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By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By Michael Lenz

Predictive maintenance technologies including vibration analysis, tribology, infrared thermography, ultrasonic detection, and electrical measurements have been applied to large electric mining shovels. The predictive program was initiated on the P&H Model 2300 and 4100 electric shovels. The utilization of these technologies has shown the potential for improving electric mining shovel availability and minimizing maintenance costs. Predictive technologies provide the tools to assess machinery condition. Availability is enhanced by the condition based planning of component replacement. Maintenance costs are minimized by focusing resources through condition based prioritization.

Feb 24, 1997

By Robin J. Batterham

Alumina demand is steadily climbing around the world and is likely to continue to do so for many years. In such a commodity industry, the question arises as to what effort should be expended on innovation, given that for an individual company, the drivers of change are cost and quality as the market demand is essentially assured. This is of course a long-term view. The current conditions are less attractive. In this presentation, we review the broad issues that are considered targets for collaborative development by the industry as recently updated in the alumina industry roadmap published by the International Aluminium Institute in 2010. While they cover areas such as ?mine rehabilitation, residue management and use, alumina production from high sulfur bauxite, bauxite beneficiation, energy efficiency and alternative technologies for alkali and alumina recovery from bauxite residues,? it must be remembered that each refinery is different in terms of the feed material and the circumstances of waste disposal. Of particular interest is the more competitive area of breakthrough technologies. In the presentation, we will consider a range of opportunities that could transform the industry, from relatively near term possibilities such as bauxite activation through possibilities to eliminate crystallization as currently practiced to complete alternatives, such as the use of hyperaccumulating plants. Against this optimism, some of the realities that hold back breakthrough innovation will be presented for discussion.

Sep 1, 2012

By A. I. Kalugin, A. A. Abramov, D. E. Kozlov

As a result of thermodynamic analysis of a mineral-sodium, oleate-water system, flotation and adsorption tests at various pH values, and sodium oleate concentrations, it has been established that due to regularities of phosphate-containing minerals (fluorapatite, hydroxyapatite, carbonatapatite) flotation cannot be explained by the formation of alkali-earth metal oleates on their surface. This paper presents a novel theory that connects optimal conditions for mineral flotation with zero charge of its surface, which can explain the regularity of minerals flotation observed. The quantitative physicochemical flotation models developed based on the theory are suitable for improving industrial processes, conditioning of recycling waters, and application in automatic control systems at the plants. Key words: apatite, oleate, flotation, modeling, control, and regulation.

Jan 1, 1999

By E. Oshilna

The Mitsubishi process has many advantages pertaining to economical and environmental matters. These advantages have led to the installations of the Mitsubishi process in constructing new smelters: The Mitsubishi process utilizes highly oxygen enriched blast air and uses a special lime slag in the C?furnace. These characteristics change the . distribution of Impurities from other processes which use P.S. converters, Recently an Increased amount of secondary materials which contain impurities Is being treated at Naoshima Smelter. In order to cope with an Increment of the Impurities load and maintain the cathode quality, many Improvements have been Implemented. This paper discusses the impurities behavior In the Mitsubishi process and describes the measures taken to treat an Increased ?amount of secondary materials:

Jan 1, 1998

By P. K. Kaiser

The purpose of deformation monitoring for the evaluation of the stability of underground openings is reviewed briefly and some results from laboratory tests of small tunnels are presented. The ground behaviour is described by comparison with the response of structural systems and illustrated by the data from the testing of small tunnels. It is concluded that the main objective of a deformation monitoring system for stability evaluation is to determine the actual process of deformation and instability in the area surrounding the opening. Only when this process has been established is it possible to use deformation measurements to design support systems or to improve construction or mining procedures. Present monitoring practice is not sufficiently orientated toward the aim of process description.

Jan 1, 1981

By R. G. Siddall, W. Gale

In the UK the development of the science of strata control has been strengthened by a resurgence of interest in the specialism of roofbolting and its associated techniques. The evolution of the theories and practices of strata bolting in roadway stabilisation is discussed. Practical experiences are considered, principally the use of Australian techniques, the relationship between bond strength and annulus and the effects of stress in the ground. Areas of new technology such as cable bolting, injection anchors and on-board bolters are also discussed. The recent advances in computer technology and rock testing equipment and methods have provided the opportunity to simulate ground behaviour under various conditions. Computer modelling developments and the use of techniques to predict ground behaviour are described.

