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By Jan Willem van Bloois

IHC Merwede is world market leader in the construction of specialist dredging equipment; it is a company with a rich history. The Netherlands is a coastal western country for which water management is a very important issue. Without the enclosure of the coastal areas with dikes and dunes almost two third of the Netherlands would be flooded. These activities are mostly performed by the dredging industry and are the foundation of the dredging industry as it is today. Besides land protection this industry also carries out infrastructure maintenance and performs land reclamation projects. In essence the dredging industry is specialized in horizontal excavation activities and operations in shallow waters with the purpose of gathering bottom sediments and disposing it at a different location. The development is that the activities are moving to deeper waters to a depth of up to 150m. A few years ago IHC Merwede received a request to perform the shallow water excavation techniques at a depth of approximately 2000 meters for the deep sea mining market. In response to the increasing number of requests for deep sea dredging and mining application solutions, IHC Merwede combined all of its activities in this sector to create a new, specially equipped operational unit, IHC Deep Sea Dredging & Mining (IHC DSDM).

Jan 1, 2010

By Spencer P. A

Bacterial oxidation, previously known as bacterial leaching or bio-leaching, has been applied at laboratory and pilot plant scale to many refractory ores and concentrates around the world. The most common bacterial culture used in this process has been Thiobacillus sp. This organism is limited in commercial application, especially in Australia for several reasons. The optimum operating temperature range for this culture is 30¦C to 40¦C and high levels of some metals such as arsenic, silver, and copper have toxic effects on the culture thus reducing its effectiveness. The culture employed by BacTech (Australia) Pty lid is a moderately thermophilic culture which operates in a temperature range of 40¦C to 55¦C (which is more amenable to the Australian climate) and with higher resistance levels to metals often found to be toxic to Thiobacillus sp..

Jan 1, 1991

By Hal J. Kelly

A number of problems that developed in processing the halloysitic clays of eastern Washington and northern Idaho were investigated by the Bureau of Mines. The deflocculating effect of tetra sodium pyrophosphate is compared with several other compounds, and on the basis of current theory, the advantage of sodium pyrophosphate as a deflocculating agent is explained. The adsorption of the sodium ion by clay in a clay"-water system was established by a radioactive tracer technique, and the deflocculating action of sodium pyro- phosphate was postulated. The effective dispersion of the halloysitic clays was limited by the occurrence of tightly bound aggregates of small, individual crystals. Disaggregation of the agglomerates was investigated by liquid extrusion and ball milling of dilute slurries and by extrusion of the clay in a plastic state. The greatest increase in the production of small particles was by high? pressure liquid extrusion.

Jan 1, 1963

By Jim Buckley, Ryan Sibley, Scott G. Giltner, Thomas Pallua, Joe Schrank, Robert Cidlik

Because of variation in rock type and site conditions, it is important to create site-specific prediction models for peak particle velocity (PPV) and understand instrumentation mounting locations to better interpret the readings provided following blasting operations. The Atlanta Airport is expanding the section of underground tunnels for its Plane Train people mover, and drill and blast operations were determined to be the suitable method of excavation for the project. Extensive work was done to begin creating prediction models and determining levels of concern based on readings from various types of instrumentation. This paper analyzes the effect of close quarters construction blast vibrations and observed frequency spectrum on existing structures with data from 22 different seismographs mounted in various locations and ground conditions.

Dec 1, 2022

By B. A. Monkman

"IntroductionONE OF :THE most effective methods by which the construction industry is combatting mounting building costs is by making increased use of lightweight materials, thus reducing the dead load to be carried •by structures. This applies to non-metallic materials as well as to metallic ones, and particular attention has been given to developing lightweight aggregates for use in concrete.The use of lightweight aggregates is not new and, in fact, dates back to the Roman Empire, when pumice was used in the walls and domes of the Roman buildings. More recently, and up to a decade or so ago, the demand for these aggregates was met from deposits of volcanic cinders, pumice, scoria, etc., and from the by-products of blast furnaces and coal burning boilers. However, these sources of supply are no longer sufficient to meet the demand, for transportation costs pretty well restrict the use of the natural lightweight aggregates to the western cordillera regions where the deposits of these materials occur, and the use of expanded slag aggregates to the areas neighbouring the plants where slags are produced. As for cinders, the supply has been greatly reduced by the conversion of industry to fuel oil, natural gas, and powdered coal, and the large stockpiles which existed previously have been pretty well exhausted.Industry's approach to the problem of a decreasing supply, in the face of an increasing demand, has been characteristically direct. The solution has been to construct plants whose sole .purpose is to produce economically an acceptable light-weight aggregate from materials close at hand."

