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By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite,(Cu2S) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical equilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite (CuzS) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical eqUilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By V. A. Mironenko

The combined study of ground water regime and rock deformations has resulted in the theoretical substantiation of the common principles for analysis of the hydrodynamic and geomechanical processes Within the scope of unique scientific direction -hydrogeomechanics (Mironenko and Shestakov, 1974). The hydrogeomechanical models are widely used now for the analysis and forecasting the extremely important processes connected with the safe and efficient mining operations, as well as with the protection of geological medium. Among these processes are: -deformations of the open-pit slopes and spoil dumps; -consolidation of rocks due to the ground-water pressure drop; -water-end-rock material inrush into mine workings caused by deformations of the undermined rock mass; -geodynamical processes due to the changes in ground water regime; -artificial hydrofracturing in rocks; -transformations of clay linings under the tailing ponds and other technical water basins.

Jan 1, 1990

By Kenneth N. Weaver

Introduction and Historical Background State Geological Surveys have been deeply involved in industrial minerals from their inception beginning in the first half of the 19th Century. To Massachusetts belongs the credit of having carried out the first Geological survey under state auspices on the Western Hemisphere. One of the causes leading up to this survey was. Governor Lincoln's message to the legislature of May 29, 1830, from which I quote in part: "Much knowledge of the natural history of the country would thus be gained (from a geological survey), and especially the presence of valuable ores, with the localities and extent of quarries and of coal and lime formations, objects of inquiry so essential to internal improvements and the advancement of domestic prosperity, would be discovered.". Similar phraseology is present in practically all of the initial organic acts creating the first State Surveys. High on the list of priorities for these embryo surveys was an inventory of the mineral resources of the State with particular emphasis on the industrial minerals. Prom these early beginnings, the state surveys have developed a great wealth of geological data either directly or indirectly relating to the development of mineral resources. One can gain some conception of the effort that state surveys today place on industrial minerals studies by noting the projects in which they are engaged as reported in the State Geologists Journal. In 1970, for example, approximately

Jan 1, 1972

By R. H. Reist, R. D. Dey, V. Castranova, J. P. Durham, Y. Rojanasakul

"Silicosis is a fibrotic pulmonary disease produced by inhalation of silica-containing dusts (Peters, 1986). Chronic silicosis may develop 20-40 years after initial exposure to crystalline silica, and the disease may progress from a simple to a complicated form. Few symptoms are evident in simple silicosis with pulmonary function being relatively normal. However, chest radiographs reveal small rounded ·opacities in the upper lobes of the lungs. These silicotic nodules consist of collagen arranged in a distinctive circular pattern. As fibrotic changes become more severe, the disease progresses to complicated silicosis (progressive massive fibrosis). Complicated silicosis is associated with shortness of breath and decreases in pulmonary function characteristic ofrestrictive lung disease. Chest x rays reveal numerous large silicotic nodules which may be associated with scar emphysema. Several mechanisms have been proposed to explain the cellular events which result in silica-induced lung damage and fibrosis (Lapp and Castranova, 1993). They include: ( l) direct cytotoxicity of silica, (2) activation of oxidant and enzyme release from alveolar macrophages, (3) recruitment and activation of polymorphonuclear leukocytes, and (4) stimulation of fibroblast proliferation and collagen synthesis.Tetrandrine is a bisbenzylisoquinoline alkaloid derived from the Chinese herb Radix Stephania tetrandra. It has a molecular weight of 622.73 and an empirical formula of C38H420 6N2. The chemical structure of tetrandrine has been published previously by our laboratory (Castranova et al., 1991 a). Its structure is characterized by methoxy groups at C7 and C12 , uncharged nitrogens at N2 and N’2 and two 17-carbon ring members connected by a double oxygen bridge between Ca-C7 and C11-C12. Tetrandrine has been shown to reduce both silica-induced fibrosis and the elevation of lung collagen content in rats (Huang et al .. 1981; Yu et al., 1983; ldel, 1987). Furthermore, tetrandrine has been used as an antifibrotic agent in Chinese clinical trials (Li et al.. 1981 ). Preliminary results suggest that administration of tetrandrine to patients with silicosis results in substantial improvement of symptoms, increases in diffusion capacity, and decreases in the size of shadows on lung x rays."