Jan 4, 1992

By Y. Luo

Based on the concept of slope stability analysis, a formula for determining an important parameter required in the mathematical model for the prediction of mining subsidence in hilly terrain has been proposed. The slope geometry and soil physical and mechanical properties of the surface natural slope can all be considered in the formula. Incorporation of this new formula into an existing mathematical model provides an integrated approach in studying ground movement in hilly regions.

Jan 1, 1998

By Albert E. Ketler

The AirBoss*200 is a unique ambient airflow sensor with important improvements in accuracy, especially in the critical low end, 0-61 m/min (0-200 fpm) where MSHA regulations apply. All solid state, its design is rugged, and there are no moving parts or delicate filaments. An on-board microprocessor calculates air velocity, linearizes and corrects for temperature, while driving voltage and current loop analog outputs to .3 meters/minute (1 ft/min) resolution. Recent developments also cover both positive and negative flow directions. A hand held computer is available to readout data and to adjust stored range selection, alarm set points, calibration data and the speed of response. Installation in hazardous areas is covered by MSHA Classes G, H and L.

Jan 1, 1993

By M Randall, P Ebzery, F Burns, C Aisthorpe, P Blanz

SAG Mill process control classically maintains the SAG mill volumetric filling within a set operating range. Typically a SAG mill weight measurement, by either bearing pressure transducers or load cells, is used as an inferred measurement of volumetric filling. To maintain volumetric filling within a set operating range the SAG weight setpoint use for process control requires regular review due to changes in SAG mill charge density (rock:ball ratio) and the wearing of mill liners. At Lihir Gold Mine in Papua New Guinea, the use of SAG mill weight for process control is additionally complicated by compromised load cells and drifting bearing pressure measurements. The need for an improved method of measuring and controlling volumetric filling led to the recent installation of the Outotec MillSense, a SAG mill toe angle instrument. This paper presents the integration of the toe angle control in to the Lihir SAG mill process control philosophy as replacement for the traditional mill weight control.CITATION:Burns, F, Aisthorpe, C, Blanz, P, Randall, M and Ebzery, P, 2018. Toe angle measurement for SAG mill control at Lihir gold mine, in Proceedings 14th AusIMM Mill Operators&#39; Conference 2018, pp 59–76 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Brochot. Stephane, Manuel Gonzalez Fernandez

"HPGR (High-Pressure Grinding Rolls) is widely used today for grinding of various kinds of ores such as iron ore or base and precious metal ores. It can be used as first stage of grinding replacing tertiary crusher and SAG mill, but also as regrinding stage to enhance mineral liberation. In addition to better energy efficiency, the advantage of HPGR is to produce much more internal particle fractures allowing faster leaching as it has been demonstrated for some gold ores. This grinding mode of compression and fracture generation also promotes mineral liberation without overgrinding. Mineral processing modelling and simulation associated to detailed ore characterization constitute a powerful tool for plant design and optimization. The mathematical models of the units of operations (grinding and separation) have to reproduce the mineral deportment for which the mineral liberation plays a central role. The present paper is focused on the HPGR modelling with the objective of plant optimization or advanced design from pilot plant tests. The traditional approach of the population balance linked to the energy dissipation and the residence time distribution is generalized in association with a mineral liberation model. The effect of the specific HPGR breakage matrix and grinding function on the mineral liberation rate is discussed and compared to the tumbling mill. The implementation of this mathematical model into a plant simulation tool is illustrated by the example of the optimization of an iron ore concentrator."

Jan 1, 2014

By S. Davis

It has been accepted almost as dogma that sampling contributes most of the error to fluctuations in gold fire assays. Differences in assay results on pulp material from the same sample interval are frequently regarded as evidence of the presence of the so called "nugget effect" or relatively coarse gold particles. It is true that if coarse gold particles are present they contribute to substantial sampling fluctuations, but while the process of sampling is probably the major source, the analytical process cannot -be completely ignored as a possible contributor to erratic assay results. In order to maintain a stable assay process, the analytic part of the system must be kept in control as well as the sampling and preparation part. One way of monitoring the performance of the analytic system is to systematically assay standard material whose sampling characteristics are carefully controlled. Gold assay standards are not prepared nor can they be prepared to account for both sampling and analytical errors. It is not possible to send coarse material to a lab for preparation (which includes both the processes of comminution and splitting) followed by fire assay, to make inferences only about the fire assay process. Because most gold ores are very heterogeneous, sampling errors would in most cases completely mask the contribution of the analytical errors. Assay standard material is prepared only to assess the accuracy and variability in the fire assay process.

