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By C. C. Clark, J. R. Mihalisin, K. G. Carroll

OBSERVATIONS made in this paper were for the purpose of exploring the anomalous behavior of a particular heat of Type 310 stainless steel. The alloy, of nominal composition 25 pct Cr, 20 pct Ni, was observed to form a grain boundary precipitate at exceedingly high rates. A sheet of this metal, 0.060 in. thick, after cooling in air from 2000°F showed the presence of the grain boundary material, whereas none was found after water-quenching from the same temperature. X-ray techniques were applied without success and, in view of the ex-

Jan 1, 1958

Seam gases are the most important atmos- phere contaminants in Australian collieries, their importance increasing with depth; C02 as well as CH4 may be important in intruded envir- onments. The generally high rank of the coal, with low moisture content, makes for abnormal dust production. The other contaminants are introduced and subject to better control, in- cluding products of spontaneous combustion. Due to market situations the generally lower rank and higher sulphur coals more prone to self heating are mined less. Future mining at greater depths should see greater problems with atmosphere contaminants.

Jan 1, 1983

By E. Sabah

A series of adsorption tests are carried out to understand the ability of cationic surfactants and metal ions to adsorb onto sepiolite. Adsorption tests conducted as a function of heat treatment reveal that sepiolite is rather conducive to the uptake of both organic and inorganic ions. An ion exchange mechanism between surfactant or metal cation and magnesium ion followed by chain-chain association is proposed to explain the incorporation of cationic surfactants into the structure of sepiolite.

Jan 1, 1998

By Goran Lande, Bernt Larsson, Dennis Clark

The effects of vibrations on close surroundings has been studied in Europe and the United States extensively in the past three to four years due to the ever increasing demands of environmental control. Therefore, "routine measurements" or "standard vibration consulting services" are being carried out by numerous firms with widely different qualifications.

Jan 1, 1983

By Heric Henrique Souza e Silva, Johne Jesus Mol Peixoto, Natalia Barros Barony, Itavahn Alves da Silva, Weslei Viana Gabriel, Carlos Antonio da Silva, Varadarajan Seshadri

In this work the circulation rates have been determined in a 1:7.5 scale physical model of RH reactor (Ruhrstal Heraeus) and using oil/water and oil/zinc chloride solution to simulate steel melt/slag in the prototype with the objective of evaluating the influence of density and viscosity on the entrainment of oil simulating slag. A technique based on strain gage bridge and particle image velocimetry was developed to assess the circulation rate, as the usual tracer method is not feasible due to the presence of chloride ions in ZnCl2. The critical velocity and critical diameter of oil drops for slag (oil) entrainment in water/oil and ZnCl2/oil systems were estimated using equations from the literature. Due to the difference in density, the ZnCl2/oil system, showed a critical velocity that is 28% higher than the silicone oil/water system while the maximum size of the entrained droplets was about 65% lower than that for water/oil system.

Mar 1, 2017

By W. W. Odell

Once it was believed that anthracite or coke were the only fuels generally available and suitable for the generation of water gas, particularly so when this gas was made in the generators of standard carburetted water-gas sets such as are commonly used in the manufacture of city gas. During the past 8 years, practice has changed considerably and it is now common to find gas plants operating without anthracite or coke and using bituminous coal in the generator. This change in fuel has appreciably increased the marketability and sales of certain coal producers' products; accordingly it is of interest to coal operators and others to know the reason for this change, the present trend in practice and the adaptability of various coals for generation of water gas. This paper briefly discusses these conditions and some of the factors relating thereto. Bituminous Coal not Ideal but Cheaper than Coke In spite of many changes which have been made in both process and generating apparatus for using bituminous coal as generator fuel more efficiently, in general it is not an ideal fuel for this purpose. It is supplanting coke because it costs less; it is so much cheaper per ton delivered at the gas works that water gas made therefrom costs less per unit-volume than that made from coke, even though the quantity of generator fuel consumed per therm (100,000 B. t. u.) of gas made is greater with coal. This is the reason why so many city gas plants, as well as others, are using bituminous coal instead of coke. Conditions Favoring Change from Coke to Coal The conditions which have made it possible and feasible, as well as economical, to supplant coke with coal may be summarized as follows: (1) Changes in methods of operating and alteration in generating apparatus; (2) lowering of the calorific standards for city gas, and (3) availability

