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By J. B. F. Champlin

The continuing development of the nuclear industry in the United States requires a program of waste disposal that insures against the release of large amounts of radioactivity to the environment. This paper describes research on one proposed means of disposal of this waste, that of injection into geologic formations at depth. Nuclear production plant wastes were simulated and injected into samples of sedimentary rock obtained from outcrops, quarries, and deep wells. Changes in the chemical and physical characteristics of the rocks caused by the interaction of ions and suspended particles in the waste solutions with the cementing material and claylike particles in the rock are discussed. Laboratory tests show that nuclear wastes can be injected into many natural porous, permeable geologic formations. Injectivity can be maintained over a longer period by monitoring the ionic balance and particle-size distribution of waste streams. The combination of permeability and porosity with low cation-retention capacity, as exhibited by most sandstones, would satisfy the engineering requirements for the subsurface disposal of nuclear waste. Shales and clays with their low permeability and high cation-retention capacity would make excellent confining formations. The amount of cation retained by sedimentary rocks increases with increasing valence or concentration of the cation or decreasing brine concentration. The use of rock cores as model reservoirs had proved successful in determining some of the parameters that need to be considered in full-scale field disposal of wastes.

Jan 1, 1967

By R. Degel

Keywords: Pyrometallurgy, DC furnaces, electric smelter, FeCr, FeNi, FeMn, Si metal, ferro-alloys, platinum production, circular furnace, energy recovery system In 1906, the first submerged-arc furnace was supplied by SMS Siemag. Since then, the division has become established in various industries such as ferro-alloys and non-ferrous metals, and in numerous other special applications. During the evolution of this technology, more efficient units with longer lifetimes were developed. Today, especially the potential of DC-based smelters, raises worldwide attention, with some projects having already started to implement this kind of technology. This paper evaluates SMS Siemag?s general viewpoint regarding the potential application of DC smelter technology and possible options for the ferro-alloy and non-ferrous industry. SMS Siemag is currently executing a FeCr project in Kazakhstan, where four of the world?s largest closed-type DC smelting furnaces, with a power input of 72 MW, will be installed. These furnaces include the latest technological features of modern DC smelters, which are described in this paper. SMS Siemag has started a long-term research and development project allowing a direct comparison of AC versus DC technology on a large scale, using a recently installed 1 MVA test furnace at the IME at the University of Aachen, in Germany. For open-type ferro-alloy and Si-metal furnaces, SMS Siemag has developed an energy recovery system, which is presented in this paper.

Jan 1, 2011

By P Jonsén, S Larsson, M Parian, B I. Pålsson

The question of effective energy utilisation in grinding mills is not new. There are several conflicting arguments about tumbling mills, whether the efficiency is around 1 per cent or maybe 10 per cent, or even much lower. The energy not used is assumed to be lost as heating of the pulp, the grinding mill body, the charge, generation of shock waves and vibrations, etc. Stirred media mills on the other hand are generally considered to have better energy utilisation, but their energy efficiency is still not that clear. To shed some light on this a pilot-scale, wet stirred media mill was investigated over a range of operating conditions. The wet stirred media mill is a Drais PMH 5 TEX pearl mill fitted with an electric motor at 11 kW. It has been investigated over a range of operating conditions to try to balance the dissemination of the input energy in forms of the net grinding energy, mechanical energy losses, and the heating transferred to the pulp, the mill, the charge, and the cooling water. It is found that approximately 20–40 per cent of the input energy accounts for the grinding process. Also, that the difference between gross and net input electrical energy is mainly disseminated as heating of the pulp and cooling water. Mechanical energy losses appear to be much smaller than the heating effects. The use of a dispersant seems to mainly influence the heating effect.