Jan 1, 1995

By A. V. Tarasov

Regeneration of carbide waste from hard-alloy (sintered carbide) manufacture is an important scientific and technical objective aimed at improving the degree of recycling of rare metals (W, Co, Ta, Ti, Nb). Currently, the degree of recycling of those metals does not exceed 25% to 35% of their total production even in industrially developed countries. This is attributed to a significant extent to the substantial drawbacks of the technologies applied for their processing (environmental pollution, limitations to the use of regenerated products for important applications, sophisticated equipment to be used). An innovative environmentally sound technology has been developed in the Institute of Metallurgy of the Russian Academy of Sciences (IMET RAN) for processing of carbide waste of WC, TiC, TTC and other carbides using asymmetric alternating current of industrial frequency (the electrolyte used for this purpose is nitric acid solution). The current efficiency under optimal conditions is as high as 96% to 98%. The process has been tested on bench scale. The following commercial-grade products are obtained: pure ammonium paratungstate, tungstic acid, cobalt oxide, titanium dioxide and tantalum-niobium concentrate. The total metals recovery is 98% to 99%.

Jan 1, 2006

By T. Negeri, M. Boisclair, A. Bouajila

CanmetMINING has been working on process development for separation and concentration of rare earth bearing minerals from various ores. Among others, the flowsheet development for the Montviel Rare Earths/Nb deposit, located at the north end of the Abitibi region in Quebec and owned by GeoMegA Resources Inc. (GeoMegA) is now at an advanced stage. The concentrate produced by a flotation-only process at the early stage of the project accounted for higher than 90% TREO and Nb recovery in 40% mass. This concentrate was submitted to SGS Lakefield for hydrometallurgical processing. Lixiviation of the concentrate using hydrochloric acid yielded approximately 99 % REE. An overall (from ore in ground to final precipitate) REE recovery of 80% was obtained through a series of selective precipitation steps. Recently significant additional developments have been made. CanmetMINING is steadily improving the quality of concentrate produced through a simplified, more efficient flowsheet which consists of flotation, magnetic separation, and a thermal treatment procedure. The paper discusses aspects of the process that allowed obtaining 82% recovery of TREO and Nb in 16% of mass, the best result to-date.

Jan 1, 2014

By A C. Robertson

World urban expansion puts constraints on the available land surface area of our major cities both for accommodating people as well as providing infrastructure and services whilst at the same time attempting to preserve the remaining natural environment. Whilst consideration is often given to underground planning for private and public transport infrastructure, the author is of the opinion that the current lack of underground planning of our cities that are suitable for underground development will have major long implications when finally the need for underground space planning is critical and ultimately recognised. This paper identifies the need for our city planners to integrate surface planning and underground planning as a ‘total planning solution’ where the city plan incorporates the elements of underground space planning as identified in this paper. Investigations by the author reveal that there are very few cities in the world that actually incorporate underground space planning in their city plans. The author uses the City of Brisbane as a case study for the potential introduction of underground space planning as part of the city plan. Despite efforts by the author to include the planning concept of underground commercial development in the latest Brisbane City Plan 2014 as well as four underground space workshops in Brisbane over the past 20 year through the Australasian Tunnelling Society (ATS), underground space planning for the City of Brisbane, apart from infrastructure projects, is not considered of significance to the City of Brisbane.CITATION:Robertson, A C, 2014. Commercial underground space – planned development for the future, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 513–518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By R. L. Miller