Nov 1, 1995

By Carl H. Beal

The oil industry in the United States is further advanced than in any other country, because of American initiative and the development of industries dependent in some way on petroleum or its products. For this reason the output has constantly increased (fig. 1), and as a result this country has produced more than half of the total output of the world. Trw total past output of the world is approximately 7,000,000,000 barrels of 42 gallons each; of this the United States produced about 4,000,000,000 barrels, or about 57 per cent. The limit of production in this country is being approached, however, and although new fields undoubtedly await discovery, the yearly outpnt must inevitably decline, because the maintenance of a given output each year necessitates the drilling of an increasing number of wells. Such an increase becomes impossible after a certain point is reached, not only because of a lack of acreage to be drilled, but because of the great number of wells that will ultimately have to be drilled. According to figure 1, the daily production per well each year has increased during the last few years. However, this increase is abnormal, being caused by the new pools brought in. Although such a condition may continue for several years, the average production per well will finally begin to decrease on account of the lack of new pools to make up for the normal decline in production of the old ones.

Jan 1, 1919

By T. F. Torries

The primary merit criteria used by the mining industry is internal rate of return (IRR) rather than net present value (NPV) although NPV is favored by academicians. This paper discusses the problems with IRR and NPV and compares the multi-goal nature of decision makers and their need for information with the characteristics of NPV and IRR. Conclusions are that both NPV and IRR are needed for investment ranking, that NPV suffers the same multiple root problem as does IR.R, and the determination of incremental IRR to reach NPV consistent project ranking is misguided in practice.

Jan 1, 1997

By M J. Pejovic, S BoÜevski, I Miljanovic, M Hudej, A Milutinovic, A Petrovski

The paper deals with the problem of managing the supplies of consumables (energy resources, lubricants, explosives, explosive supplies, tires, spare parts, etc) in mines. After the introductory remarks and comments, a general stochastic model of supply, relating in general to the dynamic programming method is presented. A selection of stochastic supply model for experiments and research by the authors of this paper is not a coincidence, based on of their long experience, showing that this type of model is the most suitable to provide support for decision-making and management of supplies of consumables in mines.In order for the problem?of?consumables?supply?management to be reviewed, in whole and objectively from the aspect of risk, experimental tests of the stochastic model in real conditions were performed at the limestone open pit mine æZelenikovecÆ near Skopje, the capital of Macedonia. The scope of the experimental research enabled reliable analysis. The results obtained confirm the efficiency and reliability of the stochastic model and two separate manipulative-operational positions regarding its application, which may have an important influence on the optimisation of supplies.

Sep 26, 2011

By R. P. Foster, ed.

The short selection of papers in the special issue provides an insight into the level of exploration activity in Africa and the science and technology that are underpinning it. A country-by-country survey is followed by discussion of geochemical exploration in tropical soils, the Liptako region of Niger, structural styles of deposits in Zimbabwe's Bulawayo-Bubi greenstone belt, structural controls in Zimbabwe's Eldorado shear zone, the regional framework for deposits in the Odzi-Mutare-Manica greenstone belt of Zimbabwe and Mozambique, and the Iperindo deposit in Nigeria's Ilesha schist belt