Jan 1, 1955

By Robert F. Kaufmann

INTRODUCTION In response to the Uranium Mill Tailings Radiation Control Act (Public Law 95-604, Section 114c), a report has been prepared by the U.S. Environmental Protection Agency (1980) which describes the potential health and environmental effects associated with uranium mine wastes. The author was responsible for the geology, hydrology and aqueous pathways analysis portions of the report. All potential sources of contaminants, solids, liquids, and airborne emissions, which might cause adverse impacts upon the environment or health of nearby populations were considered. Wastes at both active and inactive uranium mines (Hans and O'Connell, 1981) are described and assessed with respect to dose and health effects (Blanchard et al. 1981). The emphasis of this paper is on the liquid emissions and the aqueous pathway. Model uranium mines were developed for surface and underground mines. The model underground mine was placed in New Mexico while the model surface mine was in Wyoming. Development of a generic assessment was complicated due to the inherent variability of uranium mines. Also, most information available relates to uranium mills rather than to mines, or reported measurements were often influenced (biased) by wastes from a nearby mill and did not specifically reflect mine discharges. Consequently, the assessment presented is often based on conservatve (maximizing) assumptions which are identified as such, and which were based on knowledge from field investigations, available literature, and consultations inside and outside the U.S. Environmental Protection Agency. Maximum use was made of available data, supplemented with limited field studies in Colorado, Texas, New Mexico, and Wyoming. PREVIOUS INVESTIGATIONS Stream survey work in Colorado by the Water Pollution Control Commission and the U.S. Geological Survey (Moran, 1974; Wentz, 1974) mentioned a portion of the Uravan Mineral Belt and uranium mines therein, but the work did not emphasize uranium mines. Significant amounts of acidity and total trace metal concentrations were found in streams from 18 different mining areas. Dilution and chemical precipitation below mine drainages decreased concentration and increased the pH. Given enough time and distance, the streams recover naturally, but the accumulations of trace metals in the sediments increase. Field observations in 1971-72 of streams in most of Colorado indicated that approximately 724 km of streams in 25 different mining areas were adversely affected by mine drainage (Wentz, 1974). Discussions of the impacts of uranium mining on water quality or quantity are incidental in numerous impact statements and environmental reports prepared by industry and (or) the U.S. Nuclear Regulatory Commission as an integral part of licensing or relicensing uranium mills. Coverage on mining is usually minor as the principal focus is on milling impacts. The same is true for the recently prepared generic EIS on regulation of uranium milling (U.S. Nuclear Regulatory Commission, 1979). Radiochemical assessment of surface and groundwater in uranium mining districts of New Mexico is done by self-monitoring programs associated with NPDES permits. Also, radiochemical assessment studies have been funded by the New Mexico Environmental Improvement Division and U.S. Environmental Protection Agency. Unfortunately, there has been no concerted effort to prepare broad assessments of the cumulative impacts of mining and milling in areas of interest in Texas, New Mexico, and Wyoming. Critical review and synthesis of these types of data can produce rather useful information. For example, the publication "Water Quality Impacts of Uranium Mining and Milling Activities in the Grants Mineral Belt, New Mexico" (U.S. Environmental Protection Agency, 1975) addresses the groundwater and surface water changes as the result of extensive uranium mining and milling production in a relatively confined area. A more recent report by the Wyoming Department of Environmental Quality summarizes 16 years of aqueous radium and uranium data. The study reports significant amounts of radium-226 and uranium were present in surface water in the Shirley Basin as a result of inadequate mine water treatment (Harp, 1978). In Texas, surface water and groundwater monitoring conducted by industry, as well as by State and Federal agencies, reveals little or no change of chemical quality attributable to uranium mining and milling (Gesell, 1977; Kallus, 1976). This conclusion is based on 586 samples collected from 198 stations over a period of 39 years, but primarily from 1961 to 1975. The State monitoring program by several agencies is continuing, but data reporting and interpretation is lagging. One survey (Itin, 1975) showed that none of the mine water from the 10 lakes that were sampled was suitable for human use. The lakes were also unsuitable for irrigation due to mineralization of the water by sulfate, chloride, and TDS. One of the 10 was suitable for stock watering.