Jan 1, 1927

By I. D. Shah

The Bureau of Mines investigated the sequence of principal chemical reactions taking place during the roasting of covellite (CuS). Practically all covellite is converted to digenite (Cul.SS) before oxidation to Cu20 begins. Part of the Cu2O is then converted to CuO, which in turn forms CuS04 through CuO?CuS04 as an intermediary. CuS04 and CuO'CuS04 decompose at 600° to 700° C to yield CuO and S03 (g) as final products. An overall mechanism is proposed for chemical reactions occurring at different interfaces of partially oxidized CuS pellets.

Jan 1, 1970

By Takeyasu Ito, Mayumi Someno, Kazuhiro Goto

SINCE the pioneering work by Kiukkola and Wagner,1 many experiments have been reported on solid electrochemistry at elevated temperatures. However, the studies have been confined to experiments under isothermal conditions. One may conceive many situations under nonisothermal conditions. With two different temperatures T1, and T2 at the two electrodes, the electromotive force, E of a Galvanic cell will be expressed by the following equation under a steady state heat transfer in solid electrolytes of zirconia-lime and thoria-lime. E = ^ $ l&-dGO2+a(T2-Ti) [1] where tO2- is the transference number of oxygen ions in the electrolyte, Go, is the chemical potential of oxygen, and a is the coefficient of the thermoelec-tromotive force due to the temperature difference. The objective of the present study was to evaluate the coefficient of the thermoelectromotive force for zirconia-lime and thoria-lime under isobaric condition. The physical meaning of this coefficient is out of the scope of the present communication. The experimental cell assembly is schematically shown in Fig. 1. The zirconia-lime electrolyte tube and thoria-lime electrolyte tube were 8.0 mm OD and 5.0 ID, from commercial sources with chemical analyses of 94.8 wt pct ZrO2, 3.85 pct CaO, 0.83 pct SiO2, 0.25 pct TiO2, and 0.05 pct Fe2O3; and 95.0 pct ThO2, 4.0 pct CaO and rare earth metal oxides, respectively. The specific gravity was 5.5 g per cu cm for zirconia-lime and 9.8 g per cu cm for thoria-lime. Original powder size before shaping and sintering the tube was several microns for both electrolytes. The distance separating the two electrodes was 4.0 or 5.0 cm. Platinum wire of 0.5 mm diam was used for the electrodes. The temperature gradient was controlled by heating one electrode with a small heating coil of nichrome wire. The temperatures at the two electrodes were measured with two calibrated Pt-13 pct Rh:Pt thermocouples, directly contacting the two platinum electrodes. The atmosphere was either air or pure oxygen. The partial pressure of oxygen in air was considered equal at the vicinities of the two electrodes, with negligibly small thermal segregation in the gas phase. The difference of the chemical potential of oxygen was controlled only by the temperature difference at the two electrodes and not by the oxygen pressure difference. The temperature ranges were 600" to 1200°C for zirconia-lime and 850" to 1200°C for thoria-lime electrolytes. Fig. 2 shows the relation of the measured electromotive force and the difference of the oxygen chemical potential at the two electrodes for zirconia-lime and thoria-lime electrolytes. The electromotive forces in the figure were measured by a *0.05 mv potentiometer. The chemical potential difference was calculated by the following equations.'

Jan 1, 1970

By Mohammed Sakr

The use of helical piles for permanent foundation applications has become a practical and feasible alternative to the traditional cast-in-place concrete or driven steel piles. Research and development, installation equipment and manufacturing improvements in the helical piling industry have led to this trend. Moreover helical piles are typically smaller in size and weigh less than traditional piles, and require relatively smaller equipment and therefore it is a cost effective option. The latter is a very attractive feature for foundations installed in remote sites across Alaska. This paper presents full-scale pile load test results of helical piles and driven steel pipe piles installed in a site located in Anchorage, Alaska. Four full-scale pile load tests were carried out including two axial compression and two uplift load tests. Both helical piles and driven steel pipe piles were installed and tested at the same site under similar conditions to provide a direct comparison. The results of the full-scale load tests indicate the superior performance of helical piles compared to driven steel pipe piles. This paper describes the pile installation and test setup, presents the test data, and discusses the results.