Apr 1, 1996

By B L. Coulter, E Wightman, A S. Burrows

With their commitment to sustainable development in an increasingly carbon-constrained world, many resources companies are focused on reducing the energy required to create their final products. In particular, the comminution and smelting of metal-bearing ores are both highly energy-intensive processes. If resource companies can optimise the energy efficiency across these two processing stages, they can directly reduce their overall energy consumption per unit mass of metal produced and thus reduce their greenhouse gas footprint. Traditional grinding and flotation models seek to improve the efficiency of mineral processing, but they do not consider the energy used by downstream metal production, eg smelting and refining. Concentrators and smelters individually may be running efficiently, but are they optimising energy consumption of the overall system? A key step towards answering this question is to understand whether it takes less energy to remove an impurity in the concentrator or the smelter. Analysis of the complete concentrator û smelter process chain may show that there are times when the concentrator should use more energy to reduce the overall energy requirements across the mill and smelter. The new methodology discussed here will integrate downstream processing energy with mineral processing energy, to find the overall most energy efficient circuit design and operating strategy. The proposed methodology includes: determining what grade and recovery positions can be achieved in the concentrator by using different combinations and amounts of grinding and regrinding, thermodynamic calculations of the energy used to process the different concentrate grades to metal, and integrating the concentrating and smelting models to find the lowest total energy for the system. A case study which investigates the effect of increasing regrinding energy on the overall mineral processing û smelting energy consumption is presented. For the copper-nickel sulfide ore investigated the addition of regrinding results in 11 per cent less energy being used in the overall concentrator û smelter process chain per tonne of metal produced. Although regrinding is often seen as an energy-intensive process, in this case study the use of 1 kWh of energy for regrinding reduces the overall energy consumption by 12 kWh. The new mill to melt methodology will allow companies to model energy consumption from mill to smelter with a view to reducing the energy-intensity and greenhouse gas footprint of their processing and smelting operations.

Jan 1, 2009

By E. P. Youngman

Titanium ranks as one of the more abundant elements, is widely distributed, and occurs in concentrated form in numerous deposits. This substance was discoveres 140 years ago; but despite the efforts of metallurgists and chemists to find a place for it in industry, only within the last 10 or 15 years has the increased use of titanium pigments provided any extensive outlet for titanium ores. Even to-day titanium is confined to a few highly specialized industrial applications. The metal itself is now quoted regularly in trade journale, but scarcely yet can it be said that the production or use of the metal. has progressed very far beyond the laboratory stage. Ferroalloys containing the element were largely used for a time, especially in connection with the manufacture of Bessemer steel rails; but as American rail- ways adopted open-hearth rails in preference to Bessemer rails, the demand for the alloys in the rail manufacture gradually dwindled into insignificance. New outlets for ferrotitanium have been found in the steel industry; and the production of titanium alloys, both in the United States and in Europe, has increased in recent years. By far the largest use of titanium at the present time, however, is in pigments. The manufacture of titanium white began in Norway, but at present the United States is the leading producer. One of the two companies now operating in the United States is also the leading factor in European production. Although titanium occurs, in many minerals, the principal commercial sources are rutile (the natural oxide, Ti02) and ilmenite (iron-titanium oxide, FeO. TiO2). The latter is a coal-black mineral, but it is the one used in the manufacture of the titanium white of commerce, as well as in the manufacture of ferroalloys and arc-lamp electrodes. Rutile, the natural oxide, is not pure white and, being less common in nature, costs more; it is, therefore, reserved for use in the manufacture of titanium chemicals employed in relatively small amounts in dye works and bleacheries and for sundry minor purposes. This paper summarizes the titanium industry, with special reference to its economic aspects. It is offered as a survey of current trade literature and as a digest of material in the files of the bureau and is presented in response to numerous inquiries from prospective producers as to ways and means of exploiting deposits. (At present, much of the ilmenite consumed in this country comes from overseas, principally from British India..). A forthcoming circular, devoted to deposits of titanium-bearing ores, deals with foreign and domestic sources of supply.

Oct 1, 1930

By Richard W. Smith

THERE are three distinct varieties of phosphate rock, in Tennessee, known commercially as: (a) the "brown" rock, which is the residual pro- duct of the weathering and natural concentration of certain phosphatic Ordovician limestones; (b) the "blue " rock, which is an unaltered phosphatic stratum of Mississippian or Devonian age; and (c) the "white" rock, which is the result of chemical replacement and deposition. Before 1894, South Carolina and Florida had supplied most of the phosphate of the United States, South Carolina leading until that date and Florida from then until the present time. In December, 1893, the blue phosphate of Tennessee was discovered almost simultaneously on Swan Creek, in Lewis County, by two independent parties-by one as the result of a careful and systematic search for a workable deposit of the long known kidney phosphate, and by the other through mistaking it for a "bloom" of coal. Leases were taken and, with further prospecting disclosing other deposits in the region, the development progressed as rapidly as 'could be expected without railroad transportation

