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By Willian Facundes

Algumas qualidades de aço UltraBaixo Carbono têm exigido teores de fósforo cada vez mais baixos. Quando se obtém teor de fósforo fim de sopro no convertedor acima dos níveis exigidos pelo cliente, faz-se necessário realizar um retrabalho na corrida ou promover desvios, utilizando-a em aços para outras aplicações. Para reduzir ainda mais o teor de fósforo durante o vazamento do aço do convertedor para a panela desenvolveu-se uma escória sintética desfosforante a ser utilizada quando o teor de fósforo não atende ao especificado no fim de sopro. Foram comparadas corridas com utilização da escória sintética e corridas utilizando somente cal. Obteve-se um aumento de 28,2 pontos percentuais na taxa de remoção de fósforo durante o vazamento com a utilização da escória sintética. Diante dos resultados obtidos, o produto foi aprovado para utilização na Aciaria 2 da Usiminas Ipatinga

Aug 17, 2017

By Danilo Mendes Amorim

No setor de trocadores de calor para refrigeração industrial e câmaras frias o maior desafio é a corrosão do equipamento quando exposto a intempéries. Esta situação em regiões litorâneas é agravada devido ao ataque de sal e ácidos provenientes da atmosfera. Diante disto este mercado sempre procura um aumento na resistência dos componentes das unidades evaporadoras. Neste contexto as aletas, que são feitas utilizando folha de alumínio com revestimento epóxi orgânico dourado, tem papel de grande importância. O presente trabalho visa entender os mecanismos de corrosão da folha nos principais fatores, tais quais, liga, têmpera e revestimento em relação a resistência a corrosão em áreas litorâneas. Os materiais escolhidos foram as ligas 8006 e 8079, na tempera O e com revestimentos base Epóxi e Poliéster. As amostras foram ensaiadas no laboratório utilizando ensaios de corrosão salina e acida que simulam as condições encontradas.

Aug 17, 2017

By S. D. Viljoen

The use of ceramics to protect equipment subjected to wear in abrasive and corrosive applications has been accepted by most plants as the industry norm. Little is, however, known about alternative special ceramic based products which are available for the protection of plant assets. With careful engineering, impact resistant ceramics can be used in high impact zones using modern ceramic technology. Properly selected and properly installed, ceramics will provide a tough wear resistant lining for protection against abrasion and impact. Basalt, on the other hand, is widely used in coal washing plant process pipes with varying degrees of success. Basalt is normally not used for the lining of bends, ?T? pieces or reducers due to the reduced wear resistance compared to alumina ceramic. The advantage is a much reduced initial capital cost. A patented ceramic composite non-return valve solved an old problem encountered in the operation of medium sumps. The design approach overcomes the lack of functionality of alternative designs and reduces valve wear while preventing medium settlement during plant shutdown periods. Direct bonded ceramic pulley lagging is becoming the industry norm, eliminating most of the problems encountered with conventional pulley lagging systems.

Jan 1, 2010

By B. D. Cullity

INTRODUCTION THIS investigation of bismuth-selenium alloys was made in an attempt to find a suitable material for use in thermoelectric generators. These devices are simply thermocouple circuits designed for the efficient production of electrical energy from thermal energy, which may in turn be derived directly from solar radiation or from the combustion of fuels. The requirements of a material for use in a thermoelectric generator are obviously quite different from those of a material used in a temperature-measuring thermocouple. Naturally, for power generating purposes, the thermoelectric power (voltage produced per degree difference in temperature between the junctions) must be as high as possible. Furthermore, in order to obtain reasonably high power outputs, the materials used in the generator must have an electrical conductivity which is as high as possible. Finally, in order to minimize heat lost by conduction to the cold junction, the thermal conductivity must be as low as possible. The relation between these several factors and the efficiency of conversion of thermal into electrical energy-the thermoelectric efficiency-has been discussed by Telkes1 in a recent review of the subject. She gives the thermoelectric efficiency as: [ ] For many materials, some of the desired properties (for example, high electrical and low thermal conductivity) are almost mutually exclusive; the problem thus becomes one of finding a material which has the optimum combination of properties. BISMUTH-SELENIUM ALLOYS Work on the equilibrium diagram of the bismuth-selenium alloys has been reviewed by Hanson,2 who gives the diagram reproduced in Fig I. There are two intermediate phases in this system, BiSe and Bi2Se3. The existence of an alpha and beta modification of BiSe has not been demonstrated satisfactorily and the writer found no evidence of it in the present work. BiSe and Bi2Se3 have, like bismuth, a rhombohedral crystal

