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By Neha Shukla, Nikhil Dhawan

The current study examines the extraction of rare-earth elements from trichromatic phosphor of discarded tube lights via baking processes. The Y2O3: Eu3+ (YOX) and BaMgAl10O17: Eu2+ (BAM) phases completely decomposed during acid and alkali baking with > 90% Eu and Y extraction. Prior, selective acid leaching of the YOX phase enhanced the acid baking process at a lower temperature (< 230 ℃). Feed acid baking showed a maximum 87% Tb, 36% La, and 17% Ce extraction at 500 °C, 0.5 h, 1 ml/g H2SO4, and alkali baking yielded 16.1% Tb, 86% La, and 73% Ce at 300 ℃, 0.5 h, 50 wt.% NaOH. The acid baking of the acid-leached phosphor yielded 72% Tb, 95% La, 63% Ce, ~ 95% Y, and Eu extraction at 300 °C, 0.5 h, 1.05 mL/g H2SO4. Lower Tb extraction during the acid baking of acid-leached phosphor can be attributed to the formation of Ba3Tb( PO4)3 and BaTbO3 phases. Insoluble Si3Tb5 phase formation and partial decomposition of CeMgAl11O19: Tb3+ (CMAT) phase in the alkali baking route leads to lower Tb extraction. The acid baking process is suitable for extracting Tb, Eu, and Y, whereas the alkali baking process is suitable for La and Ce. The thermal analysis of phosphor and flux interaction depicts that alkali baking is less energy-intensive than acid baking. In comparison, the one-step acid baking process and the two-step alkali baking process yielded desirable extraction results (87% Tb, total RE (rare earth) 78.5% and 50.4% Tb, total RE 59.3%). The product yield in the acid and alkali baking route of feed, acid-leach phosphor is 36%, 29%, and 39%, 28.2%, respectively, with ~ 98% mixed rare-earth oxide purity.

May 5, 2022

By P. G. Barnard

The Nation&apos;s steel industry is largely dependent on shipments of manganese from foreign sources for steel production. An adequate substitute for the manganese requirements of our present steel technology would improve our national self-sufficiency and also contribute substantially to the conservation of our manganese resources. As each of these objectives is a major interest of the Bureau of Mines, possible substitutes for manganese in steel were investigated. Titanium was selected as the most promising substitute because the published results of several investigations indicate that titanium would perform the most obvious function of the manganese in steel: The elimination of iron sulfide and its deleterious effects. The investigation involved extending the published data on titanium additions in steel to provide enough information for an accurate evaluation of the practical value of the substitute. Therefore, quantitative data were obtained on the partition of sulfur and carbon between iron and relatively small titanium additions.

Jan 1, 1962

By Dennis D. Fischer

The second underground coal gasification experiment conducted by ERDA&apos;s Laramie Energy Research Center at a site near Hanna, Wyoming, was completed on July 30, 1976. During the experiment production reached 0.32 Mm 3/d (12 Mft3/d) of 6.9 MJ/m3 gas (175 Btu/ft 3 ). Approximately 6100 tonne (6700 ton) of coal were gasified during the experiment. Energy return ratios of 4.5 to 5.3, cold gas - thermal efficiencies of 76 to 89 percent, and overall process efficiencies of 65 to 74 percent were achieved during the second Hanna experiment. This paper describes the experiment and the results obtained with emphasis given to the determination of the energy recovered relative to energy consumed in conducting the test. Data from this determination are compared with previously published data from the first test conducted at Hanna during 1973-1974.

Jan 1, 1977

By A. LA. Salama, D. B. Hyma

"The Western Research Centre (WRC) of CANMET located in Devon, Alberta, is a modern research facility offering services ranging from fundamental research to pilot plant investigations. Recently, a 0. 76 metre diameter by 7.9 metre high Flotaire column flotation cell was installed as a demonstration unit for Canadian coal producers. Because the column cell is intended to be used for research, development and demonstration, WRC recognized that additional sensing equipment and improved process control would be required to generate good data for subsequent column scale-up and engineering design.A low cost, personal computer based control system was, therefore, designed and installed. This paper describes the stepwise procedure in developing the control strategies, selection of system software and hardware, and installation and configuration of the system.Preliminary performance data on a western Canadian coal sample are also presented. Future testwork is planned on additional coal samples to expand upon existing database."

