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By Pedro Jorge Walburga Keglevich de Buzin

The steel production in mini mills generates several process residues, among them there is the electric arc furnace dust (EAFD). This residue has as main elements Fe, O, and Zn, being classified as hazardous by the presence of Pb and Cd. Thermodynamic studies related to the formation of mineral species containing Fe, O and Zn elements were carried on due to the influence of these compounds in hydrometallurgical EAFD recycling processes. In recent years, a rise in the chlorine content of this residue was observed, mainly motivated by the increased use of scrap with polymeric impurities containing this element. In this work, based on computational thermodynamics tool FactSage, a general overview of gaseous and minerals species (found in EAFD) formed by Fe, Zn, O, Cl, H and C is shown – representing the organic origin of chlorine. For this study, the PVC polymer was used as the chlorine carrier substance which contaminates the EAF load.

Jul 30, 2018

Jan 1, 1922

Jan 1, 1922

By D. J. Parker, D. Harrington, L. H. Harrison

"INTRODUCTION The necessity for protection against the hazards of lightning manifests itself from time to time in the mining industry by reason of loss of life, damage to electrical equipment, fires in surface structures at mines, and accidents in the handling and use of explosives. This paper is intended to assemble, correlate, and present some of the salient points embodied in the available literature on the subject and at the same time give some factual data concerning instances of such loss of life and damage to property, with special application to the mining industry.The annual loss of life and destruction of property by lightning is considerable; the former may be prevented to a limited extent, though use of common sense as to exposure is required and not always followed; the latter can be prevented to a considerable degree. The manufacturers of electrical equipment, through improved types of lightning arresters, have done much toward the protection of electrical equipment, with consequent safeguarding of life and of property. Education based on unfortunate experiences has gone far to discourage the handling of explosives and blasting accessories during thunder storms, especially in open pits and quarries, and to a much smaller extent in underground workings. The lowly lightning rod plays an important role in the protection of certain types of buildings (especially isolated buildings), stacks, monuments, and other structures.LIGHTNING PHENOMENAIn 1751, Franklin proved that, lightning was simply a visible display of electricity - an extended spark; and until a generation ago little had been added to his exposition to define the various phases of the phenomenon. Matters pertaining to lightning are discussed in the following references:"

Apr 1, 1948

By Robert M. Becker

The evaluation of existing rock stresses from measurements of the change in diameter of a borehole that is stress relieved by overcoring has become a common practice, The stress evaluation has been generally based ,on isotropic relations whereas rock in varying degrees is anisotropic. A plane elasticity solution for a circular hole along one axis of an orthotropic medium is adapted for evaluation of in situ stress from borehole deformation measurements. A consistent triaxial testing approach for determining elastic properties of the overcore is also outlined. Comparison of isotropic with anisotropic interpretations of the state of stress show that large errors in evaluation may occur if the anisotropic character of the rock is neglected.

Jan 1, 1967

By C. Özgen Karacan

This study presents the results of core-log analyses from the exploration boreholes, the analyses of face advance rates, and the results of downhole monitoring studies performed in gob gas ventholes for calculation of changes in hydraulic properties in the longwall overburden at a mine site in southwestern (SW) Pennsylvania section of Northern Appalachian Basin. In the ?rst part of the study, coal measure rocks in overburden strata were analyzed and the locations where possible fractures and bedding plane separations would occur were evaluated. In the second part, the hydraulic conductivities were computed by two different slug test analyses methods using the water level changes measured in gob gas ventholes as longwall face approached. Hydraulic conductivities were analyzed with respect to the changes in overburden depth, the locations of the borehole, and mine face advance rates. These data were used to interpret the potential productivities of the gob gas ventholes as a result of fracturing and changes in hydraulic conductivities. The general results showed that the probability of fracturing and bedding plane separations in the overburden increase between strong and weak rock interfaces. Also, the probability of bedding plane separations increases as the interface is close to the extracted coal seam. Evaluation of slug tests showed that the hydraulic conductivity developments in the boreholes and their potential production performances are affected by the underground strata and the roof materials. In situations where the roof material is stiff and thick, the development of high permeability fractures around the borehole will be less. Results also indicated that borehole location with respect to face position affects the fracturing time and permeability evolution as well. Greater overburden depths generally cause earlier fracturing as longwall face approaches, but eventually result in lower hydraulic conductivities and potentially less effective boreholes. Increasing mining rates also resulted in generally lower hydraulic conductivities in the overburden. The results of this study were intended to improve the interpretation of gob gas venthole performance and to provide better siting of these boreholes.