Jan 1, 1981

By R. A. Wood, R. I. Jaffee, H. R. Ogden, D. N. Williams

The tensile properties, creep resistance. and thermal stability of highly alloyed Ti-Al-Zr alloys were examined. On the basis of these studies, the Ti-7Al-1ZZr composition was selected for more complete evaluation. The alloy was found to be weldable and free from excessive directionality. In addition, it developed maximum properties without requiring heat treatment other than an annealing operation in the alpha field. The alloy was recommended for scale up and is presently being investigated on a production-level basis. One of the more attractive properties of titanium alloys is their ability to withstand stress at moderately high temperatures, and a considerable amount of effort has been devoted to increasing the maximum service temperature of titanium alloys. This work has suggested that the optimum alloys for high-temperature service will be single-phase a (close-packed hexagonal) alloys containing significant amounts of aluminum. However, the maximum amount of aluminum which can be alloyed with titanium is between 6 and 8 pct,l since at high-aluminum contents an embrittlement reaction occurs in the anticipated service temperature range, 800" to 1100°F. It has been shown that the embrittlement reaction involves decomposition of the high-aluminum a phase to one or more new phases.' Since this reaction does not occur at intermediate or low-aluminum contents, it was felt that intermediate Ti-A1 alloys might be strengthened by a-soluble ternary additions without inducing the embrittlement reaction. The first alloying addition considered was tin, which shows extensive solubility in a titanium and has moderate strengthening tendencies. Unfortunately, it was soon apparent that tin also promoted the embrittlement reaction, and that to obtain a stable alloy, the aluminum content had to be reduced as the tin content was increased. The second alloying addition considered was zirconium, which is similar to tin in its effects on titanium. This element did not contribute to the embrittlement reaction and, in fact, appeared to increase the maximum amount of aluminum which could be alloyed with titanium without inducing instability. This paper describes an investigation of the Ti-A1-Zr a alloy region. Alloys containing from 4 to 12 pct A1 and from 6 to 15 pct Zr were examined. The properties of these alloys are described and the bases for selecting an optimum composition is outlined. This composition, Ti-7A1-12Zr, is presently being scaled up in tonnage quantities, and is being evaluated extensively throughout the industry. In addition to presenting the basis for its selection, this paper presents a description of the properties developed in laboratory material as determined during the alloy investigation. These properties suggest that this alloy can fill an important position in applications requiring light weight, fabrica-bility, weldability, and strength to 1000oF or higher. EXPERIMENTAL PROCEDURES Titanium alloy ingots were prepared by inert electrode arc melting under an argon atmosphere. Alloying elements used were 110 Bhn titanium sponge, high-purity aluminum, and reactor-grade zirconium. Pancake-shaped ingots were prepared weighing approximately 300 g. The composition of the ingots was checked by weight measurements before and after melting. The pancake ingots were forged at 2000°F to approximately half their original thickness to give a flat plate roughly 1/2 in. thick. This plate was then rolled at 1800' to 1600°F to 0.250 in. thick. All of the alloys examined fabricated well. However, alloys containing 15 pct Zr tended to overheat due to exothermic oxidation, and scaling was excessive. As might be anticipated from its effect in decreasing the ß transus, increased zirconium appeared to improve fabricability somewhat, especially during rolling at lower temperatures. Except for a limited study of heat-treatment response, all alloys were examined in the a-annealed condition. Prior to heat treatment the a and ß tran-sus temperatures were determined by metallo-graphic examination of samples quenched after annealing at 50-deg intervals in the transformation region. These data are shown in Fig. 1. Recrystal-lization appeared to occur in about 1 hr in the range 1300º to 1500ºF. Therefore, alloys were annealed for 1 hr at 1550ºF (4 and 5 pct Al), 1600ºF (6 through 7-1/2 pct Al), or 1650°F (8 or more pct Al). This produced an equiaxed a grain structure. In most alloys, a "ghost" structure was visible after the a-annealing treatment, as shown in Fig. 2. This structure apparently resulted from the acicular

