Search Documents

By E Werner, B R. Leavitt

The chemistry of acidic mine drainage discharging from flooded coal mines is commonly reported to improve with time after flooding. This investigation describes a 18-year dataset of post-flooding water chemistry for a below-drainage underground coal mine within the northern Pittsburgh coal basin (Pennsylvania, USA). The Montour mine is a 5650-hectare below-drainage coal mine of maximum 260 metres depth. Montour was closed in 1980 and flooded to within 38 metres of land surface within 4.8 years. Pumping averaging 210 L/s was then employed to maintain water levels at this elevation. The flooded proportion of the mine (by volume) at full flooding was 56 per cent. The shaft where water was pumped from Montour for water control is located about 70 per cent of the distance between the mine water table and the back of the mine ù that is, it is close to the back of the mine. The residence time (total water volume at flooding divided by pumping rate for control) is estimated at 5.6 years. Time series of chemical analyses show three phases of chemical behavior in post-flooding discharge. In Phase I (zero to two years after flooding), iron concentrations were high and reached their maximum (1100 mg/L). In Phase II (two to four years after flooding), a transition was begun to alkaline conditions, with decline in iron and other solutes. In Phase III (>4 years), net alkaline conditions began, with iron concentrations declining exponentially to 50 per cent of mined volume. This attainment of net alkalinity in this case may have also depended on abundant calcite in overburden extended up to 30 m above the mine floor.

Jan 1, 2003

By P. Louis

Although cobalt is known and used for its hardness and wear resistance, ductile cobalt can be obtained by electrolysis in chloride solutions, under the following conditions : pH : 1.5 - 2, Co++ : 30 - 60 g/l, current density : 100 - 500 A/m2, temperature 40 - 70°C. No explanation was found for the ductility of the deposit under these conditions. Indeed the ductile P (FCC) cobalt and the hydrogen contents in the cobalt deposits are nearly the same as those obtained in a sulfate media, which gives brittle depo¬sits under equivalent electrolysis conditions. Malleable cobalt sheets can be easily obtained under the proposed conditions which could lead to new applications for cobalt.

Jan 1, 1988

By Earnshaw Cook, H. S. Avery, J. A. Fellows

TEe increased use of heat-resistant alloys (26 per cent Cr, 12 per cent Ni; 16 per cent Cr, 35 per cent Ni; 12 per cent Cr, 60 per cent Ni; etc.) in recent years has been accompanied by continued demands by the consumer for improvement in properties. The manufacturers of these materials, of necessity, have resorted to more critical studies of the basic causes of variations in fundamental properties. To keep pace with the need for augmented information, previous techniques of investigation have been refined and new test methods and instruments created. It is the purpose of this paper to describe the apparatus, experimental technique and precision of measurement that were employed in the exploration of properties of heat-resistant alloys presented in a companion paper. The detailed precautions in experimental procedure essential for attainment of accurate and comparable data at elevated temperatures cannot be too highly emphasized. The Creep Test Since the fundamental concepts of creep testing have been recognized for the past 20 years, present interest is restricted to refinements in equipment and experimental procedure. The creep-test iaboratory constructed for the American Brake Shoe and Foundry Co. is designed to permit I000-hr. tests in the temperature range of I200° to 2 200°F. with a choice of applied stress extending from jo to 50,000 lb. per sq. in. in increments of 50 lb. per sq. in. To simplify the calculation of weight combinations, the loading beams (Fig. I) are provided with counterweights to eliminate the tare. The precision of the knife-edges (10:I ratio) is such that a 10-gram weight placed on the upper specimen grip will be exactly balanced by a I-gram weight attached to the loading shackle. Check of the loading weights proved the maximum error to be 0.06 per cent. Axial alignment is provided by crossed knife-edges in the grip seats. The furnaces are similar in design to those of Crane and Company, Battelle Memorial Institute, and the U.S. Steel Corporation. An 80 per cent Pt, zo per cent Rh No. 19 B. and S. gauge wire is used as the heating element. The details of -construction are shown in the radiograph reproduced in Fig. 2. The windings are held in place on an alundum tube with aludum cement; the distribution of turns is adjusted to give a maximum temperature gradient of , I°F. over a 4-in. gauge length (Fig. 3). To avoid sharp temperature differentials at the ends of the test section, the length of the furnace is four times the gauge length. Sixteen-inch coupons are used „ to reduce the temperature of the threaded joints and thus to facilitate removal from the grips. Thermal losses are minimized by refractory insulators cut to shape and surrounded by diatomaceous ear,th. The taps

