybdenum concentrations. Without the molybdenum plant, penalties would become excessive and some product might not accepted by the refineries.This paper will describe the current Key Lake mill process with emphasis on the molybdenum solvent extraction process. It will cover the chemistry of the process, process development in the mid 1980's, and current operating practices.The Key Lake milling process consists of five individual plants, crushing and grinding, leaching -counter current decantation (CCD), solvent extraction, yellowcake/crystallization and bulk neutralization (Figure 1. Simplified Mill Flowsheet). A detailed mill flowsheet can be found in the appendix."

Jan 1, 1996

By R. J. Snoby, J. K. Alderman

Although once fairly common as a method of coal preparation in the United States, dry cleaning has virtually disappeared. Low-rank coals used for power generation in the western U.S. are suited for dry cleaning because water has limited availability in the American west. Surface moisture added through wet cleaning offsets energy improvement achieved from mineral matter reduction. Information will be presented on the commercial application of dry cleaning in North America, the historic development and current status of the technology, and the introduction of modern processing theory and control technology to the design of dry cleaning equipment and plants.

Jan 1, 2001

By T. R. A. Gokcen

THE possibilities of separating and purifying metals by high vacuum distillation were examined by Kroll.1 He suggested vacuum treatment for the removal of zinc from the lead produced after Parkes desilverizing. The St. Joseph Lead Co. developed the first commercial vacuum dezincing process at their Herculaneum refinery, as described by Isbell.² The Broken Hill Associated Smelters at Port Pirie, Australia, has, after several years of pilot plant operations and fundamental investigations, developed a continuous process, which will be described briefly in a forthcoming publication." As the full-scale continuous vacuum dezincing plant at Port Pirie is still experimental, publication of full practical details of the plant will be deferred until the unit is operating as a normal part of the continuous refinery. This paper deals only with theoretical aspects of vacuum distillation processes, with particular reference to vacuum dezincing. The method of mathematical analysis is of general interest as it may be applicable to other metallurgical separations which have been investigated recently.4-6 Evaporation Processes At about atmospheric pressure, or higher, most liquids possess a boiling point—a temperature at which any heat put into the liquid is absorbed only as latent heat, not as specific heat. If a steady heat input is supplied, the liquid's temperature rises to this value, then remains constant while bubbles of vapor form beneath the surface. The rate of evaporation is determined solely by the rate of heat transfer to the liquid; the temperature of boiling is determined by the partial pressures of the volatile constituents in the liquid, and the total pressure above the surface. If the rate of heat transfer to the liquid is increased, the temperature remains constant, and the rate of boiling increases. When evaporating metals under vacuum, however, the partial pressures concerned are generally so small that boiling does not occur, because at even a fraction of a millimeter below the surface the hydrostatic pressure is usually too great to permit the formation of a pocket of vapor. In addition, the high thermal conductivity of metals tends to prevent the local superheating which is necessary for bubble formation.' Although this effect is doubtless also exerted when boiling metals at higher pressures, the magnitude will be less because the degree of superheat required to form bubbles is very much less at the higher temperatures involved. Under vacuum, therefore, evaporation of volatile constituents takes place only from the exposed surface, and the rate of evaporation depends upon the surface area, the surface concentration of volatile constituents, the surface temperature, and the partial pressures of volatile constituents immediately above the surface. If the heat input is raised above a certain level, the effect is not to increase the evaporation rate at constant temperature, but to raise the temperature of the liquid until at some higher level an increased rate of evaporation (and thus of latent heat absorption) again balances the heat input rate.? Many substances (including metals) have a very large intrinsic evaporation rate at quite low temperatures—far below their normal boiling points. However, at atmospheric pressure, the large numbers of atoms evaporated are almost completely deflected back into the liquid (or solid) surface by air molecules. Thus the back condensation rate is practically equal to the gross evaporation rate, and the net evaporation rate is practically zero. It can therefore be seen that an overall distillation rate depends not only upon the intrinsic evaporation rate, but also upon the ability of the volatile atoms to move away from the evaporating surface. This movement is facilitated by the provision of a condensing surface close by. Vacuum Distillation: The function of the vacuum above the evaporating surface is to remove foreign molecules, so that the chances of deflection of an evaporated atom back into its source are reduced. When the residual gas pressure is reduced so far that the evaporated atoms have a high probability of reaching a nearby condensing surface without suffering collision with a foreign molecule, the state of affairs is termed "molecular distillation." This process is practiced commercially today for the purification of numerous organic chemical products of high unit value, but not, to the writer's knowledge, for any metallurgical separation. When the degree of vacuum produced in a still is not sufficient to promote molecular distillation, then the evaporated molecules must diffuse through the

Jan 1, 1954