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By P. R. Taylor

This work is concerned with the extraction of refractory metals using an electro-reduction process, in which a molten oxide melt, instead of halide, is used as the electrolyte. The process may provide an alternative method of producing refractory metals from their ores through use of a reverse-polarity direct current (DC) plasma arc heating process. In such a process, the plasma torch itself acts as an anode, and resulting liquid or solid product metals work as a cathode, whereas the molten oxide melt plays the role of an electron transfer layer. The focus of this study is: the electro-reduction of scheelite; vanadium pentoxide; and chromite. For the vanadium pentoxide, the proposed melt is mainly composed of CaO-V2O5/Li2O-B2O3-V2O5or FeO-CaO-SiO2-V2O5-Li2O with the addition of other alkali and alkaline metal oxides. In the case of scheelite ore, the SiO2-CaO-Li2O-WO3system is used as melt and metal aluminum or nickel could be used as a collecting media. As for the reduction of chromite ore, SiO2-CaO-Cr2O3-Li2O system with trace amount of CaF2is used as the melt. As a demonstration, chromium was successfully produced at a laboratory scale through the plasma driven electro-reduction process. One of the studied slags had a composition of 13.8% CaO; 4.9%CaF2; 36.4% Cr2O3; 6.9% Li2O; and 38.0% SiO2. Two observations are significant in this laboratory scale study. The first one was that the amount of Cr2O3and FeO, which were predominantly electronic conductors in the oxide melt, greatly affected the conducting mechanism of the melt. With high concentration of Cr2O3and FeO in the melt, the current efficiency was fairly low. In this case, chromium was found to be barely reduced because of electronic conducting mechanism. For example, with initial slag of 60% Cr2O3, no chromium was found reduced. With low concentration of Cr2O3and FeO in the studied melt, typically no more than 30% Cr2O3, it was observed that chromium was readily reduced due to the dominant ionic conducting mechanism. The second observation was that the addition of SiO2tothe melt helped to make the oxide melt more ionic, which was apparently desirable to the molten oxide electrolysis. However, high content of silica had a negative effect on the fluidity of the melt. This was resolved by adding trace amounts of CaF2to the melt. Therefore, by judicious selection of oxide melt, refractory metal oxides might be dissolved into it and yet the melt itself retains the required ionicity. A reverse-polarity DC plasma driven molten oxide electrolysis may prove to be a viable alternative route for the extractive metallurgy of refractory metals.

Jan 1, 2003

By D. J. Carney, E. C. Rudolphy

Large macroscopic nonmetallic inclusions were related to altered fireclay refractories by chemical and microscopic means. Pouring refractories are discussed as a source of these large inclusions. Nozzles and wells are major contributors. Use of alkali and titania contents as tracers is described. Recommendations are offered to minimize the sources of inclusions from pouring refractories. IN any attempt to improve the cleanliness of plain carbon and alloy steels, consideration must be given not only to the proper deoxidation practice to minimize inclusions, but also to sources of inclusions from pouring refractories. In some cases, the inclusions resulting from deoxidation may be minor in amount, yet a relatively dirty steel may be produced as a result of improper care in the pouring practices for the steel. The number of studies of inclusions resulting from pouring refractories has increased recently and some excellent reports on this subject have already been published.'4 Some of these reports were reviewed briefly in a companion paper by M. P. Fedock.5 Mr. Fedock's contribution is a fine addition to the studies necessary to improve steel cleanliness for the ultimate benefit of all steel producers and consumers. In the interest of constantly improving cleanliness, the authors have been actively engaged for the past two years in experimentation to determine more closely the sources of inclusions in steel. One phase of this work was associated with efforts to define more closely the sources of macroscopic inclusions which have been experienced on occasional heats. The term "macroscopic inclusions" is defined in general as those inclusions which are visible to the naked eye or at low magnifications of the order of less than X25. These inclusions sometimes can be seen in the macro-etch tests of billets and slabs. This report summarizes a few of the field experiments and laboratory studies conducted at the South Works of the United States Steel Corp., which were made regarding nozzles, wells, and ingot scums, as well as inclusions occurring in steel products. The data in the present study, together with the data of Mr. Fedock concerning ladle erosion, should be of value in regard to future studies of inclusions arising from pouring refractories. The knowledge gained as a result of data collected thus far at South Works has been helpful in improving the cleanliness of the products and in pointing the way toward further improvements. Similarity of Large Inclusions to Refractories and Altered Refractories In the routine inspection of billet etch tests, occasional inclusions visible to the naked eye have been observed. These large inclusions most frequently occur near the top of the ingot and near the billet surface. When such material was encountered, careful examinations were made in an attempt to determine the origin of these inclusions. In a relatively few cases, examination revealed that the material was unaltered fireclay refractory of a type similar to that used for hot-top material, with only the surface of the inclusions having an altered appearance under the microscope. However, the great majority of these inclusions were completely altered-refractory material. The term "altered refractory" is defined

