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By M. del C. Ruiz

The extraction of Nb and Ta from a columbo-tantalite of San Luis, Argentina, is being studied by using a pressure reactor and HF as leaching agent. The reagents and products have been characterized by several techniques such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDXS), X-ray fluorescence (XRF), X-ray difracction (XRD), surface area (BET) and size particle analysis. Experimental results have shown that the extraction of niobium and tantalum increases with increasing temperature, reaction time and acid concentration. For particle size between +80 and -355 mesh no significant changes are detected. It is also slightly affected by the stimng speed. XRD analysis of the residues did not show formation of new crystalline structures.

Jan 1, 1999

By M. T. Worley

This paper reports investigative work conducted to develop a method of estimating the groundwater influx from a homogeneous permeable formation into a vertical mine shaft during sinking. A method of analysis was developed using data obtained from pumping tests and a modification of the Theis non-equilibrium interpretation technique. Excess influx of groundwater into mine shafts has long been one of the more important problems encountered in the development of a mining property. Much work has been done on methods of preventing such influx and on pumping schemes to control inflow if preventive measures fail. The fundamental aspects of the problem, on the other hand, seem to have been neglected. The purpose of this paper is to review the fundamentals of groundwater flow and to propose a rapid method of analyzing hydrologic data in order to estimate influx from a homogeneous permeable formation into a mine shaft. Such an estimate of the quantity of water to be encountered is of value in planning grouting, pumping and other programs designed to control that influx. It is emphasized that the proposed method of analysis should be regarded only as a tool to be used in evaluating the problem before investing the capital necessary to begin development of a property. FUNDAMENTALS OF GROUNDWATER FLOW In order to effectively approach the problem of estimating influx into a mine shaft, a knowledge of the fundamentals of fluid flow through a porous medium is necessary. Darcy, in 1856, developed an empirical relationship to explain the flow of water through sand filters. This relationship V = k (dh/dl), is the basis for all other flow formulae. It has been shown that Darcy's relation is a solution of the Laplace equation and thus is analagous to other natural phenomena such as heat flow. Theis, using the analogy of heat flow by conduction, developed an expression for determining the transient or time-dependent groundwater flow through a homogeneous, isotropic medium. The resulting equation Was also derived by Jacob using hydrologic considerations alone.' The individual terms in the equation are described in Table I. It is important to understand the assumptions upon which this equation is based. 1) The medium through which the fluid flows is infinite in areal extent, homogeneous and isotropic. 2) The well into which the fluid discharges completely penetrates the medium. 3) The characteristics of the medium remain constant at all times. 4) The initial pressure surface is horizontal. 5) The confining media are impervious and horizontal. 6) Fluid is removed from storage instantaneously by a decline in pressure. 7) The diameter of the discharge well is infinitesimal with respect to the drainage radius of the medium.

Jan 1, 1962

Selective Flocculation process development generally involves single mineral flocculation tests to identify the appropriate polymer and experimental conditions for achieving the desired selectivity. Invariably the selectivity predicted on the basis of such tests is not realized when mixed mineral tests are conducted. A systematic experimental investigation revealed that adsorption of the polymer on various substrates is critical to selecting the suitable flocculent. Simultaneously, a mathematical model was developed to predict the overall process efficiency with a given polymer. In this paper, results of these efforts to scientifically design a suitable selective flocculation process are presented.

Jan 1, 1991

By Jian Ye

Recycling of aluminum scrap, such as Used Beverage Container (UBC) scrap is steadily increasing. In secondary remelting of such scrap, it is a common practice to use protective molten salt cover. An appropriate salt protects metal from oxidation, promotes coalescence of the suspended metal droplets, and separates clean metal from the oxide contamination. The molten salt also reacts with metal. This causes metal loss and change of resulting metal composition. In this paper, role of molten salt fluxes in melting of UBC scrap is discussed, and selection criteria for molten salt are provided.

