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By H S. Smit, P Lotz

Gold mining companies who are signatories of the International Cyanide Management Code (visit www.cyanidecode.org for further information) are required to measure WAD cyanide on-line and destroy WAD cyanide in excess of specified limits. Weak acid dissociable (WAD) cyanide refers to those cyanide species liberated at a moderate pH of 4.5 such as HCN(aq) and CN-, and the majority of Zn, Cd, Cu, Ni and Ag complexes with low dissociation constants. It is potentially toxic to humans and animals. Recognising and in response to the gold mining industryÆs need for an on-line WAD cyanide measurement device, Mintek recently developed the WAD Cynoprobe. The WAD cyanide analysis technique is based on the use of a ligand exchange reagent that liberates WAD cyanide from metal-cyano complexes. The ligand exchange reaction is represented by the following chemical equation: Metal(CN)X + yLigand <-> Metal(Ligand)y + xCN- The plant filtrate is treated with a ligand exchange reagent, to liberate WAD cyanide, before measuring the free cyanide concentration via amperometry. The instrument proved to be accurate and reliable in the laboratory as well as under industrial gold plant conditions during various trials. It has gained wide-spread commercial acceptance both locally and internationally. However, itÆs recent exposure to complex ore types have called for refinements to the analysis technique. It has been further developed to improve its precision and accuracy and to remove reagent and thiosulfate interferences. Its compatibility with the most commonly used destruction oxidants has also recently been investigated. The WAD Cynoprobe may be configured to measure both free and WAD cyanide concentration. Its fast analysis time, approximately 5 min, makes it suitable for use in the control and optimisation of the cyanide destruction and recovery process. Proper oxidant dosage control and monitoring of effluent concentration levels will ultimately result in less cyanide and post-destruction salts discharged into the environment.

Jan 1, 2008

By Charles Vaught, Jeff Duncan, Michael J. Brnich, Lisa J. Steiner

This document contains most of the materials needed to use the exercise. The main part of the document is the instructor's copy. It tells how to use the exercise, presents the objectives, the master answer sheet, the scoring key, and discussion notes to be used following the exercise. The next section summarizes results from field tests of the exercise, and reports the miners' evaluation of the activity. The last part of this document is three appendices. Appendix A is the exercise problem booklet. This booklet can be duplicated locally. The booklets are reusable. One is needed for every person in the classroom. Appendix B is the answer sheet. Copies of this answer sheet must have the latent image (invisible) ink answers that appear in Appendix C printed on them.3 Answer sheets are consumable. One is needed for each person or each small group of persons who work the exercise. Exercise Summary Read this section first. It determines if the exercise is appropriate for your classes. If you choose to use the exercise, examine the table of contents and review the remainder of this document. Type: Latent image Audience: Remote control and extended cut miner operators and face crews Length: Eight questions (30 minutes for administration plus 30 for discussion) Skills: Remote control mining procedures including remote control mining, taking extended cuts, resetting breaker on mining machine, and setting timbers. Communicating mine conditions, influencing safe behaviors when mine conditions are less than stable Location: Underground coal mine, four section continuous mining operation Average seam height is 48 inches Problem: Your regular job is on the general labor crew at Cripple Creek #9 mine, a four section continuous mining operation. The mains are 9 entries wide and panels are 5 entries across. You and the rest of the crew had annual refresher training about 3 months ago. For the past few days you have been sent to 2 South panel to fill in as the third shuttle car operator. This morning, however, your buggy is down. The face boss asks you to get the scoop and take seven or eight timbers to the number 5 entry because the last shift got off sight line. The miner will be working in entry 5 while the bolter crew pins entry 4. When you get up to the face you see that Mo, the remote control continuous miner operator, has rounded off the left inby corner in order to make his first cuts in the right hand rib. Now, he has squared around enough so that you and Red, the miner helper, can set some posts on the corner. The two of you set posts along the left inby rib of #5 entry while the shuttle car operator waits. You are in a tight spot when Mo decides to start mining. You must decide where the best place is to stand for safety and to be out of the way.

