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An evaluation was made of the wear and performance characteristics of liter bars, and the cost-life effectiveness of backing materials for rotary-mil liners. In a large run-of-mine mil in which the liter bars were mounted on grid liners of austenitic manganese steel (AMS), the liners had an average life that was five to six times that of equivalent unprotected liners. For a single mil, this is equivalent to annual savings in the cost of materials of up to R320 000, and to a downtime of 100 hours. Of the five materials tested in a large pebble mil grinding quartzitic ore, AMS grids and 'white iron' blocks performed best on a cost-life basis, with possibly improved performance from a real white cast iron. (The 'white iron' was shown by microstructural analysis to contain flake raphite and pearlite, being in reality a grey cast iron.) The high-chromium white iron had by far the longest predicted life, with mild steel a surprising second. Rubber was shown to last well in this type of mil. The wear rates of liners change during their lifetimes. The protective effect of liter bars was clearly illustrated by the reduction of over 40 per cent in the wear rates of the liners when the lifter bars were renewed to a height of 80 mm from a fully worn height of 35 mm.

Jan 1, 1991

Capital, as represented by mineral resources, is being exhausted rapidly without possibility of identical replacement. The public must be discouraged from thinking-why worry about the bank balance so long as there are plenty of blank checks? Instead of each man, woman, and child being owners of a mineral capital of $89,000 as former Secretary Ickes once stated, they are really the guardians of a mineral reserve which, when harvested, cannot be reproduced. The proper use of this material is the basis of modern civilization and military power. The best American institutions cannot be maintained or transmitted to our children unless this trust is guarded. It is unfortunate that more attention has not been focused on the fact that this country is headed for a have-not status in the family of great nations if some- thing is not done to preserve its mineral heritage. It is the privilege of the United States now to champion and implement democracy because it is industrialized and can get at its raw materials. A high price is being paid every day in mineral depletion for the privilege. No one can eat his cake and have it too. The United States still must face world-wide economic competition and, perhaps, World War III. In the final analysis all wealth comes from the ground, whether plant, animal, or mineral. Value is in-

Jan 1, 1950

By Gerhard Derge

A SERIES of studies of the corrosion of tin is under way in the Metals Research Laboratory at the Carnegie Institute of Technology. The complete program includes examination of the corrosion properties of high-purity tin and the changes produced in these properties by the addition of varying amounts of alloying elements. Other studies of this subject have been made recently under the sponsorship of the Inter-national Tin Research and Development Council, but these researches have been confined largely to the weakly acid environments commonly encountered in the canning industry.1 There is little information avail-able regarding the corrosion of tin under alkaline conditions, but such data would be of value, for a large amount of the metal is used under such conditions. The potential measurements to be described were made because they seemed to offer the most rapid method for obtaining a general view of the conditions to be encountered in such service. These experiments will also serve to establish a technique that will be of value in further studies. It must be emphasized that the results reported are those of controlled laboratory experiments and that the conclusions drawn cannot yet be applied to service conditions; rather, they point to the directions in which, more exhaustive experimental work may be clone to best advantage.

Jan 1, 1938

By Gerhard Sauer, Heimo Gold

The main advantage of the New Austrian Tunneling Method over conventional drill and blast techniques, TBMs and shields is its outstanding flexibility. Many different support concepts help to cope with all but the most adverse conditions. A considerable variety of unique additional support measurements provide a functional tool when dealing with particularly difficult conditions or restricting requirements. The resulting adaptability of NATM with respect to geometric and geologic changes is a cornerstone to providing an economic design and to a safe and unhindered execution of the tunnel work. To take best advantage of this flexibility and to emphasize its cost-saving capacity, NATM explicitly extends the design period into the construction phase. In accordance with corresponding ground classes or other anticipated conditions, a number of basic support categories and an array of additional support measurements are established during the actual design phase. The decision for applying a particular support category at a specific location and for necessary additions to the given support scheme, however, is regularly made on site after each advance, and is determined by the key persons involved in the construction. Contract documents must reflect this approach to facilitate the execution of the work and to curtail construction costs. Biased distributions of risks, however, can adversely effect the envisioned benefits. Consequently, the respective responsibilities of engineer, contractor, and client need to be redefined.