Jan 1, 1963

By G W. Scott, H M. Lukey

The Lake Superior Region has been a producer of iron ore for over 150 years. Early mining operations concentrated on direct shipping ores, which are the result of post-depositional upgrading principally by deep weathering. As direct shipping ore reserves became depleted, the focus changed to the production of iron ore pellets from taconite. The post-depositional processes responsible for upgrading taconite are regional metamorphism, contact metamorphism and hydrothermal processes (Clout and Simonson, 2005). While these processes are important in iron ore genesis they can also contribute to liberation problems and in some instances reduced pellet quality (Han, 2004). Low-grade metamorphic mineral assemblages can negatively impact liberation and pellet quality. Low-grade iron formation may contain a suite of carbonate minerals including ankerite, dolomite, kutnohorite, siderite and magnesiosiderite. Variation in the distribution and composition of siderite and magnesiosiderite makes controlling the MgO content of pellets difficult. Carbonate minerals also require calcination in the pellet induration process, which requires additional heat to be added to the system, slowing down the induration process and reducing throughput. Prediction of carbonate mineralogy and carbonate mineral chemistry is an important goal of ore characterisation for pelletising properties. Contact metamorphism causes changes in mineralogy and grain size (Klein, 1973; Gunderson and Schwartz, 1962). Increasing the grain size of magnetite should improve its liberation characteristics. However, plant grinding targets may not allow the coarse-grained, more easily liberating magnetite ores to increase throughput and can actually result in decreased throughput due to recirculation. While magnetite and martite ores are well understood (Lukey, Johnson and Scott, 2007) late open-space filling microplaty haematite ores are not. These ores, while composed of similar minerals, have a unique genesis that results in fine grain size and complex textures that present liberation challenges and often make interpreting laboratory metallurgical test results more difficult.

Jan 1, 2007

By K. D. Eng, W. T. Tierney

"During the past century, the development of vehicular transportation has benefitted tremendously from the performance improvement in engines in a situation where low-cost, plentiful fuel supplies were the order of the day. Engine advances were enhanced by and also dictated fuel modification to better adapt the energy source to the power plant.In discussing the several aspects of the change in approach from ""an engine and its fuel to a fuel and its engine"", the authors touch on the following areas:1. Description of an engine concept that provides the needed flexibility in fuel appetite at good efficiency to cope with future requirement s.2. The constraints placed on liquid fuel resource energy utilization efficiency by special engine-required fuel properties and the fuel efficiency of the various engine types available.3. Future vehicle engine fuel sources. This review will put into perspective the problem associated with the net energy available from future fuel sources under extensive research and development at present.4. A brief review of test data to show that fuel-tolerant and fuel-efficient engines are viable and that, in a fuel-resource-limited future, they can be a ""light at the end of the tunnel.""The Texaco Controlled Combustion System (TCCS)The TCCS is a unique means for stratified charge operation of an internal combustion engine in such a manner as to eliminate the requirement for octane or cetane number specification for the fuel. Octane rating is an empirical engine test method that evaluates a gasoline's resistance to spontaneous ignition or ""knock."" Cetane is based on a different engine test, which determines a diesel fuel's ease of spontaneous ignition . High cetane number enhances cold starting and permits high-speed diesel engine operation. As one would expect, the fuels in current use cover a band when the two values, octane and cetane, are plotted against each other."

Jan 1, 1982

By Thomas M. Barczak

The decade of the 90's brought an unprecedented increase in the development of innovative technologies to provide more effective and easier to install roof support in underground mines. To facilitate the application of these technologies to improve mine safety. National Institute for Occupational Safety and Health (NIOSH) developed the Support Technology Optimization Program (STOP). STOP is a windows based software program that provides mine operators with a simple and practical tool to make engineering decisions regarding the selection and placement strategy of these various standing roof support technologies. This program includes a complete data base of the support characteristics and loading profiles obtained through safety performance testing of these supports at the NIOSH Safety Structures Testing Laboratory. Support design criteria in the form of the required support load density at a specified convergence can he established from four options: ( 1 ) a data base of measured ground reaction data from various mines or ground behavior information inputted by the user. (2) determination of loading requirements based on a detached roof block or rock failure height. or (3) criteria based on the current roof support system, and (4) arbitrary criteria set the by user. Using these design criteria, the program will determine the installation requirements for a particular support technology that will provide the necessary support load density and convergence control. Optimization routines are also available to determine the most efficient support design for a user specified support installation- In addition to these performance measures. STOP can be used to compare material handling requirements and installation costs. Comparisons among the various support technologies are easily made including graphical analysis of relevant support parameters. This paper describes the STOP and its application to optimize standing secondary roof support systems.