Jan 1, 1942

By J. A. Fellows, Earnshaw Cook, H. S. Avery

TEe increased use of heat-resistant alloys (26 per cent Cr, 12 per cent Ni; 16 per cent Cr, 35 per cent Ni; 12 per cent Cr, 60 per cent Ni; etc.) in recent years has been accompanied by continued demands by the consumer for improvement in properties. The manufacturers of these materials, of necessity, have resorted to more critical studies of the basic causes of variations in fundamental properties. To keep pace with the need for augmented information, previous techniques of investigation have been refined and new test methods and instruments created. It is the purpose of this paper to describe the apparatus, experimental technique and precision of measurement that were employed in the exploration of properties of heat-resistant alloys presented in a companion paper. The detailed precautions in experimental procedure essential for attainment of accurate and comparable data at elevated temperatures cannot be too highly emphasized. The Creep Test Since the fundamental concepts of creep testing have been recognized for the past 20 years, present interest is restricted to refinements in equipment and experimental procedure. The creep-test iaboratory constructed for the American Brake Shoe and Foundry Co. is designed to permit I000-hr. tests in the temperature range of I200° to 2 200°F. with a choice of applied stress extending from jo to 50,000 lb. per sq. in. in increments of 50 lb. per sq. in. To simplify the calculation of weight combinations, the loading beams (Fig. I) are provided with counterweights to eliminate the tare. The precision of the knife-edges (10:I ratio) is such that a 10-gram weight placed on the upper specimen grip will be exactly balanced by a I-gram weight attached to the loading shackle. Check of the loading weights proved the maximum error to be 0.06 per cent. Axial alignment is provided by crossed knife-edges in the grip seats. The furnaces are similar in design to those of Crane and Company, Battelle Memorial Institute, and the U.S. Steel Corporation. An 80 per cent Pt, zo per cent Rh No. 19 B. and S. gauge wire is used as the heating element. The details of -construction are shown in the radiograph reproduced in Fig. 2. The windings are held in place on an alundum tube with aludum cement; the distribution of turns is adjusted to give a maximum temperature gradient of , I°F. over a 4-in. gauge length (Fig. 3). To avoid sharp temperature differentials at the ends of the test section, the length of the furnace is four times the gauge length. Sixteen-inch coupons are used „ to reduce the temperature of the threaded joints and thus to facilitate removal from the grips. Thermal losses are minimized by refractory insulators cut to shape and surrounded by diatomaceous ear,th. The taps

Jan 1, 1942

By I. WILKOMIRSKY, J. BECKER, F. Parada

The current processes that aim to purify molybdenite concentrates are not able to dissolve some copper compounds, hence limiting the processes. Typically, the copper content results are from 2 up to 4 weight percent in the last concentrate. Such values are still too high for the molybdenite concentrate to be further processed to molybdenum trioxide by roasting. In order to achieve lower levels of copper — but also avoid excessive molybdenite losses — a continuous sulfation-leaching process is investigated and applied successfully on a pilot scale. Additionally, a reactor prototype and its process parameters are proposed for a commercial plant.