Jan 1, 1955

MRS. SIDNEY J. JENNINGS, President MRS. ARTHUR S. DWIGHT, First Vice-President MRS. KARL EILERS, Second Vice-President MRS. H. W. HARDINGE, Third Vice-President MRS. BRADLEY STOUGHTON, Recording Secretary MRS. AXEL 0. IHLSENG, Corresponding Secretary MRS. HARRIS K. MASTERS, Treasurer Welfare Committee MRS. C. C, BURGER, Chairman Sub-Committees Americanization Belgian Relief MRS. LEVI HOLBROOK, Chairman MRS. HENRY H. KNOX, Chairman Emergency MRS. HERMAN A. PROSSER, Chairman A very successful meeting Of the Council of the Woman's Auxiliary was held Wednesday, July 18, and plans for war relief work were thoroughly discussed. The Belgian Relief Committee has sent out the following letter to the ten local sub-committees, which were formed to raise money to feed the Belgian children: "The Commission for Relief in Belgium announced in a letter from Mr. Hoover that after the first of June the United States Government would take over the relief of Belgium and Northern France and called attention to the following paragraph: ?Naturally, having built up such an effective organization you will desire to keep it alive as far as possible, and we venture to suggest that, although the general relief of the countries involved will now be met by the Government appropriations, emer-gencies and special conditions may arise which could only be met by private donations. In such circumstances your organization will afford a ready means of meeting the demands of the situation, whatever they may be. Should any of your contributors

Jan 9, 1917

By Kazimierz Gwizdala

In the paper the method for estimation of settlement of vertically loaded piles in a group is presented. The method is generally based on the hybrid procedure with non-linear solution for single piles and with interaction between them for the low-strain shear modulus. Some attention is paid to the influence of deformation and strength parameters used in calculations. The applied model is verified in the framework of the research programme carried out recently in the Geotechnical Department of Gdansk Technical University. It concerns monitoring and analysing the settlements of the existing structures on piles. A comparison of calculation and measurements results for two tested buildings is presented as an example.

Jan 1, 2002

By B Yang, L Wang, C Y. Ng

Flotation process intensification is often achieved through changing chemical reagent scheme or flotation machine or both, which likely brings a hefty burden to the flotation plants in terms of capital or operating expenditure. A novel approach to flotation process intensification is the use of acoustic sound, which has been demonstrated to be effective in improving the flotation of various mineral systems with different type of flotation cells. This approach was based on the dynamic stabilisation effect of acoustic sound on the flotation froth. The present work aims to understand the influence of various experimental conditions on the effectiveness of the approach. First, the effects of sound frequency and amplitude were studied with column flotation of silica particles. Results showed that the flotation performance was improved only within a certain range of frequencies and above certain amplitude. The study was then extended to the mechanical flotation of quartz particles with various size ranges and at two solids concentrations. With sound, the recoveries of different size fractions within the range of 20–212 μm were all increased. In particular, the recovery of 150–212 µm particles was increased from 0 per cent to approximately 25 per cent, demonstrating the potential for extending the upper limit of particle size in flotation by using acoustic sound. Furthermore, mechanical flotation of chalcopyrite particles at various collector dosages (50–150 g/t) was carried out with and without sound. Results showed that the increment of the final flotation recovery was increased with sound at different collector dosages. Overall, acoustic sound has the potential to be used as an effective and versatile method for flotation process intensification.