Jan 1, 2000

By D. Lauzon, H. de Ruiter

"In 1988a decision was taken to design and install a computerized mine monitoring and control system. This system had to monitor and control all pumping and ventilation underground. The operation of the mine air heating, using waste heat from the mine water and compressors, was to be part of the system. It ultimately also had to interface with the four existing Canadian General Electric Series 3 PLC's which controlled the No .3 shaft loading pockets. Beside operational control and trouble shooting, the system is a valuable tool in energy management and ultimate savings are estimated at $50,000 per year.The final equipment selection was a General Electric Series Six PLC on surface with a total of 17 Series One Plus and Juniors PLC located underground. Data is transferred through a two-pair shielded cable using modems. Both analog and digital functions are being utilized.The basic monitoring and control system was commissioned during 1989and, due to a higher level of technology today, further improvements have been planned for the future. The system was designed by Walter Dow together with Gordon Champion of D.G. Champion Engineering Ltd. of Toronto. Advice for the ventilation part of the project was obtained from Maurice White, Independent Ventilation Consultant.The Ministry of Energy, Mines and Resources and the Ministry of Energy of Ontario approved this project together with the waste heat recovery project to qualify for a grant of$135,000 under the Enerdemo-Canada program.IntroductionThe Macassa mine is a narrow vein gold mine situated about 2 km west of the town of Kirkland Lake in northeast Ontario. The mine has been in continuous operation since 1933 and a total of about 3.0 million ounces have been recovered out of 6.6 million tons of ore ."

Jan 1, 1991

By AIME AIME

THE report of the united. States Steel Corporation for the' year 1928 gives the, following ,figures of raw materials and' finished products . Raw materials, tons :

Jan 1, 1929

By Felipe P. D. Lopes, Caroline G. de Oliveira, Sergio N. Monteiro, Lucas A. Pontes, Janine F. de Deus

For decades, natural fibers have been studied as an economical and environmentally viable alternative to use instead of some types of synthetic fibers, for example fiberglass. To find the best way to make composites, the investigations shall be under various configurations, which is extremely important to understand the potentialities and facilities. To aim the comparison of impact performance of epoxy matrix composites reinforced with ramie fabric, the composites were produced by two different methodologies: under pressure and vacuum. The results show that the composites produced under pressure have greater resistance to both the Charpy and Izod Impact than under vacuum conditions.

Mar 1, 2018

By D. S. Rowley, F. C. Appl

Assuming that rock behavior, during cutting with a single diamond, may be approximated by that of a rigid, Coulomb, plastic material, a theory of single diamond cutting action has been developed. Using this theory, the stresses on the diamond cutting surface and the components of the cutting force have been determined. Theoretical results agree reasonably well with available experimental data. The theory of cutting of single diamonds may be used as the basis for subsequent study of the perfonnance of surface set diamond drill bits and other surface set diamond cutting tools. INTRODUCTION For more than twenty years, surface set diamond bits have been used successfully in the mining and petroleum industries to drill and core rock formations that range from medium hard to the hardest known formations. Most extremely hard rock formations cannot be economically drilled or cored by any other means. In view of the growing use and importance of surface set diamond drill bits, it is reasonable to study the way in which these tools cut, and the factors that influence wear of the diamonds. Such knowledge will contribute to better bit design and will improve operating procedures. To analyze the cutting performance of these tools it is appropriate to consider the way in which an individual diamond cuts. Once this is established, the over-all performance of the bits can be determined by considering the total effect of the individual diamonds. In recent years there has been a growing interest in rock mechanics and there now exist several publications dealing with the deformation and failure of rocks. Notable experimental work has been reported by Bredthauer,1 Handin and Hager,2, 3 and Gnirk and Cheatham.4 An extensive collection of data pertaining to rock properties at low confining pressures has been given by Wuerker.5 Cheatham and Gnirk have recently presented an excellent review of the state of knowledge regarding analytical and experimental rock deformation and failure.6 Generally rocks are extremely weak in uniaxial tension, and weak or only moderately strong in uniaxial compression. Both tensile failure and compressive failure are generally brittle in nature. This means that there is little or no deformation or "flow" of the material before shear or tensile fracture occurs. Thus, until fracture occurs, rock behaves very nearly like an elastic material in uniaxial stress. Significant changes in behavior of rock occur under conditions of triaxial compressive stress. There is generally a marked increase in compressive strength and in ductility. It has been demonstrated that the failure becomes plastic (in a macroscopic sense) at sufficiently high values of confining pressure. Sharp wedge chisel indentation studies conducted by Gnirk and Cheatham indicate that many rocks behave in a plastic manner at relatively low triaxial compressive stress states.4 If "failure" under triaxial compressive conditions is considered to be either complete rupture or macroscopic plastic flow, then the general failure characteristics of a rock can be reasonably well represented by the commonly known Mohr envelope. This certainly is not a perfect failure criterion (since the effect of the intermediate principal stress is neglected) but it has been found to be adequate for most engineering purposes. Mohr envelopes usually are constructed graphically using experimental triaxial test data. For purposes of analysis it is convenient to represent the envelope in equation form. Among the several approximate forms appearing in the literature, a parabolic form is suggested by Cheatham,7 and an exponential form is suggested by Paone and Tandanand.8 The exponential form has been adopted for this study, and based on published data, appropriate parameters have been established for 19 rock types. A typical plot of the data compared with the approximate envelope, and a summary of the rock properties and