Jan 1, 1995

By A. W. Schlechten, A. H. Larson

Equilibrium H2S/H2 ratios were determined as functions of temperature (500o to 900°C) and composition in a hydrogen-circulation apparatus. Within the composition range studied there exists a two-phase region of "Zr3S4" and "ZrS2". The upper composition limit of this two-phase region is hounded by a disulfide phase and is practically constant over the temperature range investigated. The lower composition limit of this two-phase region is bounded a "Zr3S4 " phase and varies appreciably with tem- perature. The upper composition limit of the homogeneous region of the disulfide phase is not definitely determined, but it appears to he bounded by the stoichiometric composition of ZrS2. The lower composition limit of the homogeneous region of the Zr3S4 phase could not he determined due to the extremely low values of the equilibrium H2S/H2 ratios. Various thermodynamic quantities are evaluated from the data. PUBLISHED free-energy data for the Zr-S system are practically nonexistent. Strotzer, Biltz, and Meisel1 measured the sulfur pressures for the reaction 2ZrS2(s) + S2(g) = ZrS3(s) in the temperature range 783" to 874°C. The average heat of reaction calculated from the temperature dependence of the sulfur pressure is -47 keal. It should be noted, however, that according to these investigators, the two-phase region as determined by sulfur pressure constancy under isothermal conditions extended from approximately ZrS2, 3 to ZrS2.7. From consideration of X-ray data they concluded that the homogeneous regions of the disulfide and trisulfide phases are ZrS1.8-2.0 and ZrS2.8-3.2, respectively. Hahn and coworkers2 have made a structure study of the zirconium sulfide phases. They summarized the zirconium sulfide phases as follows: the compounds ZrS3 and ZrS2 with narrow homogeneous regions, a "Zr3S4" phase with a homogeneous region roughly within the limits of ZrSl.5 and ZrSo.9, the compounds ZrS and Zr4S3, and a "Zr3S2" phase with a homogeneous region within the limits ZrSo.8 and ZrSo.5. It is noted that the compounds ZrS and Zr4S3 are only formed in the gaseous state through sublimation of a phase which has the approximate composition of the compound. This paper describes the determination of the stability of the zirconium sulfide phases by a hydrogen-reduction method in which hydrogen is circulated over the heated sulfide until equilibrium is attained. The resulting H2S-H2 mixture is then analyzed. Partial molar free energies, enthalpies,

Jan 1, 1964

By C. K. Man

Coal dust explosions are routinely conducted within the full-scale experimental mine at the National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory?s (PRL) Lake Lynn Experimental Mine (LLEM) to meet the needs of numerous safety and health research programs. Many of these explosion tests over the years involved igniting different coal dust and limestone rock dust mixtures (up to 80% by volume rock dust). Following four more recent tests, floor dust samples have been collected and analyzed using the alcohol coking test and scanning electron microscopy (SEM) and the results compared to estimate the flame travel.

Jan 1, 2009

By Wendi H. Cooksey

This paper examines two comminution circuits on a hypo­thetical gold ore deposit with both small-scale (1,000 short tons per day) and large-scale (35,000 short tons per day) production rates. The most appropriate circuit is dependent on the highest economic performance with a combination of crushing and grinding equipment to achieve the desired product size. The selected circuit is dependent on costs associated with project cri­teria, equipment selection and ore characteristics. Factors influ­encing the selection of the comminution circuit require system­atic evaluation to optimize plant performance and maximize eco­nomic return. The small-scale circuit economics responded best to three-stage crushing followed by a single-stage ball mill. The large-scale plant favors a primary crusher followed by SAG milling and ball milling. The conclusions from this paper indi­cate that each project must be evaluated separately to determine the most economic means of reducing the size of the ore.

Jan 1, 1998

By Lynch A. J

The success of the Australian mining industry depends on the quality of its skills. High quality skills supported by a culture which demands success lead to innovations, good practices and prosperity. Average skills lead inevitably to mediocrity. Universities play an essential role in the development and use of skills but the crucial industry-university links have been subordinated to conventional academic interests in training mining and processing engineers. It is only in the area of post-graduate research degrees which are oriented towards the mineral industry that Australia can claim world leadership. Deficiencies are not due to lack of training resources, they are due to inadequate utilisation of the resources that are available. Australia can and should have the world's best mineral engineering school, with a branch in Asia where many of its customers are and close ties with South America where some of its production operations will be. Some steps which might be taken to achieve this are proposed.

Jan 1, 1995

By Clifton W. Livingston

So many factors influence blasting results that theories and rules are usually dismissed as impractical; the practice prevailing today is arrived at by cut and try. Usually the first step is to experiment with drillhole patterns and spacing until an arrangement is found that gives best results. The next step is to experiment with different types of explosives and sequences of blasting until the most satisfactory degree of fragmentation is achieved and until no further reduction in cost is immediately apparent. Improved fragmentation is generally attributed to the type of powder used, the sequence in which the holes are blasted, or the use of millisecond delays. Various types of drill rounds have been evolved in tunneling operations, underground development headings, and stoping, and various patterns of blasting in open pit mines and quarries. These practices usually are carried from mine to mine or from district to district, and great skill is exercised by those experienced in the art of blasting.