Jan 1, 2009

By H. B. Smith, B. Egererg

In a previous paper1 the authors dealt with the physical properties of cold-rolled and heat-treated Britannia metal of the approximate composition Sn, 91 per cent., Sb, 7 per cent. and Cu, 2 per cent. It was found that cold rolling to more than 50 per cent. reduction produced a continuous softening of the metal when measured by the Brinell machine, whereas the Shore instrument indicated increased hardness; that the strength of the material followed the Brinell hardness and that the metal therefore became weaker the more it was cold-rolled; and further, it was found that hardness and strength could be largely restored to the cold-rolled metal by "baking" for about one hour at any temperature between 200" and 450" F., the melting point. The higher the baking temperature, the more effective was the heat treatment as far as increased hardness was concerned. It seemed to be of little importance whether the metal was soaked or not at the baking temperature for a great length of time and the rate of cooling seemed to be immaterial. The present paper deals with the same alloy and more particularly with the resistance towards various forms of stress — tensile, bend and deep drawing. The metallography of Britannia metal has in part also been covered and an explanation attempted for the abnormal behavior of this alloy. Tensile and Bend Tests Two ingots 73/4 in. wide, 11 in. long and ¾ in. thick were cast from the same pot. One ingot was cold-rolled in one direction to a strip 0.241 in. thick, which furnished the tensile test specimens; the other ingot was rolled in the same way to 0.253 in. and furnished the specimens for the bend tests. The ingots were cast as described in the previous paper and cold-rolled in six passes.

Jan 1, 1930

By P Andersson, P Marklund

Evaluation of different techniques for bottom fill stabilisation showed that frozen fill was the most economical method. In order to test the method a full-scale field test was performed in the Rehnstr÷m mine. The test was instrumented with temperature gauges and extensometers. Before the field test, frozen fill was tested at the laboratory. The mechanical properties of the frozen fill were determined by uniaxial compression and creep tests. A deformation model for the frozen fill was set up. Calculation procedure for design of spacing between the freezing tubes, time for freezing and calculation of the necessary capacity of the refrigeration plant was developed. These procedures were calibrated against the field test. The results of these investigations allow the following conclusions: From a mechanical point of view, frozen fill has excellent properties as a structural member and it also has excellent properties to support itself and the fill above. Methods for the thermal and mechanical design of freeze stabilisation have been developed and found adequate. The need to place the freezing tubes several years in advance of the future sill pillar mining, requires careful long-term planning and accurate documentation.

Jan 1, 1998

By Euler De Souza, Jason Chew, Aldrich Philip Dirige

Sillmats are structural elements upon which the safety and economics of underfill mining or sill pillar recovery in stopes of moderate width with steeply dipping ore zones, depend. The traditional stability design of cemented sillmats appears to have developed from experience and from standard static physical model tests such as uniaxial and triaxial compression. Such standard static physical model testing approach arrives at some approximate parameters, normally used to describe or predict the behaviour of sillmats in analytical or numerical models. This approach offers inherent limitations and generally results in conservative designs. Centrifuge modeling studies are combined with numerical modeling in this paper to provide insights into sillmat strength behaviour. The results of both modeling techniques suggest that, in stopes with smooth rock wall conditions, sillmat failure is driven by the fill self-weight and has minimum dependency on the fill binder content. In stopes with rough rock wall conditions, however, the wall roughness contributes significantly to the stability of the sillmat during underfill mining. This study indicates that the stability of paste fill sillmats can be designed with confidence using centrifuge physical modeling in combination with numerical modeling.