Jan 1, 1989

A formalised approach to risk management has been regulated in the United Kingdom (UK) since the Construction (Design and Management) Regulations 1994 (CDM) came into force in 1995. These regulations have recently been revised in 2007. In response to a series of significant claims around the world the UK insurance industry published a code of practice for risk management of tunnels in 2003, and that was followed by an international version in 2006. Probably one of the main contributions of this new approach is the recognition that health and safety risks can best be addressed early in the process, initially by the owner and then by the designers. One of the aims is to achieve elimination of risks by good design. The advantage of a risk-based approach to tunnel design is that all risks are considered explicitly, and any residual risks in the design are communicated clearly to the construction team. This paper looks at the implementation of this formalised approach to risk management with reference to the A3 Hindhead Project. The design has been undertaken in accordance with the requirements of the CDM regulations, and also in compliance with the Joint Code of Practice for Risk Management of Tunnel Works in the UK. An outline of the risk-based design process used is provided, including examples.

Jan 1, 2008

By Henry Howland

INTRODUCTION DURING the last decade no topic has created more interest or received more thought among blast-furnace men than colic. One reason for this is, undoubtedly, the remarkable increase in the use of byproduct coke. Formerly our coke was made at a distance from the furnaces and by a distinct organization. There was little cooperation or development possible under these conditions. Today the situation is greatly changed. Much of our coke is made by the organization operating the furnaces and the coke oven is operated with the primary object of obtaining the best results in the blast furnace. The effect of changing the method of coke manufacture, even in some minor detail, is often felt almost immediately at the blast furnace. There naturally results one of the most valuable assets of the byproduct coke oven, -i.e., the possibility of increased blast-furnace efficiency clue to close observance and correct operation of the ovens. The results are evident, but it often is difficult correctly to account for them. In attacking the solution of a problem of as much importance as why one coke is better than another, there are facts which should be kept clearly in mind The author hopes, in this paper, to bring out some points relative to the use of carbon in the blast furnace which will be of value in solving this question.

Jan 3, 1916

By C. A. Hansen

Page Introduction............................206 Power Characteristics in Zinc Sulfate Electrolysis........... 207 Current Efficiency......................... 207 Corrosion Rates..........................216 Voltage Required by the Zinc Cell..................219 Power Requirements of the Zinc Cell ................221 Impurities in Zinc Electrolyte.....................222 Non-cumulative Impurities.....................223 Cumulative Impurities ....................226 Impurities in General........................228 Temperature and the Stability of the Zinc Cell..............229 Practical Expedients for Control of the Zinc Cell...........234 Acknowledgments...........................234 Appendix................................235 Discussion...................:.......... - 236 Introduction It has been the experience of the writer, during some five years' work with electrolytic zinc, that the zinc cell is perhaps more sensitive to impurities in the electrolyte than the analytical methods as yet developed for the chemical identification and determination of these impurities; but that, when proper purification methods have been applied to a given solution, the behavior of the cell is quite independent of the original sources from which the zinc sulfate has been derived. It has also appeared that the behavior of the zinc cell is the best and surest check on the correctness and thoroughness of the purification methods used, because it indicates the presence of both current impurities and cumulative impurities derived from the leaching of the ore; it also indicates whether these impurities are current or cumulative, at least in so far as they are of serious importance commercially.

Jan 1, 1919

Following the preparation of tantalum oxide and carbide (1) an investigation of the details relating to the production of tantalum metal powder was planned. From the literature (2) it was evident that tantalum could be produced either by reduction of potassium tantalum fluoride with an alkali metal or by electrolysis of a fused salt mixture containing a tantalum compound. The latter method appeared to be the more suitable and, as there was considerable divergence of opinion in the literature as to the nature of the reactions involved, it was decided to study the electrolytic process. The ultimate aim in any case was to produce tantalum pOWder for use in an investigation of the problems relating to the preparation of consolidated tantalum.FACTORS GOVERNING ELECTROLYSISAfter a few preliminary exploratory electrolyses several factors which needed amplification were revealed. These will be mentioned before the details of the electrolysis experiments are given.COMPOSITION OF THE BATHWithout the knowledge gained in the preliminary experiments it would be thought that the best material for the bath would be that one which underwent electrolytic decomposition. Consider what at first appeared the most likely - namely - potassium tantalum fluoride. The melting point of K2TaF7 was determined to be 630°C with volatilization and decomposition taking place at that temperature so that it would not have been very satisfactory.