Jan 1, 1969

By R. Marandi

Biosorption of heavy metals can be an effective process for the removal of heavy metal ions from aqueous solutions. In this study, the adsorption properties of nonliving (boiling in NaOH) biomass of phanerochaete chrysosporium. For Pb (II) and Zn (II) were investigated by using batch adsorption techniques. The effects of initial metal ion concentration, initial pH, biosorbent concentration, stirring speed, effect of temperature and contact time on biosorption efficiency were studied. Experimental results indicated that the uptake capacity and adsorption yield of one metal ion were reduced by the presence of the other metal ion. In the experiments the optimum pH value was found out 6.0. The experimental adsorption data were fitted to the Langmuir and Frundlich adsorption models. The highest metals uptake was calculated for Zn (II) and Pb (II) were 57 and 87 respectively. desorption of heavy metal ions was performed by 50 mM HNO3 solution. The results indicated that the biomass of p.chrysosporium is a suitable biosorbent for removing heavy metals ion from aqueous solution.

Jan 1, 2014

By J. Platt

Debate over acid rain legislation has presented a moving target for coal and utility company planners attempting to figure out how legislation will affect their business environment. In spite of disagreement among experts, the prospect for continued change, and persistent --perhaps even growing --uncertainty, a great deal has been learned about coal market dynamics. This paper reviews progress and describes some of the major problems and controversies.

Jan 1, 1990

By Wen L. Chen

The steam coal quality is less stringent than metallurgical coal quality. The steam coal is prepared either by cleaning full size range of raw coal or cleaning coarse coal only, leaving the fine coal raw. The latter scheme is more cost competitive. It is particularly applicable to U.S. eastern soft coal where low ash coal is concentrated in fine sizes. For raw coal size separation, a recently developed Rotating Probability Screen, developed by the British Coal Board, may be advantageously used for easy change of raw coal separating size and to avoid screen deck plugging when handling wet and clayey raw coals.