Aug 24, 2022

By Ping Yang, Tian-bin Li, Min-hui Wu

"The process of filtrate loss of low solid-phase drilling fluid at different content of polyanionic cellulose is investigated by the standard filtration test. The test results showed that when time of filtration is same, the filtrate volume decreases linearly with the increase of content of polyanionic cellulose. When content of polyanionic cellulose is same, the velocity of filter loss decreases nonlinearly with the increase of time and the velocity of filter loss will reach a stable value. The filtrate volume in 7 to 8 minutes can reach half of the total filtrate volume. At the same time, the velocity of filter loss of drilling fluid decreases nonlinearly with the increase of viscosity. When apparent viscosity is between 3.5~4.15 mPa.s, decrease speed of velocity of filter loss is quick. The results are helpful for characteristics evaluation of filtrate loss of drilling fluid and control of filtrate loss.IntroductionDuring the process of drilling, water of drilling fluid can leakage into stratum, the water can result in instability and collapse of borehole wall. At the same time, the original ratio of drilling fluid will change. The density of drilling fluid will increase, the performance of the drilling fluid will change. Controlling amount of filtration is important to drill successfully. The additives of controlling filtrate loss are mainly two types, particle materials and polymer materials. High-molecular polymer is a kind of high-molecular material, has the adsorption effect, high polymer protection, can improve the advantages of slurry viscosity (Xu,2004 and Dehghanpour,2001). Some scholars carried out some study on the polymer material fluid loss agent in recent years, these study mainly focused on CMC, HEC, MHEC, CMHEC, starch and its derivatives(Zhang,2005 and Chevron,2009).About PAC (polyanionic cellulose) as drilling mud additives, a few of scholars carried out some relevant work. Plank (1992) applied PAC into ordinary freshwater drilling fluid and analyzed temperature stability of freshwater drilling fluid. Bennion (2000) applied PAC into drilling fluid and analyzed effect of polyanionic cellulose on strata inhibitory. Huang (2011) analyzed effect of PAC on properties of the high-density water-based drilling fluid. Mahto (2004) applied PAC into fresh water and salt-water drilling fluid and analyzed effect of PAC on rheological properties of the drilling fluid. Wang (2008) applied PAC into alkaline drilling fluid to study various performance of drilling fluid. PAC is a renewable resource and has good application prospect (Ankara, 2005). So it is very important to understand the effect of PAC on filtration process of drilling fluid.The test was conducted by changing the content of the PAC in drilling fluid. The object of this paper is to understand effect of polyanionic cellulose on filtration process of the low solid-phase drilling fluid."

Jan 1, 2017

By Gordon L. Kinney

The only economically important mineral currently produced in Bangladesh was natural gas. Bangladesh was not a world? ranked producer of any mineral commodity, but the possibility of producing and exporting commercial amounts of liquefied natural gas (LNG) was being examined. Proved reserves of natural gas were sufficient to supply most of the country's industrial and domestic heating and electric needs and still support an export-oriented LNG plant. Other mineral production was of virtually no significance to the economy, although there were a few prospects for nonmetallic mineral development. Bangladesh continued to make economic progress during 1978 and into early 1979. Gross domestic product (GDP) at current prices rose from $6.6 billion in 1976-772 to $8.2 billion in 1977?78 and $9.3 billion in 1978.79.2 In fiscal 1979, the economic conditions were favorable until a severe drought hit most of the country. It W88 reported that conditions were the worst in 40 years, and 88 of July 1979, substantial crop losses were predicted. The agricultural sector accounts for over 53% of the GDP and about 75% of all employment. The poor weather will cause economic problems in the form of slower growth, larger trade deficits, and a higher rate of inflation. The 1978.79 statistics showed that real GDP increased just 4%.