Jan 1, 1948

By John D. Sullivan, Edwin J. Rogers, Chester R. Austin

THE problem of making a building unit combining the necessary physical and mechanical properties and good thermal insulation has been foremost in the minds of architects and ceramic and construction engineers for many years. This paper presents the results of studies on thermally expanding shales or clays to produce light-weight cellular products suitable for making building units. An expanded clay block suitable for building purposes should be large enough so that substantial savings may be effected in labor costs in laying the wall. The permeability should be low and it should have sufficiently good "dry-wall" characteristics to permit exposing the exterior surface to the elements, and to permit plastering directly the inside wall surface. The thermal conductivity should be low and the mechanical properties should be adequate. Obviously, a unit possessing satisfactory qualities for constructing an outside wall would be satisfactory for interior walls and for back-up purposes. The results of studies on bloating various shales or clays[t] and the properties of the expanded products are reported. In another paper1 basic factors involved in bloating of clays are discussed. Manufacturers of ceramic products, particularly structural clay, may encounter bloating of the ware during burning, and precautions must be followed to avoid this phenomenon. About 1927 the C. F. Burgess Laboratories, Madison, Wis., while carrying on an investigation for the American Face Brick Research Corporation, conceived the idea of intentionally bloating clay while holding it in a restrained condition, with the hope of producing a unitary cellular mass. Work was carried on until about 1931, when studies were terminated because of business conditions. These studies were continued later by The Western Brick Co., Danville, Ill., which developed a process of "inwardly expansive bloating."2 The major purpose of the latter investigation was to produce back-up tile to compete with concrete blocks made from Haydite or cinder aggregate. Haydite is a light-weight aggregate formed by heating certain clays or shales rapidly in a rotary kiln. While the investigations at the C. F. Burgess Laboratories or at Western Brick Co. were not carried far enough to lead to the commercial production of material for the construction of walls, particularly outside walls, they showed that certain clays could be thermally expanded and that it was possible to produce a material of low permeability with a large percentage of the total voids or cells closed. Commencing in 1939, the Ozark Chemical Co. sponsored a research program at Battelle Memorial Institute for the purpose of determining whether it is technically feasible to make thermally expanded building units, and specifically to get answers to the following questions:

Jan 1, 1942

By A. J. S. Benade, N. B. Strydom, W. H. Van Der Walt

The performance of the improved microclimate suit by N. B. STRYDOM M.Sc., Ph.D. (Illinois) (Fellow), A. J. S. BENADE, B.Sc. (Potch.) (Visitor), and W. H. VAN DERWALT, M.Sc. (Potch.) (Visitor) An assessment has been made of a new improved microclimate jacket when worn by men working for four hours in a hot environment (wet-bulb temperature of 33,9°C and an air speed of 0,4 m/s) and at work rates of 35 Wand 70W. At the lower rate of work in heat, the use of microclimate suits maintained the rectal temperatures of the men at almost the same level as when they worked without that protection at normal room temperature (20°C). At the greater rate of work without protection, the men's rectal temperatures rose to 40°C within two to three hours, so that they could not complete four hours of work. When they wore microclimate suits, they easily completed four hours of work, and their rectal temperatures were lower than when they worked at the lower rate without protection.