Jan 1, 2023

By Jilai Xue, Jun Zhu, GermainKouma Ndong, Luxing Feng

High-temperature corrosion behaviors of Fe-Ni-Cr alloy as inert anodes for aluminum electrolysis have been studied. The effect of anodic overpotential on layer growth of anodic surface is specially considered. The corrosion layers on the anodes tested were analyzed using XRD and SEM-EDS to provide a fundamental understanding of the layers growth at metallic anode surface. The dissolution of the scale layers on the metal anode occurred with low overpotential, while AlxM3-xO4 spinel phase within the scale layers was found with an increased overpotential. A mixture of multiple MyO layers existed on the anode substrate. The results may be useful for understanding and controlling the corrosion behaviors of Fe-Ni-Cr anode for potential application in aluminum electrolysis.

Jan 1, 2015

By Fred D. Wright

A drill unit designed by Bureau of Mines engineers for testing various types of rotary bits has been in use since April 1950 at the experimental oil-shale mine near Rifle, Colo. The unit has a hydraulic drill and feed system, which provides the wide range of operating conditions necessary for adequate testing of drill bits and for obtaining data needed for the design of production scale equipment. Through the use of this unit, it has been proved that rotary drilling of vertical holes for mining the benches of the oil-shale mine is much cheaper than percussion drilling, and it is believed that in the near future the rotary drilling of horizontal blast holes in the top heading of the mine will prove equally economical.

Jan 1, 1952

By A. E. Back

A method is described in which particulate iron, as distinguished from high purity iron powders used in powder metallurgy, is a precipitant for copper contained in dilute solutions. A new precipitation apparatus utilizes particulate iron precipitants to recover copper more efficiently than is possible in a conventional launder precipitation plant. In the search for lower cost methods of recovering copper from mine water, the use of sponge iron or particulate iron (as distinguished from iron powder used in powder metallurgy) as precipitants in place of tin cans, detinned scrap iron, or scrap iron is an intriguing possibility. The relatively faster copper precipitation rate obtained with particulate iron as compared to scrap iron promises economic and processing advantages when, and if, particulate iron becomes competitive cost-wise with available scrap iron. Kennecott has developed a precipitation cone,' see Fig. 1, utilizing various particulate iron precipitants and has demonstrated the process successfully in a prototype at a flow rate of approximately 1000 gal of solution per min. Essentially complete precipitation of copper is obtained, the cone overflow solution is clear and contains no particulate copper, and the iron factor is more favorable than in a conventional launder plant. Initially, sponge iron produced at the Ray Mines Div. Kennecott Copper Corp. for use in a Leach-Precipitation-Flotation process was used in exploratory tests to develop a suitable apparatus to take advantage of the rapid precipitation rate and efficient iron utilization for the recovery of copper from dilute solutions. Here it was demonstrated that, when sponge iron was added to a launder, the particles of iron collected in the bottom of the launder and tended to cement together. This resulted in incomplete precipitation of the copper and inefficient utilization of the iron. Next, sponge iron was suspended in glass columns to study the dynamics of the precipitation reaction. Again it was observed that the particles tended to cement together at low solution flow rates, while at higher flow rates large amounts of the precipitant overflowed the column, resulting in loss of precipitant and an inefficient process. Next, the precipitant was suspended in an inverted cone in a rising column of solution. Dynamic suspension of the solids was maintained at relatively rapid solution flow rates with instantaneous and complete precipitation of copper and with improved iron utilization. The first tests were conducted on a batch basis and it was determined that a dynamically suspended bed of precipitant was necessary for satisfactory operation. More than 99% of the metallic iron could be converted to metallic copper by careful control of the residence time in the cone and copper precipitation was essentially complete, even when the available iron precipitant was almost depleted. Several cones were built, ranging in capacity from 1 to 200 gal of feed solution per min, and finally, a prototype cone was constructed which was 20-ft high