Jan 1, 1983

By C. C. Harris

The characteristics of some common size distribution equations are critically discussed. A generalized form of several well-known size distribution equations is obtained from a differential equation describing statistical distributions. The equation contains three parameters and can describe the major features of size distributions in the fine and the coarse size regions. A graphical method for its implementation is provided. The application of this and other equations to sets of data are compared both for the quality of fit and from a comminution kinetics viewpoint. If a narrow size range of a brittle material is broken sufficiently to obliterate the feed sizes, but not so severely that excessive secondary breakage occurs, a plot of cumulative fraction by weight undersize (Y) vs. sieve size (X) on a log log grid (sometimes called the Gates-Gaudin-Schuhmann plot)1-3 gives a straight line of slope ~ 1 over much of its range. On closer inspection, deviations in the extreme coarse range covering perhaps 10 to 30% of the total sample may be apparent (frequently, a change in slope from ~ 1 to a value different from unity) together with over-all slight irregular departures from a smooth line. One model of breakage postulates that the same fracture pattern persists throughout all size ranges.4 The fracture pattern is characterized by the slope of the line on a log log grid. Accordingly, a distribution of sizes broken in the manner specified earlier is expected to produce a size distribution having the same slope as that of a broken narrow size range. Additionally, the slight irregularities mentioned above should even out in the summation process, giving a smooth straight line of slope ~1 on a log log plot. This idealized state of affairs does not, however, describe the distribution of a multi-event process such as that for a tumbling mill product. On the average, these curves (plotted again log log) tend to have a slope in the fine region different from and usually less than unity,5 while the coarse size region curves with increasing slope for cases of mild reduction, and with decreasing slope when moderate or severe size reduction has occurred. In addition, there are usually slight irregular deviations from a smooth curve. Most curves display two distinct regions — fine and coarse — and a few curves show one or more intermediate regions. Feed size studies6,7 show an effect which theory is required to explain. For the same material, mill loading and other operating conditions, and the same time of grinding, plotting the dimensionless ratios Y vs. X/(feed size) does not reduce the size distribution data to the same curve. Y vs. X does not correlate the coarse region, but it can provide a crude correlation of the fine region which improves as size diminishes and as grinding time increases. The size distribution in the coarse region is somewhat more dependent on the feed size than is the distribution in the fine region wherein the degree of dependence diminishes as time proceeds; the distribution of sizes in the fine region are determined largely by the nature of the material and the comminution conditions. A comprehensive model of comminution must recognize that several different patterns or modes of breakage can occur in a mill; 5,8,9 that there can be some selection in that some size ranges are broken more than others; and that, while some particles may be the product of a single fracture event, or may even remain unbroken, others result from multiple rebreak-age. Thus, breakage in a tumbling mill is more complex than the Schuhmann4 model admits in that several different types of comminution micro-events* occur rather than just one type, and these events, though different in size scale, are of the same overall pattern as that which is visualized by the model. The concept of an average comminution micro-event has, therefore, a mathematical rather than a physical connotation, at least for tumbling milling. Equations with which to describe particle size distributions have been sought for over half a century.10-13 No equation presently in general use was first derived from an analysis of the statistical mechanics of breakage; whatever theoretical basis the existing

Jan 1, 1969

By D. Lunt

This paper describes and sets in context the commercially proven uranium extraction processes. It also discusses some of the technologies that are currently being pursued with the aim of reducing costs and overcoming a number of technical issues that are faced by process designers and operators. In doing so, opportunities for the transfer of extraction technology from other industries/commodities are identified. The key processing areas that are examined include: ?The influence of mineralogy. The type of uranium mineralization and the nature of its association within a particular deposit will have a major impact on process route selection. Uranium minerals are classified according to their influence on extractive metallurgy. As the uranium price has risen in recent times, so opportunities are increasing for the recovery of uranium from less conventional resources such as phosphates and fossil fuels. ?The opportunities for employing techniques aimed at reducing the capital and operating costs of the overall process such as heap leach and beneficiation. Preconcentration by screening, gravity separation and radiometric sorting can potentially reduce the mass flow to the downstream leach and recovery plants. ?Purification or separation of uranium in carbonate systems. While it is possible to directly precipitate uranium from clarified leachate, the presence of impurities such as vanadium, molybdenum and others may dictate that ion exchange or selective precipitation is employed. Advances have been made in other industries in terms of improved ion exchange equipment aimed at reducing resin inventories and hence costs. ?Separation in acid leach systems. Earlier developments included the use of combined SX-IX systems (Eluex or Bufflex) and the introduction of continuous countercurrention exchange (CCIX). Column SX has found a ready application to uranium in view of the rapid extraction kinetics. With the renewed interest in uranium processing, efforts are being redirected towards further development of resin-in-pulp (RIP) as a means of driving down capital and operating costs. ?Extraction in a chloride environment. Australia and Namibia are desert countries where good quality water comes at a cost. However, both have access to saline water from either the ocean or subterranean aquifers. The issues associated with operating a uranium extraction operation in such environments is discussed. ?Extraction from less conventional sources. Recent price increases for U3O8 have resulted in a number of companies examining the recovery of uranium from sources such as fossil fuels and phosphate deposits. Both of these areas were examined in the 1970s and 1980s and a number of approaches were commercialized. The paper reviews the extraction options.