Jan 1, 1993

The plans for the activities of the Petroleum Division for the coming year do not differ materially from those of the past several years. The fall meeting is scheduled for Oct. 12 and 13 and is to be held at Tulsa, Oklahoma. The Division, of course, will take part in the annual meeting of the Institute at New York. A fall meeting will also be held in California at approximately the same time as the meeting at Tulsa. A number of papers are to be presented at the two meetings simultaneously. The various committees are at work arranging the programs. The Division will continue to be active in its various fields of endeavor, such as stabilization, production reviews, and economics, but special stress is to be laid on the engineering and research fields. In the past the Division has served as a forum for open and frank discussion of problems confronting the engineers in the oil industry. It is hoped that it will continue to function in this capacity. Papers presenting original ideas and extending the boundaries of knowledge and understanding in the field of petroleum production will be welcomed. Members who have interesting information to contribute should not wait until called upon by one of the Committees, but should offer a paper at the earliest opportunity. The past year has seen a decided strengthening of the control over production, with prospects of even more rigid control in the future. It is essential that production programs under such control be carefully planned and it is highly desirable that petroleum engineers take an active part in the planning, to insure efficient production of oil and minimize the waste of this natural resource. At a time like this, when it is difficult to keep the production of oil within reasonable limits, it may seem unnecessary to improve the efficiency of production methods, but, as has been aptly said, the trouble is not that we have too great a reserve of oil but that we are producing tomorrow&apos;s oil today. Therefore it behooves those who are entrusted with the engineering and scientific phases of production to learn how to get the greatest yield economically possible from the present and future fields in order that we may enjoy the advantages of petroleum products for a long time to come.

Jan 1, 1934

By R. Bhima Rao

Performing a magnetizing roast in a furnace or kiln is a well-established technology. However, the use of microwave heat for the magnetization of hematite in the beneficiation of ferruginous bauxite is a new approach. This paper reports on an investigation of this procedure, which is followed by comminution and magnetic separation. The results of this investigation indicate that a nonmagnetic product containing 80% A1203 and 2.5% Fe203 with a recovery of 80% can be made from a crude bauxite ore containing 55.9% A1203 and 5.6% Fe203. This product is suitable for refractory use. The mechanism is explained by the ability of the microwave radiation to heat specific points within the bauxite. These heat-specific points are at the location of iron minerals. In a reduced atmosphere, the microwaves promote faster conversion of the iron minerals to a magnetic phase, which improves the magnetic-separation process.

Jan 1, 1997

By J. C. Hawkins

Determining moisture content and rate of flow of a solid product make measurement and control of dryers unusually difficult. This paper de-scribes a method of accomplishing this with readily made air-temperature measurements. The system can cope with changes in feed moisture and feed rate. It does not measure solids temperature. The system's application to several typical rotary dryers is described, and control schemes using feedforward techniques are explained.

Jan 1, 1971

By V. Svalbonas

With the occurrences of serious mill structural failures on both ball and primary mills, the mining industry has entered the era of detailed fabrication specifications. Such specifications, however, have been developed as individual entities, often by people not related to the mill design function. Therefore, there has been no effort to relate mill failure or safety to the existence or elimination of specific fabrication flaws; that is, no cause-effect failure relationships have been developed. The omission of this step produces a specification which can be termed uneconomical at best. The present paper attempts to fill this void, by reviewing methods for design consideration of flawed structures, and describing experimental tests used to tie such data to a meaningful quality assurance program in fabrication.

Jan 1, 1985

By John C. Edwards, Gerald S. Morrow

The U.S. Bureau of Mines has constructed a smoke chamber and developed sensitivity tests for smoke detectors. Response of ionization- and optical-type commercially available smoke detectors have been investigated. Six smoke detectors were measured with respect to visually obscuring smoke characterized by a corresponding optical density for smoldering and flaming coal combustion in the smoke chamber. It was determined that for one type of ionization smoke detector the alarm time was nearly equivalent to that of an odor monitor&apos;s alarm for smoldering coal combustion experiments and earlier for flaming coal combustion experiments. The experiments showed that an average CO concentration of 5 ppm corresponded to an optical density of 0.022 m for smoldering and flaming-1coal combustion. Two of the commercially available ionization-type smoke detectors were more responsive to flaming than smoldering coal combustion at an optical density of 0.022 m, whereas the optical smoke detectors-1showed the opposite trend. The responsive characteristics of the detectors evaluated with respect to known smoke conditions in the smoke chamber shows their potential for use as mine fire sensors or part of a mine atmospheric monitoring system to improve mine safety.

