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By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

By G. T. Lineberry

Horsepower requirement is recognized as a most important equipment characteristic. Other critical equipment characteristics will be isolated and analyzed by traditional operations research techniques, using off-highway trucks as an archetype. A computer search technique has been developed, employing various production and cost analyses. With this model, the optimum combination of horsepower, capacity, and velocity can be found, minimizing handling cost per ton. An example of the program's use and interpretation of its results will conclude the paper.

Jan 1, 1984

By C. V. Deutsch, O. Babak, J. G. Manchuk

High levels of geological heterogeneity occurring over relatively short distances pose a challenge to the unconventional open-pit techniques used in oil sands mining. There is strong motivation to mine selectively and minimize dilution and loss; however, the large equipment and high mining rate used to meet production targets tend to reduce selectivity. A numerical model is developed to account for geological complexity, mining equipment, regulatory criteria, and other operational parameters. This framework is used for more accurate forecasts, optimization of equipment, and other operational decisions. An example demonstrates the approach in light of Alberta Energy Regulator criteria.

Jan 1, 2014

By Miguel Reyes, Bruce Whisner, Joseph Bickson, Lincan Yan, David Yantek, Justin Srednicki, Nicholas Damiano, Eric Bauer

Built-in-place (BIP) refuge alternatives (RAs) are designed to provide a secure space for miners who cannot escape during a mine emergency. Heat and humidity buildup within RAs may expose miners to physiological hazards such as heat stress. To minimize the risk of heat stress, Title 30 Code of Federal Regulations (CFR), or 30 CFR, mandates a maximum allowable apparent temperature (AT) for an occupied RA of 35 °C (95 °F). The National Institute for Occupational Safety and Health (NIOSH) has conducted extensive research on the thermal environment of occupied RAs intended for use in underground coal mines. NIOSH research has demonstrated that a fully occupied BIP RA can exceed the AT limit by more than 5.6 °C (10 °F) in mines with elevated mine strata and air temperatures. In this circumstance, an RA cooling system could provide a solution. This paper provides an overview of test methodology and findings as well as guidance on improving the performance of a cryogenic air system prototype by optimizing the flow rate, increasing the tank storage capacity, and improving the efficiency of the heat exchanger of the cryogenic system. This may enable BIP RAs to meet the 35 °C (95 °F) AT limit in mines with elevated temperatures. The information in this paper is useful for RA manufacturers and mines that may choose to implement a cryogenic air system as a heat mitigation strategy.

By P. A. Mingione

AEROPHINE® 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn-and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treat-ing different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.

Jan 1, 1991

By Zhiwei Jiao, Ziqing Guo, Mushen Wang, Yueda Fang, Qiuming Tang

In order to achieve anti-terrorism, production safety, better explosive performance, lower cost, and environment protection, we developed HMS (emulsification in borehole).Long-process PM (plant-mixed) and SM (site-mixed) emulsion trucks are reviewed and compared to a new type of short-process HM (hole-mixed) truck for onsite emulsion manufacturing. The short-process HM truck has demonstrated many advantages over its PM and SM counterparts in areas such as process safety and security, energy efficiency and environmental impacts: 1) No emulsion matrix is manufactured in the plant, transported on public roads, or even present on the surfaces of blasting job sites. Such characteristics are certainly beneficial in eliminating risks of the product being diverted and used by unlawful players; 2) This short-process involves "micro-fluid control to form super oil phase-rich" in tubular emulsification process, making it intrinsically safe; 3) There is basically no residual matrix left in the truck or on the job site to clean up, which greatly reduces environmental impact of the process; 4) Comparing with typical PM and SM trucks, the HM truck has eliminated the needs of many power equipment and critical pump pressure for turbulent flow forming a static emulsification with super oil phase -rich is only 0.2Mpa. These is therefore quite energy efficient.