Jan 1, 2001

By C. R. Stephan, N. B. Greninger, S. J. Luzik

The U.S. Bureau of Mines conducted explosion tests on various full-scale cementitious bulkheads used in abandoned mine areas to evaluate the ability of the bulkheads to withstand gas explosion over-pressures of 20 psig. Tests were performed on 120-ft2 solid-concrete-block seals of varying thicknesses and designs. Of the seven solid-concrete-block seals tested, only the standard-type seal, having a 16-in thickness, keyed at the floor and ribs, all joints mortared, wedged at the roof, and a center pilaster, maintained its integrity when subjected to a 20-psig pressure wave. After being subjected to repeated explosions, the standard seal only showed a small hairline crack and had an air leakage of 87 ft3/min at a pressure differential of 1 in H2O. Tests were performed on cementitious foam seals of varying thicknesses and compressive strengths. Explosion tests have shown that 200-psi strength, 4- and 8-ft-thick seals can withstand a 20-psig pressure wave. At a pressure differential of 1 in H20, no air leakage was detected through the 200-psi, 8-ft-thick foam seal.

Jan 1, 1991

By Britta Schoesser, Zdenek Zizka, Markus Thewes

"The support pressure of a slurry shield corresponds to the in situ earth and groundwater pressure to ensure the stability of the tunnel face. The support fluid (bentonite suspension) penetrates from the excavation chamber into the pore space and transfers the support pressure to the granular structure of the soil within this zone. At the same time, the cutting tools rotate periodically with the cutting wheel and remove the penetrated soil up to a certain cutting depth at the face. Shortly after the tool passing, the penetration process starts again. Both, the support pressure and the soil excavation, act in the same direction at the tunnel face, but they are subject to different cyclic intervals. This relationship between the time needed for the transient penetration process and the interval of the cyclic passage of the cutting tools at a local point at the face is examined and the impact onto the global face stability is discussed. INTRODUCTION Slurry shields are usually deployed for excavations in soft ground. The main application range is in non-cohesive soils (DAUB Recommendations 2010). In non-cohesive granular soils, the tunnel face stability is one of the key design issues. The slurry shields make use of pressurized bentonite suspension (slurry) to support the unstable tunnel face. To support the tunnel face effectively, the slurry pressure has not only to counter the groundwater pressure, but also has to be transferred into an effective stress to support the soil grains. In general, the pressure transfer can be achieved in two ways: (1) with a thin flexible membrane or (2) a penetration zone. The membrane (1), called filter cake, creates a thin impermeable layer from bentonite particles directly on the tunnel face, and enables a transformation of excess slurry pressure into effective stress. In case of penetration zone formation (2), the excess slurry pressure is transferred onto the soil skeleton along the entire penetration depth by shear stresses between slurry and soil grains. These theories, presently applied to assess the pressure transfer on the grains within slurry shield tunnelling, are originating from diaphragm wall technology, e.g. Müller-Kirchenbauer (1977), Kilchert and Karstedt (1984). They assume that the support pressure transfer mechanism is built-up instantaneously on the whole tunnel face and is not damaged or influenced by the interaction with excavation tools. These assumptions are valid for conditions during the excavation of diaphragm wall trenches whose bottom is excavated and the walls of the trench are supported. At the tunnel face of a slurry shield, the support suspension acts on the same area as the soil excavation. Hence, the conditions on the tunnel face are transient (time dependent) due to the time period needed for the penetration process of the slurry and the periodical damage of the pressure transfer mechanism by excavation tools (Fig. 1a)."

Jan 1, 2016

By C. R. Hopkins

"The petroleum refiners of the United States made rapid strides in fuel economy in 1928, when the calculated number of B. t. u. required to refine a barrel of crude petroleum was 637,000 as compared with 698,000 in 1927, a decline of 9 per cent. The major portion of this indicated increase in fuel efficiency was undoubtedly due to the gain in use of the pipe-still and the continuous process of refining as contrasted with the old batch method of distillation.,Almost without exception the new refineries are equipped with one or more pipe-stills, and many of the older plants are changing over to this type of equipment. The refineries of the Appalachian area are among the oldest and most conservative of the country, yet a number of them dismantled their old shell and cheese-box stills and installed pipe-stills in 1928.The more extensive use of the pipe-still was not the only way in which the refiners lowered their fuel requirements in 1928. The use of heat-exchangers, in which the heat from hot vapors to be condensed is used to heat the incoming cold oil, also increased in 1928, and in addition the refiners have kept abreast of the times in saving fuel through better insulation and improved burners.For the year 1928 the refiners burned as fuel the following: 46,400,000 barrels of-fuel oil; 3.362,000 short tons of coal; 114,950,000,000 cubic feet of natural gas; 77,313, 000,000 cubic feet of refinery or still gases; and 470,000 short tons of coke, in addition to a little electricity. This fuel was calculated to have produced a grand total of 582,156 billions of B. t. u., as compared with 578,784 billions B. t. u. in 1927.The total of 46,400,000 barrels of fuel oil burned represents an increase over 1927 of about 5,000,000 barrels, which made it about equal to the 1926 figure. Practically all of the refinery districts used more oil as fuel in 1928. The most important increase - over 2,000,000 barrels - occurred in the East Coast district, where greatly expanded throughput of foreign crude was instrumental in increasing fuel-oil production.The use of coal for fuel at refineries again registered a material decline, the total for 1928 of 3,362,000 short tons being 33 per cent below that of the previous year. The outstanding decrease in the use of coal in 1928 occurred in the East Coast district, where coal was probably replaced by oil. The use of coal for fuel at refineries in the States of Ohio, Pennsylvania, and West Virginia declined materially in 1928; the substitute used in the majority of cases was oil burned in pipe-stills."

