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By M. Kawahata

Methane sensors using principle of catalytic oxidation of methane are employed for determination of methane content in ambient air of coal mines. Certain foreign gases or vapors in the air poison the catalyst of the sensor effecting the sensor's response. After literature search of poison compounds of Pt and Pd oxidation catalyst, experimental studies of catalyst poison kinetics were made for three siloxane compounds, tributyl-phosphate, monobromotrifluoromethane, and hydrogen sulfide, selected as poison vapors. Concentration range of the poison vapors was varied in a range from 3000 to 0.1 ppb (v/v). Three siloxane vapors produced strong catalyst poison effect, followed by tributylphosphate, hydrogen sulfide and monobromotrifluoromethane for the high concentration level of the poison vapors. The poison effects are influenced significantly by concentration of the vapors. Threshold poison vapor concentrations where effect of the poison vapors on the sensor is minimal were determined experimentally. Experimental studies were made further for prevention method of catalyst poison by adsorption techniques. Use of activated carbon cloth inserted on the sensor's head prevented catalyst poisoning efficiently.

Jan 1, 1981

[This Report represents the culmination of work perfomed under Contract No. .,JG1551A8 for the U.S. Bureau of Mine.The &apos;.:o-< embeded a site evaluation, engineering E:-y- ,, esign, and preparation of specifications for construction of a Transport Research 7 :4 (HTRF)The HTRF is designed as a research facility J evaluate the hydraulic transport of large lump coal at a prototype ;e scale. The HTRF is to be constructed and operated by the Pittsburgh and Safety Research Center of ;. re U.-AN a*, their Bruceton, Pennsylvania test center. In terms of technical capability, the HTRF will have transport pipeline:: of -, twelve-, and eighteen-inch diameter _&apos; with supporting coal handling n , water forage a.^ &apos;d conveyance, mixing, pumping, and dewatering equipment, plus instrumentation and controls. Maximum design velocity 13 20 ft/sec.; solids concentration, by, volume, will; 1 be a maximum-- of sixty, percent. Each test loop is designed to accommodate solids of up to one-third the diameter e - of the pine. The Final Report Pr.-&apos;I-rents information of t HTHF,. including the site evaluation, design criteria, a description of the a description of the procedure to be used for operation of the facility, an estimate of the cost to construct the f^Cilit:r, 1 p el_~lli.&apos;iU construe`, icn Schedule, and a construction suicJ_iicaT.l_ccn&apos;. T e c011SLr?Jc&apos;.ion soecl_ i.on _ccnta_i:s technic.&apos;..i re7,uir: (-n`,s for !&apos;urr1S~ &apos;~latcr..al. and ec-uipr,ent for :":C1 C_`:_C ti on of ti,_ H ice&apos; u:&apos;.:i ._II u s(-.6 for ~.Iir: .3!7 soliciting bids. `.l_o included n cc&apos;;,art_- c?r~.air sV:et..: :s ^nd rr^.?]

Jan 1, 1976

By A. T. Adema

The cohesive zone, where the ore fed into the blast furnace softens and melts, is critical to the blast furnace performance and stability due to its influence on the gas and solid flow. This paper de-scribes a project for the development of a process model to predict the cohesive zone properties and the results of its first step; the solid flow model. The process model is expected to describe a realistic solid burden flow and the formation of the cohesive zone, its shape, location, structure, permeability, and in particular the mineralogical changes within the cohesive zone. This will be achieved using various simulation and computing tools: a combination of the Discrete Element Method (DEM) and Computational Fluid Dynamics (CFD), the DEM?CFD hybrid approach, together with models for the thermodynamics and reaction kinetics. The key benefits of the hybrid approach lie in the coupling of the continuous phase and the discrete particles, and the possibility of introducing thermodynamics and reaction kinetics into the system in a more realistic manner. Two DEM simulations are presented for a small scale blast furnace to investigate the influence of non-spherical particles on the solid flow. This influence can be observed from a more even solid flow pattern and a reduced deadman size. The results indicate the requirement to include non- spherical particles in a blast furnace simulation to achieve a realistic solid flow.

Jan 1, 2014

The STATE MINERAL SUMMARIES publication provides estimated data and summaries of mineral activities at the State level for 1990. Most of the estimates are based on nine months data. These summaries have been prepared in cooperation with State geological surveys or related agencies. Individual State summaries are published separately as State Mineral Industry Surveys and copies can be obtained from the appropriate State Activities field office.