Aug 24, 2022

By J. E. Johnson

IT is the purpose of the present paper, while not excluding chemical considerations, to deal more extensively with some of the physical and mechanical aspects of the blast-furnace process, and to point out its dependence in these respects on well-known laws. The quantity and cost of ore and flux required to make a ton of iron being determined by circumstances over which the furnace-man, under given conditions as to quality and quantity of product, has commonly little control; the principal item of cost, apart from the saving of labor, which he can aspire to reduce, is that of fuel. To determine the limits of possibility in this direction is clearly the first step in d practical inquiry; and this step is represented herewith in Fig. 1, a diagram showing the total useful effect obtained from a pound of fuel under various conditions, and thus permitting direct comparison, under any given conditions, between actual results and the maximum possible results. The following statements will explain the basis upon which this diagram has been constructed. One pound of fuel, containing 90 per cent. of fixed carbon (which represents average conditions), is taken as the unit. The degree of oxidation of the carbon is measured by the ratio of the two oxides of carbon contained in the top-gases. It is necessary to remember that a considerable quantity of carbon is brought in as carbon dioxide by the flux, and to take account of it and of its condition. It is here considered that the carbon dioxide liberated by the limestone does not affect the analysis of the toll-gases, and that the ratio of CO to CO., will remain unchanged by the addition of limestone; enough CO, being reduced by the solution

Sep 1, 1905

By Dao-Wu Yang, Ju-Lan Zeng, Li-Xian Sun, Yan Yao

"The hydration heat of the pure cement, the fly ash single-dopped cement, as well as the fly ash and fluorgypsum co-dopped cement were investigated by means of micro-calorimety with an eight-channel micro-calorimeter (TAM Air). The results showed that the hydration heat and the hydration rate could be reduced significantly by fly ash and fluorgypsum. However, the reduction was not proportional to the loading of dopant. The exothermic peak of the fly ash and fluorgypsum co-doped cement was appeared earlier than the fly ash single-doped cement. As the temperature decreased, the hydration heat and the hydration rate of the doped cement were reduced, and the exothermic peak appeared later. The effects of fly ash and fluorgypsum on the compressive strength of cement were also investigated. The results revealed that the early compressive strength of concrete made up of the co-doped cement was largely higher than that of the fly ash single-doped cement. Based on the experiment results obtained in this paper, we could conclude that fluorgypsum is a suitable additive for fly ash-doped cement.IntroductionFly ash and fluorgypsum are industrial waste. In 2008, nearly 400 million tons of fly ash has been produced by coal-burning power plants in China. And it is estimated that this number would exceed 500 million at the year of 2015. Besides, every year the fluoride salt factories in China discharge more than 100 million tons of fluorgypsum. Tremendous of fly ash and fluorgypsum occupy considerable land and contaminate air and water sources [1]. As a result, comprehensive utilization of this two industrial waste has draw great attention from all over the world.Cement is the most-used construction material on earth. But the production of cement consumes huge energy and destroys the environment. This problem might can be partly solved by applying fly ash and fluorgypsum as additive for cement [2-4]. During the last decade, some papers that focused on applying fly ash and fluorgypsum as additive for cement have been published [5, 6]. However, to the best of our knowledge, none of these papers investigated the hydration heat of the fly ash and fluorgypsum co-doped cement.The hydration of cement is an exothermic reaction, which can result in serious problem for mass concrete: The interior of the concrete could reach very high temperature as the hydration proceeded [7-9]. As a result, the great temperature difference between the interior and the outer of the concrete would exist and cause serious thermal stresses. Thus, the concrete would be destroyed by the cracks which in tum are resulted from the thermal stresses [10, 11]. The heat released by the cement hydration and the hydration rate is commonly regulated by adding mixed materials or transferring additive such as fly ash and fluorgypsum [12-14]."

Jan 1, 2011

By S. Vorberg, J. Preussner, B. Fischer, U. Glatzel, R. Völkl, M. Wenderoth

Pt-Al-X alloys have shown good mechanical properties and adequate oxidation resistance. Starting from a promising Pt-Al-Cr alloy, the influence of Ni additions was investigated. After ageing finely dispersed precipitates are observed. Nb, Ta, Ti and Re increase strength when added as partial substitute for Al. Minor additions of B increase creep resistance and rupture time remarkably, owing to strengthening of the grain boundaries. The evolution of the alloy development programme as well as selected properties of the multi-component Pt-base alloys are presented.