Nov 1, 1929

By Ben E. Lindsly

The study of "bottom-hole samples follows in natural sequence the study of samples obtained under high pressures at the well heads of flowing wells. The principal object of this phase of gas-solubility research, started actively in January, 1930, was to gain a more accurate knowledge of the physical and chemical characteristics of the oil-gas mixtures that exist in natural reservoirs.. In possession of actual data regarding the condition of the oil; the quantity of gas liberated from solution upon dimunition of pressure; and the relative volumetric proportions of gas to oil at various pressures throughout the flow string in a well, it should be possible to predict, with a fair degree of accuracy, That physical changes these mixtures would undergo throughout the life of a pool. Such information not only is important in designing flow strings in flowing Tells but is important also in solving problems relating to pumping efficiency and the power required for pumping. Although certain fundamental data were obtained in the study of samples taken at the well head, "bottom-hole" samples are more representative of subsurface mixtures of oil and gas because they are obtained at reservoir temperatures, and before the oil has had the opportunity of intermingling with extraneous gas; that is, gas which either was not in solution originally, or which was liberated from solution at higher pressure, and later became mixed with the original undissolved gas.

Jan 1, 1933

By Stephen G. Hardcastle

Worldwide, metal mines are going deeper. For example in Canada there are six such mechanized mines planning production at 3000m (10,000?). Working at such depths challenges all aspects of mining including the provision of ventilation to supply an equitable working climate for personnel and machinery. This paper explores the overall challenges of supplying ventilation in Canada?s deepest mines and how the volumes required could be minimized. This is essential because it must be remembered that ventilation and refrigeration are not only costly items to supply, but the magnitude of their cost is also very sensitive to the volume supplied. For ventilation this is obvious because of the cubic relationship between volume and cost. In deep mines, the main function of ventilation is the removal of heat transferred from the strata and generated by the mining machinery, and the air volumes supplied are designed accordingly. The second consideration is the removal of other pollutants that could be harmful to humans such as diesel and explosive fumes. However, the need for ventilation at its present design levels could be reduced. This paper discusses the implications of such technologies as: teleremote mining and alternatives to diesel equipment on the magnitude of the volume supplied; ventilation-on-demand which recognizes ventilation as a costly and limited resource; plus other aspects, such as the benefits of controlled recirculation, local cooling, and heat rejection back to the strata to gain further advantage from new developments. Furthermore, this paper advances the need to be able to design ventilation systems more cost effectively and how such new advances as process simulators can be used in conjunction with ventilation simulators to explore the diverse options that could affect the air volumes required and provide more realistic economic data upon which to base design decisions.