Jan 1, 1924

By Frederick Bloetscher

Means of improving the U.S. Bureau of Mines Brattice Window Method have been investigated by Goodyear Aerospace Corporation (GAC). An extensive series of laboratory tests at GAC and a series of tests in three operating coal mines of the Bethlehem Mines Corporation were conducted. The GAC laboratory tests defined the window coefficients and the accuracy of the method using different measuring techniques for a range of window sizes and shapes with window areas from 0.0873 to 4.0 square feet for flow velocities through the windows of from 100 to 1000 FPM. The results indicated that for the range of window sizes and window flow velocities investigated a single window coefficient value can be used with little error for each window size and for each flow direction, for the investigated range of window flow velocities. The mine tests developed techniques for quickly erecting the Temporary Test Stopping (TTS) in a cross-out, making the measurements, taking down the TTS and moving it and the test equipment to the next cross-cut. The time period for the total cycle ranged from 15-45 minutes depending on the properties of the cross-cut's surfaces. The total weight of the TTS and test equipment carried by the two miners conducting the tests was approximately 40 pounds. Correlation was obtained between the sum of the leakage values past 10 consecutive individual stoppings using the brattice window method and the value for the difference in the airway flow values before and after the 10 consecutive stoppings when the value for the sum of the leakages for the 10 was significant when com¬pared to the airway flow values. The mine tests reiterated the importance of using the largest TTS window(s) consistant with making accurate anemometer measurements for the best results with the brattice window method.

Jan 1, 1978

By Goran Mathisson

In several investigations the correlation has been studied between the fuel consumption and the reducibility of the charged material in the zone of indirect reduction in the blast furnace (1, 2, 3, 4, 5). It has been found that increased reducibility allows greater gas utilization which accordingly lowers the fuel consumption. In direct reduction units this relation has not yet been fully established partly owing to the lack of accurate test methods and experience with different materials as regards reducibility. However, since the production rate in a direct reduction unit is closely related to the time required to reach high degrees of reduction, the reducibility must be regarded as one of the most important properties of the material.

Jan 1, 1979

By Arash Khosravifar, Nason McCullough, Stephen, Milad Souri, Scott Schlechter, E. Dickenson

The results of five centrifuge models were used to evaluate the response of pile-supported wharves subjected to inertial and liquefaction-induced lateral spreading loads. The centrifuge models contained pile groups that were embedded in rockfill dikes over layers of loose to dense sand and were shaken by a series of ground motions. The p-y curves were back-calculated for both dynamic and static loading from centrifuge data and were compared against commonly used API p-y relationships. It was found that a significant reduction in ultimate soil resistance occurred in dynamic p-y curves in partially/fully liquefied soils as compared to static p-y curves. It was also found that incorporating p-multipliers that are proportional to the pore water pressure ratio in granular materials is adequate for estimating pile demands in pseudo static analysis. 1. INTRODUCTION Liquefaction-induced ground deformations can cause severe damage to pile-supported wharves and other waterfront structures. A common approach in analyzing the lateral behavior of piles against seismic loads is using the beam on nonlinear Winkler foundation (BNWF) or p-y spring analysis. One common p-y relationship for sand is the one proposed by the American Petroleum Institute, also known as the API sand model (API 1993). While the API sand model was originally developed for the static loading conditions, it is common to modify the API sand curves for the effects of cyclic loading. However, there is no consensus on how to modify the static p-y curves for the effects of liquefaction and pore water pressure generation in loose granular soils. In previous studies, p-y springs of piles in liquefying soils were back-calculated from case histories, centrifuge model studies (e.g., Wilson et al. 2000; Brandenberg et al. 2005; Abdoun et al. 2003), full-scale tests (e.g., Rollins et al. 2005; Chang and Hutchinson 2013), and numerical analyses (e.g., McGann et al. 2011). In general, these studies found the softening effects of soil liquefaction on p-y curves, as well as a hardening behavior attributed to the dilative response of the liquefied soil around the pile. However, these studies provide varying recommendations on how to modify the static p-y curves to capture this complex behavior. Some design guidelines propose softening the static p-y curves using p-multipliers (e.g., Caltrans 2012). Other studies propose an upward concave shape for p-y curves in liquefied soils (e.g., Franke and Rollins 2013; Chang and Hutchinson 2013).