Jan 1, 1981

Analysis of the 2001 Australian census data set can be used to gain a detailed insight into the trends and levels of employment in different industry sectors. There is a common perception that employment of geoscientists within the mining industry and indeed across all industries has decreased significantly. However, the data shows that the number of individuals stating that they are geoscientists employed across all industries has decreased by only five per cent from 5336 in 1996 to 5067 in 2001. Within the mining industry (Australia and New Zealand Standard Industrial ClassificationÆs û ANZICÆs mining class), the number of geoscientists employed has decreased by ten per cent from 2701 in 1996 to 2441 in 2001. These figures, while showing a decrease, do not reflect the magnitude of the decrease commonly perceived. However, further analysis shows the number of geoscientists employed in mineral exploration may have decreased significantly more.

Jan 1, 2003

Exploration of a coal deposit provides the data on which a range of mine plans can be developed during project feasibility. The stages of exploration use methods and procedures which initially outline the deposit with more detailed data gathering and analysis of the specific site complexities. The in situ coal resource and reserves are calculated. The mine plan is a function of the mining method chosen and can have significant impact on the recoverable reserves. Other factors which can impact on the recovery of the reserves and the ability to maintain planned production levels are those which were either undetected during exploration or were misinterpreted. Exploration programs should be detailed enough to minimise to an acceptable standard the recognised and potential risks. Past programs which explored to achieve a minimum exploration density required to satisfy measured reserve status have generally proven to be inadequate, placing reserves and production at risk.

Jan 1, 1997

By L. W. Saperstein, M. C. Radomsky, D. L. Passmore, J. D. Bennett

About 60 small surface coal mines in Pennsylvania participated in a program designed to improve safety performance in the workplace. The method involved the use of safety sampling and observation to assess the degree of safety exhibited by workplace behavior and conditions. Data were collected through the use of on-site safety instruments covering seven major occupational positions typical of small surface mines. Workplace events observed (acts and conditions) were assigned a hazard classification. Feedback was initiated to improve safety performance in areas failing to conform to appropriate safety standards. Results suggest that the variety of unsafe acts and conditions associated with the companies observed are extensive. Further, the experiences drawn from this pilot project have proven the need to pursue this behavioral approach. Future research should concentrate on subjecting the present approach to a strict experimental design involving randomly selected “poor risk” mines.

Jan 1, 1987

By J. S. Smart

The six countries which make up the European Economic Community-Belgium, France, German Federal Republic, Italy, Luxembourg and The Netherlands-are populated by about 170 million consumers. Their economic abilities and their standard of living have increased at a high rate during the past few years. Consequently, the policies and trade practices adopted by the group will have International repercussions within the nonferrous Industry whether or not other nations are eventually admitted to the group. Considering the hopeful prospects of only a few months ago, it is surprising that we must now face up to the fact that Great Britain and Norway, in particular, will achieve membership status only after prolonged and difficult negotiations, if at all. However, this is but one of many factors that should remind us that the Common Market is yet in its formative stage and has by no means reached maturity.

Jan 6, 1963

By John H. Ratcliffe, Hans T. Lundberg

In airborne gravity surveys effects of acceleration and irregular movements of the aircraft must be balanced out or overcome. The gradient of vertical gravity is recorded, therefore, by using two masses instead of one. As the amplitude variations are infinitesimal and difficult to measure accurately, at of gradient during flight is positive or negative. The positive portions of the pattern can then be indicated and contoured. Even with these simplifications, the source of energy must be exceptionally stable. General Principles: In the conventional gravimeter the weight of a standard mass is determined at a number of selected points within the survey area. In most systems weight is determined by comparing the gravity pull with extension or torque produced in a wire spring. The instruments employed are sensitive to the slightest movement; they cannot be used on a moving platform unless velocity is kept strictly uniform.

Jan 8, 1959

By Phil Hulse

The Atlanta mine is located in east-central Nevada, approximately 360 km (225 miles) from Las Vegas. It lies in Lincoln County, 116 km (72 miles) south of Ely and 80 km (50 miles) northeast of Pioche. The property is currently operated by the Standard Slag Co. under a joint venture agreement with Bobcat Properties Inc, of Fort Lauderdale, Fla. Operations began in May 1975, and the mill is currently processing 109 000 to 122 500 t/y (120,000 to 135,000 stpy) of gold- and silver-bearing ore. Open-pit mining takes place in a breccia zone that occurs between Ordovician limestones and dolomites on the footwall and Tertiary rhyolites on the hanging wall. The quartz breccia ore is among the most abrasive in the world-shovel teeth must be replaced every week, 19-mm-thick (3/4-in.) steel chutes last about a month.