Jan 8, 1975

By E. P. Gush

Diamonds, an enigma in a mineral resource sense. Chemically, diamonds are no more than carbon crystals in a cubic system-formed one might add under conditions of great pressure and temperature. They have certain physical properties which are fairly unique. They are very hard, they have a high refractive index, they luminesce, some of them fluoresce, they have a high specific gravity, they don't wet and they are a good conductor of heat. In a way, a rather clinical set of qualities. Of course, these qualities are what give diamonds their use and their beauty. It is on the emotional side that they get complex and stir memories of legends, of beauty, of wealth and romance, of war, happiness, bad luck and curses. It is on the emotional side that the value of a diamond is established, if such a thing is possible. Diamonds are extremely varied, there are more than 5000 categories into which they are sorted, so there is room at each point across the spectrum for their individualities to emerge, and accordingly their attractiveness to each buyer is unique.

Jan 1, 1994

Dynamic hydrothermal modeling is a tool that can aid in studying problems associated with hydrothermal ore deposits and can help increase our understanding of the spatial distribution of ore within hydrothermal systems. Models are constructed by a sequence of steps involving development of a conceptual model, followed by its mathematical description in terms of governing equation with accompanying initial and boundary conditions. This equation is then solved either analytically or numerically. The four model types ò that fully describe a hydrothermal 'system are those for fluid flow, heat and ore solute transport, and deformation. At Renison, models have been used to help understand two major exploration problems. These are the controls on ore localisation in dolomite horizons and feeder faults respectively. The types of models used ò have simulated the distribution of all mineral zones, pyrrhotite, and temperature in the dolomites. This has allowed evaluation of the effects on ore localisation by physical and chemical heterogeneities within the dolomite host rocks, and allowed estimation of potential controls in different physical and chemical environments.

Jan 1, 1987

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

Benjamin B. Thayer was elected as representative of the Institute on the John Fritz Medal Board of Award vice Albert Sauveur, whose term expires. Robert M. Raymond was confirmed as member of the, Engineering Foundation Board for two years in accordance with the By-Laws of the United Engineering Society. The following preambles and resolutions were passed: WHEREAS, the Chamber of Commerce of the United States is taking a vote, through the Chambers of Commerce, Boards of Trade and other constituent members of the National Chamber situated throughout the country, on the question whether or not the primary natural resources, comprising timber, the ores and deposits of useful metals, and' the deposits of minerals, which are a source of heat, light and power, should he exempt through remedial Congressional legislation from the restrictive limitations of the Anti-Trust Acts, and WHEREAS, a Committee of the National Chamber, the Chairman of which is a Past President of the American Institute of - Mining Engineers, has recommended favorable action upon this question, and

Jan 2, 1917

By P. V. Barr, Y. -H. Li, A. P. Watkinson

Subsequent to a campaign of pilot-kiln trials of firing bio-oil and natural gas, scale-up to commercial lime kilns was made using an in-house mathematical kiln model. Both dry limestone and lime mud kilns of 3.5 m OD. by 100 m length were used for bio¬oil firing simulations. Comparisons were made against natural gas firing on the basis of specific firing rate, off-gas volume, energy consumption and overall lime quality. Model simulation results indicate that conversion from natural gas to bio-oil with no productivity loss will increase energy comsumption by about 7.5% and total off-gas volume by about 8%. Alternatively, a 6% decrease in productivity would be expected if off-gas volume is maintained constant. The calculations are sensitive to deviations in the lower heating value (LHV) used in the simulations. A 5% increase in the LHV of the bio-oil, which could result from a 3% decrease in the moisture content, reduces the energy penalty to 2% coupled with a slight reduction in off-gas volume.