Jan 1, 2006

By Neville T. Moxen, Stuart K. Nicol, Malcolm D. Engel

Ion flotation is a process in which ions of interest are complexed with a suitable surfactant molecule. A dilute solution containing these complexes is then aerated, under which circumstance the surface-active complex concentrates at the air-water interface and is transferred to a froth. The present work describes some of the phenomenology of this process and experimental work leading up to the design and use of a pilot scale laboratory facility. Early experiments suggest that selective recovery of gold can be obtained in a manner at least equivalent to conventional CIP processing at low capital cost. Under favourable conditions, upgrade ratios of gold ions of the order of 180: l have been achieved from reclaimed residue dam water with as low an initial gold level as 0.2ppm. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal processing.

Jan 1, 1990

By Joaquin Marti, Peter A. Cundall

This paper reports on some recent work in which several schemes were developed to model jointed rock under high stress, with particular reference to the phenomenon of "block motion" observed during dynamic loading of underground structures. Three approaches were made, corresponding to an increasing relative importance of internal block deformations as compared to rigid block movements. The first one uses distinct element method and assumes internally rigid blocks, which can break, repeatedly, whenever an empirical crack criterion is met. In the second approach each block is allowed three degrees of freedom to deform internally. The third approach, still in the development stage, permits arbitrary deformation of all blocks, which are internally decomposed into finite-difference zones and automatically rezoned during slip to preserve the calculation accuracy on joints. The last two schemes allow arbitrary constitutive relations for the intact rock, and all three schemes permit the geometrical arrangement of joints to be arbitrarily complex, in contrast to normal Lagrange, finite-difference programs, which are unsuited to model discontinua.

Jan 1, 1979

By Jan W. Oberholzer, Jan J. L. Du Plessis, Gerard Appelman, Andrzej M. Wala

The use of on-board scrubbers on continuous miners is an important aspect in efforts to reduce the amount of dust that heading workers are exposed to. As part of the CSIR:Mining Technology's research programme to combat dust, a collaborative project with the University of Pretoria was conducted to evaluate scrubbers. Based on fundamental parameters that were identified to play a role in determining the efficiency of scrubbers, a protocol for testing scrubbers in the laboratory environment, as well as the working section, was established. Tests on various prototype scrubbers were conducted in the laboratory environment. These tests proved some of the fundamental premises according to which scrubbers were designed. By testing some of the newer scrubber types underground, insight into the effect of alternative design aspects on scrubber efficiencies was obtained. The importance of the factors which play a role in reducing the amount of dust in the air is illustrated, as well as the role which other non-design factors play in the reduction of dust levels.

Jan 1, 1995

By R. H. King

This paper describes the results of an underground coal mine trial installation of a shielded trailing cable. The cable was a three conductor, round, type SHC-GC and was installed on a shuttle car in a conventional room-and-pillar mining section. The purpose of the study was to evaluate proposed legislation that would require shielding on low-voltage trailing cables. Such legislation would require machine modifications to cable reels, packing glands, and couplers; increase cable splicing complexity; and necessitate additional splicing materials and training. Furthermore, fault location might be more difficult. Even though shielding will cause some problems for the mine operator, it can reduce electrical shock hazard to mine workers. This paper presents information that mine operators can use to solve most of the problems encountered if they are required to install shielded cables. The in-mine evaluation was funded by the US Bureau of Mines; however, the views and conclusions in this paper are those of the author and should not be interpreted as necessarily representing official policies of the US government.