Jan 10, 1999

By Larry D. Nichols

Poroplastic membranes containing ion exchange liquids were studied for separating cobalt from nickel-containing solutions similar to ammoniacal laterite leaches. The driving force for cobalt transport was differences in pH and composition between the leach and extraction streams. Using a diketone ion exchange liquid, a leach pH of 6.5 to 7.0, and a strip pH of 2.3, cobalt was extracted from a 750 ppm solution containing 2500 ppm of nickel at rates ranging from 1 to 10 µg/cm2 .min in single membrane cells, and from 10 to 100 in more closely spaced multiple membrane cells. Rates were variable, with evidence that cross -membrane flow pasterns were a key factor; a reproducible rate of 30 pg/cm .min would be economically viable. Loss of transport observed after several days of continuous operation was restored by flushing membranes with fresh ion exchange liquid. A major effort was devoted to preparation of thin, leak-free membranes; the resulting membranes endured operating conditions without mechanical failure.

Jan 1, 1982

By A. M. Khan, I. Fatt

A new type of steady-state thermal conductivity apparatus is presented and described. Results of measurements on Berea sandstone, Solehofen limestone, Bandera sandstone and Bakelite are presented. The measurements were made in a two-hour period at temperatures up to 80C and axial stress to 125 bars. Results show that the thermoelectric heat pump and tbermistor-controlled electric heater can be used in a steady-state apparatus for measuring thermal conductivity of mck. Steady-state is reached within two hours. With Urethane foam insulation, not more than 3 per cent of heat is lost by radial flaw. The apparatus can be used as a comparator or for absolute thermal conductivity determinations. INTRODUCTION Calculations of heat flow through the earth, both for scientific purposes and engineering design, require thermal-conductivity data on rock. However, the high variability of rock often makes handbook thermal-conductivity data of little value. For engineering purposes in particular, it is desirable to have measured data on samples of the rock mass under study. Laboratory methods for measuring thermal conductivity of rock use either time-dependent1-3 or steady - state temperatures .4,5 The time -dependent (transient) techniques give thermal diffusivity from which thermal conductivity can be calculated if the specific heat and density of the sample is known. Most transient techniques require lengthy and involved sample preparation. Also, the accuracy tends to be low. Steady-state techniques are more exact and are the most commonly used. The steady-state methods, however, also have their difficulties. A long time is often required to reach steady state, troubles have been encountered in establishing good thermal contact between the heating and cooling elements and the rock sample, and unaccounted-for heat losses are difficult to prevent. In this paper we present a description of a new type of steady-state thermal conductivity apparatus. With it, measurements have been made in two hours at temperatures up to 80C and axial stress to 125 bars. Sample preparation is simple and no thermal conductivity standard is needed.6 APPARATUS Our steady-state apparatus is an improvement . over the conduction pile used by Zierfuss and van der vliet4 and Somerton.5 A linear heat flux is established through a conduction pile consisting of the rock sample and a standard material of known thermal conductivity in series. The thermal conductivity of the sample is calculated from the ratio of the temperature drop across the sample

Jan 1, 1966

By B. R. Hart, S. S. Dimov, J. Fournier

Carbonaceous matter (c-matter) in sulphide ores can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob, gold from a cyanide leach solution. This paper describes a standardized procedure for characterization of c-matter in an ore sample providing detailed information on its composition, maturity and preg-robbing capacity. The procedure utilizes the following complementary analytical techniques in conjunction with several chemical tests and assays: SEM/EDX Raman spectroscopy and TOF-SIMS. Results of the test can be used as a predictive tool to estimate the impact the c-matter will have on the gold recovery process. A comparison between predicted preg-robbing behaviour and cyanidation test results are presented.