Jan 9, 1978

By Dadan Munawar, Benny Gunawan

Blasting at Sebesi in Central Tutupan Pit area in South Kalimantan, Indonesia is planned to be using emulsion, where used oil makes up 50% of the total emulsion fuel. The significant amount of used oil from various mining operation units had been of deep concern since it might be reused to implement environmental programs by substituting 50% of fuel with used oil in emulsion, thus decreasing fuel consumption and increasing efficiency by reducing fuel cost. Used oil must pass laboratory test to meet the Indonesian National Standards (SNI) No. 7642:2010 of used oil specification. Other considerations include the location which is adjacent to the mine office facilities with a radius of <1,750 meters (5,741 feet). Thus, appropriate methods must be performed to meet the SNI No. 7571:2010 of vibration threshold in order to implement safe blasting technique and prevent potential damage.

Jan 1, 2015

By D. F. Kaufman, H. R. Spedden, A. M. Gaudin

MANY studies of comminution have been made to ascertain the size distribution of the product and to evaluate the work of comminution in the light of the size distributions of the feed and product. Up to now, these studies have been essentially statistical in character, that is, a certain lot of feed was subjected to comminution in some specified way, and the aggregate product was fractionated into sizes, thereby losing all knowledge of individual relationship of feed to product pieces. Radioactive tracers offer a means to do something in this respect which could not be done before, namely, to follow the rupturing of some particular piece in its normal environment of other pieces. That is, it permits going beyond the usual statistical limitations of size distribution studies to what may be termed a personalized or individualized study. The purpose of this paper is to present some preliminary experiments conducted with this tool. The method employed was to mark radioactively some constituent of a feed. It is possible, of course, to consider the preparation of two lots of material of which one is radioactive and the other is not, and to blend the two ahead of the comminuting step; but to do so is open to the objection that the two preparations may not be identical. Therefore a technique has been chosen that removes this objection by merely taking out a size fraction of a comminution feed, rendering that fraction radioactive by exposure to a neutron flux, and then by returning it to Table I. Size Distribution of Offspring Albite Particles Originally 28/35 Mesh and in Admixture with Other Sizes After Grinding 2 min in a Steel Ball Mill Specific Activity &apos; Cumu- Corrected Distrl- latlve Size for Back- butlon In Distri- Fractlon ground, Weight, Product, button, of Product, cpm/gm g Pctb Pct Mesh (A). (W) (P) (ZP) + 28 0 56.0 0 100.1 28/35 62.6 54.0 24.8 75.3 35/48 62.8 59.4 27.7 47.6 48/65 41.1 53.0 16.2 31.4 65/100 29.6 45.7 10.2 21.2 100/150 23.7 37.0 6.6 14.6 150/200 23.3 25.1 4.4 10.2 200/270 20.1 19.0 2.9 7.3 270/400 17.8 21.2 2.9 4.4 -400 22.9 25.2 4.4 — 100.1 a These activity determinations were made in rapid succession in the order given. The specific activity (Ao) of the active 28/35 mesh fraction of the feed was measured at the beginning, after the measurement on the 65/100 mesh size fraction of the product, and; The end. The decay-corrected activities at those times were 246.7, 241.0. and 236.9 cpm per gm. The weight (W0) of the active 28/35 mesh fraction in the feed was 55.0. b Example of calculation for P in the 65/100 mesh oroduct frac- A W tion; A = 29.6, W = 45.7, Ao = 242.7, Wo = 55.0: P = — x — Ao Wo = 0.102 = 10.2 pet. the remainder of the charge for the comminution experiment. A relatively simple procedure was developed by which albite, containing sodium, was activated in the M.I.T. cyclotron. The cyclotron makes highspeed deuterons which impinge on a beryllium target, thereby producing a concentrated neutron flux. The mineral was exposed to this flux for 2 hr. This treatment changed enough of the sodium to sodium 24 (14.8 hr half-life, 1.4 mev ß) as to make detection and measurement easy. The nuclear reactions taking place were: 11Na23 (n,?) 11Na24 (irradiation) 11Na24 ß,?,? 12Mg24 (decay) The detailed technique of the experimentation was as follows: 40 kg of hand-sorted, lump albite were crushed to pass 10 mesh. After careful mixing of the lot, a screen analysis was made. The whole lot of material was fractionated on standard Tyler screens from 14 down to 200 mesh. Samples for experiments were compounded from these fractions in accordance with the screen analysis. When it was desired to make an experiment in which, for example, the 28/35 mesh size fraction was to be studied, the blend of size fractions was made as indicated above, except that the 28/35 mesh size fraction was added only after irradiation in the cyclotron. The blended charge containing the activated albite was ground for 2 min in a laboratory ball mill with a steel ball charge of controlled size distribution. The ground product was carefully sized on a set of Tyler screens in a Ro-tap. Each size was analyzed for radioactivity by the use of an end-window Geiger-Mueller counter and standard scaling circuit. This analysis was carried out in detail as follows: a 20-g sample was placed in a Petri dish, packed carefully to obtain reproducible geometric distribution with reference to the Geiger-Mueller tube, and the activity was counted for a 2-min period. Several determinations of the activity of the active size fraction in the feed were made at various times to establish the decay in activity with time. Linear interpolation was used to evaluate the activity that the active size fraction in the feed would have had at any given instant. The ratio of the observed activity in a size fraction of the product to the activity that the active size fraction in the feed would have had at the same time gives the fraction in the product size that came from the irradiated size in the feed. The general formula for finding the distribution, P, of a specific individual size fraction in the feed