Jan 1, 1968

By L. G. Evans, W. W. Simpson, W. A. McKinney

In conventional dump leaching of strip wastes from open-pit porphyry mining operations, many years are required to extract a fraction of the copper from the contained sulfide minerals. Furthermore, none of the molybdenum, gold, or silver is recovered by current leaching practices. Because the copper sulfide minerals and molybdenite generally are distributed in the minute fractures throughout the host rock, the mineral values tend to concentrate in the finer fraction of the strip material. This suggests the possibility of segregating the enriched fines in as-produced or coarsely crushed strip wastes for blending with the ore grade flotation mill feed. In the past, extra handling or crushing of mine wastes to enable better leach extraction has been deemed uneconomical. However, recent articles on mobile crushing plants and conveyor haulage systems indicate possible cost improvements for these techniques over conventional truck haulage of ore and mine wastes. Another potential benefit from removal of the fines from copper-bearing mine waste derives from the increased permeability of the coarse dump material to leach solutions and air. Better permeability should result in faster oxidation of the sulfide minerals, less channeling of leach solutions, and fewer perched solution tables caused by compacted fines. Therefore, in addition to the metal values recovered by flotation, higher copper recoveries by leaching also might be achieved. The Salt Lake City Metallurgy Research Center of the U.S. Bureau of Mines undertook an investigation to determine the feasibility of removing enriched fines from strip waste material for separate treatment by froth flotation for early recovery of part of the copper, molybdenum, gold, and silver. Percolation leaching tests were made on mine-run and sized fractions of the dump material to determine the effect of fines removal on copper extraction. Samples Tested Three 10-ton samples of copper sulfide-bearing mine waste were obtained for the investigation. Partial chemical analyses of the samples are given in [Table 1] and the consolidated results of detailed screen analyses made on the samples are given in [Table 2]. The -1/4-in, fine fractions contain from 16 to 32% of the copper and 19 to 40% of the molybdenum in 11 to 18% of the total waste. The samples also were crushed to -3 in. to determine the feasibility of crushing to obtain a higher distribution of the metal values in an enriched fine fraction while providing a more leachable coarse fraction that could be transported by a conveyor system to a dump. The -%-in. fine fractions screened from the crushed mine waste were almost identical in grade to the natural fines. From 2 to 4% more1/4-in. fines were produced by crushing to -3 in. Copper distribution was increased by about 3% over that in the natural fines, while molybdenum distribution was increased by about 10%. The -1/4-in. fines screened from the mine-run and crushed strip waste were almost as high in grade as the ore being treated at the mills. In addition, the fines

Jan 1, 1974

By S. Q. Zhu

Coal Water Mixtures (CWMs) are densed suspensions of coal particles in water. Viscosity is one of the most important rheological properties of CWMs and it is desired to be as low as possible. The slurry viscosity was influenced significantly by additive formation, the particle size distribution and the ash content of the coal. However, the influence of dispersants is most obvious. At present, there are several kinds of dispersants such as polymeric styrene sulfuric sodium, lignin sulfonate, humate, polycarboxy salt, ethylene epoxide surfactant. In this paper, a newly synthesized CWM dispersant has been reported, which is an efficient anionic surfactants of polycarboxylic acid type. The synthesis process includes three steps. At the beginning, the polyglycol acetate ester has been performed by acetic acid and polyethylene glycol (PEO) on the condition of acetic-acid/PEO ratio 1:1.1, at 368~373K for 30 minutes. Then the macro-monomer is prepared through the esterification of 85.71% acrylic and 14.29% polyglycol acetate ester, at 368~373K for 10 minutes. After that, the polycarboxylic acid CWM dispersant is polymerized using proper proportion macro-monomer, acrylic (AA) and sulfonic styrol sodium, at 368~373K for 1 hour. This new dispersants are used in the coal water mixtures formulation. Four kinds of coal used in the experiment are Shuang Yashan, Tunliu, Luning, Changcun samples. ? The highest concentration for shuanyashan coal is 70% when the dosage of dispersant is 0.4%, and the content of -200 meshes particles is 75.53%. As the dosage of dispersant de-creases to 0.25%, the Shangyashan CWM concentration is 67%. ? For Tunliu coal CWM concentrations are in the range of 76% to 75% when dosage of the dispersant changes from 0.4% to 0.25% at the same particle size distribution of 83.5% minus 200 meshes. ? The highest concentration for Luning coal is 69% when dosage of the dispersant is 0.4%, and the content of -200 meshes particles is 88.86%. ? For Changcun sample, the coal concentration of CWM is 73%~75% when dosage range of the dispersant is 0.35%~0.5%. The experiments show that the synthesied dispersant is quite promising for some coals CWM preparation, but a little bit coal-dependent. The Proximate and Ultimate analysis, surface characteristic measurement have been made to investigate the interactions between coal and additives.