Jan 1, 1982

By S. P. Goplen, M. Henriksen, T. F. Barron

In the past decade, numerous large scale drilling projects have made use of reverse circulation air lift methods. Reverse air lift pumping can be established by injecting gas into a column of liquid; the subsequently decreased density of the gas-liquid mixture allows atmospheric pressure outside the lift conduit to establish flow. The rate of flow can be controlled by varying the gas to liquid ratio. A typical reverse circulation air lift system is depicted in [Fig. 1]. Allen 1 has described a number of reverse air lift drilling projects. Although cited examples are generally related to large diameter holes, the method has seen use in other applications such as sand dredging, chemical pumping, water well pumping. and continuous coring. One particular benefit obtained with enclosed reverse circulation drilling is elimination of lost circulation. The required air/water ratio for pumping at a given submergence and lift has been established experimentally by Gibbs.2 His data, however, do not reflect sensitivity of flow rate to air/water ratio. Further, in Gibbs' work, air apparently is injec-

Jan 1, 1980

By R. G. Mallon, R. L. Braun

Primary copper-sulfide ore deposits that are well below the water table can be chemically mined by in-situ high-pressure leaching. The leaching is accomplished by pumping oxygen gas into the bottom of a large underground flooded column of rubblized ore. Part of the injected oxygen dissolves under the high hydrostatic pressure in the column. With a high enough injection rate, the excess oxygen gas induces a convective circulation of oxygenated solution within the rubble column, which transports dissolved oxygen throughout the system. At elevated temperatures, this results in a relatively rapid dissolution of the copper minerals. A method of calculating the leaching rates is presented. The calculation is done by means of a finite-difference computer code that couples all of the processes relating to copper leaching, convective circulation, and the injection, dissolution, and consumption of oxygen. Results of the calculation for a typical case show that over 70% of the copper can be extracted in less than six years with good efficiency in oxygen utilization.

Jan 1, 1976

By M. H. Basiri

Crude oil, as a central commercial commodity, is tied to major economic activities in all nations. Also its price fluctuation plays a significant role in global political and economic situation, as a change in the price invariably affects the cost of other goods and services. Therefore reliable forecasts of the price of oil are interest for a wide range of applications. Several approaches have been proposed over the past few years. These may divide into three categories; artificial intelligent, statistical techniques and hybrid methods. The neuro-fuzzy is one of the sub divisions of hybrid method, containing neural network and fuzzy techniques. In this paper a novel forecasting model based on adaptive neuro-fuzzy inference (ANFIS) is proposed to predict monthly crude oil price. To be able to train and test the model, the statistical data from 1990 to 2010, was obtained from West Texas Intermediate oil prices. The results are compared with a multi criteria regression analysis, it is demonstrated that the neuro-fuzzy lead an accurate and more promising forecast.

Jan 1, 2012

By Rundqvist

The best method to minimise disturbances from traffic to the neighbourhood and in Urban is probably to go underground. For obvious reasons this will cause vibrations, noise and other environmental effects which need very strict regulations and quality assurance in order to complete the work successfully. One project is “Southern Link”, a part of a ring road system. The system of tunnels includes 16 kilometres of tunnels right beneath the south part of the city of Stockholm. At least 20.000 people will be or could be affected by different kinds of disturbances and pollution such as vibrations, noise, gas and groundwater. Another project is the “Arlanda Link”. A new railway with three stations has been built under the existing and running to Arlanda airport with its terminals. Authorities have carefully judged these projects, which cause complaints from neighbours due to disturbances. The blasting operations are professionally managed by the contractors and controlled by consultants to keep the regulations according to the Swedish standards, which are well described in the tender documents by risk analysis and technical descriptions. In spite of that, one conclusion is that it is not always possible to go underground without exceeding stipulated regulations with existing technique. Some of the regulations also double the cost of excavation

Jan 1, 2001

By Tuncel M. Yegulalp, Anuta Belova

This paper expands on the ZECA (Zero Emission Coal Alliance) technology, which is aimed at making coal a sustainable source of clean energy in the near future. The technology proposed immediate capture of carbon dioxide and other pollutants upon generation, thus alleviating their negative effects in the Earth’s atmosphere. ZECA proposes using chemical energy of coal to produce hydrogen; the latter is then used to produce electricity via fuel cells or Hyrogen-Oxygen turbines. In this study, a chemical engineering package, AspenPlus 12.1, is used to simulate the reactor (reformer) in which hydrogen is produced from methane water and lime as part of the zero emission power plant. Thermodynamic conditions, pressure and temperature, are optimized with respect to molar hydrogen production. Under the proposed conditions, molar conversion efficiency, carbon to hydrogen, of 95% is achieved. Further studies are required to model the complete power plant and to optimize it for efficiency.