May 1, 2003

By Nicholas J. Grant, Henry Epstein, John Chipman

FOR many years steel producers have been concerned with the presence of hydrogen in steel. Hydrogen dissolved in excess of its solid solubility at the melting point may cause bleeding and gross unsoundness in ingots and castings. In fully-killed steels the hydrogen content which results in these difficulties varies with the alloy content1 and may range from 6 to 12 ppm.* It is also recognized that of heat treatment diminishes rapidly as the size of the part to be treated increases. The time required to remove a specified fraction of the hydrogen present increases as the square of the diameter of the section, making the treatment of large- sizes impractical. In order to prevent bleeding and gross unsound-ness due to hydrogen, and in view of the inadequacy of corrective heat treatment alone to provide optimum properties when hydrogen is present in large sections, efforts to limit the hydrogen content must be taken while the steel is still liquid. The main subject of this paper is a discussion of the factors affecting the hydrogen content of liquid steel in acid and basic open hearth, and basic electric two-slag furnace processing. Literature Survey Because many of the results and observations reported in the literature have a direct bearing on the results obtained in the present research and form part of the basis for conclusions reached, a brief summary of the findings is necessary. Methods for experimental investigation of hydrogen in liquid steel are comparatively new. The first attempts to estimate the hydrogen content of the open hearth bath were by Kalling and Rudberg,6 who devised a method for collecting gases evolved from the boiling bath of a basic open hearth furnace. They found that the gas during the boil generally contained 2 to 3 pct H2. From this and Sieverts'

Jan 1, 1958

By N. S. Greensfelder

The firing of explosive charges by electricity dates back to 1745 when a Doctor Watson is said to have used an electric spark for igniting gunpowder. His method failed in practical application because, to ignite blasting powder, heat must be applied for a period longer than the duration of an electrostatic spark; Wheatstone found that this does not exceed 1/24000 sec. The usual result, therefore, of an electrical discharge in gunpowder is to scatter the grains, without igniting them. Benjamin Franklin partly overcame this difficulty by confining the powder and crushing grains that lay in the line of discharge. In 1822, after the primary cell had been discovered by Volta, Robert Hare, professor of chemistry at the University of Philadelphia, noticed the heating of a short piece of wire placed in the circuit of a voltaic battery. Later work by Oersted, Faraday, Wheatstone, and Henley resulted in the developmcnt of the magneto blasting machines. Fulminates of gold and silver are thought to have been discovcrcd by Cornelius Drebbel, about 1600. Pepys, in his diary for November 11, 1663, recounts a conversation with Doctor Allen, who told him about aurium fulminans "of which a grain ... put in a silver spoon and fired, will give a blow like a musquett and strike a hole through the silvel spoon downward, without the least force upward.'ll This fallacious belief that explosives act downwards only is still held by many who should know better. Fulminate of mercury was discovered by Howard in 1799. J. Shaw of Philadelphia is said to have invented a fulminate-of-mercury cap in 1814; his idea was later adopted by gunmakers in England and France. The principal advantages of mercury fulminate for use in detonators are the simplicity of exploding it and the great shock developed by its explosion.

Jan 1, 1923

By N. S. Greensfelder

The firing of explosive charges by electricity dates back to 1745 when a Doctor Watson is said to have used an electric spark for igniting gunpowder. His method failed in practical application because, to ignite blasting powder, heat must be applied for a period longer than the duration of an electrostatic spark; Wheatstone found that this does not exceed 1/24000 sec. The usual result, therefore, of an electrical discharge in gunpowder is to scatter the grains, without igniting them. Benjamin Franklin partly overcame this difficulty by confining the powder and crushing grains that lay in the line of discharge. In 1822, after the primary cell had been discovered by Volta, Robert Hare, professor of chemistry at the University of Philadelphia, noticed the heating of a short piece of wire placed in the circuit of a voltaic battery. Later work by Oersted, Faraday, Wheatstone, and Henley resulted in the developmcnt of the magneto blasting machines. Fulminates of gold and silver are thought to have been discovcrcd by Cornelius Drebbel, about 1600. Pepys, in his diary for November 11, 1663, recounts a conversation with Doctor Allen, who told him about aurium fulminans "of which a grain ... put in a silver spoon and fired, will give a blow like a musquett and strike a hole through the silvel spoon downward, without the least force upward.'ll This fallacious belief that explosives act downwards only is still held by many who should know better. Fulminate of mercury was discovered by Howard in 1799. J. Shaw of Philadelphia is said to have invented a fulminate-of-mercury cap in 1814; his idea was later adopted by gunmakers in England and France. The principal advantages of mercury fulminate for use in detonators are the simplicity of exploding it and the great shock developed by its explosion.

Jan 1, 1923