"Miners worldwide use a tremendous amount of energy in producing finished minerals for the end user market. In accomplishing this goal, they incur energy costs that can range from 20% to 30% of the total cost of production, so there is fertile ground for cost savings. To unlock this huge value in cost reduction, energy analysis is the key and is broken into several segments: 1. Fuel analysis for power generation 2. Energy supply & demand 3. Opportunity cost for lack of power 4. Backup power 5. Power contracts 6. Energy efficiency 7. Renewable energy 8. Continuous energy management FUEL ANALYSIS FOR POWER GENERATION What is the first thing we evaluate when looking at power supply alternatives for the mining industry’s large power requirements? Is it 1) site, 2) engineering, procurement, and construction companies, 3) independent power producers, 4) turbine vendors, 5) grid connections, or 6) fuel supply, logistics, and infrastructure? In evaluations of power supply alternatives for mining companies with special emphasis in developing countries, there is one over-riding conclusion: reliable fuel supply drives the energy generation economic engine. Evaluating several different fuels including liquefied natural gas (LNG), natural gas, diesel, heavy fuel oil, and liquefied petroleum gases (LPG) among others, the best project outcomes are those where fuel supply, pricing, logistics, and infrastructure are given an extensive amount of time during the analysis stage. In an assessment of the twenty-year costs of generating power from multiple fuels, each fuel’s costs were placed into three separate net present value (NPV) buckets of: 1) capital, 2) operating and maintenance, and 3) fuel. Within a range of 65% to 85% for all fuels, fuel cost was the largest component of the NPV of the life cycle power generation costs. So if 65% to 85% of your life cycle power generation cost is one item, shouldn’t miners spend a corresponding amount of time in the analysis stage fully understanding this key determinant for a successful power project? In developing countries where power generation infrastructure may not exist or does not exist at the same level as is found in North America and Europe, fuel analysis becomes even more important. One of the key questions for fuel importation in developing countries is the draft at existing ports to allow larger vessels to dock at the jetty. Can larger ocean-going tankers dock at the port for off-loading, or is the port’s draft too shallow, thus forcing a Single Point Mooring (SPM) system or Conventional Buoy Mooring (CBM) system to be constructed at substantial capital expense? Once fuel can be imported, sufficient onshore storage capacity should exist, or must be built to off-load the entire fuel cargo from the larger ships. Additionally, the throughput capacity of the pipeline from SPM/CBM must allow a rapid unloading of the fuel from ship to shore to eliminate steep demurrage costs for the project."

Jan 1, 2017

By P. T. Luckie

More efficient classification with a single hydrocyclone through equipment and/or operating design changes does not appear possible. However, improvement in classification efficiency by increasing the sharpness index and decreasing the apparent by-passing while changing the cut size is possible through proper staging of inefficient hydrocyclones. But feasible multistaging requires achieving the necessary material balances around the units. Because of the interactions among the units, these balances require extensive iterations. The final step before commerical installation should be a laboratory demonstration, in order to define the control algorithm required to maintain stability. However, eventually a sufficient knowledge base should be developed that will permit simulation in place of laboratory testing as well as the incorporation of a feed forward strategy.

Jan 1, 1989

The mineral processing industry is in boom times. The focus on mill availability and therefore profitability has never been greater, as grinding mill maintenance often dictates the entire plant shut down duration. Advances in mill systemsÆ quality and reliability and the faster, safer relining afforded by RMEÆs Mill Relining Systems have significantly enhanced grinding plant availability and utilisation. Yet relining performance is still affected by the design and planning by a team of stakeholders long before the maintenance team set foot in the mill. For a greenfield grinding plant project, these team players include: 1. project owner, 2. project manager, 3. mill supplier, 4. liner supplier, 5. plant operating personnel, 6. plant maintenance personnel, 7. mill relining crew, and&nbsp; 8. mill reline system supplier (RME). The complex and sometimes competing design demands of mill construction and operation together with the pressure of tight timelines can result in even simple maintenance requirements being overlooked let alone optimising plant design and planning for maintenance. This paper identifies all the involved stakeholders in an effective mill relining &apos;team&apos; and gives principles and considerations for each to more effectively achieve the goals within their vital roles. This paper is aimed to be a practical guide for grinding mill designers and planners to more fully exploit the advances in Mill Relining Systems and improve their mill profitability.

Jan 1, 2008

By H. Q. Fan

Construction equipment is an important type of resources of heavy construction contractors. Since equipment breakdowns can cause project delays and significant financial losses, the contractors are eager to know those factors causing equipment failures directly or indirectly, related to equipment design, maintenance, and operations. Although Bayesian network can be used for diagnostic analysis of failure events or making predictive analysis, building a Bayesian network for such purpose can be difficult as the cause-effect relations can be subjective and their conditional probabilities change with a wide variety of causal factors. A hybrid approach is proposed in this paper to update the Bayesian diagnostic network structures and parameters using real life data, the conditional probabilities and cause-effect relationships can be dynamically updated with observed failure records to reflect the real life situations of a complex equipment system. A case study is conducted to show the benefits of the hybrid approach in construction equipment diagnostic analysis.

Aug 1, 2013

By E. Neumann

With fuel costs unstable but escalating, solid fuels are playing an increasingly larger part in industrial concerns. Coal, petroleum coke and wood are examined from a burner system design viewpoint and from operational experience in kilns, hot gas generators, etc. The burner of today must also handle multi-fuel tasks and allow immediate, painless switching from one fuel to the next as well as the simultaneous burning of two or mope fuels. The paper discusses the principle of burning alternate pulverized fuels as well as the practice both in the United States and around the world.

Jan 1, 1983