Jan 1, 1991

By M. S. Seehra, R. S. Pandurangi

"INTRODUCTION Silica and kaolin (a layer aluminosilicate) are among the major constituents of most coal mine dusts.' Whereas kaolin is cytotoxic in vitro but nonfibrogenic in vivo in humans and experimental animals,2-4 the cytotoxic and fibrogenic potential of silica is rather well established.5 Wallace and co-workers 6-8 have studied the cytotoxic potentials of both native and surface-modified silica and kaolin and inferred that retoxification is slow in the case of occluded silica vis-à-vis native silica. Recent epide¬miological studies indicate that silica concentration alone in a mine dust, as determined by transmission IR spec¬troscopy (TIRS), does not correlate well with the pro¬gression of coal workers' pneumoconiosis. 9 This obser¬vation has led to the suggestions that silica particles occluded by clays such as kaolin may not be fibrogenic. This proposal requires accurate estimations of kaolin, silica, and occluded silica. The current method of silica analysis in a mine dust sample employs TIRS of the 797- cm -1 band of silica, although its accuracy, as well as that of x-ray diffraction studies, is no better than 25 % , even in a laboratory-generated dust.° In this paper we have employed the techniques of diffuse reflectance spectros¬copy (DRS) and photoacoustic spectroscopy (PAS), in conjunction with an FT-IR spectrometer, for the quan¬titative determination of silica in laboratory-generated silica-kaolin mixtures.One of the main advantages of DRS and PAS is that, in these techniques, problems arising from sample prep¬aration of the KBr-based disks used in TIRS are avoided. There are, however, several other considerations (e.g., particle size effects and saturation phenomenon) which complicate the use of DRS and PAS for quantitative work. 10-25 In this paper, we have carried out a systematic comparison of the quantitative abilities of the two tech¬niques, as applied to the silica-kaolin mixtures, with par¬ticular attention to the saturation behavior of several bands with different absorption coefficients. In particular, we show that a weaker band for silica at 1875 cm-1 is suitable for quantitative purposes, and that quantitative accuracy is higher in DRS than in PAS. Details of this work are given below."

Mar 1, 1992

By R. V. Ramani, R. Bhaskar

"The National Academy of Sciences (1) recognized the importance of studying the spatial and temporal characteristics of respirable coal mine dust atmospheres. In this paper, the progress to date of a research project on dust transportation and deposition in mine airways is presented. A mathematical model is proposed for studying the transport of dust. A source representative of dust generation in underground coal mining is defined. The influence and applicability of surface roughness, dispersivities, coagulation and reentrainment to vine dust flow arc examined. A convective-diffusion model is proposed for the transport and deposition of dust in mine airways. Using the model, the spatial and temporal characteristics can be evaluated in terms of dust concentrations in the mine atmospheres.INTRODUCTIONThe prediction of the behavior of fine particles Is Important in many fields of science and engi¬neering including physics, chemistry, mining, mineral processing, and atmospheric science. In mining from the health point of view, fine coal dust is associated with the appearance of pneumoconiosis in miners exposed to the dust. Also, in addition to being a nuisance factor obscuring visibility and general mobility of miners, it can lead to sudden catastrophic incidences of explosions. This paper outlines the progress to date of a research project on dust transportation and deposition in mine airways. A mathematical model is proposed for studying the transport of dust for the various mechanisms. The dust dispersion is defined in terms of a dispersion term determined from experimental data by Skubunov (23). Coagulation is considered as one of the mechanisms that can lead to changes in the particle size distribution. Reentrainment as a possible secondary source of dust was examined during model development but was not included in the final model."

Jan 1, 1988

By X. M. Yu

A large amount of polluted sludge is produced by a nonferrous metal factory after treating waste water with lime/ferrous salt. The concentration of arsenic in the dried sludge is high to 5.84%, a toxicity test is taken on the sludge according to GB5085.3-2007 and the extraction content is 15.75mg/L, which surpasses the arsenic extraction standard [As]=5mg/L, the sludge is categorized as hazardous waste. If put outside without disposal, it would be very harmful to environments. Here we report an optimum protocol to extract arsenic; S2- alkaline liquor is utilized to treat the arsenic sludge. At 85?, 10L 7% S2- liquor is added into 1kg dried sludge and the resulting mixture is stirred for 120min at 250r/min, then separated by centrifugation and the compressed waste residue dried naturally. The average arsenic content is 1.40mg/L, lower than GB5085.3-2007 Standard and arsenic-free residue is consistent with GB18598-2001 Standard, which can be bury safely. The extracted arsenic is transferred into copper arsensite for use as addictive in copper electrolysis and the waste water can be recycle after calcium is removed.