Jan 1, 2005

By S. Yano, S. Takagi, Y. Nagaya, T. Akai, T. Ishida, Z. Bennour, T. Suzuki

"It is often reported that the concept of single-plane-fracture is not sufficient to account for the productivity from shale gas/oil wells. Many researchers introduce the concept of the stimulated reservoir volume to describe observed production behaviour. However, the characteristics of the stimulated reservoir volume are not well understood. In this study, to investigate the characteristics of fractures and surrounding region induced by the hydraulic fracturing, a devised hydraulic fracturing experiment was conducted using the cylindrical shale specimens in the laboratory.Two resins were prepared as the fracturing fluid for the experiments: cyanoacrylate, an instant glue, mixed with a fluorescent paint (resin A), and methyl metaacrylate, a thermosetting acrylic resin, mixed with a fluorescent paint (resin B). These resins were able to fix within the specimen after fracturing. This is because the present study aimed to only detect fractures induced by hydraulic fracturing. Cut sections of the specimens were observed under ultraviolet light irradiation. It is expected that the hydraulically induced fractures and the surrounding regions will be detected because the induced fractures filled with the resin should emit light, while the other parts will not.The specimens, which were collected from the Kushiro Coal Mine in Hokkaido, Japan at the depth around 275 m, were roughly 85 mm in diameter, 170 mm in length, and cored normal to the sedimentary planes. An injection hole with a 10-mm diameter was drilled onto the center of the specimen parallel to the sedimentary plane to simulate hydraulic fracturing in shale gas development. The experiment was conducted under a uniaxial loading condition of 3 MPa and the fracturing fluid was injected into the sealed injection hole at a constant flow rate using a syringe pump.After the fracturing experiment, the resins were fixed in the specimens and then the cut sections were observed under ultraviolet light irradiation. As a result, the hydraulically induced fractures, which were filled with the resin, are clearly observed. Detailed microscopic observations show that the main fractures are tortuous and are accompanied by many thinner ramified fractures. Additionally, fractured regions where the resin penetrates significantly are observed around the main fractures in the specimens fractured by the resin B. These induced fractures and fractured regions are considered to be the stimulated region in which permeability is improved. The necessity of estimation on the features of fracture tortuosity and ramified fractures is indicated for more accurate understanding of the well production and the stimulated reservoir volume."