Jan 1, 2011

By D. Weijie, S. Kai, Y. Hu, X. Ning, M. Shiyi, W. Junpeng, Z. Guihong, L. Xianjie

Flotation is one of the most important processes in the copper production industry. The copper grade in the concentrate is a pivotal indicator of the flotation process performance. However, it is difficult to achieve real-time measurement through hardware sensors. Based on the production data provided by an industrial operation, a novel soft sensor based on multi-layer perceptron (MLP) is proposed for effective monitoring of this pivotal indicator. The proposed soft sensor uses the nonnegative garrote (NNG) to perform global variable selection for MLP, while a local search (LS) approach is incorporated to improve the model presented by NNG. Simulation results show that the proposed algorithm has higher prediction accuracy and better model simplicity than other algorithms. Furthermore, the variables selected are consistent with the field experience, and the developed model can provide reference of feedback control for the optimisation of the process. Keywords: Flotation process of copper ore, nonnegative garrote, local search, soft sensor, multi-layer perceptron

Jan 1, 2020

By S. L. Ducummon

Inactive underground mines now provide essential habitat for more than half of North America's 44 bat species, including some of the largest remaining populations. Thousands of abandoned mines have already been closed or are slated for safety closures, and many are destroyed during renewed mining in historic districts. The available evidence suggests that millions of bats have already been lost due to these closures. Bats are primary predators of night-flying insects that cost American farmers and foresters billions of dollars annually, therefore, threats to bat survival are cause for serious concern. Fortunately, mine closure methods exist that protect both bats and humans. Bat Conservation International (BCI) and the USDI-Bureau of Land Management founded the North American Bats and Mines Project to provide national leadership and coordination to minimize the loss of mine-roosting bats. This partnership has involved federal and state mine-land and wildlife managers and the mining industry. BCI has trained hundreds of mine-land and wildlife managers nationwide in mine assessment techniques for bats and bat-compatible closure methods, published technical information on bats and mine-land management, presented papers on bats and mines at national mining and wildlife conferences, and collaborated with numerous federal, state, and private partners to protect some of the most important mine-roosting bat populations. Our new mining industry initiative, Mining for Habitat, is designed to develop bat habitat conservation and enhancement plans for active mining operations. It includes the creation of cost-effective artificial underground bat roosts using surplus mining materials such as old mine-truck tires and culverts buried beneath waste rock.

Jan 1, 1997

By H. Nemutolluhi

Discussion by G.E. Agar In the April issue of Mining Engineering there is a technical note "New size laboratory ball mill for Bond Work Index determination" written by M. Nematollahi which is very confusing. My recollection is that a description of an experimental procedure should be such that someone skilled in the art should be able to reproduce the results. Applying this test to this particular article would according to me cause a failure to be registered. There are apparently three batch laboratory test procedures referred to in the article. One of these is the traditional Bond test with all its limitations such as dry grinding followed by exclusively dry screening, two attributes which fail to simulate conventional industrial grinding. There is a second procedure (NSBM) which the author is advocating as an improvement of the Bond procedure but from the description I doubt that anyone would be able to repeat the procedure. For instance, is the grinding to be done wet or dry, if wet at what pulp density, and how is the screening to he done, wet or dry or a combination? On top of that uncertainty the author refers to a simplified "Anaconda" test. No reference is provided for this procedure and in the text the results of the technique are referred to "Denver wet ball mill" results and say nothing of Anaconda results. Reply by H. Nematollahi I think that the method proposed to determine the Bond Work Index in this paper is clearly described in the paper as follows: •The method of grinding is dry (Ref. paragraph I, subject Method description); •The size of ball mill, the quantity and size of balls are noted (Ref. paragraph 1, subject Test equipment); and The test procedure is described in detail (Ref. paragraphs 1, 2 and 3, subject Test procedure). As it is noted in the paper, the test has been worked out under the same condition as Standard Bond Test with ball mill, so dry (screening should be dry also), but using a smaller ball mill and a smaller quantity of sample. Considering the above mentioned points, I believe that the method has been fully and clearly described and it ought to be repeatable as well. The Anaconda test is a method for determination of Work Index and could be done by any types of laboratory wet ball mill (Yan, R.F., et al., cf. References). I applied this method using a laboratory Denver ball mill (Ref. paragraph I subject Determining the Bond Work Index). So the results referred to Denver wet ball mill can be equated the same as Anaconda method.