Jan 1, 2014

By Robert Fritzsch, Ragnhild E. Aune, Mark William Kennedy, Behzad Mirzaei

"The quantitative particle concentration can give important information about the cleanliness of melts for quality control in primary and secondary production of aluminum. Manual quantification of the particle concentration is normally a time consuming process and human control can bias the acquired images and particle count.The present paper explains the automated image-processing steps for the quantification of SiC-particles, with equivalent diameters from 2 to 25 µm, in solidified A356. A total of 700 micrographs, acquired with a standard white light microscope with 10 x magnification, were analyzed. The applied software (Image Pro-Plus 7.0 from MediaCybemetics®) allows for programming of macros which in tum provides the user with a higher degree of control. The automated results are compared with the results obtained by manually counting the particles in the same micrographs. The impact of the automated results on the estimated filtration efficiency was established to be only -3%.IntroductionInclusions are both indigenous and exogenous particulates that are present in commercial metals such as aluminum. If large individual or large numbers of inclusions are present, they can have a significant negative impact on the appearance, mechanical and chemical behavior of products produced from the metal. Aluminum is known to contain large numbers of inclusions: =50 µm in size, e.g. typically <l ppm by volume or <100,000 inclusions of>20 µm per kg of metal as detectable using a Liquid Metal Cleanliness Analyzer, LiMCA [1]. Depending on the final application of the aluminum, inclusions can render the metal 'not fit for purpose', and result in serious economic consequences to metal producers.It is not surprising that the aluminum industry has developed a number of treatment processes to improve metal cleanliness, given the large number of high value products whose quality can be adversely affected by inclusions. CFFs are the most commonly applied filtration process and have been used to filter >50% of the world production of aluminum since the 1990's [2].Inclusions in aluminum may be particles, bifilms [3] or clusters of: oxides (Al2O3 , SiO2), spinels (MgO· Al2O3), carbides (SiC, Al4C3), nitrides (AlN), borides (TiB2), sulfides, phosphides and intermetallics [ 4]."

Jan 1, 2013

By M. Cassir

"The unique properties of molten carbonates offer a large scope of applications in the field of energy. In effect, these molten salts are in the center of chemical and electrochemical reactions involving carbon and carbonaceous species, carbon dioxide and carbon monoxide, significant for energy generation or even for the production of fuels. Moreover, such media have also an oxidative character; they dissolve molecular oxygen and oxygen reduced species, O 2-, O22- and hypothetically o-, which may have an important role in waste treatments, homogeneous catalysis and synthesis of oxides. In this presentation, an overview will be given on the principal physicochemical properties of molten carbonates, before focusing on their main known application, the molten carbonate fuel cell (MCFC). Progress in other new fuel cells applications will also be analyzed, such as direct carbon fuel cell (DCFC), hybrid carbon fuel cell (HDCFC) and composite high-temperature fuel cells combining the features of MCFC and solid oxide fuel cell (SOFC). Afterwards, membranes for the separation and capture of C02 will be reviewed. Finally, other topics, as the oxidative coupling of methane in molten carbonates, will be briefly mentioned.IntroductionIn the thirty past years, the molten carbonate science and advances have been mainly dedicated to the understanding and optimization of the molten carbonate fuel cell (MCFC), which is still a major issue in the heart of a new vision of energy development. More recently, new topics related to other kinds of fuel cells (DCFC, composite SOFC/MCFC systems) and C02 capture have emerged and are concentrating important research and technological efforts. Moreover, new fields of implementation, related to molten carbonates, are also present: geology, glasses, production of nanocarbon particles etc. Considering other areas where this molten phase plays a major role, such as catalysis, waste destruction, surface treatment, it can be confirmed that the field of molten carbonates is very rich and offers many opportunities for fundamental science and competitive applications. Whatever their specific application, molten carbonates activity is associated to more efficient energy systems with low production of C02 and, in a prospective sense, to non-polluting energy using the value of C02. A recent event, the International Workshop on Molten Carbonates & Related Topics, IWMC201 I, held in Paris in 2011 , have put in evidence the importance to improve and exploit this investigation and technological domain."