Jan 1, 1995

By J. P. H. Steele, T. Vincent, C. Debrunner, M. Whitehorn

For a variety of reasons, the need for automation of underground mining equipment is growing dramatically, e.g., improved safety and health, availability of labor, deeper mines, and desire for more focused excavation. While there has been tremendous progress made in this direction, much needs to be done to reach the holy grail of an autonomous mining machine. This paper reviews a number of technological developments and presents research and development needs for future development. A report on our current project for the Western Mining Resource Center at CSM is included.

Jan 1, 2000

By Edward L. McHugh, Jami M. Girard

While less than 1% of reported accidents are associated with slope stability problems, slope failures were responsible for about 15% of all U.S. surface mine fatalities between 1995 and 2001. Small rockfalls, which may involve hand-sized rocks weighing only a few kilograms, can cause fatal injuries to workers away from the protection of large machinery. Massive highwall failures containing a million cubic meters of material or more can be fatal even for heavy equipment operators. As part of an ongoing study at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, several remote-sensing technologies are being evaluated as tools to monitor slopes for hazards and to assess slope stability. Field tests of a hyper spectral imager were conducted to assess its value for improving geologic maps of potentially unstable alteration zones on mine slopes. An interferometric radar device capable of detecting very small displacements on slopes awaits final assembly and field testing. Computerized monitoring methods using images from digital and video cameras are being assessed for application to mine slope surveillance. These and other techniques will eventually provide new tools to augment current methods for monitoring ground control hazards in mines.

By H Lehtonen, H Mansikkaviita

In primary copper smelters, the received copper concentrate and other materials contain a certain amount of moisture, ranging from six to 14 per cent. Moisture in wet concentrate has a negative effect on the performance of the smelting furnaces when it is fed directly to the furnaces, namely increasing the energy consumption and the off-gas flow. There are several drying technologies available for drying copper concentrate, varying from direct heated rotary dryers and flash dryers to indirect heated steam dryers. Application of steam dryers has changed the drying process for copper smelters. Produced from a waste heat boiler, steam as heating medium enables plant-wide heat utilisation. Fossil fuel used from outside sources to remove water is no longer required and the combustion chamber is not required. In addition special attention has been paid to overcome the known problems of pollution emissions, excessive wear, clogging and frequent maintenance. The Kumera steam dryer is featured with many advantages based on principal improvements in reducing tube element wear and increasing drying efficiency. Thus, it has been considered as the first choice for those smelters where steam is available.

Jan 1, 2006

By Ben Hogg

Since the development of the top-submerged lance (TSL) technology for copper and lead smelting by the cooperation of Mount Isa Mines (MIM), now owned by Glencore, and the Commonwealth Scientific Industrial Research Organisation (CSIRO) the core of the ISASMELT™technology has always resided in the lance system. Through continuous innovation and operation of our own smelters, first at MIM, subsequently at Mopani, and also at both the Kazzinc Copper and Kazzinc Lead smelters, Glencore Technology have expanded the core equipment supply to enhance the plant operability. The success of Glencore Technology’s expertise can be directly measured by the success of the Kansanshi Copper Smelter plant, which achieved 100% nameplate capacity within three months of start-up. This paper describes the ISASMELT™ core equipment and how it is applied to smelt sulfide materials. It highlights the strength of the ISASMELT™: continuous innovation to facilitate the versatility and continued increased capacity with every plant implementation.

By Amy McBrayer, Andrea Brickey

Limited research has been conducted related to the development of mathematical optimization models for production scheduling at large surface coal mines using the area, i.e., strip, mining method. Increased economic and technical challenges have led to a new interest in production schedule optimization models for these type of mining operations like those currently applied to model underground and open pit mines. While area mines share similar characteristics to both open pit and underground metal operations, neither an open pit nor underground production scheduling model adequately depicts an area mine mathematically. We present an integer programming model with blending constraints and discuss the challenges and opportunities related to the implementation for area mines as well as future research in area mine production scheduling.