Jan 1, 2004

By Robert H. Richards

In the latter part of December a batch of amalgam was retorted and the tin in the retort uncovered while at a low red heat, and allowed to cool slowly to a temperature more suitable for ladling into moulds. It was then ladled and made what appeared to be nice, white, malleable block tin. On February 15th our attention is called to the fact that the tin is brittle, and on examination we find that the molecular condition of the pigs has changed to the extent of one-half its material. The change shows itself by an enlargement appearing on the surface something like crystallization, and comes in spots. The condition of the metal in these spots is very peculiar. It has changed from a malleable metal to a brittle one, with a structure somewhat resembling stibnite, and a color very considerably darker gray than tin. The analyses of the two parts of this tin pig showed the following results: Mercury. Tin. Specific Gravity. Crystalline part,.....2.62 97.24 6.175 Malleable part,.....2.38 97.50 7.387

Jan 1, 1883

By Charles F. Brush

THE compression of gases to a very high degree, for purposes of scientific research, has long presented serious difficulties to the physicist. Great advances have been made of late years in the construction of ordinary air or exhaust pumps, while very little has been done towards the improvement of compression pumps. The principal difficulties encountered in the construction of such apparatus are the existence of the so-called "dead space" in the pump barrels, leakage of the piston packings under high pressure, and the trouble arising from the unequal expansion of parts caused by the development of the latent heat of the gas during compression. Of these obstacles to success, the "dead space" is far the most serious, as it fixes a limit to the performance of the pump beyond which it is impossible to carry the compression. The writer having occasion, some time since, to make a series of investigations on gases very highly compressed, and finding no apparatus, or description of apparatus, adequate to produce the required

Jan 1, 1876

By Charles F. Brush

The compression of gases to a very high degree, for purposes of scientific research, has long presented serious difficulties to the physicist. Great advances have been made of late years in the construction of ordinary air or exhaust pumps, while very little has been done towards the improvement of compression pumps. The principal difficulties encountered in the construction of such apparatus are the existence of the so-called "dead space" in the pump barrels, leakage of the piston packings under high pressure, and the trouble arising from the unequal expansion of parts caused by the development of the latent heat of the gas during compression. Of these obstacles to success, the "dead space" is far the most serious, as it fixes a limit to the performance of the pump beyond which it is impossible to carry the compression. The writer having occasion, some time since, to make a series of investigations on gases very highly compressed, and finding no apparatus, or description of apparatus, adequate to produce the required

The thirty-ninth meeting of the Boston Section was held at the Engi- neers? Club on Monday evening, Dec. 4, 1916. Thirty-three members and guests sat down to dinner; There were present as section guests; Dr. L. D. Ricketts, and Prof. Bradley Stoughton, President and Secretary of the parent society, and each was called upon to speak. Mr. Stoughton spoke of the growth of the Institute during the past year and described the very numerous and important activities, of which the junction of the American Society of Civil Engineers with the other three societies is perhaps the most important. Dr. Ricketts, the advertised speaker of the evening, spoke on Recent Progress in Mining and Metallurgy of Copper Ores. In discussing the improvements in mining, he traced the mining methods from square- set mining to the modified Ohio System now so successfully used at Inspiration: In metallurgy, he described the growth of reverberatory-smelting ant1 allied problems such as the utilization of the waste heat for generating steam. He laid stress on the importance of sampling and bedding of

Jan 6, 1917

By S. K. Kawatra, S. J. Ripke

Iron ore concentrates pellets are currently in duration heat hardened (sintered) under oxidizing conditions. Pellets produced from magnetite ore concentrate are completely oxidized during induration and finish as hematite pellets. These pellets then require a blast furnace to reduce the hematite to metallic pig iron. Partially reduced pellets would save energy and fuel during transportation and further reduction. It has been stated in the literature “the most important single factor responsible for the development of strength in fired magnetite pellets containing no additive is the oxidation of the magnetite to hematite and the subsequent recrystallization and grain growth of this constituent.” However experiments shown in this paper reveal that oxidation is not necessary to produce high-strength pellets. Magnetite concentrate pellets developed similar strength when indurated at 1350°C under either oxidizing (air) or inert (argon) atmosphere; the pellets sintered under argon remained magnetite. In addition, magnetite concentrate pellets indurated under reducing (CO) atmosphere also remained as magnetite, but required induration temperature of approximately 150°C less than the other pellets.