Jan 1, 1960

By John A. Hansuld

Molybdenum presents a series of baffling geo- chemical puzzles. It can exist in six different valence states, possessing three different coordination numbers. As a result, it combines with other elements to form a wide variety of negatively and positively charged ions and complexes whose exact chemical nature are relatively unknown. Its rather complex chemistry might be described as "ambidextrous, bi-sexual and polygamous". It is little wonder then that the geochemistry of molybdenum is relatively unknown, and compared to most common metals its geochemical behavior is somewhat unique. The behavior of a particular element or metal, such as molybdenum, in a given dispersion media is largely controlled by the stability relations among its various oxidation products. Recognition of these products and an understanding of their stability relations is therefore a prerequisite to a proper understanding of its observed behavior. Because most secondary dispersion media represent aqueous chemical systems, stability relations are best expressed as functions of Eh and pH.

Jan 12, 1966

By Laurindo De Salles Leal Filho, Arthur Pinto Chaves

The Serrana Process was developed in the 60's to concentrate an igneous low grade phosphate/carbonate ore using tall oil as a collector and corn starch as a modifier in alkaline medium. Nowadays, although tall oil has already been substituted by a new amphoteric synthetic collector, starch hasn't been substituted yet. This study is an attempt towards understanding the role played by corn starch in this specific system. By means of bench scale flotation test, it was observed that corn starch was capable of promoting the flotation of apatite, phlogopite and dolomite. No effect over calcite was observed. The best efficiency of separation apatite/gangue minerals was yielded at the concentration ranges of 17 to 20 mg/l of starch and 13 to 17 mg/l of tall oil. The starch concentration showed a strong influence over the characteristics of the froth produced by the flotation tests, mainly over the volume of the froth and its mineralization.

Jan 1, 1993

By Steven A. Bradbury

INTRODUCTION Passive dust control systems are quickly gaining acceptance in the bulk solids handling industries. The number of applications is increasing due to proven performance, especially in US power plants burning Powder River Basin coal. Air Control Sciences ®, Inc., of Boulder, Colorado, has over forty (40) patented Dustless Transfer ® systems in operation. All of the installations control workspace dust levels to less than 2.0 mg/m3, and in some applications reduced conveyor dusting by over ninety-eight percent (98%). Passive systems control fugitive dust emissions by minimizing the induced airflow in bulk material transfer and slowing its velocity. Traditionally, fugitive dust control in the mining industry was accomplished using either dust collection systems or dust suppression systems. The term passive dust control, indicates these methods don't use any active dust collection or suppression. Passive dust control systems are best suited to transfer from one conveyor to another. They can also be applied to transfers from feeder to conveyors.

Jan 1, 2004

By D. K. Sengupta, T. K. Rout, A. R. Prasad, B. P. Singh

The filter cake from the vacuum drum filters of a uranium ore processing plant still contains some leach solution. If the filter cake is not efficiently washed the associated leach solution is lost. Therefore, it is necessary to produce a filter cake that is permeable enough to allow efficient washing. The dewatering characteristics of the solid-liquid system must be improved to obtain flocs with sufficient strength to withstand the suction pressure of the filtration system. To facilitate efficient filtration with minimum cake moisture, studies were undertaken to improve the dewatering characteristics of the cake using different types of flocculants and surfactants. In these studies, flocs were formed with anionic, cationic or nonionic flocculants. The best performance was obtained with a low cationic high molecular weight flocculant. The filtration parameters, namely, capillary suction time, cake resistance, cake permeability and final moisture content of the filter cake, are improved by using a combination of flocculant and nonionic surfactant.

Jan 1, 2002

A mining joint venture presents a real management challenge to achieve harmony with the other participants in the successful development and operation of a mine. This can best be facilitated by a detailed agreement and guided by a set of joint venture principles which recognise the differences of the interests of the parties and seek to establish sound business and personal principles by which differences not anticipated in the agreement might be resolved. The major and minor co-venturers can and do present potential difficulties to one another. This paper, one of the pair in the joint venture panel discussion session, predominately presents the minor's viewpoint. Usually commercial matters such as project finance, areas of interest, divestment, pre-emptive rights and decision-making can be adequately covered in the agreement. However, when the parties disagree and have difficulty in resolving their differences, the joint venture principles should be used to advantage to resolve relationship difficulties.