Jan 1, 1946

By Mohammad Ranjbar Hamghavandi, Mohammad Ranjbar, Zahra Manafi, Mohammad Hassan Fazaelipoor, Mahin Schaffie

The present study introduces a new approach to understand the copper dissolution rate and to find an adapted mathematical statement for particle shrinkage rate in a batch bioleaching system. Four size classes of a chalcopyrite concentrate, namely [D1 : (−54 + 44)μm, D2 : (−44 + 38)μm, D3 : (−38 + 25)μm and D4 : (−25)μm], were used in the batch bioleaching tests by applying a mixed culture of moderately thermophilic microorganisms. The pulp density and temperature were 8 (%w/v) and 50 °C, respectively. Findings delineated that the bioleaching time can be divided into two specific time intervals: first, the surface reactions were the prevailing controlling step; second, the prevailing mechanism was diffusion through the product layer, whereas the overall rate of the process may be related to both through a Q factor using a mixed model. A mathematical model was developed based on particle size distribution (PSD) and a kinetic model. Experimental validation of the mixed model was accomplished by the representative sample with d80 = 54 microns. Results showed that the PSD of the specific sample was in good agreement with Rosin–Rammler function. Besides, the simulation result of the conversion fraction had the best conformity with the experimental data (with a maximum error of approximately 7%). This paper should be considered as an initial part of a larger, global model for chalcopyrite concentrate bioleaching.

By L. A. Neumeier

The Bureau of Mines evaluated the properties and anisotropy in properties of rolled Zn-Ti and Zn-1.0 wt pct Cu-Ti alloys containing up to 0.36 wt pct Ti. Finish rolling was at varied temperatures to total reductions as high as 92 pct. Alloy properties are very sensitive to various combinations of composition, rolling temperature, and reduction. Properly rolled Zn-1.0 Cu-Ti alloys are superior in strength to Zn-Ti alloys. Conditions are described that lead to best tensile properties. Creep resistance for Zn-Ti alloys decreases with increased rolling temperature when finish rolled to 92-pct total reduction: but not when finish rolled to 33- or 67-pct reduction. Creep resistance for 7n-1.0 Cu-Ti alloys improves with increased rolling temperature to about 480° F. Heavily cold-rolled Zn-1.0 Cu-Ti alloys have fine grain sizes and poor hardness, tensile, and creep properties, but high ductility. Thermal expansivity is markedly affected by the copper addition. Data show the anisotropy of tensile, creep, and thermal expansivity properties. Large idiomorphic crystallites of TiZn15 appear in both Zn-Ti and Zn-Cu-Ti alloys when more than about 0.2 pct Ti is present. A new Zn-Cu-Ti intermediate phase was also identified. Empirical equations are presented relating creep rates with major process variables.

Jan 1, 1971

By Lynn B. Hales

Everywhere you turn today there are articles on artificial intelligence and the rapid emergence of expert systems. Expert systems form a class of software that has developed as a result of the large research effort to develop computers and software that think intelligently. By definition, an expert system is a computer program that contains the knowledge component of an expert skill, can offer intelligent advice and justify its line of reasoning. Expert systems can advise people on what actions to take and when, assist in the diagnosis of the physical condition of a human patient or piece of equipment, or even take actions without human guidance, as in process control applications. Expert systems can also explain the line of reasoning behind a particular piece of advice or query for information from the user. Expert systems can be used as advisors to newcomers in any field in which mastery is attained by many years of experience. They often can provide expertise more uniformly and rapidly than human experts. Expert systems can also provide a means of documenting expert knowledge and procedures and provide a common repository for a changing knowledge base. The expert system can represent the best expertise available, thought out in the absence of pressure situations. Each of these attributes or characteristics should be helpful in improving typical concentrator control systems.