Feb 1, 2020

Gullies are the vital in-stope excavations that provide access for mining personnel and material to, and mined ore from, the producing faces in the tabular hard rock mines. They pose a serious problem in most mines because they induce stress orientations, which, combined with blast damage, produce adverse rock fracture patterns that contribute to the loss of hangingwall and sidewall integrity. Rock-related injury statistics confirm this by highlighting gullies as the second-highest risk area in South African hard rock mines. Inappropriate gully geometries, poor blasting practice, and non-adherence to accepted standards worsen the problem. The aim of this work is, firstly, to provide guidelines to select the correct gully geometry and appropriate support for a particular geotechnical environment and, secondly, to review the practical issues behind gully safety and stability. In order to meet these aims, this paper reviews the available literature on gullies and their history, and reports on an industry-wide survey of practices and opinions. Then it covers observations from underground visits to 107 gullies situated in the respective geotechnical environments of the Basal Reef, Beatrix Reef, Vaal Reef, Carbon Leader Reef, Ventersdorp Contact Reef, Kimberley Reef, Kalkoenkrans Reef, Merensky Reef, and UG2 Reef. Despite the differing geotechnical conditions and gully geometries, common problems are experienced with geological structure, stress, and fracturing. Results from numerical modelling are also presented to help analyse the underground observations and to quantify the merits of the different gully layouts. It is concluded that there are no new techniques available to improve gully stability, but that significant improvements in safety are attainable by employing the correct gully geometry for the geotechnical environment, good blasting practice, and appropriate support.

Jan 1, 2002

By George R. St. Pierre

A method for the quantitative description of activity interactions between solutes in a metallic solvent which is consistent with stalistical thermodynamic principles is presented. The chemical potential of a solute in an alloy is derived from the weighted mean of its values in the individual solvent components, µi = S?jµi(i). The weighting factors, ?j, are obtained from the distribution functions. The resulting equation contains far fewer adjustable parameters than the Epsilon Formalism and because of its correct functional form it provides an improved fit to the available data on a variety of alloy systems containing oxygen, carbon, sulfur, nitrogen, and hydrogen. For a binary metallic solvent ( A, B ) containing a solute (i), it is shown that

Jan 1, 1995

By Yuta Yamamoto

Seafloor massive sulfides (SMS) which contain Au, Ag, Cu, Zn, and Pb have been interested in as a target of commercial mining these 15 years. Japan has large potential of SMS and a national R&D project for the mining has been active these 5 years. However, the economy of SMS mining is very bad, because the waste tailing disposal cost is very expensive in Japan. A slurry flushing method is experimentally examined in this study for the improvement of the economy. During the flushing, because of density difference between the metal-rich ore and the waste rock, a kind of gravity separation is possible. The results suggest a possibility of the actual application.

Sep 14, 2011

By C. A. Pickles

At the present time, pyrometallurgical processes are employed for the recovery of lead from battery scrap. These processes have serious pollution problems, primarily due to the emfssion of sulphur dioxide and airborne lead in the form of dust and fume. In addition it is necessary to dispose of solid wastes and liquid effluents which contain lead and in some cases sodium sulfide-containing compounds. In this work an improved process was investigated for the recovery of lead from battery residue. This involved pelletization of the residue with sodium carbonate and moisture. Then, the pellets were melted without carbon and the .sodium sulphate salt was removed. Subsequently, the molten lead oxide was reduced with carbon. This process minimizes the sulphur dioxide emissions and leads to very low sulfide contents of the sodium sulfate salt

Jan 1, 1992

By A Dal-Corobbo

Traditional acid and metalliferous drainage (AMD) wastewater treatment focuses on the iron co-precipitation/adsorption process as this is a very effective method of reducing heavy metals, including copper, lead, zinc, arsenic, etc, to parts per billion (ppb) levels in AMD wastewater streams. One of the drawbacks to this method however is the large volume of sludge produced and subsequent disposal costs for the mine site concerned.A proprietary metals treatment system called high density sludge (denoted HDS) which significantly reduces the quantity of waste generated is described in this paper. This process generates a dewatered sludge that contains in the order of 50 to 55 per cent solids. This sludge is denser than conventionally dewatered sludge, which typically contains only 20 to 30 per cent solids. This advanced process has a wide range of applications and can be easily retrofitted into existing AMD treatment systems. It has been successfully installed at several mine sites to treat AMD wastewaters. This paper discusses the high density sludge process, its benefits and provides data and operating results from pilot test installations.CITATION:Dal-Corobbo, A, 2013. High-density sludge process for treating metal bearing acid and metalliferous drainage wastewaters, in Proceedings Water in Mining 2013 , pp 217-220 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By M. Polat

A combined heavy medium-flotation process which incorporates the advantages of two widely employed cleaning methods, namely, heavy medium separation and flotation was used to achieve improved separation of coal from ash at fine sizes and to recover the heavy medium as a substantially recyclable product. The investigation was carried out in two successive phases. In the first phase, tests were performed to deter-mine the effect of different variables such as the medium density, flotation time, magnetite type, etc. on the efficiency of the process using in-plant samples from Homer City Coal Preparation Plant. In the second phase, the optimum conditions determined in the first phase were employed to determine the applicability of the process to a few Central Pennsylvania coals. It was observed that the process was very effective in recovering the magnetite. In most of the cases investigated, the magnetite was separated from the non-magnetic material at approximate-1 to 99 % recovery with a grade ranging from 95 to 99 %. The grade of magnetite decreased with increase in ash content of coal and with decrease in size of magnetite.