Jan 1, 1996

By D. S. Scovira, T. Gustavsson

Exiting WW2 (mid-1940s), the potential of nitrates (ammonium nitrate, calcium nitrate, sodium nitrate) and hydrogen peroxide for application as a commercial explosives for mining, construction, and other industrial purposes both became known. The technology stream advanced the development and uptake of nitrate based explosives to the point that they are the current global standard for blasting. Today, environmental issues are shaping the strategic agenda across various industries. Most global mineral resource, construction houses, and explosive manufacturers have publicly announced ESG carbon reduction commitments in support of COP26 Net Zero 2050. The mid-2010s saw a renewed interest in hydrogen peroxide explosives to eliminate NOx fume. Carbon reduction initiatives in the early 2020s provided additional impetus to investigate hydrogen peroxide based explosives for industrial use. Hypex Bio has recently pioneered the formulation, manufacture, and end-use delivery of a Hydrogen Peroxide Emulsion (HPE) on an industrial scale. The HPE is composed primarily of hydrogen peroxide (H2O2) plus a lesser amount of fuel and emulsifier phase. The base HPE is produced in a low energy intensity modular plant using industry proven mixing techniques. The base HPE is a white, highly viscous emulsion that is similar in consistency to base nitrate emulsions. To enable end blasting use, a mobile charging unit gases the base HPE to a detonable density. The HPE is compatible with current priming and initiation systems. Hydrogen peroxide explosives offer a significant reduction in total carbon emission as compared to nitrate based explosives. The production of ammonium nitrate (AN) emulsion is energy-intensive and not carbon neutral. Based on the EU Average and for the oxidizer phase only, 1 kg [2.2 lb] of AN emulsion emits 2.3 kg [5.1 lb] of CO2 as compared to the production of hydrogen peroxide emulsion that results in 0.23 kg [0.5 lb] of CO2. This is a difference of 90%. HPE contains no nitrates and does not generate post blast nitrous oxides (NOx). HPE generates no aqueous nitrate or ammonia pollution and is a solution to meeting increasingly regulated mine site water discharge limits. Hypex Bio recently conducted a successful underground HPE evaluation with a major mining company in Sweden. HPE blast designs were the same as those done with nitrate based emulsions. Rock breakage, advance, muck displacement, and excavator performance were equivalent. Ventilation and re-entry times were reduced. The mining company has expressed further interest in assessing HPE and is demonstrating industrial leadership by exploring this transformative explosive technology

Jan 1, 2024

Background ArcelorMittal?s (formerly QCM?s) Port Cartier iron ore pelletization operations 2 side-by-side induration furnaces each producing 578 t/h of cured pellets Firing No. 6 fuel oil and coke breeze (in bed) Very large heat losses to be addressed primarily by gas recirculation