Jan 1, 2003

By R. B. Gavert, David J. Mack

ROOM- and elevated-temperature compression tests were made on the binary 3/2 electron compounds AuZn, CuAu, AgZn, AgMg, AuCd, and NiA1. These compounds possess either the B2 CsC1-type ordered structure or the A2 bee disordered structure represented commonly as ß and ß on equilibrium phase diagrams. In testing at room temperature, cylindrical specimens 0.508 cm by 0.330 cm diam were seated directly on an instron compression load cell (CF 0 to 10,000 lb). At elevated temperatures, testing included a special apparatus with a furnace heat source and a protective atmosphere.' The specimens were strained at a rate of 1 pet per min. The compounds were prepared from 99.99 pet or better high-purity elements. Vacuum and/or argon cover gas was used throughout the mixing, melting, and specimen drawing processes. The generally equi-axed specimen grains varied in size from 0.5 to 1.5 mm for the five different compounds. The stress-strain curves in compression showed

Jan 1, 1968

By Roberto Parra

The wear and corrosion phenomena in the furnace lining of the ferrous and non ferrous pyrometallurgical processes are complex problems where chemical, interfacial and mechanical phenomena are presents. The characteristics of the processes determine the conditions to which these materials are submitted, where the thermal conditions reached during the operation is one of the most important parameter. Assuming that all the degradation phenomena are thermal activated, the rate of the different steps of the wear mechanism will depend on the thermal field in the lining. In view to apply the independent physicochemical knowledge of degradation mechanisms to the analysis and design of furnace lining the methodology of the Nodal Wear Model (NWM) was done. It combines the mathematical modelling of the heat transfer in the lining with the physicochemical control equation for the wear-corrosion phenomena. The NWM has been applied to different examples: theoretical analysis, laboratory scale test and industrial applications. We present in this paper the theoretical background of the model and two examples of applications: the sole of an electric furnace and the earth of a blast furnace.

Jan 1, 2006

By D. C. Wilder

Deformations during heating and cooling of three drifts in granitic rock were influenced by the presence of faults and shear zones. Thermal deformations were significantly larger in sheared and faulted zones than where the rock was jointed. but neither sheared nor faulted. Furthermore. thermal deformations in faulted or sheared rock were not significantly recovered during subsequent cooling thus a permament deformation remained. This inelastic response is in contrast with elastic behavior identified in unfaulted and unsheared rock segments. A companion paper (Butkovich and Patrick, 1986a) indicates that deformations in un- sheared or unfaulted rock were effectively modeled as an elastic response. We conclude that permanent deformations occurred in fractures with crushed minerals and fracture filling or gouge materials. Potential mechanisms for this permanent deformation are asperity re-adjustments during thermal deformations. micro-shearing, asperity crushing and crushing of the secondary fracture filling minerals. Additionally, modulus differences in sheared or faulted rock as compared to more intact rock would result in greater deformations in response to the same thermal loads.

Jan 1, 1986

By E. Kokinou

The main scope of the present study is to investigate the suitability and sensitivity of the magnetic susceptibility as a pollution monitoring tool in urban areas. For this purpose, a municipal park located in the centre of Chania city, which may be affected by traffic and domestic heating pollution, was selected as the study area. In the context of the present work, magnetic susceptibility measurements were conducted in two phases. Surface soil samples were collected in 2006 from the area under investigation and they were analyzed in order to estimate the spatial distribution of the magnetic susceptibility. One year later, mapping of the magnetic susceptibility has been contacted in situ using Bartington MS2D and MS2F sensors. Additionally, soil samples were collected from selected positions in order to compare the values of the magnetic susceptibility with that estimated in 2006 research. Both investigations indicate high values of the magnetic susceptibility around the park near the roads and in a small area inside the park where a café is located.

Jan 1, 2008