Jan 1, 1987

By N. H. Emmons

THE work of a consulting engineer or manager, when controlling mining-operations, requires that he have all the information concerning the mine in as concise a form as possible, and as the ore-reserves and their depletion and enlargement are the vital points to be studied, it is well to have them kept up to date and in some convenient form. The present paper describes a method adopted by me, which shows in a very clear manner the ore-reserves in a mine. The case illustrated is that of a vein near enough to the vertical for the vertical elevation of the mine to be the main working-map. A flat ore-body would be represented on a similar plat, but instead of the horizontal thickness of the vein being shown in the circles, the vertical thickness would be inserted. Fig. 1 represents an ideal longitudinal elevation of a mine, plotted in the ordinary way, using 100-ft. blocks and section-lines. In a mine where the block-numbers are posted by the engineer underground, the system of keeping the ore-tonnages extracted from the different blocks is easily maintained, and the actual tonnages of ore extracted can be kept so that the surveyor can have a check on his estimate from time to time. The ore-reserve sheet, Fig. 2, should be the same size as the map it is to accompany. Each square is used for the description of the ore-reserve in the block it corresponds to on the elevation. Where the section-lines cross the levels a circle is drawn, in which are written the widths of ore at that point, these widths being used in the calculations of each block cornering in the circle. It has been found convenient to show the figures in black in the lower half of the circle when the actual widths of ore are known, and when it is necessary to make up the figures of probable ore, as at the time of making

Jun 1, 1912

By Mark Van Dyke, Gamal Rashed, Khaled Mohamed, Timothy Barton, Morgan Sears

"The unconfined compressive strength (UCS) of coal is an important parameter that controls the stability of coal ribs in underground mines. Estimation of the UCS of coal units composing the rib is required for conducting the rib stability assessment technique. This technique requires conducting large numbers of conventional UCS tests in a laboratory, which are expensive and time consuming. The research work outlined in this paper examines the use of indirect strength estimation methods—the point load test (PLT) and the in-situ Schmidt hammer test (ISHT)—for evaluating the intact strength of coal. The conventional UCS test was conducted on 80 coal specimens from 10 different coal seams for eastern coals. For each coal seam, the PLT and the ISHT were compared with the UCS test results to establish a correlation between the strength indices from the PLT or ISHT and the UCS. Moreover, to simplify the estimation of the UCS, a correlation between the megascopic coal lithotype and UCS was established.INTRODUCTIONBased on Mine Safety and Health Administration (MSHA) reports, rib failures have resulted in 17 fatalities, representing 52% of the ground-fall fatalities in underground coal mines in the United States over the past decade (MSHA, 2018). In an attempt to control rib failures in underground coal mines, the National Institute for Occupational Safety and Health (NIOSH) is working on developing a coal rib stability rating technique to provide a quantitative means to characterize the stability of coal ribs and to provide guidelines for early selections of rib support. The unconfined compressive strength (UCS) of coal units composing the ribs is one of the key input parameters required to estimate coal rib stability. The UCS of coal is an important parameter that controls the resistance of coal ribs to fracturing and slabbing. Direct determination of the UCS is time-consuming and expensive. Moreover, the UCS may be limited to testing only the strong coal samples since the weak or highly cleated samples might not survive the transportation and the preparation process (cutting and grinding). Therefore, alternative methods have been tested to indirectly find the intact strength of coal, such as the point load test (PLT) and the in-situ Schmidt hammer test (ISHT). The acronym ISHT refers to Schmidt hammer tests that were conducted in-situ on coal pillar ribs, while the acronym SHT refers to tests that were conducted on small scale blocks of coal."