Jan 1, 2014

By Karl S. Hughes

ANY one of the mining engineers who spent three years under the benevolent and protective custody of the military forces of His Imperial Nipponese Majesty will admit that he has survived a most disagreeable experience, but our friends here in the States all demand that we tell them something about our thrilling adventure. Many of the younger men who were on Luzon in December 1941 joined up with the Army, either as civilian technical employees or through their reserve officer status. They served through the Bataan and Corregidor defense and had five months of thrills and hardship, if that is what constitutes adventure. Unfortunately, too many of them are not alive to tell their stories. But for most of us, our internment as alien civilians was just one long, drawn-out pain in the neck. Yes, we starved; yes, we contracted beriberi, dysentery, typhus, dengue, and for a while had no quinine to fight the ever-present malaria; but these things are not exciting, neither is the account of them interesting. Our contingent from Mindanao, 250 .in number including 25 mining men, went through one period of starvation at Davao. When the activity of the Allied fleet interfered with the importation of staple foodstuffs, and the natives stopped bringing fruit and vegetables into the market, the food situation became acute, and in December 1943, with stocks in sight and in prospect insufficient to provision their own soldiers, our custodians decided that we must be moved to Manila. The story of that ten-day voyage in an antiquated Jap freighter is too disgusting to tell, but hardly more adventurous than the account of a game of solitaire.

Jan 1, 1945

By T. A. Klinefelter

ONE OF THE many services rendered by the Federal Bureau of Mines is the identification and general examination of ore and mineral samples. Many of these, coming from almost every State in the Union, are clay and shale samples. Other Government agencies, State geologists, universities, and other laboratories are often requested to make similar examinations. This publication describes methods of testing these samples. An earlier paper, published in 1943, described Bureau of Mines methods of testing such clays.3 This paper was to be followed later with another (part II) that would describe much more thorough testing than did the rather general outline of part I. Part I has been out of print for some time and needs revision, and part II was never written; hence, the present publication is designed to include part I and also those additions intended as part II. The tests presented in part I were simple, requiring only the ordinary equipment to be found in any good chemical laboratory. The second publication was to include a greater number of test procedures and information on increasing the accuracy and precision of those previously given.

Jan 1, 1957

By R. W. Pauls

"Many tens of thousands of hectares of forested land will be disturbed and reclaimed in the surface mineable Athabasca oil sands area during the next few decades. The surface area disturbed by Syncrude’s Mildred Lake development alone exceeds 10 000 ha to date. It is not clear that reforestation of disturbed areas will best accommodate the aspirations of all stakeholders, particularly traditional users of the land. A five-year research program by Syncrude Canada Limited and the Fort McKay First Nations has examined the feasibility of raising bison on land reclaimed after disturbance by oil sands development. Forage productivity and carrying capacity for bison was comparable to that of grasslands elsewhere in Alberta. Concerns regarding compaction of newly rebuilt soil by bison traffic proved unfounded. Bison demonstrated weight gains typical for ranched bison and calving rates averaged 90%, a value typical for ranched bison. The animal husbandry problems encountered were typical of those occurring on bison ranches elsewhere in Alberta. An economic analysis indicates that a 1000 ha bison ranch on reclaimed land has a net present value that compares very favourably with a similar area supporting commercial forest. Subject to approval by Alberta Environmental Protection, the current research project will be expanded as a pilot commercial ranching venture in order to explore its commercial viability as a business venture by the Fort McKay First Nations. At the same time, measures will be implemented to resolve various regulatory issues associated with commercial bison production in the oil sands area.BackgroundSyncrude Canada Ltd. (Syncrude) is proposing, in its land reclamation strategy, a feature that is, depending on one’s background and perspective, regarded as an innovative approach to land reclamation, a threat to the regional forest industry, a creative response to aboriginal stakeholder concerns, a reneging on reclamation commitments, an opportunity to provide an ongoing economic base for postoil sands regional economy, or an environmentally unsound use of the land. These diverse and sometimes strong reactions have been generated by the proposal to introduce bison, either free-ranging or commercial ranched, to the reclaimed landscape."

