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By Jiang Feng, Zhang Libo, Peng Jinhui, Guo Zhanyong, Ju Shaohua, Lei Ting

The clean utilization of the residue containing chloride, CuCl residue, produced from zinc hydrometallurgy is very important for the recycle of valuable metals. And drying is the main process in recycling. In this study, response surface methodology was used to optimize operating conditions of the drying of CuCl residue in a convection oven and desirability function used as the methodology for the optimization. Optimization factors were air temperature (80–100°C), material thickness (10–25mm) and process time (80–120min) while investigated responses was final moisture content. The optimum conditions were found to be the temperature of 95.48°C with the material thickness of 13.47mm for the process time of 89.48 min. Under optimum conditions, the predicted moisture content of CuCl residue was 4.11% while the experimental date was 4.13%. The experimental value after process optimization was found to agree satisfactory with the predicted value. After drying, XRD was used to analyze the main phases of CuCl residue. The CuCl residue is made up of CuCl,Cu2O, ZnS and other compounds.

Jan 1, 2015

By J. R. Perumareddi, V. S. Sastri, M. Elboujdaini

It is well known that high strength steels used in aerospace industry, are generally susceptible to hydrogen embrittlement during surface treatment such as electroplating with zinc on cadmium. Hydrogen embrittlement reduces ductility and results in brittle fracture rather than failure by plastic deformation. Hydrogen embrittlement of high strength steels is mitigated by surface treatment such as plating with other metals. Data on the hydrogen contents of steels before and after surface treatment by hot extraction-thermal conductivity, secondary ion mass spectrometry (SIMS) and UV-visible spectroscopy along with the mechanism are presented.

Jan 1, 2006

By J. Mastoris

The growing environmental awareness and the need for providing social service to the community, urge the primary sector companies (such as mining) to find new solutions, by adjusting their operations with the special, local conditions and meeting everyday problems in practical ways. We hereby present a real case of re-design of an open pit, closed-bench type industrial minerals (clay) excavation, for the purpose of rehabilitation and utilisation as a water reservoir. The potential use of rainfall water was studied on the basis of covering the irrigation needs and improving the living standard of the neighbouring farmers and also as a project or recreational development of the area by shaping a wetland. The experience from the project progress and the reservoir use has been positive to date and the reclamation plan seems to have the acceptance of the local community.

Jan 1, 2002

This paper will examine some of the significant developments in the training field in Australia in the past decade and the application of these changes to the mining industry generally, and the coal sector specifically. Three major aspects will be examined:1. Competency - the use of Industry Competency Standards and how these can be used for achieving enterprise performance requirements2. Assessment - making judgements about an individual's competence, and using a rigorous assessment system as the basis for the "authorisation" system at a mine3. Evaluation - ways to evaluate the return on investment in training, and convincing CEO's/shareholders that your training dollar is being spent wisely.Before examining these issues, it is important to understand the drivers of change in the training systems in Australia, and the functions that Industry Training Advisory Bodies (ITABs) perform.

Jan 1, 1998

By Dae S. Young

A new probabilistic approach is introduced for slope stability analysis including adverse impact of blasting vibrations. The material strength within a slope area is randomized in this bi-variate joint probability analysis. To be a completely general engineering method, the new probabilistic approach employs the random variable transformation technique: the Hermite model of the Gaussian transformation function, which transforms the experimental histogram of strength values to the standard Gaussian variables. Because bi- normal joint probability is analyzed on the true probability region projected on the Gaussian transformed variable plane, it is an exact solution of slope stability based on the available sample data. Details of the probabilistic approach are given through a case study on an iron ore mine. The case study demonstrated that the probabilistic approach is effective and simple enough to be a routine engineering practice for slope analysis.

Jan 1, 1984

By James J. Norton, Lincoln R. Page

Effective methods for determining grade and reserves of pegmatites in advance of mining have been developed in recent years. When intensive work began on the economic geology of pegmatites during the early years of World War II, it was widely believed that grade and reserves could be estimated only in a most general way. The literature indicated that not all pegmatite deposits are unpredictable, but statements emphasizing unpredictability and irregularity seem to have been more widely accepted. Many standard references reflect the prevailing opinion that minerals are unsystematic in their occurrence in pegmatites. Pegmatites have been de- scribed as "notorious for their irregular structure," and minerals within pegmatites as "irregularly distributed," "irregularly disseminated,'' of "erratic occurrence," "proverbially erratic in distribution," "characterized by extreme irregularity in size and distribution of the essential minerals, and variety and proportion of the accessory minerals, and "spotty."