Jan 1, 1997

By Rashad MZ

The evaluation of ore deposits consumes much effort, cost and time, hence research work must aim to minimize these inputs with no loss of accuracy. The present study is devoted to assess the optimum conditions and methods of calculations which give minimum costs of ore exploration. An area of (a x a) where "a" is the zone of influence of the semi-variogram, i.e. (2800 x 2800 square metres) located within the Abu Tartur plateau is the subject of the intensive study. The distances between boreholes are varied ie. a/4, a/6, a/8 and a/ 10 respectively. The average ore grade (G), thickness (t) and relative ore reserves (tG) are calculated by four methods. The results indicate that at a distance equal to a/5, the inverse distance squared method gives the best results. These parameters save about 50 percent of the cost of exploration with a map accuracy greater than 90 Percent.

Jan 1, 1987

By A. M. Al Taweel, S. M. El Mofty, T. A. Hassan, M. R. Moharam, A. M. Ramadan

The axial mixing characteristics of a pilot-scale flotation column were investigated with the objective of identifying means to mitigate the extent of axial mixing that adversely affects its grade/recovery performance. A wide range of design and operating conditions was investigated and the experimental results, obtained using the dynamic response method, were analyzed using three axial mixing models. The dynamic response of the column can best be described using the axial dispersion model. The results obtained suggest that the value of the axial dispersion coefficient, EL. can be signi6cantly reduced by judicial selection of hydrodynamic conditions and/or the use of column inserts that suppress the onset of hydrodynamic instabilities inherent to the operation of conventional flotation columns. Up to 40% reduction in the value of EL was thus obtained by using spargers that produce more uniform bubble sizes, while up to 30% reductions were obtained by controlling the residual frother concentration.

Jan 1, 1995

By Morinaga K

The optical basicity (A, Pb2+ as probe ion) of various oxide glass systems has been measured to establish the new basicity scale of slag melts. Best conditions of glassy fragments to measure A were as follow, (1) 1 ti 4 x 10-2 wt% Pb content, (2) 0.2 mm in thickness, (ii) enough annealing (about 10 hr) at a temperature 200¦C below Tg., and (4) polishing a surface well. the variation of A with composition was correlated to that of relative oxygen activity of slag melts. The estimation of basicity of slag melts from it could be valid. The A of opaque and coloured quenched slags could not be measured. An approximately linear relationship, however, exsisted between the isomer shifts (b) of Fe3+ ion in slag derived from the Mossbauer effect and A. Therefore, -4 of various metallurgical slag could be estimated from this relationship. These results can be expected to establish the new basicity scale of slag melts as the Louis basicity.

Jan 1, 1980

By Barlow S

The Kelian Gold mine project won two excellence awards from the Victorian Division of the Institution of Engineers, Australia. It was a challenging project, fast tracked in a remote and inhospitable tropical environment. The creation of a profitable and efficient mine was a significant engineering and project management achievement. The difficulties encountered and the way they were managed provide valuable lessons. These include the importance of sufficiently detailed engineering in all aspects of the job to enable the best estimates possible to be prepared during feasibility studies, the need to prepare the project scope and execution plan with disciplined and rigorous attention to detail by a highly experienced team and the value of identifying, assessing and mitigating risk and uncertainty during execution. The practical benefits of applying these lessons were demonstrated in the successful management of technical uncertainty on the recent diversion of the Kelian River to allow the expansion of the Kelian mine.

Jan 1, 1997

By Reinhardt Thiessen

IN THE general study of coal, all evidence points in the one direction -that coals had their origin in a manner analogous to that of peat. The best method of studying coal, whether it concerns its chemistry, composition, or physical condition, is to study peat. The essentials in a study of peat are a knowledge of the chemistry of plants, knowledge of decay and of the transformation process of plant-substances into peat. A number of facts must be emphasized, namely, (1) peat is formed under wet conditions only; (2) plants grow in the place where peat is formed; (3) all the plant substances go into the bog; and (4) all the plant substances are subjected to a series of phases of decay which are (a) in the air completely above the water level but in relatively moist conditions; (b) above the water level, but covered by debris; and (c) completely submerged by both water and debris.

Jan 3, 1925

By Nemick JA

Recent advances in computer simulation together with field measurements of caving and microseismic activity about longwall panels, has allowed a much better understanding of the caving process and the variability due to geology. The joint research between SCT Operations and CSIRO Division of Exploration and Mining has initiated new methods of computational modelling predicting various caving patterns and strata failure far ahead of the longwall face. This work was validated by field measurements of caving and microseismic activity at the longwall face.The rock fracture distribution and the caving characteristics of a range of strata sections have been simulated by computer methods. Validation studies of the method were addressed together with case studies. The interaction of caving with support convergence and face control is presented. The method allows the simulation of longwall support behaviour under various geological conditions. The system also allows a prediction of the monitoring data, which is best suited to give an early warning of weighting events or signal various key caving characteristics.

Jan 1, 1998