Jan 1, 2009

By Alexander E. McHugh

A study of some variables affecting the recovery of molybdenum from oxidized molybdenum minerals was made. The effects of variations in contact time, temperature, pulp density, particle size, and solvent concentration on the recovery of molybdenum using acid and alkaline solvents were investigated. Chemical analyses, screen analyses and microscopic examinations were made and the presence of important elements determined. A hydrometallurgical method was developed to recover the molybdenum from the oxidized molybdenum ore by simultaneous dissolution of the molybdenum with sulfuric acid, adsorption on activated charcoal and flotation of the charcoal. The molybdenum was extracted from the activated charcoal with sodium hydroxide, precipitated with calcium hydroxide as calcium molybdate and this regenerated sodium hydroxide for additional stripping. A solvent extraction method, using mines, was also studied to recover molybdenum from both alkaline and acid molybdenum solutions. Satisfactory results were obtained.

Jan 1, 1967

By Basant L. Tiwari

An electrolytic process, based on a three-layer concentration cell, to extract magnesium from commercial aluminum alloy scrap has been examined. The process was repeatedly tested at 1025 K with two cells of d1fferent sizes, 0.6 kg and 5 kg feed aluminum, to have a better understanding of the opera ting parameters and evaluate the scale-up potential. In both cells, the magnesium content of the scrap was selectively reduced ?from 1. 1 to less than 0.1 wt.% at anodic current dens-Hy as high as 1. 1 A/cm2 with current efficiency exceeding 85%. Magnesium was recovered in the form of salt coated globules. Comparison of performances for the two cells suggests that the process can be scaled up. With further development, this process could become a viable alternative for demagging secondary aluminum.

Jan 1, 1985

By Tai Luu, Michael McNicholas, James C. McIntyre

The Jersey City Municipal Utilities Authority (JCMUA), discovered that an existing sewer pipe had collapsed under the New Jersey Transit Conrail Railroad between Pine Street and Ash Street in Jersey City New Jersey. Immediate action was taken to abandon the pipe in place and install a new sanitary sewer. The borings showed 10-20 ft (3.04 m.- 6.09 m) of competent fill overlaying approximately 8 ft. (2.44 m.) of compressible peat and organics. Groundwater was at 8 ft (2.44 m) below ground level. The poor condition of the soils at subgrade could not withstand the extreme weight of the jacking machine or the thrust force required to push the casing from the launching pit to receiving pit. The support of excavation (SOE) would therefore not only need to retain the soil to allow the jacking equipment to reach subgrade at 14 ft (4.27m) below working grade, but also the back wall of the SOE would need to be sufficiently robust to function as the reaction block for jacking operations. The alignment and allowable tolerance for the jacked casing was minimal, therefore the performance of the SOE was extremely critical to the success of jacking operations. This paper will discuss in detail the design concepts that were developed and implemented by the team to overcome these obstacles. HISTORY The discovery of a collapsed section of an existing sanitary sewer led the Jersey City Municipal Utilities Authority to act on an emergency contract. The project design team was tasked with developing an abandonment plan for the broken pipe and installation of the new pipe through challenging geology. The new 180 ft.(54.96 m) long, 54-in. (1.37 m) . diameter sewer pipe was designed to be contained within a 72-in. (1.83 m) protective steel casing. The installation of the new sewer pipe would require a detailed understanding of the geology. The geotechnical subcontractor assembled a subsurface investigation report on November 2nd, 2017. It was quickly realized that the only way to replace the pipe was with a jacked pipe system since the large grade change and the Conrail Right of Way created no other alternative. Delaying or closing the railway was absolutely not an option as that particular railway served as the main heavy-haul route to and from Jersey City. It became apparent that a major obstacle to pipe jacking was the challenging geology present across and beneath the proposed sanitary sewer. The following challenges faced the design team prior to the installation of the replacement pipe:

Jan 1, 2019

A symposium on pneumatic transportation of solids was held at Morgantown, W. Va., October 19-20, 196'), under the cosponsorship of the Institute ref Gas Technology. Chicago, Ill., and the Bureau of Mines. Objective of the symposium was to present information on developments and projected programs in the technology of feeding, transporting, recompressing, and utilizing gas-solids mixtures Dr. Henry R. Linden, Director, Institute of Gas Technology and Harry Perry, Director of Coal Research, Bureau of Mines, in the initial addresses at the symposium welcomed more than 140 representatives of industry, educational institutions, and government from 16 states, Canada, Great Britain, etc.