Apr 1, 1956

By Finn Ouchterlony

"Recently detailed fragmentation data from blasts fired with electronic delay detonators (EDDs) in the Red Dog mine in Alaska were presented. They include a comparison with pyrotechnic detonators fordifferent in-­-row delays in a standard pattern and EDDs in an expanded pattern. Fragmentation was measured on the belt after the primary crusher. The Rosin-­-Rammler function (RR, two parameters) was used to describe the crusher product. This was combined with the JK SimMet crusher model and the CZM blast model (Crushed Zone Model, three to five parameters) to estimate a reasonable crusher feed (muck pile fragmentation or run of mine, ROM) for each fitted product. In this way the effect of delay timing and electronic detonators on the median fragment size x50 and uniformity coefficient n for both crusher product and the blasted rock was determined. "

Jan 1, 2012

By James Arthur

In deep coal mining the support of the underground roadway is fundamental and without knowledge of the mechanics of ground control a mine is unlikely to be operating safely and efficiently. It is therefore important for the support system to be designed sat¬isfactorily for the size of the excavation required and to do so an understanding of the behaviour of the surrounding strata is re¬quired. Over the last 15 years there has been a major change in the industry and the support systems adopted. The industry has been privatised, legislation has been updated, a comprehensive research programme has been carried out and guidance docu¬ments produced. The paper will show how privatisation has not allowed support standards to deteriorate, highlight research, the legislation and guidance documents updated and how this has led to a reduction in accidents and falls of ground..

Jan 1, 2002

By W. L. Brown

"The Normetal mine is about 7 miles east of the Ontario-Quebec boundary, and 13 miles north of the town of Dupuy on the Canadian National railway. The mine workings are largely on lots 44 and 45 in the south half of range 10, Desmeloizes township.The surface outcrop is reported to have been discovered by a trapper previous to 1925, but the details are obscure. The property was originally owned by the Canadian Exploration Company of Amos, Quebec, and was later transferred to Abana Mines, Limited. The latter Company carried out underground work from two shafts down to the 550-foot level. The property was acquired by Normetal Mining Corporation in 1931 and was reopened in 1933, when development work was carried down to the 800-foot level. The mine was closed down in 1935 because metal prices did not justify production at that time. It was reopened early in 1937 and milling commenced in September of that year. To the end of 1945, a total of 1,497,- 169 tons of ore was milled from which was produced 184,533 tons of copper concentrates containing 84,738,368 lb. copper, 2,744,100 oz. silver, 26,230 oz. gold, and 153,524 tons of zinc concentrates containing 163,752,433 lb . zinc."

Jan 1, 1954

By C. V. Davis

In the lnvestlg::ìt1on of mAthods for aSS8.7ing platin",. conducted by the Bureau ot MinAs, reoent experiments have d~velopad tha~ with ce..tain orei, especially when thr, quantity Of platinum 1s eonlidarablfl, nit'!le acid w111 not etfßct a iepard-Han of platinum and pa11adium. 'lhe following m;lthod has been found to be accurate and to reiu1 t in a complete S''lun''ation of' th~3:l metals. It is therefo 1" '!eeommei:ed that 1 t ba followed rath::r- than the method of separation with nitrio acid, givèn in Technical Pape'! 270.* At line 22, pagi 14, of that paper, bAglnnlng with ~tarm th,~ metals '.'ith dilute¡ nitrio acid," strikE out the rest of the paragraph, and substttutt~ the pro_t cedure g1 ven below. ?lunder and Thuringer.. have developed mnt¡iods for th"i sflparation of palladium from all the platinum metals exoept platinum bj m ,ans of dlmethy- 19lyoxlme. They state that the~ is no action for several hours if an excess of dimeth¡lglyoxime is added to an aqueous solution of ohloroplatinic acid in the cold, alio that only on boiling is the platinum pTecipi ated ¡~d than only PST't of the platinum i srenoved from the sUut1on. They found that palladium 1s p~ecipi tated quati tat! vely in the oold as (CaH 4N40 Pd) which is insoluble tn water, dilute hydroohlorio acid, dilute acetIc aofd or in 50~ ethyl alcbhol. All of their pT'90ipi tations we~p Carl". ied out ~hile the solutions were being heated. This caused a pal"tia~recipltation of the platinum along wi th the

May 1, 1922

By H. R. Pierce

Bureau of Mines engineers end others have endeavored to deter-nine a fundamental method for gauging the capacity of gas wells to deliver gas under different pressure conditions. Their studies show that for accurate gauging two factors must be determined: (1) The actual pressures at the face of the sand in the well (usually referred to as "at the sand"), acid (2) the relation between such pressures and the rates. of flow of c as through the sand. This paper, the first of a series, describes a method of attacking the problem of determining the actual pressures at the sand by means of observations of pressures and volumes at the well head.