Jan 1, 1992

By Chris Groccia, Damodara R. Chinnasane

Vale is in the process of resuming mining in the lower 810 ore body (810 OB) below 4130L at Copper Cliff Mine – South Side. Production in the lower 810 OB had continued until it was temporarily ceased in 2017 to allow for the execution of activities associated with Copper Cliff Mine Phase 1 project. While mining the stopes in both the lower and mid part of the 810 OB, a seismic response was experienced that resulted in rockbursts and challenging mining conditions. The majority of the rockbursts experienced in the past were associated with stopes mined in a bottom-up mining sequence under a diminishing pillar situation between 3350L and 3540L. The current mining plan is comprised of both top-down and bottom-up mining fronts using a center-out chevron sequence of long hole open stopes to manage induced stresses. Numerical modeling assessments have been carried out to forecast the response of the rock mass due to the planned mining. Seismicity and stress induced damage surrounding excavations are anticipated, and areas requiring extra attention have been identified. A tactical approach is being used to prepare the area for production, including replacement of ground support elements that are damaged or have insufficient residual capacity, and installation of dynamic support in areas anticipated to experience bulking and/or dynamic loading that would exceed the current support system’s capacity. A series of monitoring programs are being put in place to confirm current conditions, and to monitor the response of the rock mass to proactively implement ground control tactics should the need arise. This paper provides a summary of the approach used to forecast, monitor, and manage the behavior of the 810 OB rock mass response to continued mining at depth.

Apr 26, 2022

By T. Rockley, B. Goertz, S. McDaniel, J. Brune, K. Bakhsh

"Researchers at the Colorado School of Mines, under a project funded by the Alpha Foundation, have developed a working prototype of a dust sample collection device designed to determine if sufficient rock dust has been placed in an underground coal mine to prevent coal dust explosions. When used in conjunction with the Coal Dust Explosibility Meter (CDEM), the device will provide near instantaneous results on the quality of rock dusting at the tested location. The sampling device applies a pulse of air to a testing surface and collect a representative sample of mine dust based on the pneumatic entrainment process during a mine explosion. The use of both physical testing and Computational Fluid Dynamics (CFD) modeling has allowed researchers to refine the design to accurately represent the particle entrainment and optimize the sample size collected for the CDEM. The prototype is being tested in a mine environment to produce information of usability and practical aspects of mine dust sampling. This paper is a progress report summarizing the current status of sampler development. Researchers expect to have a fully developed and tested sampler in early 2016. INTRODUCTION Underground coal mines face the danger of methane and coal dust explosions. The disaster at Upper Big Branch mine (2010) has demonstrated the impact of a violent coal dust explosion that fatally injured 29 miners. Reviewing the history of coal dust explosions, researchers found that that mine operators and mine inspectors do not have a reliable method of collecting dust samples to assure that sufficient amounts of rock dust have been places to inertize the coal dust. This is a problem specifically with small mines that do not have dedicated safety departments to track rock dusting work. The aim of this research is to develop a simple, portable device that can help underground mine examiners collect dust samples from workings and test the explosibility of the sample near instantaneously. Researchers determined that the current brush-and-pan sampling method required by MSHA (MSHA 2013) is flawed in several aspects: Mechanical sampling with a brush exerts forces on the mine dust that may differ significantly from those present during an explosion. Also, U.S Bureau of Mines research (Nagy 1965) has determined that only the top 0.125 inches of the mine dust layer will be entrained in a coal dust explosion. Using a handheld pan and brush, it is difficult to correctly and repeatably sample a layer of this exact thickness. The following will describe the CFD modeling and experimental testing for the development of the prototype sampler. Researchers analyze the accuracy and performance of the prototype during the course of the build process."