Jan 1, 2018

By M. L. Holzworth, Philip R. Sperry, Paul A. Beck

INTRODUCTION THE basic work of Z. Jeffries1,2,3 has long ago established the main features of grain growth in the presence of a dispersed second phase. Working with sintered specimens of initially fine grained tungsten, to which various amounts of thoria have been added, Jeffries found that grain growth was inhabited, that is, practically prevented, up to a certain annealing temperature. When this temperature, which increased with the thoria content, was exceeded, extremely large grains developed abruptly from the fine grained matrix. Such a "coarsening temperature" was later found by Gross mann13,14 in certain types of steel, while Bain showed" that in other steels grain growth was gradual, without inhibition and abrupt coarsening. Later work16,17,18,19,21 demonstrated the connection between coarsening and aluminum additions. The viewpoint that the direct cause of inhibition and coarsening in aluminum killed steels is a fine dispersion of aluminum oxide21 appears to be held quite generally, although some doubts have been voiced even very recently.20 In steels with Ti additions the titanium carbide phase is considered responsible for the inhibition effects found.20 The coarsening temperature increases, with the titanium content. That coarsening may occur, as a result of certain heat treatments, even in low carbon rimmed sheet steel, was shown by Samuels,22 He also detected coarsening in a steel ingot of similar composition, after giving it the same heat treatment as that used by him for the sheet material, In this instance the identity of the inhibiting phase has not been determined, However, Tangerding found 23 that even the few small carbide particles, which occur in carbonyl iron, have a very marked inhibitive effect. As a result of an oxidizing anneal at 850°C, large grains begin to form at the surface of the carbonyl iron specimen, and gradually grow inward as the subsurface oxidation of the carbide particles progresses and eliminates the obstruction, The carbide particles can be removed also by annealing in hydrogen, with similar results. But if the oxidizing anneal of 10 hr at 850°C in air, is followed by annealing in hydrogen for 75 hr at the same temperature, grain growth is more spectacular; usually the whole specimen is transformed into a single crystal (approx. 1,5 cm X 5 cm). The reversed procedure, that is, hydrogen annealing followed by oxidizing annealing leads to smaller grains. Tangerding arrived at the logical conclusion that there must have been in his specimens some additional obstruction to grain growth resulting from a minor impurity, other than carbon. It seems likely that this obstruction was caused by an oxide formed during the oxidizing anneal and gradually reduced during the subsequent hydrogen-annealing. Other instances of grain growth inhibition of varying severity, associated with a dispersed second phase, have been described by several authors. Notable examples: lead with 0.06 pct Cu or Ni,24 cartridge brass with 0.12 pct Cr,25 or with up to 0.15

Jan 1, 1948

By S. Frederick Ravitz

FOUR liquids are ordinarily present in the lead blast furnace during lead smelting. At the bottom is the lead bullion, which is metallic lead containing about one per cent of impurities, including gold, silver, copper, bismuth, arsenic and antimony. Above this is the speiss, which consists essentially of arsenides and antimonides of iron and copper. The speiss is followed by the matte, which consists principally of sulfides of iron, copper and lead1. The top layer is the slag, of which the major constit-uents are silica, lime, alumina, zinc oxide and iron oxide. Similar products are obtained from the dross furnace, which treats the dross obtained in decopperizing lead bullion. The distribution of gold and silver among these various products is of considerable importance in the smelting of lead. In general, the matte and speiss cannot be treated in the lead smelter, and usually are sent to a copper smelter. It is usually desirable, therefore, to keep their gold and silver contents as low as possible, and to collect the precious metals in the bullion. If the bullion, speiss, matte and slag exist together in equilibrium, the gold and silver should distribute themselves among these four liquids in a definite manner, which, other conditions being equal, should depend only on the amounts of gold and silver in the charge to the furnace. It is thus apparent that a knowledge of whether such equi-librium exists is necessary before attempting to study the effects of various compositions of matte and speiss on the distribution of gold and silver among the furnace products2. Moreover, systems consisting of four liquids in equilibrium are very rare, and are of considerable scientific interest.

Jan 1, 1936

By S. Frederick Ravitz, Kenneth E. Fisher

Four liquids are ordinarily present in the lead blast furnace during lead smelting. At the bottom is the lead bullion, which is metallic lead containing about one per cent of impurities, including gold, silver, copper, bismuth, arsenic and antimony. Above this is the speiss, which consists essentially of arsenides and antimonides of iron and copper. The speiss is followed by the matte, which consists principally of sulfides of iron, copper and lead1. The top layer is the slag, of which the major constituents are silica, lime, alumina, zinc oxide and iron oxide. Similar products are obtained from the dross furnace, which treats the dross obtained in decopperizing lead bullion. The distribution of gold and silver among these various products is of considerable importance in the smelting of lead. In general, the matte and speiss cannot be treated in the lead smelter, and usually are sent to a copper smelter. It is usually desirable, therefore, to keep their gold and silver contents as low as possible, and to collect the precious metals in the bullion. If the bullion, speiss, matte and slag exist together in equilibrium, the gold and silver should distribute themselves among these four liquids in a definite manner, which, other conditions being equal, should depend only on the amounts of gold and silver in the charge to the furnace. It is thus apparent that a knowledge of whether such equilibrium exists is necessary before attempting to study the effects of various compositions of matte and speiss on the distribution of gold and silver among the furnace products2. Moreover, systems consisting of four liquids in equilibrium are very rare, and are of considerable scientific interest. In order to ascertain whether equilibrium existed, the distribution of gold and silver among the four liquids was determined. The speiss,