Jan 1, 2012

By Kenneth L. Clifford

We have heard a lot during the recession about the mining industry now competing in a world market for sales of such commodities as copper, lead, zinc, molybdenum, iron ore, and phosphate. If the US mining industry is to survive, do we not have to reduce direct operating costs to a minimum? How significant is labor cost compared to consumables, electricity, fuel, maintenance, materials, and transportation? Ore grade is ultimately the dominant factor; but can we offset its dominance by improving productivity? Is the US mining industry perhaps only 25-30% as productive as it might be? What prevents the industry from being more productive? Can we retrofit older plants to be more productive or does it take a new plant with the largest equipment available for each unit operation? Present Productivity A copper industry study a few years ago covering 13 US copper concentrators ranging from about 10-45 kt/d (11,000-50,000 stpd) showed that productivity did not vary with capacity above 18 kt/d (20,000 stpd). Operating productivity varied significantly, however, from about 180-635 t/d (200-700 stpd) per operating hourly worker in most units, but one operation had 900 kt/d (1,000 stpd). Concentrators with more than 545 t/d (600 stpd) per hourly worker were in the 23 kt/d (25,000 stpd) or more category. Maintenance productivity covered about the same range, but most concentrators were in the 270¬635 t/d (300-700 stpd) per hourly maintenance worker. Again, one company stood well above others by exceeding 1 kt/d (1,100 stpd). Total hourly productivity ranged from 125-280 t/d (140-310 stpd) per hourly worker for most concentrators. The company with the most productive operation, however, was above 455 t/d (500 stpd). Salaried worker productivity for most operations was in the 725 t/d to 1.2 kt/d (800-1,300 stpd) per salaried worker range. The best operation was 2.2 kt/d (2,400 stpd). The end result is, of course, tons per day per total personnel. Most operations fell in the 110-220 t/d (120-240 stpd) range with the best operation at 400 t/d (440 stpd). This is the productivity definition that is most directly related to unit costs. Many of these operations have made some productivity progress

Jan 11, 1983

H. W. Glen (ed.). Proceedings of Asbestos Symposium, Johannesburg, South, Africa, 3rd-7th, October, 1977. Randburg, National Institute for Metallurgy, 1978. 158 pp. (Copies obtainable from the Department of Mines, P.O. Box 4584, Johannesburg, 2000 South Africa.) This Symposium, which concentrated on the theme of dose-response relationships for asbestos-related diseases, was attended by an internationally representative group of experts in this field. Bulk solids The Powder Advisory Centre announces its third annual International Conference on Bulk Solids Swrage, Handling and Flow, to be held at the Holiday Inn, Liverpool, on 7th to 9th November, 1978. This sequel to the extremely successful November &apos;76 Stratford and November &apos;77 Nottingham Conferences is again to be co-sponsored by a number of internationally acknowledged professional societies, including the Institute of Materials Handling (through its Bulk Solids Panel), the Institution of Production Engineers, and the American Society of Mechanical Engineers (through its Materials Handling Engineering Division). NIM reports Report no. 1943 A review of the literature on the separation and determination of rare-earth elements. (23rd Mar., 1978.) Report no. 1947 The cation- and anion-exchange behaviour of various base-metal chlorides in polar organic solvents. (lOth Mar., 1978.) Report no. 1948 The measurement of trace amounts of gold in solution by atomic-absorption spectrophotometry and carbon-rod atomization. (28th Feb., 1978.) Report no. 1949 The kinetics of the leaching of zinc sulphide concentrates in acidic solutions containing ferric sulphate. (23rd Mar., 1978.) Report no. 1950 Factors affecting the carbon contents of alloys formed during the prereduction of chromite ores. (31st Mar., 1978.) Report no. 1952 The effect of slag composition on copper losses to silicasaturated iron silicate slags. (31st Mar., 1978.) Report no. 1953 A fundamental investigation into the depression of copper-activated sphalerite. (28th Apr., 1978.) Report no. 1956 An improved ion-exchange separation of rare-earth elements for spectrographic analysis. (10th Mar., 1978.) Report no. 1960 The recovery of ferrochromium from furnace slags and related products. (20th Aug., 1976; declassified 31st Mar., 1978.) Process instrumentation The National Institute for Metallurgy and the South African Institute of Measurement and Control are organizing a symposium that will draw the attention of researchers and industrial workers to the importance of metallurgical process instrumentation.