May 1, 2011

By J Cook, S Pike, D Pridmore

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The application of high-resolution seismic reflection to map structure and/or mineralisation in hard rock environments has progressed significantly in the last decade. Improvements in equipment, field practice, processing and understanding has seen the seismic reflection technique emerge as a cost-effective tool for high-resolution three-dimensional structural and lithology mapping to depths far greater and with superior accuracy than other more conventional geophysical techniques.This paper outlines results and preliminary interpretation of 2D and 3D seismic reflection surveys aimed at defining fault zones and locations for quartz load development in favourable host lithologies at the Cracow low-sulfidation epithermal gold system in Queensland, Australia.As this is possibly the first time that high-resolution seismic reflection data has been used to define the structurally-controlled location of low-sulfidation epithermal gold mineralisation, an important aspect of this work was the derisking or due diligence steps taken prior to commissioning the full 3D surveys at each site. This included full wave sonic logging, vertical seismic profiling and trial 2D lines. Interpretation of the 2D profiles and the drilling of interpreted structure provided the confidence to proceed with the full 3D survey.The advantage of collecting 3D data extends beyond ensuring that the received reflections are located correctly in 3D space. The final 3D data cube can potentially map the entire fault network, thus highlighting flexures and changes in orientation of the structures both vertically and along strike, which is an important aspect in the deposition of gold and for direct targeting.CITATION:Smith, R, Cook, J, Pike, S and Pridmore, D, 2015. Application of high-resolution seismic reflection surveys to exploration for blind vein systems at the Cracow low-sulfidation epithermal field, in Proceedings PACRIM 2015 Congress, pp 77–84 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Robin Dill, Wei Song, Andrew Perham, Leo Martin

"AECOM completed a subsurface exploration program for an 18-foot diameter, approximately 4-mile long rock tunnel project in Hartford, CT. The tunnel crosses the regional geologic trend through the middle of a sedimentary basin, passing through four separate rock formations, including two volcanic flows. Faulting is prevalent, with at least 15 faults encountered during the site investigation. Severe artesian flows were also experienced in several of the borings, requiring highly specialized drilling equipment. Sixty-two borings and associated testing were performed to characterize the structural geology, hydrogeology, rock properties and ground conditions. A phased program was carefully planned and implemented with participation of geotechnical and geologic specialists, with thoughtful evaluation along the way to react to the ground conditions encountered, and make appropriate refinements. This paper will discuss the subsurface program details; the integrated efforts used to effectively characterize the ground; and will summarize the final characterization presented in the GBR. PROJECT DESCRIPTION The South Tunnel Conveyance and Storage Tunnel project is part of the Metropolitan District (MDC’s) Long Term Control Plan to address discharges to various water bodies throughout the greater Hartford area. This program includes a main conveyance and storage tunnel; a tunnel boring machine (TBM) launch shaft and retrieval shaft; adit tunnels with associated drop shafts and connection structures; consolidation conduits and manholes; and a tunnel pump station (TPS) at the downstream end of the main conveyance tunnel. AECOM is serving as prime designer for the MDC on this project. The main conveyance tunnel (hereinafter referred to as the “South Tunnel”) will be a deep rock tunnel with an invert depth of approximately 180 feet at its downstream end and approximately 218 feet at the TBM retrieval shaft. The tunnel will have a finished diameter of 18 feet. The tunnel will rise in grade at a slope of 0.1 percent to its upstream end. Total invert depth along the deep tunnel alignment ranges from about 180 ft. to as high as 320 feet. The total length of the tunnel will be 21,754 feet. The South Tunnel will be constructed using a shielded TBM and fully lined with pre-cast concrete segments."