Jan 1, 2015

By J. M. Snook, F. C. Langenberg

FOR a better understanding of the melting and refining processes, the oxygen content of the steel bath should be determined. The oxygen content influences many process and product variables such as the efficiency of alloy recoveries, the ingot structure (through reaction with carbon in the steel), certain reaction rates, cleanliness (formation of indigenous oxide inclusions), and mechanical properties. Many methods of sampling liquid steel for oxygen have been devised. These methods can be divided into two main groups: 1) taking samples directly in the furnace or ladle;'-'0 2) removing the metal from the furnace or ladle in a sampling spoon and pouring it into a mold, or drawing the metal from the spoon into a sample holder.11-l4 The advantages and disadvantages of the two general sampling methods are presented in Table I. The bomb-sampling technique described by Huff, Bailey, and Richards8 has been used by the Crucible Steel Co. in certain research projects where oxygen contents were needed. It was recognized that a localized boiling condition could result when the mold is introduced into the steel bath, although the work of Gilbert and Bailey9 seems to indicate that the carbon boil occurring in the bomb-sampler cavity has a negligible effect on the oxygen content. In order to confirm the reported negligible effect of a carbon boil, additional work was done with adaptations of the conventional bomb sampler. The methods used are shown in Fig. 1 and are as follows: 1) Type A: aluminum wire (0.125-in. diam) coil in cavity; steel cap over mouth 2) Type B: aluminum cup in cavity; aluminum cap over mouth, 3) Type C: aluminum cup in cavity; steel cap over mouth, 4) Type D: fine aluminum wire (0.013-in. diam) in cavity; steel cap over mouth. The amount of aluminum wire in the Type A and D samples varied from 0.8 to 1.2 pct of the sample weight. The aluminum cups averaged 2.0 pct of the sample weight; the latter were used to ensure that the steel contacting the walls of the bomb cavity was fully killed. Samples were taken from plain carbon heats made in open-hearth furnaces. This grade of steel before silicon additions is essentially an Fe-C alloy and the effects of other alloying elements on the oxygen activity can be neglected. The results of sampling with the bomb samplers is shown in Fig. 2 where the percent oxygen is plotted against the percent carbon on log-log paper. Spoon sample results on the same grade of steel where the sample was killed in the spoon are shown in Fig. 3. The oxygen contents were determined by the vacuum fusion method. A comparison of Figs. 2 and 3 shows that the oxygen concentrations obtained with the spoon-sampling method (metal killed in the spoon after slag removed

Jan 1, 1960

By Dennis R. Dolinar, Christopher Mark, Gregory M. Molinda

Despite more than half a century of experience with roof bolting, no design method has received wide acceptance. To begin to improve this situation, National Institute for Occupational Safety and Health (NIOSH) conducted a statistical study of roof bolt performance at a number of mines throughout the U.S. Case histories were collected from 37 mines with a variety of roof bolt types and patterns in a wide range of geologic environments. Performance was measured in terms of the number of roof falls that occurred per10,000 ft of drivage. The study found that roof falls are rare when the roof is strong and the stress is low, even with light roof bolting patterns. The focus of this paper is on the more difficult conditions, where the roof is weaker and/or the stress is higher. Analysis of the results led to guidelines that can be used to make preliminary estimates of the required bolt length, capacity, and pattern. The guidelines are based on the depth of cover (which correlates with stress) and the roof quality (measured by the Coal Mine Roof Rating (CMRR), and the intersection span. Another contribution is a formula for estimating the horizontal stress level in the eastern U.S. coalfields as a function of the depth of cover. The design guidelines are currently being implemented into a computer program called Analysis of Roof Bolt Systems (ARBS).

By James C. Foley

In-situ characterizations of green state part density and sintering state have long been desired in the powder metal community. Recent advances in non-contact electromagnetic acoustic transducer (EMAT) technology have enabled in-situ monitoring of acoustic amplitude and velocity as sintering proceeds. Samples were made from elemental powders of Al (99.99%), Al (99.7%), Ag, (99.99%), Cu (99.99%) and Fe (99.9%). The powders were pressed in a uniaxial die and examined with acoustic waves for changes in velocity and amplitude during sintering. The changes in acoustic properties were correlated with mechanical properties. Evolution of a series of reverberating echoes during sintering is shown to provide information on the state of sintering, changes in sintering kinetics as well as having the potential for detection of interior flaws.

Jan 1, 2001

By G. I. McPhail

The authors have conducted several investigations into the prediction of the beach profile of high-density tailings and have found that there are a number of important considerations that need to be taken into account over and above the reliability of the beach profile prediction methodology. These considerations relate to the chemistry of the slurry and specifically the influence of pH and flocculation, both of which have a significant influence on the rheology of the slurry at the discharge point. A number of examples are discussed and a potential testing protocol that will assist in assessing the influence of chemistry ahead of the beach profile predictions is presented. A methodology for assimilating the results of the testing into the likely field situation is discussed, and suggestions are made on application of the results in beach profile prediction. The suspected influence of residual flocculation on the stratification

Jan 1, 2012