Jan 1, 1978

By Kenneth J. Hartman

Introduction The term kaolin is derived from kauling, a Chinese word meaning high ridge. This was the name of a hill in China where kaolin was first mined several hundred years ago (Murray, 1976). Other common names used for kaolin include clay and China Clay. Clay technically has a broader meaning and could refer to bentonite and ball clay as well as kaolin. China clay, as a descriptive term, apparently results from kaolin&apos;s origin. But it could also be due to a significant historical use in ceramic applications. The terms kaolin and clay will be used interchangeably in this analysis because of the common practice of using these terms in the paper industry. Major reasons for kaolin&apos;s wide-spread industrial usages center on kaolinite&apos;s physical features of good color, low viscosity, and inertness. Kaolin is described as a hydrous aluminum silicate with an approximate composition of 2H2O • A12O3 . 2SiO2. A new version of the product is calcined clay with modified hydration content. It is gaining widespread use. Components of any particular kaolin, in addition to alumina and silica, are viewed as impurities. The more values deposits and, hence, higher priced kaolin products are those of the highest purity. Kaolin is the most widely used mineral in paper manufacturing throughout the world. Key production centers are located in England and the US. Most of the Tatter&apos;s production is located in Georgia. The key markets for Georgia kaolin are paper markets - both paper coating and paper filling. These paper markets extend throughout the world, not just to domestic markets. In fact, export markets are second in size only to domestic paper markets for Georgia&apos;s producers of kaolin. Just as the paper markets are important for kaolin producers, kaolin is an important raw material for papermakers. Compared to the other three major pigments - titanium dioxide, calcium carbonate, and talc - kaolin&apos;s 1984 tonnage for papermaking represented 85% of the total. Even though titanium dioxide&apos;s unit value is much higher, kaolin&apos;s estimated total 1984 value still represented 51% of total dollars spent by papermakers for the four pigments. Kaolin grades- are briefly defined using particle size and brightness as principal means of classification. Likewise, grades of papers using kaolin are defined using the American Paper Institute&apos;s guidelines. From these definitions, associated kaolin grades used in particular grades of paper are reviewed. Special emphasis is placed on how qualities desired in certain papers are achieved through the use of specialized kaolin grades. World kaolin production World production statistics (Coope, 1979; Table 1) demonstrate that kaolin is produced in many areas of the world. About 60% of production is centered in the US and England (Fig. 1). Deleting Eastern Europe&apos;s produc-