Jan 1, 2019

By John E. Miller

Absolute viscosity values for gases usually are determined with a capillary tube viscosimeter, One of the correction factors applied to the experimental data is that for nonuniformity of the capillary bore. This report contains useful analytic expressions of the nonuniformity correction for the following cases: ellipse, cone, sine wave, sawtooth wave, square wave, and the general case. The methods herein described are applied to estimate the nonuniformity of a section of stainless steel capillary tubing to be used at the Bureau of Mines Helium Research Center. Several other examples are given to illustrate the usefulness of the present results.

Jan 1, 1967

By F. M. Doyle, G. Sidhu, A. J. Dussault, A. Raygani

There is a growing demand for rare earth metals for use in high strength permanent magnets, most notably Nd2Fe14B. Rare earth metals are extremely reactive, with reduction potentials around -2.5V SHE, and are conventionally produced by molten salt electrolysis. The current work was done to investigate an earlier report of electrodeposition of a neodymium ferroalloy from aqueous solution, to determine whether this approach could be an environmentally and economically competitive commercial approach for producing feedstock for permanent magnets. Such a process would be analogous thermodynamically to the Castner- Kellner process, in which aqueous sodium chloride brine is electrolyzed in cells with mercury cathodes. Metallic sodium forms an alloy (amalgam) at the cathode, thereby lowering the activity of the metallic sodium significantly below unity and making the reduction potential of sodium significantly less negative than the standard reduction potential. Here we report the effects of Nd/Fe ratio in the electrolyte, current density, temperature and two different complexing agents, glycine and cysteine, on the composition and morphology of the electrodeposits, along with current efficiency. The energy needed to produce neodymium as Nd:Fe alloys by aqueous electrodeposition was compared with values estimated for production by molten salt electrolysis and the thermodynamic energy requirement.

Jan 1, 2014

By Robert Slivinski, Kyle Hobbs, Michael Stern, John Willox, Brad Jewson

Prairie Mines & Royalty Ltd. produces over 12 million tonnes annually of thermal coal for TransAlta’s Sundance and Keephills power stations from the Highvale Mine. This opencast mine is next to a lake and is surrounded by cottages and farms, which means that blast vibrations and air overpressure have to be kept to a minimum.

Jan 1, 2008

By K Ellis, B Lumsden

A full-scale statistically-based on/off plant trial of a new flotation conditioning technology designed to improve fine mineral recovery was undertaken to determine whether the recovery of selected fine sulfide minerals can be increased. The technology is selective for certain sulfide minerals only, including chalcopyrite and sphalerite. The technology has been shown to selectively aggregate the fine chalcopyrite and sphalerite minerals giving increased flotation recovery. The plant trials have shown an increase in the mineral recovery, without decreasing selectivity. Size by size recovery shows a significant increase in the fine (

Jan 1, 2005

By David De Klerk, Maximilian Richter, Thirunavukkarasu Pathmathas, Indresan Govender

We consider the average power dissipation distribution for dense granular flows of an idealised mono-sized charge (5 mm glass beads) in a 300 mm diameter tumbling mill operated in the cascading-to-cataracting Froude regime. By combining the inherent frictional nature of particles within a dense flow regime and noting that tumbling mills are typically characterised by collisional and turbulent stresses, we derive the power dissipation distribution for athermal boundary conditions. The input data to the model (velocity, solids concentration, pressure and flow depth) are obtained directly from non-invasive measurement using a nuclear imaging technique: Positron Emission Particle tracking (PEPT). The power dissipation due shear stresses is shown to be the dominant mode of dissipation in the tumbling mill with up to two orders of magnitude difference between pressure induced dissipation and shear.

Jan 1, 2014