Jan 1, 1929

By Yves Fouquet

Recent exploration demonstrates that hydrothermal systems related to upper mantle ultramafic outcrops are common in the modern ocean. Most sites are located on slow spreading ridges with a low magmatic budget. Volcanogenic Massive Sulfide (VMS) deposits, associated with basalt, along the Mid Atlantic Ridge (MAR) are volcanically controlled near the topographic highs at the center of the segments. Three preferential settings are identified for ultramafic sulfide mineralization: 1) Off axis, on rift valley walls, near the amagmatic ends of the segments; 2) Non-transform offsets and 3) Ultramafic dome structures at the ridge transform fault intersection. The upper surface of these domes is often interpreted as a detachment fault. Three processes are considered for driving hydrothermal cells in ultramafic rocks: 1) regional heat flow at the ridge axis 2) Cooling of a deep gabbroic intrusion and 3) exothermic heat produced during serpentinisation. Along the Mid Atlantic Ridge, four types of ultramafic hydrothermal mineralization are observed: 1) High temperature (>350°C) sulfide mineralization related to low pH fluids, (ex. The Logachev field at 14°45? N and the Rainbow field at 36°14 N); 2) Medium temperature carbonate chimneys (<100°C) related to high pH fluids (ex. The Lost City site at 30°N); 3) Low temperature diffuse venting associated with extremely high methane discharge and pervasive alteration and silicification of both volcanic and ultramafic rocks (ex : The Saldanha field at 36°34 N); 4) Stockwork mineralization and quartz veins with sulfides related to gabbroic intrusions within ultramafic rocks (15°N). When compared to mineralization in a basaltic environment, sulfide deposits are enriched in copper, zinc and specific elements related to an ultramafic rock source such as Ni and Co. They are also significantly enriched in gold which, unlike in basaltic environments, has a bimodal occurrence both in low temperature Zn-rich assemblages and in high temperature Cu-rich mineral assemblages. The Cu-Zn-Co-Au deposits along the Mid Atlantic Ridge seem to be more common than on land where few similar VMS deposits are known. We consider that ultramafic VMS deposits on slow spreading ridges constitute a specific marine type of mineralization that is less easily than back arc deposits, incorporated into the continent during obduction processes.

Jan 1, 2004

By John Goodell

CIVIL engineers seem to number in their ranks more advocates of licensing than are found among the practitioners of other branches of the pro-fession. Licensing was not originated by civil engineers but it was forced upon them in two ways. In the first place, the civil engineering profession has hangers-on like every other profession. The first legislative result of their imperfect accomplishments with which I am familiar occurred in the far West. It was found that early irrigation works were so badly planned in some cases that not only were water rights made very uncertain but considerable sums were invested in structures and ditches which proved inadequate and occasionally complete failures. Water was too valuable to be wasted in that way and money too hard to obtain. In those sections, therefore, laws were passed many years ago which made it obligatory for the design of irrigation works and other structures utilizing water to be made by engineers who had satisfied a board of examiners that they possessed the technical qualifications to plan such works properly. The basic thought on which such laws rest is the same as that on which laws governing the licensing of boiler operators rest, namely, the safety and welfare of the public. While boiler explosions still occur and irrigation works are built which are not wholly satis-factory, these laws have helped the, public, it is gener-ally agreed.