Jan 1, 2016

By S. M. Rupprecht

"Artisanal mining is basic mining characterized by manually intensive work methods utilizing primitive or simple equipment and conducted by individuals or small groups exploiting deposits. Artisanal mining in Rwanda and Burundi is further complicated in that the techniques applied are often inadequate, resulting in low productivity and poor recoveries, and workers are paid low wages with owners reluctant to reinvest in the mining operations. A consequence of this vicious circle is often poor working conditions, with miners operating under unsafe and/or unhealthy working conditions. An additional problem is that mining is conducted in a manner that is detrimental to the environment.Artisanal mining is commonly more dangerous than large-scale modern mining operations. Artisanal operations are generally subsistence activities with the miners focusing more on immediate concerns than the long-term consequences of their activities. When miners have no other source of income, they will usually find ways to evade controls and carry on working. Machinery tends to be expensive and often far beyond the reach of most artisanal miners, and therefore there is a general tendency for workers to focus on labour intensive and riskier mining methods.This paper proposes the introduction of small-scale mechanization with labour-intensive manual mining utilizing a bench mining approach in artisanal mines operating in Central Africa. From the 1950s to the 1980s bench mining was successfully conducted in Burundi utilizing manual labour. In order to achieve a balance between job creation and project economics, the combination of manual and mechanized mining is proposed. Manual mining offers the benefit of local job creation while ensuring good mining techniques, such as minimizing mining loses and dilution. Through the introduction of mechanized loading and hauling activities, areas of high stripping ratios can be viably mined, thus increasing the amount of resources that can be exploited. The use of a loader and tractor-trailer arrangement is proposed, thereby improving throughput, productivity, and worker safety and, reducing the impact on the environment."

Jan 1, 2017

By T. Fernandez, V. Juchen, C. Petter, F. Cantini, V. Lenz, V. I. Araújo, R. Petter, R. Darrigo, A. Young, I. G. da Costa, J. Oppermann

There are many methods to estimate costs quickly. One of these is the Parametric Method, where costs are estimated from general algorithms (or curves). Derived from an original tool based on the O’Hara model, a software called MAFMINE was developed. MAFMINE is based on parametric models to estimate investment and operational costs in mining. The software itself is based on the use of a computer model known as client-server. However, the model needs new inputs from advances made by the mining industry, mainly in terms of electrification, automation, digital transformation and preconcentration to face Environmental, Social and Governance (ESG) concerns. Thus, this work was to prepare a new core module ready to incorporate the new technologies aiming to deliver operation and capital costs associated with environmental impact mitigation. The tool generates an order of magnitude estimate for CAPEX and OPEX to establish a very first Discounted Cash Flow (DCF) in a mining venture. For quick evaluations, at a preliminary level, the results are very promising.

Mar 2, 2022

Jan 1, 1993

By Shahriar Vandani, Andy Herlache, Andrew Bro, Wei-Yu Chen

"The Presidio Parkway Project will reconstruct approximately 1.6 miles (2.6 km) of highway, including seven new bridges, three new cut-and-cover tunnels, and a new undercrossing connecting the Golden Gate Bridge to the City of San Francisco, California. The project site is approximately 5.6 miles (9 km) from the San Andreas Fault, capable of producing magnitude 8 earthquakes. Seismic hazards include strong ground shaking, soil liquefaction, ground settlement, and lateral spreading. The Main Post Tunnels (MPT) are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) long. The MPT site underlain by loose sandy soils susceptible to liquefaction and lateral spreading. Excessive racking and permanent displacement due to lateral spreading are identified as the main seismic vulnerabilities. Analyses showed that without ground improvement, tunnel racking of over 5 inches (13 cm) and permanent lateral tunnel displacement of up to 15 feet (4.6 m) could be anticipated. Cement Deep Soil Mixing (CDSM) is proposed to mitigate slope displacements and increase lateral stiffness of the foundation materials to reduce tunnel racking. A series of 2-D fully dynamic time domain analyses were performed to evaluate the performance of CDSM, confirm that performance criteria are met, and optimize the CDSM geometry and replacement ratio. The use of CDSM reduced the permanent tunnel displacement from over 15 feet (4.6 m) to less than 1 inch (2.5 cm). Tunnel racking was also reduced significantly. The adopted analytical approach presented herein can be considered for future tunnel design projects in seismically active areas.Introduction The Main Post Tunnels (MPT) are an integral component of the Presidio Parkway project which will replace the existing facility with a new multi-lane roadway between the Golden Gate Bridge and the City of San Francisco. The MPT are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) in length. As shown on Figure 1, the project site is located in a seismically active area, about 5.6 miles (9 km) east of the San Andreas Fault and 12.5 miles (20 km) west of the Hayward Fault. The San Andreas Fault can generate magnitude 8 earthquakes while the Hayward Fault is capable of producing magnitude 7.3 earthquakes. The design Peak Bedrock Acceleration (PBA) is 0.46g for the upper level design earthquake. The project alignment is shown on Figure 2."