Jun 25, 2023

By J. van Deventer

Volatile gold prices in the face of rising costs for mining and refining is causing the mines to look for new ways to reduce costs and increase recoveries. This task is complicated by the fact that the gold in hereto unexploited reserves is associated with increasingly complex ores - either preg-robbing, refractory, associated with high concentrations of copper, or all of the above. Ion exchange resins can play a significant role in this quest for improvement. Although ion exchange resins have been used in Former Soviet Union (FSU) countries for the recovery of gold for many decades, it is still not widely used in the Western World. Synthetically manufactured ion exchange resins can be tailor-made to suit the chemical and mechanical characteristics of a specific application. As such, ion exchange resins can be used in a variety of solution matrices (e.g. cyanide, thiosulphate and acid), and process designs (recovery from clear liquor after solid-liquid separation or directly from the leached pulp). In this paper, a number of applications are discussed along with a review of recent developments in ion exchange technology.

Jan 1, 2014

By E J. Sellers, A Cocker

Movement of the fragmented rock mass is an inevitable consequence of open cut blasting. Uncontrolled, unaccounted movement from blasting commonly causes ore loss and dilution from waste mixing. Therefore, the prediction of the post-blast location of both ore and waste is vital in grade control and of direct interest to mining geologists. Direct measurement techniques have matured significantly over the past decade, but their use remains expensive and labour intensive. Access and safety issues are further disincentives to regular movement monitoring. What is needed is a combination of direct measurement to establish baselines and reliable predictive modelling.The W H Bryan Mining and Geology Centre of the University of Queensland has pioneered 3D blast movement modelling using ‘physics engines’ to handle in-flight collisions and predict the final resting place of blasted material. Open cut metalliferous mines are a demanding environment for this style of modelling as they can involve complex geometries and variable buffering, which leads to inconsistent confinement. A version of the model designed to deal with these complexities is under development. A well-controlled field trial was needed to validate this new version.A validation trial was completed at a gold mine in South-East Asia. The aim was to increase throughput by increasing the blast powder factor without losing grade through dilution and mixing with waste. Four blocks were blasted to identify the effect of bench height and face confinement on ore movement, fragmentation and process throughput. The powder factor and blast timing were kept constant. Movement of the broken rock was measured by placing blast movement monitors at known positions in the block and then locating them after the blast. The majority of sensors were recovered, providing a unique insight into blast movement dynamics and generating a substantial data set for model validation.The model (called ‘MetaMove ‘) was calibrated for one blast and applied to investigate the extent of grade loss and possible mitigation strategies. Conventional mining techniques that involved firing across the strike of the orebody, and no post-blast boundary adjustment of the ore/waste boundaries prior to digging, were found to cause up to 44 per cent loss of high-grade ore, depending on the grade distributions. Post-blast adjustment of the ore/waste boundaries can negate this loss. The model indicates that altering timing and ensuring that the block boundaries are well confined can further constrain the movement of ore/waste boundaries. Thus, the model can be successfully applied to minimise grade dilution and limit misclassification of ore as waste whilst using higher powder factors to increase mill throughput. Application of a calibrated model to move ore/waste boundaries prior to digging will enable the production geology team to add significant value to the mining operation.CITATION:Cocker, A and Sellers, E J, 2014. Modelling blast movement for grade control at an open cut gold mine, in Proceedings Ninth International Mining Geology Conference 2014 , pp 377–386 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By V. Thangadurai

The critical problems in commercialization of the present solid oxide fuel cells (SOFCs) and useful electrical and physical properties of IT-SOFCs electrolytes are discussed briefly. The conductivity behavior of the perovskite-type and perovskite-related structure metal oxides are summarized. Perovskite-type La0.9Sr0.10ao.8Mgo.203_8 (LSGM) exhibits high ionic conductivity of 0.1 S/cm at 800 °C. In order to improve the electrical conductivity of LSGM and the In analogue of LSGM, substitutions have been made at the A-and B-sites. Substitution of trivalent La3+ by isovalent Pr3+ in LSGM and La09Sro ilno.sMgo.202.85 (LSIM), yield new mixed conductors. Among the investigated compounds in the present study, La0APro.4Sro.21no sMgo.2028 exhibits the highest total electrical conductivity of 3.2 x 10-5 S/cm at 200 °C in air with the lowest activation energy of 0.44 eV (200-700 °C). LSIM and Pr-substituted LSGM and LSIM perovskites show p-type electronic conductivity in the oxygen partial pressure range 10-5 ? 0.21 atm at 750 °C. The perovskite-type solid solution SrSn1-xFex03 exhibits compositionally driven phase transitions. For example, compound of the composition x = 0 to 0.3 crystallizes in an orthorhombic GdFeO3-like perovskite structure, where as that of x = 0.4-0.9 crystallizes in simple cubic SrTiO3-like, and that of x = 1 in orthorhombic structure. The electrical conductivity of SrSn1_xFex03 increases with the increasing Fe content and reaches a value of about 10-1 S/cm at 25 °C in air for x = 1. Compounds with low Fe content exhibit both ionic and electronic conductivity, while the higher Fe content 0.5) perovskites are electronic conductors over a wide range of oxygen partial pressure of 10-22? 0.21 atm at 750 °C.