Jan 1, 2007

By Lewis L. Oriard

INTRODUCTION In recent years, there has been a trend in the direction of larger drilling equipment and larger diameter blastholes. Although this change has improved the efficiencies and reduced the costs in many operations, it has increased the potential for damage to underground openings. In addition, in many instances one now finds more sophisticated delicate instruments, automated control facilities, and a large variety of structures in proximity to blasting activity. The combined effect of larger-scale blasting activity and its proximity to various features of interest is such that there is an increased need for a more refined analysis of blasting effects and their control. BLASTING EFFECTS ON ROCK SURFACES The Breakage Mechanism In order to develop techniques for controlled blasting, one must first understand the features of the mechanisms by which blasting causes rock breakage to occur. These features have not been easy to demonstrate, mostly due to the difficulty in making tests and observations at the high stress levels and short time durations involved. When an explosive charge is detonated, the material surrounding the charge is subjected to a nearly instantaneous, very high pressure [on the order of 1.4 to 13.8 GPa (0.2 to 2.0 X 106 psi), depending on the explosive]. If the charge is coupled to "average" rock, this pressure will pulverize the surrounding rock for a distance on the order of 1 to 3 charge radii in hard rock, and to a greater distance in softer rock (this is also dependent on the type of explosive). As the pressure wave passes into the rock, high tangential stresses cause radial cracks to appear, and the nearly discontinuous radial stress zones gen¬erated by the shock front may cause tangential cracks to appear. The extent of these cracks depends on the energy available in the explosive, how quickly the energy is transmitted to the rock, and the strength properties of the rock. The discontinuous shock front is quickly dis¬sipated, but the expanding gases generate a longer-acting pressure. A compressive pulse travels to the nearest face or internal rock boundary where it is reflected in tension. The tensile strengths of most rocks are roughly 40 to %o of their compressive strengths, so the rock may now fail in tension whereas it may have been able to support the diminished compressive phase without failure. The ten¬sile deflection typically produces a failure described as tensile slabbing or scabbing. Laboratory experiments and field experience have pretty well established that several mechanisms are involved. These include (1) the classical case of tensile parallel slabbing when the pressure pulse is reflected at a free surface; (2) failure under quasi-static compressive loading (the shape is normally irregular due to discontinuities in the rock); (3) radial cracking under the action of tangential stresses at the periphery of the expanding pressure pulse; (4) peripheral cracking at the discontinuous shock front which is quickly dissipated; and (5) additional mass shifting due to the venting of the explosive gases. The first three items have received much attention in the laboratory and the literature. The complex effects of gas venting are difficult to test in the laboratory because of the difficulty in reproducing the many weak planes and discontinuities typical of most field conditions, which play such a prominent role in determining the behavior of the rock mass subjected to blasting. Unfortunately, gas venting effects can be pro¬jected to significant distances under certain field conditions, and are sometimes difficult to control. It is not unusual for gas venting to be the overriding factor in determining the final geometric shape and physical condition of the finished excavation. Sources of Damage For the purposes of this discussion, damage includes not only the breaking and rupturing of rock beyond the desired limits of excavation but also an unwanted loosening, dislocation, and disturbance of the rock mass the integrity of which one wishes to preserve (such as mine pillars, underground openings, etc.). The sources of damage include, of course, all those physical features of the rock breakage mechanism. Each of these effects must be limited to the desired zone of breakage and excavation if the integrity of the remaining rock mass is to remain undiminished. The primary zone of rock breakage usually can be controlled in the normal process of field experimentation to determine proper charge sizes and location for primary excavation. However, it frequently happens that there is damage from sources which are more difficult to account for in the design process, which are often overlooked. These are (1) the overbreak due to poor drilling control, (2) dislocation of rock (mass shifting) due to venting of explosive gases, and (3) loosening or dislocation due to the influence of seismic waves (ground vibrations). CONTROL OF ROCK BREAKAGE Importance of Geometry In studying the rock mass and blasting design con¬siderations, it is important to keep in mind the geometric relationships among charge size, shape, and position, and the physical features of the rock mass to be preserved. The features of principal interest are the external shape and position of the rock mass relative to blasting, and the position and attitude of any weak planes in the rock mass. The Sequence of Blasting and Excavation Events Unfortunately, there are too many times when the task of preserving delicate rock is considered hopeless, and because of this attitude, no further effort is ex¬pended towards caution or control. In such cases there is often a failure to recognize the importance of the se¬quence of the procedures. Attention to this can greatly reduce unwanted effects at minimum cost. Perimeter Control The requirements for perimeter control are highly dependent on the special needs of each particular proj¬ect. The desirable degree of control is a highly variable

Jan 1, 1982