Jan 1, 1999

By R. A. Williams

Surface and electrochemical techniques have been used to describe the surface chemistry of ferrosilicon powders, as a function of pH and electrochemical potential, for conditions typical of operating DHS plants. The practical consequences on the likely corrosion behaviour and associated electro- kinetic particle-particle interactions (which affect stability to sedimentation) in the suspension, are discussed.

Jan 1, 1987

By Christopher D. Henry

Environmental geologic maps of the Wilcox and Jackson-Yegua lignite belts of the Texas Coastal Plain delineate land areas on the basis of their natural characteristics. Criteria used to define map units include substrate, soil, topography, geologic process, vegetation, and land use. The maps are useful in planning and reclamation of lignite mines and in meeting the requirements of State and Federal surface mining laws. Specific applications include identification of land capability, recharge areas and geometry of aquifers, flood-prone areas, areas that may qualify for prime farmland status, and other areas sensitive to lignite mining.

Jan 1, 1982

By F. E. Block, Stephen D. Hill

The necessity for measuring radiation dose is encountered in studying both the beneficial and damaging effects of ionizing radiation on materials . It is also necessary to know the radiation dose absorbed by the reactants in order to evaluate the efficiency of reactions or processes that are promoted by radiation . Thus , a significant effort was made at the Albany cobalt 60 facility to investigate techniques by which the exposure radiation dose can be determined . Methods including ferrous sulfate , ceric sulfate , and methyl methacrylate chemical dosimeters , ion chamber dosimetry , and an absolute radiation calorimeter were investigated . Isodose curves were constructed for several standard source configurations using the dosimetry techniques which were investigated .

Jan 1, 1964

By G. L. Bloomsburg

This report describes work which was done to apply an existing finite element computer program UNSAT2 to the unsteady, unsaturated flow of water through waste shale piles. The work was done in three phases: 1. Verification of program through comparison with existing data. 2. Verification of program through simulation of flow from field seepage ponds at Rifle, Colorado. Considerable laboratory work was done in this phase to obtain capillary pressure-saturation-relative permeability data and hydraulic conductivity values for retorted shale. 3. Application of program to flow due to natural rainfall in a section through the Piceance Basin in Colorado, and a typical waste shale pile.

Jan 1, 1978

By F. S. Crawford

Safety devices and guards are often looked upon as the last word in safety by the men around the shop or large industrial plant . However , thorough knowledge of the details of their jobs and of the dangers attending them are even more important . It should be unnecessary for all men to go through the experience of the first man to meet an unknown danger , but that appears to be about the only way by which many learn . Practically every danger connected with the job around a mine , blast furnace , steel mill , foundry , coke oven , cement mill , or other operation , was encountered for the first time by someone , and if he was fairly fortunate he either got hurt or just missed being injured and lived to tell his " budaies " how it happened; he spread the knowledge of that particular danger . Sometimes , but not often , a man can foresee a danger . If he could always be on guard and remember everything he had ever learned and also know everything that had happened to the other fellow , and then let that knowledge keep him aware of the dangers in his own immediate " job , " so that he would work the safe way for both himself and the other fellow , he would have what safety engineers call " safety consciousness . " Being safety conscious is a fine attribute , as it really means knowing all about one's job . A man who is really safety conscious is one of the best and most efficient workmen in the whole plant . The boss wants men of that kindmen who want to learn and who try to learn every little detail about their jobwhere there is danger of spoiling the heat or getting burned by hot metal in a steel plant or of loading rock instead of coal or ore in a mine . Such men know how to do whatever job they are on easily and with the least amount of hard work and at the same time get it done as quickly as possible with safety . A man who is safety conscious has to nearly all intents and purposes developed eyes in the back of his head , if he is in a big mill where there if something going on all around him . These eyes are not real eyes , but they are what might be termed a sixth sense which he has developed by his experience in the mill as well as in other dangerous work which he may have done before in other plants . There may be occasions when a man's safety consciousness will leave him for just a short time ; this is likely to happen when he is thinking about a quarrel he had with his wife which has not been cleared up happily , or perhaps when he has bought too many things on installment and with sickness at home