Jan 1, 1937

The Kidston breccia pipe is situated approximately 280 km west northwest of Townsville, north Queensland. It is currently Australia's largest gold producer with production varying between 8,000 and 16,000 tonnes of ore per day. Current reserves are estimated at 36.2 million tonnes averaging 1.74 C/t Au and 2.21 g/t Ag. Alluvial gold in the gullies surrounding the deposit was first discovered in the 1880's and between 1907 and 1948 small scale open cut and underground mining was undertaken. Advances in extractive metallurgy and an increase in the gold price were major factors influencing the recent exploration and development of large scale mining of the deposit by Placer Pacific and Kidston Gold Mines. The breccia pipe is trapezoid in shape with surface dimensions of 1100 m by 900 m. Clasts show only limited evidence of mixing during brecciation, with the pre-breccia stratigraphy still discernible on the basis of clast types. This lack of mixing together with the intimate association with intrusive activity, suggests that the brecia formed by collapse, probably associated with the escape of a large volume of irothermal fluid from a crystallising hatholith. Mineralisation and alteration are also sratially and temporally associated with rhyolite emplacement and brecciation. Pre-breccia mineralisation consists of laminated stockwork quartz veins associated with muscovite, quartz and orthoclase-epidote alteration. Stockwork veins contain either anomalous molybdenite or gold. Uneconomic early stage post-breccia mineralisation and alteration consists of cavity infill quartz-epidote and calcite associated with potassic and propylitic alteration respectively. Economic late stage post-breccia cavity infill and sheeted veining consists of quartz-carbonate-sulphide infill associated with phyllic alteration. The grade of gold mineralisation generally decreases downwards in the system with an increase in the amount of pyrrhotite relative to pyrite. Pre-breccia stockwork quartz veins mineralisation is genetically related to the

Jan 1, 1987

The underground storage of LPG and other hydrocarbons is in current commercial use in Northern Hemisphere countries in Europe, Asia and the USA.Elgas Pty Ltd, a 50 per cent joint venture between AGL and BOC, embarked on a worldwide feasibility investigation in 1989 to establish the viability of constructing an underground LPG storage facility in Sydney, Australia, the first of its kind in the country. Elgas recognised that with the limited 19 000 tonnes of storage capacity at Port Botany and the limitations imposed by use of small coastal ships (up to 10 000 tonnes capacity), a larger storage facility was required to utilise higher capacity ships from more remote sources such as the North West shelf and overseas. This would achieve security of supply in high demand periods and economies of scale. The underground option also provides improvements to safety and environmental standards.