Jan 1, 1966

A symposium on pneumatic transportation of solids was held at Morgantown, W. Va., October 19-20, 1965, under the cosponsorship of the Institute ref Gas Technology. Chicago, Ill., and the Bureau of Mines. Objective of the symposium was to present information on developments and projected programs in the technology of feeding, transporting, recompressing, and utilizing gas-solids mixtures. Dr. Henry R. Linden, Director, Institute of Gas Technology, and Harry Perry, Director of Coal Research, Bureau of Mines, in the initial addresses at the symposium welcomed more than 140 representatives of industry, educational institutions, and government from 16 states, Canada, Great Britain, etc.

Jan 1, 1966

By Andrew M. Wala

The determination of air quantity needed to dilute the exhaust gases to a safe level has to be individually evaluated for particular cases. The diesel powered machines are doing some specific operations in the cyclic order required by the technical process. The dynamics of this process in certain conditions has an essential influence on environmental health conditions in the working area. The main purpose of this paper is to show, using computer simulation, how the movement (dynamic) of diesel vehicles effects environmental health standards and also how to determine the required air quantity for certain conditions

Jan 1, 1983

By E. A. Sondreal

The Bureau of Mines investigated the use of lignite char for producing carbon disulfide; CS2 production rates were as high as when wood charcoal was used as raw material. The maximum space velocity for CS2 produced in the bench-scale study was 9,280 hour-1, reacting sulfur and lignite char at 792° C. The reaction temperature and the temperature at which the char was carbonized were the two most important factors in determining CS2 production rates. Increasing the carbonization temperature in nitrogen from 400° to 900° C advanced the temperature at which carbon disulfide was first produced from 550° to 850° C. The average activation energy for reacting chars with sulfur was 44,000 cal/g mole. The reaction was first order with respect to the partial pressure of sulfur. Increasing the rate of sulfur admission caused a decrease in rate of production at otherwise similar conditions. Rates were not affected by either char size or sodium carbonate catalysis. High space velocities at moderate temperatures using inexpensive lignite chars could offer an economic advantage in the manufacture of carbon disulfide provided that yields were attractive.

Jan 1, 1967

By John W. Harshbarger

The Upper Santa Cruz Groundwater Basin lies in the drainage area of the Santa Cruz River in Arizona, and extends upstream from the community of Rillito to the international boundary, see Figure 1. The principal water use area lies between and includes the cities of Tucson and Nogales. A subsurface geologic barrier near Rillito provides a reasonable dividing line between the groundwaters of the Upper and Lower Santa Cruz Basins. The Upper Basin contains the Tucson and Sahuarita-Continental critical ground- water areas. The Tucson Water Use Area encompasses the Tucson metropolitan area and extends from the northern boundary of the Basin south to the boundary between the Tucson and Sahuarita- Continental critical groundwater areas near San Xavier. The San Xavier Use Area is the San Xavier Indian Reservation. The north and south boundaries of the Continental Use Area coincide with the limits of the Sahuarita-Continental critical groundwater area. The first study of groundwater in this valley was initiated by Dr. G. E. P. Smith in 1905 and the results were published in 1910, followed by a series of bulletins of the Arizona Agricultural Experiment Station, University of Arizona, covering the general field of groundwater development and utilization. Beginning in 1939, the Ground Water Branch of the United States Geologic Survey, in cooperation with the Arizona State Land Department and the Arizona Water Commission (AWC), have published a series of bulletins concerning groundwater occurrence and utilization in various areas of the state. In 1975 and 1977, the AWC published the "Arizona State Water Plan" (1), comprising a detailed inventory of water availability and use in the State of Arizona, and a study of alternative futures.

Jan 1, 1979

By O. T. Berge

Development and production from open cut mines continued its vigorous growth trend during the year 1968. Material handling and transportation were again exposed to the use of larger equipment with shovels, trucks and front end loaders leading the way. Highlights of World Mining Activities Africa: The Anglo American Corp. opened a new high-grade copper mine in Zambia during the year. In Angola, the Companhia Minera do Lobita planned a 3 million ton iron ore production for 1968 from new mines which will ultimately produce 5 million tons per year. A feasibility study of Bethlehem Steel Co., for the development of large high- grade iron ore reserves in Gabon, was in final stages of completion this year and Pickands Mather and Co. continued its investigation of iron ore deposits along the Ivory Coast.

Jan 2, 1969

By Benjamin P. Hay

Complexation of a metal ion to a ligand often results in structural changes that introduce steric strain within the ligand. A design criterior:1 for ligands that will complex metal ions more strongly is to choose Iigar:1d architecture, that minimizes this strain. This paper describes how molecular mechanics models can be used to define the degree of ligand binding site organization in terms of' ,strain energies associated with conformational reorganization and distortion of the binding conformer. This approach yields a method to predict how modifications to ligand structure will affect metal binding affinity.