Jan 1, 1952

By Dong Hoon Han

The simultaneous sulfation by sulhr dioxide and oxygen of CaO and MgO in calcined CMA (calcium magnesium acetate) were investigated. he experiments were carried out in the temperature range from 700 to 830 "C and at the SO2 concentrations of 0.3 to 1 mol %. The oxygen concentration was kept at 5 %. Each sample was calcined completely before the temperature was lowered to the sulfation temperature. According to the ranges of partial pressure of sulhr dioxide and temperature, there exist three regions for the sulfation reaction: region I in which neither oxide is sulfated, region I1 in which only CaO is sulfated, and region 111 in which both oxides are sulfated. It was shown that the MgO in calcined CMA is sulfated at a rate comparable to that of CaO by forming a mixed sulfate phase. Thus, unlike MgO contained in other desulhrization materials, the MgO content in calcined CMA can be fully utilized for flue gas desulhrization.

Jan 1, 1999

By Franco Chiesa, David Levasseur, Bernard Duchesne

A 500kg aluminium AlSi7Mg03 casting has been poured and the metallurgical quality at different locations inside the casting has been thoroughly investigated. It included measuring the local tensile properties (YS, UTS, El) in the T6 condition, the dendrite fineness (DAS) and the level of microporosity. A correlation was found between the microporosity level, the local solidification time and solidus front velocity; this correlation allows to predict the porosity level in large aluminium castings (solidification times between 20 and 200 minutes). Quite expectedly, properties varied widely within the casting and the actual mechanical properties were much less than the "textbook values" based on measurements carried out on separately cast standard specimens. A correlation between the secondary dendrite arm spacing (DAS) and the local solidification time was in keeping with previously published data. Finally the conditions to obtain an acceptable finish on machined surface were determined.

Jan 1, 2014

By David B. Plumeau

The Cayuga Mine, a deep rock salt mining, operation, changed from a standard room and pillar mine design to a yielding pillar/pressure arch design five years ago. In general the roof conditions improved. However, entries adjacent to the abutment pillars continued to fail. It was noticed that where abutment pillars were accidentally "notched" (by driving cross- cuts one cut into the pillars), the abutment entries had better roof conditions than where there were no "notches". Experiments with intentionally notched abutment pillars showed that notching did improve abutment entry conditions. During the past four years notch configuration has been varied to suit local ground conditions. Recently, "pre-cutting" of notches has proven itself as a means of protecting abutment entries under severe ground conditions. As an added bonus, the notches improve productivity by providing more places to work and reduce costs because it is not necessary to bolt the notches.