Jan 1, 1999

By B. F. Oliver, F. Garofalo

Gas-metal heterogeneous reactions and zone-lrelting were sinultarneously employed to produce several high-purity irons with low interstitial contents in a levitating- zone melter. Successive zone-tneltitzg pusses were made in carious sequences of atmospheves which included prepuvified tank hy-drogeta, water vapor hydrogen, palladiuril-purified hydrogen, and vacuunm of 2 x 10-6 Torr. Different irons ranging in purity from 99.89 to 99.996 pct with residual curbon contents of 17, 8 to 10, and 3 to 5 ppm have been Drepared. No measuvable gradient in the residual carbon content was observed along the entire zone-melted length (6-10 in.) in I-ilz.-diameter bars. The absence of a carbon-concentration gradient in the solid indicates an apparent distvihution coefficient of 1, an unusual condition. Internal friction, solid-state extraction, and hot-hardness results indicate that the level of mobile carbon in a iron depends on the gas-metal heterogeneous reactions employed. Purification under an oxidizing atmosphere resulted in the immobilization of nearly all of the carbon present at leuels of 10 ppm or less. Continuation of purification in a reducing atmosphere veturued the carbon to a state of mobility which was aguin reversed by further purification in all oxidizing atmosphere. The immobilization of curbon at "vesidual levels " is believed to be associated with a strong interaction between carbon and oxygen atoms. frons with low carbon and nitrogen contetzts which did not exhibit a hot-hardness peak were produced after zone ynelting in vacuum. CARBON, nitrogen, and oxygen have strong and well-known effects on many properties of iron. These effects persist even at concentrations of 5 to 20 ppm. The intent of the present investigation was to establish procedures for the preparation of high-purity iron with concentrations of these elements in the range of 5 to 20 ppm and lower. The results reported here deal with the procedures employed to prepare high-purity iron, and with observations on the behavior of certain elements at "residual levels": particularly carbon. The details of the (levitating) zone melter in which the final purification steps are performed and the necessary control of the pertinent solidification variables have been described previously.1,2 MATERIALS AND PROCEDURES Commercial electrolytic iron was induction vacuum-melted and cast into 30-lb ingots. Melt additions and ingot analyses for carbon, oxygen, and nitrogen are noted in Table I. All ingots were melted in stabilized zirconia crucibles conditioned with one iron wash heat. Middle sections of the ingots were forged to 1-1/4-in. rounds, machined to 1-in.-diameter bars, then cut to 36-in. lengths. The zone-melting operations were performed on six iron bars (A to F) at a freezing velocity of 2 in. per hr with the freezing interface rotating2 at 200, 300, or 400 rpm. Liquid zones were passed through the bars in various sequences of atmospheres, Table 11, including prepurified tank H2, palladium-purified Hz, wet H2, and system vacuum of 2 x 1018 Torr. Wet-Hz atmospheres were obtained by bubbling palladium-purified Hz through water exhibiting a resistance of 3 megohms. This water was heated with a platinum-immersion heater and was degassed prior to use. Zone melting in a wet-HZ atmosphere resulted in oxidation of the elements which are oxi-dizable with respect to iron. Fine oxide particles were observed on the surface of the liquid zone, and were encased in the bar surface with the passage of the molten zone. Between each zone pass, the surface of the bar was removed by filing and deep etching; this was continued until the oxide formation ceased. The filings were magnetically separated and the residues analyzed by optical spectroscopy. These were especially high in silicon and manganese. Samples were removed from the iron bars, with few exceptions, following each zone-melting operation. A 0.08-in.-thick disc was cut with an Al2O3 cut-off wheel at a point 1/2 in. above the beginning of freezing. Material from each disc was used for hot-hardness measurements, resistivity-ratio measurements, and carbon, nitrogen, and oxygen analyses. Analyses for most other elements were

Jan 1, 1965

By S. V. Ketov, V. P. Menushenkov, V. S. Shubakov

"The glass samples were obtained by melting of the oxides mixture SrO-Fe2O3-B2O3(Al2O3) at 1200-1250°C with subsequent quenching of the melt on quickly rotating steel roller. Submicronsized Sr(Fe,Al)12O19 particles were formed in glass-ceramic matrix during the crystallization aging of glass. The aging temperature Tag varied in the range 650-950°C. The submicron-sized hexaferrite powder was obtained by removing of the matrix phases using etching. The samples were characterized by X-ray diffraction, scamiing electron microscopy and magnetization measurements. The glass-ceramic material exhibits very high coercivity value up to 10 kOe. The samples of magnets were obtained by pressing of the hexaferrite powder at RT and subsequent aging in the range 900-1200°C. The aged samples exhibit coercivity value up to 8 kOe.IntroductionStrontium M-type hexaferrites have been widely used in technology and industry mainly for production of permanent magnets owing to their appropriate magnetic properties, chemical stability and low cost [1,2]. The SrFe12019-based compounds are characterized by high magnetocrystalline anisotropy and single easy magnetization axis. The highest coercivity is received for monodomain, defect-free single crystal particles with size D - 100 mn. Finely grained strontium hexaferrite prepared by chemical methods such as sol-gel pyrolysis and oxide glass crystallization exhibits high coercivity up to 6-8 kOe [3-5]. Owing to the partial substitution of Al for Fe in the strontium hexaferrite leading to the increase in the magnetic anisotropy field Ha=2Ki/M,, the increase in the coercivity may be received [6]. The notable results were achieved using the SrO-Fe2O3-AlzO3-B2O3 glass crystallization and formation of perfect submicron crystals of alumina-doped hexaferrite [ 6, 7]. The coercive force of glassceramics reached values of up to 10 kOe. Hexaferrite particles are well faceted and have the shape ofhexagonal bipyramids with truncated vertexes [7].In the present paper, we report results of our investigation into the SrO-Fe2O3-B2O3(Al2O3) glass crystallization, hexaferrite powders and permanent magnets, which were prepared by pressing submicron-sized hexaferrite powders at RT and subsequent sintering at 900-1200°C."

Jan 1, 2012