Jan 4, 1922

By P. S. Kotva

Dislocation substructures in superalloy matrices of varyzng co)npositions have been studied. In general, it has been found that the alloys can be classified into &apos;&apos;high", &apos;&apos;medium", and "low" stacking fault energy classes based on the type of dislocation substructure observed in the matrix and that the substructure can be correlated to the stacking fault energy. The effect of different types of dislocation substructure and dislocation reactions on the intragranulur precipitation of carbide phases has been studied. In a Ni-Cv-Mo-Fe matrix, precipitation of MC carbides in association with stacking faults has been observed. In most superalloys, solid-solution strengthening and precipitation hardening are the chief mechanisms employed to achieve strength. The latter contribution to strength is usually achieved by the precipitation of / in certain wrought alloys. Insufficient attention has been given to the problem of obtaining strength in su-peralloys by controlling precipitation of carbides on imperfections within the matrix. The present work was undertaken to investigate the dislocation substructure in various superalloy matrices, to study the effect of such substructure on subsequent precipitation of carbides in the matrix, and to investigate whether certain modes of precipitation of carbide phases found in austenitic stainless steels2"4&apos;6 would occur in nickel-base alloy matrices with dislocation substructures of the same type as those found in austenitic steels. 1) EXPERIMENTAL TECHNIQUES Five-pound heats of the various alloy compositions reported here were vacuum-cast. The ingots were given light deformation by rolling to break up the as-cast structure and then homogenized for 24 hr. HASTELLOY alloy X (nominal composition: Ni-2OCr-17Fe-8Mo-0.05C) was homogenized at 2150°F and In-cone1 625 (nominal composition: Ni-20Cr-5Fe-8Mo-3.5Cb-0.05C) was homogenized at 2280°F. Fabrication of 0.004-in. sheet was achieved by cold rolling with intermediate annealing treatments being carried out at the same temperature as those used for homogeniza-tion. Each solution anneal was followed by quenching. The aim of this procedure was to redissolve as much of the primary carbide phase as possible. Samples of the 0.004-in. sheet were cut and encapsulated in quartz capsules and then heat-treated in the tube furnaces. Thin foils were prepared using an ethanol-10 pct perchloric acid bath at 32°F and at a voltage of 22 v. A "window" technique was employed. Observations were made on a JEM-7 electron microscope operating at 100 kv. 2) EXPERIMENTAL RESULTS a) Types of Dislocation Substructure. Fig. 1 shows a schematic correlation between stacking fault energy, SFE, and the type of dislocation substructure observed in various matrices of nickel- and cobalt-base alloys. A precise quantitative determination of stacking fault energy is not implied in the figure but the correlation between stacking fault energy and the type of dislocation substructure obtained allows alloys to be divided into three classes in analogy with the classification employed by Swann and ~uttin~&apos; for binary alloys of copper. Class I alloys are associated with a "high" SFE and show a cellular substructure of dislocations as typified by the micrograph of a thin foil of pure nickel deformed 4 pct at room temperature in Fig. 2. With decreasing SFE the tendency toward cell formation is lessened and dislocations tend to be arranged in coplanar groupings. Examples of this class of alloys with "medium" SFE are provided by the mi-crostructure of solution-heat-treated, quenched, and deformed thin foils of HASTELLOY alloy X, "Waspaloy" (prior to any aging), and Inconel 625. Fig. 3 shows a thin-foil micrograph of an alloy of Inconel 625 composition, solution-heat-treated, quenched, and deformed 5 pct at room temperatures. No evidence of any cell structure can be obtained in materials of "medium" stacking fault energy, Fig. 3, even after severe deformation. The stacking fault energy of the alloy shown in Fig. 3 is, however, not low enough to make the dissociation of dislocations visually obvious. As stacking fault energy decreases further, with successive addition of solute in the matrix, there is an increased tendency toward dissociation of dislocations and cross slip becomes progressively more difficult. Eventually, when the stacking fault energy is "low" enough, complete dissociation of dislocations is seen to occur as shown in Figs.