Jan 1, 2014

By R. H. Jacoby, V. J. Berry

Future depletion performance and ultimate oil recovery from reservoirs producing under volumetric control are often predicted with the aid of a material balance equation. When the reservoir fluid is very volatile, however, certain assumptions implicit in the use of the conventional methods are no longer valid. This is became laboratory differential vaporization test procedures do not adequately represent the reservoir depletion process and the performance of surface separation facilities. In such cases recovery of stock tank oil per unit of pressure decline can be predicted only from a detailed knowledge of the separator conditions and the over-all composition of the fluid entering the wellbore at each stage of depletion. Surface recovery is not simply related to the total quantity of liquid flowing into the well under reservoir conditions. In order to improve predictions for reservoirs which produce volatile oils, a step wise method of calculation has been developed. This method uses relative permeability data and multicomponent flash calculations to predict oil and gas production as a function of reservoir pressure. Calculations are presented for a reservoir containing a volatile crude oil, and predicted tank oil recovery by primary depletion is more than twice that predicted by conventional methods which are known to be adequate for ordinary black crude oils. Calculated maximum produced gas-oil ratio is less than one-fourth of the conventional prediction. Wellstream compositions have also been used to determine variation in stock tank oil composition and liquid content of the separator gas. This information is of particular importance for crude stabilization calculations and for design of gasoline plant facilities to recover LPG and natural gasoline. INTRODUCTION The estimation of oil reserves and the prediction of future recovery performance of petroleum reservoirs is a frequent task of the petroleum engineer. If the reservoir produces under volumetric control, performance calculations for primary depletion are made by combining oil and gas material balances with the gas-oil flow characteristics of the reservoir rock. For black oil reservoirs, the Schilthuis1 type material balance is commonly employed. For gas or gas-condensate reservoirs, where only one phase is flowing under bottom-hole conditions, a more simplified material balance is used. In the period in which these material balance methods were conceived and put into practice, it was common to classify reservoirs according to the type of fluid produced as (1) black oil reservoirs, or (2) gas or gas-condensate reservoirs. Recently, however, deeper drilling and more extensive studies of reservoir fluid properties have led to the recognition of reservoir fluids with phase characteristics between those of ordinary black oils, and gases or gas-condensate fluids. These intermediate fluids contain relatively large amounts of the hydrocarbons ethane through decane and are found in deep, high temperature (250°F) reservoirs. Such fluids are often referred to as high shrinkage crudes or "volatile oils." They are usually characterized by tank oil gravities above 45° API. high solution gas/oil ratios,