Jan 1, 2005

By Keith A. Heasley

The LaModel program has been used successfully in the United States for many years to design pillars to ensure global stability of pillar recovery operations. However, the recent Crandall Canyon Mine collapse showed that further research was required to improve the design of pillar recovery under deep cover. Toward this end, a new calibration procedure was implemented in LaModel. This calibration procedure prescribes techniques for calibrating the critical LaModel input parameters based on empirical abutment loading and pillar strength, as utilized in the time-tested ALPS and ARMPS programs. The calibration procedure is intended to help guide a novice modeler in choosing calibrated input parameters that produce a standard model that fits within the verification database. However, the rigid parameter specification incorporated in the calibration procedure also removes most of the flexibility in LaModel for specific calibration to the unique conditions at a given mine site. In this paper, a number of the LaModel input parameters are varied outside the bounds of the suggested calibration and the effects on the model results are analyzed. Ultimately, it is shown how the LaModel user might vary certain input parameters to adjust the model to site-specific conditions, while still maintaining the general accuracy and philosophy of the recommended calibration.

Jan 1, 2012

By Filippo Maria Leoni, Gianluca Pianezze

"As part of the Southeast Louisiana (SELA) drainage program, designed to reduce flood damages in the City of New Orleans and surrounding parishes, the SELA-22 project entailed the construction of a concrete covered canal along Jefferson Ave. and Prytania Street. The scope of the required soil improvement was to replace the soil between two parallel lines of sheet piles with a soil-cement mass to eliminate under-seepage, thus creating a so called bottom plug, and provide structural support for the concrete box culvert. The U.S. Army Corps of Engineers (USACE), New Orleans District, selected the jet grouting technology for the construction of the bottom plug to a maximum depth of approximately 40 ft, and for a total length of approximately one mile. The specialty geotechnical contractor proposed to accomplish the task utilizing their proprietary and innovative elliptical bi-fluid jet grout technology which, by limiting the overlap between adjacent columns, allowed a reduction of the overall number of installations. Approximately 2,400 elliptical jet grout columns were installed in a very challenging environment, especially under a logistical point of view. This paper will summarize the main features of the project, focusing on the innovative technological solution adopted to maximize productivity and on the several challenges faced in such limited and complicated logistical conditions.INTRODUCTIONThe Southeast Louisiana (SELA) drainage program has been designed with the purpose of reducing flood damages in the City of New Orleans and surrounding parishes. This will be accomplished by constructing new pumping stations and better drainage canals throughout. The program was authorized in 1996 by the United States Congress and administered under a project cooperation agreement between the Sewerage and Water Board of New Orleans (SWBNO) and the USACE.Prompted by the severity of damages associated with rainfall flooding in southeast Louisiana, the SELA program consists of several individual project components. The proposed work is located on both the east and west banks of the Mississippi River in the Orleans and Jefferson Parishes, as well as in portion of St. Tammany Parish."

Jan 1, 2017

By M. Mai Manga, M. Renaud, A. Faucher, C. Bazin

ABSTRACT Grinding circuits are operated in the presence of disturbances resulting from ore changes and equipment malfunctions, such as hydrocyclone overloading, worn or partly plugged apexes, surging, and internal liner detachment that may cause a loss of classification performance. Metal recovery losses in downstream leaching or flotation circuits justify the development of methods for rapid detection of hydrocyclone malfunction. Two methods are presented in this paper. The first method uses measurements from sensors available in a grinding circuit and the second uses vibration sensors installed on the individual hydrocyclones of a nest.

Jan 1, 2011