Jan 1, 1999

By P. C. Thakur

The productivity in coal mines, measured in terns of the output per manshift depends largely on the efficiency and speed of men and materials transport between working faces and the surface. The mechanization of coal winning and material handling processes has led to a great rise in the mine productivity (1). Early applications of power in U. S. coal mines were mainly electrical. The excellent traction available with the DC motor and the ease of the distribution of the DC power have made trolley wire installations for haulage very popular. In shallow mines with very limited emissions of methane it did not constitute a major hazard but as mine depths increased and corresponding emissions of methane also increased fire and methane ignition hazards have become very serious. Conveyors have proved economic where intense mechanization of coal faces generates a large output of coal from a single face, but the fire and respirable dust hazard associated with them are no less serious. Recognizing these shortcomings, the Federal Coal Mine Health and Safety Act of 1969 laid down numerous provisions for the safe use of trolley-wire haulage and conveyors (2) which generally improve safety but in some cases complicate mining operations and have decreased productivity significantly since 1969. In course of time as coal mines become deeper and hence gassier and as the emphasis on safety increases it would be inconceivable to use trolley-wire haulage under ground as already witnessed in several other countries with deep coal mines. With rising capital investments and cost of the protection against fire and respirable dust, the use of conveyors may also have to be limited to special areas, e.g. main entries. Indeed, there are only two alternatives available, namely; (1) Degasify the coal seams prior to mining and use conventional electrical power, or (2) Develop alternate sources of power which would be safer and yet efficient and cheap.

Jan 1, 1975

By J. S. Young

During 1975, the Reclasource Corporation constructed and commissioned a plant for the recovery of mill scale, coke breeze, blast furnace dust, blast furnace sludge and basic oxygen furnace dust at the site of Crucible Alloy Division, Midland, Pennsylvania. The Reclaform Process was employed as the criteria for plant design. This Process takes the solid in-plant fines as listed above, commonly found in integrated steel mills, sizes and forms them through the use of a carbonaceous binder briquetting system and cures the binder through a final heat-treating step. 15,000 tons of Reclaform briquets have been tested in the Crucible blast furnace in several campaigns structured to assess material handling properties, burden feasibility and finally culminating in an iron and carbon assessment campaign. Data are presented from the records of the blast furnace operation and conclusions are drawn that both iron and carbon utilization have been demonstrated.

Jan 1, 1977

By R. G. Reddy

The Margules .equation is used for interpreting excess Gibbs energy of several ternary systems. In the present study activity coefficient of 'a dilute solute, 2, in a binary solvent 1-3 was derived. The derived expression is used to interpret logarithmic activity coefficient of oxygen and sulfur in several metallic systems. Self interaction parameter of the solute is derived from the partial function of solute using constant compositional path. An expression for logarithmic activity coefficient and self - interaction parameter of solute is also derived using Maclaurin infinite series. The derived equation is based on Maclaurin infinite series used successfully to deduce thermodynamics of self interaction of oxygen as a interstitial atom in two metallic systems. The predicted thermodynamic parameters values using Maclaurin infinite series and Margules. equations, are in excellent agreement with the experimental data and also our predictions are far more accurate than the predictions made by other models.

Jan 1, 1996

The object of this paper is to give an insight into various metallurgical operations involved in the making and shaping of steel for shipbuilding at the Newcastle plants of the Broken Hill Proprietary Co. Ltd., Commonwealth Steel Co. Ltd. and the Port Kembla plant of Australian Iron and Steel Ltd. Whilst not steelmakers, inasmuch as their processes start with semi-finished. steel supplied by the Steelmaker, the plants of Stewarts and Lloyds (Aust.) Pty. Ltd. and their associate company, British Tube Mills, Rylands Bros. (Aust.) Pty. Ltd. and the Newcastle and Kembla plants of John Lysaghts (Aust.) Pty. Ltd. make substantial contributions to the Australian shipbuilding industry, principally by way of boiler tubing and wires for welding rods and sheet steel, including special silicon lamination sheet for electrical motors.THE MAKING OF STEELThe making of iron and steel began as an accident, slowly developed as an art and has not yet become an exact science. The iron age dawned on the day when, by chance, man's primitive ancestor built up the wall of his fire with ironstone. In the ashes of the fire he found pieces of sponge iron from which he hammered out the first sample' of wrought iron. For many centuries iron ·was manufactured in bloomeries and occasionally, when the temperature was excessive, the iron combined with some carbon and steel was produced. But it was not till '1740 that steel was manufactured under controlled conditions. In that year Huntsman invented the crucible process which held undisputed sway for over a 100 years until in 1856 the invention of the Bessemer process revolutionised the whole industry.From then on, rapid progress was made. The Siemens...

Jan 1, 1951