Jan 1, 1969

By Egil Krystad, Merete Tangstad, Kai Tang, Gabriella Trenell

"A new UMG-Si refining concept has been proposed in this paper. Liquid Si and another liquid metal phase (Me) were separated by the molten slag spontaneously based on their different physicochemical properties. Two metal/slag distribution reactions are able to occur in the system simultaneously. Experimental investigation on the B and P distribution equilibria among Si/slag/Me was carried out in the graphite resistance furnace under the inert atmosphere. The B and P doped silicon was in equilibrium with either the SiO2-CaO or SiO2-CaO-l0%CaF2 slags at 1600 and 1650°C, respectively. The pure Fe and Cu metals were used in order to ""capture"" B and P in the slag phases. B and P in samples were determined by the ICP-MS. B and P distribution coefficients for the Si/slag/Me equilibria were compared with the theoretical calculations. The possible kinetic barriers for the Si/slag/Me three-layer equilibria have been analyzed. The metal contaminations in the three-layer equilibria were also examined. The present study provides a new approach for the refining of MG-Si.IntroductionMost of the impurities in the metallurgical silicon (MG-Si) are rather ""dilute'', ranging from few to several thousand ppms. However, the target impurity levels for upgrade metallurgical silicon (UMG-Si) feedstock are often far below the level of ppm. In such extreme case, the conventional refining technologies face the great technical challenges. B removal by slagging has already been implemented industrially. Removal of Pis frequently carried out by the vacuum distillation. The separating treatments for B and P removals lead to increase refining cost, total CO2 emission and longer pay-back time of solar cell module.It is well known that the phosphate capacities of slags in equilibrium with liquid silicon are extremely lower. However, if we introduce another phase that possesses high ""phosphor capacity"" into the Si/slag system, one would expect to continuously remove P from Si through molten slag to the new ""phosphor capturer"". The so-called three-layer refming concept is thus proposed in the present study. Liquid Si and another liquid phase (Me) are separated by the molten slag spontaneously based on their different physicochemical properties. Two metal/slag distribution reactions are able to occur in the system simultaneously."

Jan 1, 2013

By J. H. Baek, D. W. Lee, B. K. Kim

Nanostructured Cu-Al203 composite powders were synthesized by thermochemical process for an electrode application. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from copper and aluminum nitrates, 2) heat treatments to evaporate volatile components in the precursor powder and synthesis of nanostructured CuO+Al2O3, and 3) CuO reduction by hydrogen into Cu. The suggested procedures stimulated the formation of the gamma-Al2O3. The mean particle size of the final composite powders was 20nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/Al2O3 composite by the conventional internal oxidation process.

Jan 1, 2004

By R. C. Urquhart, W. P. Channon, D. D. Howat

Discussion: The mode of current transfer between electrode and slag in the submBerged-arc furnace by w. P. CHANNON, R. C. URQUHART, and D. D. HOWAT J. MEINTJES I have read the paper with much interest, and I should like to make a few observations. (I) The experimental work deals with resistance heating by an electrode immersed in a slag... AUTHORS&apos; REPLY We thank Mr Meintjes for his critical analysis and helpful comments arising out of his study of our paper. Possibly we should emphasize at the outset that our experiments all related to the conditions in which the lower portion of the electrode was immersed in molten slag. We believe, however,

Jan 12, 1974

Organization Place Date 1913 Mining and Metallurgical Society of America New York, N. Y. Jan. 8 American Institute of Electrical Engineers New York, N. Y. Jan. 11 American Society of Civil Engineers New York, N. Y. Jan. 22-25 American Society of Heating and Ventilating Engineers : New York, N. Y. Jan. 22-25 American Institute of Mining Engineers New York, N. Y. Feb. 18-21 National Society for Promotion of Industrial Educa- tion New York, N. Y. Feb.. American Institute of Architects Washington, D. C. April American Iron and Steel Institute New York, N. Y. May New York Electrical Society New York, N. Y. June National Association of Stationary Engineers Cincinnati, 0. Sept. American Chemical Society Cleveland, 0. Sept.

Jan 1, 1918

By N. Thorp, S. J. Bluhm

It has long been recognized that the provision of an acceptable thermal environment minimizes the danger and the adverse effect of heat stress, which is directly linked to decreased productivity, increased accident rates, and excessive physiological strain in workmen. Refrigeration in one form or another helps to provide this acceptable thermal environment. This paper outlines the problems encountered in a working area, and the steps taken to alleviate environmental conditions in some stopes with the introduction of selective cooling employing small water-chilling units in conjunction with specially designed stope coolers. Performance figures are given for plant and stope coolers, and the effectiveness of the system is assessed from an evaluation of the improvement achieved in the environmental conditions.

Jan 1, 1986

By Robinson BW, Walker RK

Using a new highly stable automated electron microprobe analyser, detection limits for gold in arsenopyrite have been improved. Using the AuLA emission tine at 40kV and 500nA, a limit of approximately 10gpt is attained in 10- lSmins. Some unusual features of the background need to be taken into account. Several ores containing different levels of gold in arsenopyrite have been examined, and it has been shown that gold is not evenly distributed between grains (some may contain more than 1%, invisible optically), and that the grains containing gold are often zoned. Gold may be released from the arsenopy rite by weathering or by heating in an inert or slightly oxidising atmosphere.

Jan 1, 1989