Jan 4, 1987

By J. Donovan Jacobs

An underground excavation project usually is a highly organized complex of different but interrelated construction activities. It is the whole effort, including the necessary tools, which will be referred to as the System. Tunnel-driving and shaft-sinking operations are among the most systematic of construction efforts. Systems are not new in the performance of construction. It is the Systems Concept which seems only recently to have been discovered and made the subject of much study and discussion. HISTORICAL From the seventeenth century, when explosives were first utilized for rock excavation, until the successful application of the rotary-head continuous tunneler in this decade, the cyclical drill-blast-muck-support method has been standard tunnel-driving procedure throughout the world. Whatever improvements occurred were the result of development of better tools for performing the various operations of the cycle. The electric locomotive replaced the mule and permitted the use of larger muck cars. The steam drill, which ended the day of the double jack, was itself quickly made obsolete when compressed air replaced steam as the source of drilling energy. Power shovels were introduced to save the time and money involved in the hand-loading of excavated materials. A cubic yard of rock tunnel muck can be excavated today for just half the man-hours of labor required in 1948. Developments over 20 years which cumulatively have resulted in this economy include: drifter drills mounted on hydraulically controlled booms and positioners; tungsten-car- bide-tipped bits; long feed shells on the drifters, making it possible to drill the full depth of a round without changing steel; better designed,

Jan 1, 1970

By O. W. Ellis

RECENTLY there has been a considerable revival of interest in the effects of the various elements commonly added to brass for the purpose of increasing its strength. For many years the work of Guillet2? alone gave reliable information in this regard. Even today his determination&apos;s of the coefficients of equivalence of the various elements relative to zinc in brass are those universally employed in industry. This is so because these coefficients have stood the test of time-their substantial correctness has been proved in almost universal practice. It is not our intention to discuss here these coefficients or their use. Rather do we wish to emphasize the need for further systematic studies of the mechanical properties of the ternary systems of copper, zinc, and other individual elements. Since Guillet published the results of his first investigations Millington,16 Smalley33 and Thibaud45 have added somewhat to our information. In general they have confirmed the findings of Guillet, which may be stated in the following rather general terms: 1. The addition of aluminum to the 70:30 and 60:40 brasses progressively increases their hardness and strength and reduces their ductility and resistance to shock. 2. The addition of small amounts of iron to a 60:40 brass improves its strength without affecting its ductility. 3. The addition of small amounts of manganese to a 60:40 brass causes a progressive increase in its strength and reduction in its ductility. A considerable amount of information has been amassed in regard to the effect of nickel on brass (9, 22, 41) which it is unnecessary to refer to here, in view of the scope of this paper.

Jan 1, 1929

Jan 1, 2005

By Donald H. McLaughlin

PRICES paid for goods and services in paper currencies are undoubtedly determined by many interrelated factors, but among them none is more specific in pushing prices toward higher and higher levels than the vast increase in debts and monetary obligations of our own and practically all major governments. There is nothing unorthodox in the situation in which the gold miners find themselves today. With wages and the prices of all materials required in the production of gold at the high levels characteristic of a period of prosperity, phony or otherwise, and with shortages of both men and machinery to contend with as well, the spread between the returns in paper dollars that must be accepted for gold in the United States and the cost of producing it is rather painfully small for most producers. Technical

Jan 1, 1948

By L. Garner McDonald

The U.S. Bureau of Mines tangentially impacted potential coal-cutter bit shank materials against sandstone to investigate the potential of the materials to ignite natural gas by a friction-generated hot streak. The shank material samples were mounted in a 24-in, 550-lb flywheel, which was rotated at surface speeds of 400 to 900 sfpm. The sandstone was advanced toward the rotating flywheel at feed rates of 1 mil per impact. The atmosphere mixture was 7 vol pct natural gas in air. Three grades of polycarbonate resin, an ultra-high-molecular weight polyethylene, and a zinc alloy (ZA27) were among the potential materials. None of these materials caused ignition of the methane at any of the three test speeds (400, 600, and 900 sfpm), but the above materials do not have sufficient strength to hold a carbide tip during coal cutting. Of the materials having sufficient strength to hold a carbide tip, three nickel-based alloys proved less likely to cause a natural gas ignition than did iron-based alloys such as 4340 (a commonly used shank material for coal cutters).

Jan 1, 2010