Jan 1, 1981

By D. H. Forbes, H. M. Manasevit, F. L. Morritz

Single-crystal thin films of molybdenum have been grown. by the pyrolytic decomposition of molybdenum hexafluoride in a hydrogen ambient on various insulating substrates at temperatures front 650° to 900° C. Single-crystal discs of various orientations of magnesium aluminate spinel, a aluminum oxide, magnesium oxide, and the natural facets of beryllium oxide were all observed to exert epitaxial control on the depositing film. Determinations of the crystallographic relationships existing between film and substrates have been made, using X-ray diffraction three-circle goniometry and Laue back-reflection techniques. Using these data, crystallographic overlays have been constructed which suggest a possible interfacial geometry on the basis of a match between metal deposit atoms and metal ion sites in the substrate. A continuing program has been in effect in the Auto-netics Laboratories over the past several years aimed at the development of electronic materials in new and useful forms using chemical vapor deposition techniques. During the course of these investigations, the epitaxy of silicon1"5 and tungstenep7 on single-crystal metal oxide insulators was studied extensively. The deposition of molybdenum is a logical extension of the tungsten work since the crystal structure is identical and the lattice dimensions differ by less than 1 pct. The pyrolytic decomposition of molybdenum hexafluoride in hydrogen was used to grow molybdenum films on the oxide substrates AlzOs, MgA1~04, MgO, and Be0 at from 650" to 900°C, depending on the substrate material. Under the experimental conditions to be described, monocrystalline films of controlled orientation were obtained. The materials investigated and their crystal structure are listed in Table I. EXPERIMENTAL The molybdenum depositions were effected by the hydrogen reduction of molybdenum hexafluoride (MoFe) in a flowing system of hydrogen at atmospheric pressure. The schematic of the apparatus is shown in Fig. 1. The hydrogen, purified by passage through a heated palladium thimble, was mixed with the vapor of the liquid MoFe maintained in a steel bottle at room temperature (25°C). The mixture was passed over the substrate, which was heated by rf induction of a sup-

Jan 1, 1969

By V. Sovmen

The gold-ore Olympiada deposit is located within the Yenissei range (Krasnoyarsk Region, Russia). Primary sulphides ores are metasomatic changed rocks, mica-calcite-quartz structure with impurity amphiboles, chlorites, carbon, the rare thin grains of sulfides (up to 3%~5%) and native gold. The structures of ores are fine-grained, prevailing texture of ores - interspersed, vein-interspersed, band-interspersed, veinlet. The most important minerals in the deposit are: gold, arsenopyrite, pyrrhotite, antimonite, Sb-sulphosalt, quartz, muscovite, calcite, siderite, titanium minerals, chlorite and minor sulfides like chalcopyrite, galena, sphalerite, etc. A common problem in mineralogical studies applied to mineral processing (concentration, cyanidation, etc.) is the characterization of gold in ores and technological products. This paper discusses the behavior of minerals during technological process at operating factory in Olympiada Mine and gold distribution in the ores and products. For the mineralogical characterization of minerals ? combination of analytical techniques was used. Gold is encountered in the primary ores as free grains among rocks, growth with sulfides and nonmetallic minerals, inclusions in sulfides, sulphosalt, and nonmetallic minerals. The gold-sulphide ores of Olympiada deposit can be quite complicated for enrichment. With the purpose to increase the extraction of metal from concentrates by liberating the dispersed gold, forming inclusions in sul-fides, there is used technology of biooxidation of flotation concentrates in Olympiada Mine. Gold and the basic ore-forming minerals in the ores feed, sulphidic concentrates, biocakes, tailings of concentrates of flotation and products of hydrometallurgical leaching have been studied in the mineralogical research. During researches it is established that pyrrhotite was completely oxidized while arsenopyrite was oxidized almost completely in the bacterial oxidation process. Pyrite and antimony minerals behave similarly and were oxidized only partially. The main oxyhydroxides in the bacterial oxida-tion process are goethite, limonite and jarosite. The results of mineralogical researches showed reasons of losses of gold during hydrometallurgical enrichment.

Jan 1, 2014