Apr 1, 1931

By A. L. Holmes

Since the 1981 record of 54 mm tons of US fertilizer consumption, grain surpluses in the US have brought about massive acreage reduction programs, decreased fertilizer consumption, and resulting price pressures caused by excess capacity. The strong US dollar that reduced export sales of both grain and fertilizer, and new offshore manufacturing capacity using US engineering/contracting know-how have combined to put US producers of phosphate fertilizers in uncompetitive postures. While recent events suggest the industry may be growing out of this capacity problem, the cost of US phosphates will continue to be disadvantaged by such external factors as taxes, environ- mental regulations, and high power costs. There is no reason to expect help from the government in the form of reduced environmental regulation and taxation. In order to survive, phosphate fertilizer producers will have to develop technologies and adopt strategies that result in world competitive production costs. Current responses to the need to reduce costs include reduced energy costs through cogeneration, innovative reclamation techniques that create valuable land, and in- creased raw material recovery achieved by operator proficiency. While new technology offers long-term benefits for the producer, present efforts are concentrated on more mundane management efforts to reduce costs. Major attention is being given to the problems of labor utilization and productivity. Raw materials suppliers are being asked to renegotiate contracts which more appropriately reflect conditions in an industry operating at about 50% of capacity. Achievements in these and other areas will allow the producers to continue operating until longer term benefits materialize. `

Jan 1, 1986

There remains considerable controversy in the industry regarding precision type detonators and where the end user can benefit from their use. In spite of the fact that electronic detonators and other prototypes were tested over one decade ago, explosive suppliers have hedged on full scale production for many reasons. Although some of the reasons were based on solid economics, others were strongly influenced by shear internal resistance within the corporate objectives, ultimate fear of market rejection, indecision as to what degree of precision was required and limited data on defining the real benefits to the end user.

Jan 1, 1992

By J. Villeneuve

Steady-state simulation has proved to be a very useful aid in designing new plants and optimizing existing ones. The algorithms and data definitions of existing simulators often, however, require a great deal of expertise for implementing a simulation-based methodology. The constraints imposed by conventional simulators are explained and the advantages of a new algorithm, the Objective-Driven Simulation, are shown. These advantages are a) an improvement in the simulation results, which enables simplifications of the methodologies used, and b) the possibility of taking into account economic objectives for plant operation, thus extending the range of application of steady-state simulation.

Jan 1, 1992

By A. Donald Kelmers, Forest G. Seeley, B. Zane Egan

INTRODUCTION Coal ash, presently the fifth most abundant of the solid minerals produced in the United States, is expected to become the fourth most abundant by the end of this decade (1). The production of fly ash from the combustion of pulverized coal amounted to a total of 44 million metric tons (Mt) in 1977 and is expected to Increase to 91 Mt by 1985. Coal ash, which results from the Inorganic clay and mineral content of the coal, contains several elements and thus can be considered as a mined and crushed mineral resource rather than a waste material Furthermore, potential problems associated with fly-ash disposal ponds and the leaching of potentially hazardous elements through groundwater infiltration and/or rainfall provide additional incentive for processing fly ash for environ- mental control as well as for the recovery of certain metal values. Fly ash could provide an abundant domestic source of aluminum and several other metals Aluminum is now recovered from bauxite, and over 90% of this ore is imported since domestic sources are limited and cannot meet the U.S. demand There is a close relationship between the aluminum content of fly ash and the domestic consumption of this metal (Table 1).

Jan 1, 1981

By R. W. Raymond

By the death of Prof. Pettee the Institute has lost one of its earliest, most distinguished, most useful and most beloved members. Among those who survive him there are few who have rendered services of equal professional value or unselfish devotion. The warrant for this statement will be amply furnished in the present brief notice of his life and work. William Henry Pettee was born, January 13,1838, at Newton Upper Falls, Mass., where hie childhood and youth were spent. His father, Otis Pettee, a manufacturer of cotton cloth and of cotton-mill machinery, died in 1853. Up to that time, the son had been educated mainly in the district school; but, being inclined by temperament and constitution rather to books and study than to physical exertion, he had been wisely rest,rained in mental activity, and required, for a season, to work regularly in the foundry and machine-shop of his father. Unquestionably, this discipline not only benefited his health, but also constituted a valoable preparation for his subsequent professional career. In 1857, after suitable preliminary study at various New England academies, he entered Harvard College, where he took high rank in the classical course then required, was selected in his Junior gear to deliver a Latin oration; was elected a mem-

Jan 1, 1905