Jan 1, 2015

By Ray D. Peterson, Annette Revet

The optimization of secondary aluminum furnaces is critical to the efficient operation of a recycling facility. Since all metal loss occurs in the drosses, physical and chemical analyses of these by-products are valuable diagnostic tools. Dross analyses can provide information concerning total furnace metal recovery efficiency as well as identifying areas for potential improvements. A complete dross analysis is a labor-intensive process that requires significant care both in sampling and performing the analytical techniques. Experiments can be done at a bench- or plant-scale depending on the facilities available. This paper outlines the benefits and information that can be generated through dross studies. Furthermore, several analytical methods are discussed as well as the special requirements needed to gain accurate results. Experimental data from industrial studies is provided to demonstrate the use of dross evaluations for ~ace optimization.

Jan 1, 2000

By Garland Likins

The Texas Department of Transportation, now considering using Augered Cast-In-Place (ACIP) Piles (also known as Continuous-Flight-Auger or CFA Piles) in their foundations, awarded a research project to Professor Mike O'Neill at the University of Houston (UH) to study the advantages and potential difficulties with ACIP/CFA piles. ACIP/CFA piles were installed on three sites for UH; they had extra instrumentation and additional measurements by UH staff during installation which are beyond the scope of this paper. Independent visual logging of the pile was done by an experienced inspection firm. The main advantages of ACIP/CFA piles are their speed of installation and their economy. Potential savings are substantial. Disadvantages include an unknown structural condition of the shaft. Inspection is critical, but many simultaneous observations make accurate inspection difficult. Because of resulting uncertainty, many engineers have avoided ACIP/CFA piles in the past.

Jan 1, 1998

By S. Gupta

Froth flotation is a process commonly employed for the selective separation of phosphate from unwanted mineral. Column flotation has become widely accepted in the mineral processing industry, including phosphate industries, due to its ability to improve selectivity, lower operating cost, lower capital cost, and superior control. In this work, a hybrid model is developed that combines a physicochemical model with artificial neural networks. The physicochemical model is based on axial dispersion with first order collection rates. A new approach, in which both frankolite (the desired mineral containing phosphate) and gangue (undesired product) are modeled, enables prediction of grade of the recovered product. Thus, two basic parameters are required in this model: flotation rate constants for frankolite and gangue. Artificial neural networks are used to predict flotation rate constants. The model also takes into account the particle size distribution and predicts grade and recovery for each particle size range. The model then combines grade and recovery for each particle size range to determine the overall grade and recovery of the column. The model is validated against laboratory column data.

Jan 1, 1998

By L. B. Kirk, A. R. Kirk

At New World, Au-Cu-Ag mineralization occurs in stratiform car-bonate-hosted, massive sulfide-iron oxide, and skarn-replacement deposits. Regional pyritic-alteration, local massive sulfide mineralization and mine wastes generate acid drainage within the district. Water quality improves down gradient through dilution and mixing of acid and metal-rich mine water with bicarbonate-rich, low-metal surface and groundwater, and precipitation of metal-rich ferrihydroxide phases. Natural deposits of ferricrete indicate that pre-mining ARD has occurred, providing important clues to pre-mining water quality. The geoenvironmental model identifies the Cu-skarn mineralization as the primary target for ARD management. Closure success will be limited by the geoenvironmental nature of the natural mineralization.

Jan 1, 2004

By R. C. Buehl

[Improvements in refractories for high-temperature service have made possible the use of higher temperature in many processes. Consequently, it sometimes is desirable to use gases heated above 1,600° F., and for moderate rates of gas flow, there gases can be heaters best with pebble heaters. Pebble heaters of the stationary-bed type in which the chanber was lined with mullite brick and pebbles of pure alumina served as the heat-exchange medium have been used recently to heat the air blown into an experimental blast furnace4/ These pebble heaters worked well and made it possible to use air temperature up to 2,500° F. at the tuyere of the furnace. Since little has been published on this type of gas heater, a review of the construction on employed and operating data should assist in selecting applications and designing units.]

Jan 1, 1953

By T. M. Yegulalp

A numerical model is being developed to assess the enhancement of permeability by improved fracture connectivity by micro-hydrofracturing. A generic two-dimensional percolation model has been developed to test the impact of various field conditions on permeability. Field data from Cyprus Minerals' Mineral Park Mine has been used to establish statistical properties of the observed fracture systems. Results of statistical anlyses of the field data and examples of the use of percolation model are presented.

Jan 1, 1995