Jan 1, 1958

By William D. Klopp, Joseph R. Stephens

Chromium alloys were coated with silicon, alumi-nuw, and boron by pack cementation. None of these simple coatings provided adequate nitridation/oxida-tion protection for a Cr -0.17pct Y alloy substrate as shown by a substantial Increase in the ductile -brittle transition temperature after air exposure for 100 hr at 2100°F. Iron-modified silicide coatings afforded good protection, holding the transition temperature of air-exposed specimens to 350° F compared to 200° F for uncoated unexposed specimens and 800°F for un-coated exposed specimens. Additional attractive cant-binations of modi-tying elements included Fe-mo, Fe-Mo-W, Fe-,Mo-W-Ti, and V-Mo-W-Ti. THE desirability of increased operating tempera-tures as a mcans of improving the performance of ad-vanced air breathing engines has resulted in emphasis on the development of materials with high operating temperature capabilities. Chromium, because of its relatively low density (7.19 g per cu cm), high melt-ing point (3410°F), and adequate strength upon alloy-ing, is a candidate material for turbine buckets and stator vanes of advanced air breathing engines. How-even, chromium is not without severe limitations, the major one being susceptibility to nitrogen embrittle-ment upon exposure to air at high temperatures.1,2 For example, a 25-hr air exposure of a Cr-5 pct W* * All compositions in wt pct. alloy at 2100°F produces a 600°F increase in the duc-tile-brittle transition temperature.' Although dilute alloying with such elements as yttrium, lanthanum, arid thorium3,4 or strong nitride formers5 has been shown capable of reducing nitrogen embrittlement, it is apparent that some additional form of surface protection, such as coatings or claddings, will be required for long time service in air breathing engines. Studies of aluiminide6 and silicide7 coatings and of nickel-base claddingsl on chromium alloys to date have suggested that these protection systems are inadequate. Of the aluminidc systems Studied,6 a simple aluminum and an Fe-Al coating on a Cr-5 pct W-0.1 pct Y alloy showed the lowest air exposure weight gains. However, the air exposures raised the ductile-brittle transition temperature of the coated specimens to above 1600°F from an initial level in unexposed specimens of about 500°F. A second in-vestigation for protection of Cr-5 pct W-0.1 pct Y employed gas pressure bonded alloy foils as protective claddings.1 An aluminized Ni-20 pct Cr-20 pct W alloy plus an unalloyed tungsten barrier layer gave the best performance with air exposure lives based on appearance and weight gains of over 600 hr at 2100°F. However, the bend ductile-brittle transition tempera-ture was increased to at least 1000°F after 100 hr at

Jan 1, 1970

By C. R. Dale

The need for instruments to measure the movement of fluids and gas in wells has been recognized by engineers for many years. Information regarding flow in the producing interval has a direct bearing on completion practices in new wells and also provides information on the production characteristics of the well. Many hours of engineering time are spent in planning and completing wells but knowledge as to whether or not the original planning has produced the desired results has not always been complete. Many questions such as the following often arise: Why is it that two wells are completed under supposedly identical conditions, yet one well is a good one and the other is a poor one? Are the sands that look the best on the electric log contributing to the production? These and many other conditions in the producing well need to be under- stood in order to develop more efficient production practices and to improve on methods of completing new wells. It is the purpose of this paper to briefly describe one type of instrument, outline the methods of running the equipment and show the results of surveys made under various conditions. With an understanding of the use of this type of survey its importance can be evaluated in relation to the problems encountered by the operator. DESCRIPTION OF INSTRUMENT The instrument is a velocity recorder employing a clock-controlled 16mm film for recording the rpm of an extremely sensitive rotor which is rotated by the flow of fluids or gas in a well. The helical-vaned rotor and shaft, weighing one-half of one ounce are an integral unit exposed to the well fluids and are the only moving parts not enclosed in the fluid-tight housing. No packing or fluid seal of these parts is necessary and the shaft is mounted top and bottom on special jeweled bearings. Fig. A is the lower part of the instrument showing rotor and shaft with the protecting housing sleeve removed. The rpm of the rotor is recorded on the moving film by a combination electrical and optical system. The record is a series of dashes on the film, each dash and space representing twenty (20) revolutions of the rotor. (Film record of survey made in California well showing station recordings at various depths.) As the movement of the film is controlled by the clock the number of dashes and spaces in one minute of film travel represents the rpm of the rotor. The range of the instrument is from 0 to 2,500 rprn. The barrel or housing is 1-11/16 in. OD and seven feet long. Various types of expanding fluid traps are attached to the lower end of the instrument to direct the flow through the 1 in. orifice containing the rotor. The fluid trap for upward flow is shown in Figs. B and C. This assembly consists of eight arms with light spring

Jan 1, 1949

By C. R. Dale

The need for instruments to measure the movement of fluids and gas in wells has been recognized by engineers for many years. Information regarding flow in the producing interval has a direct bearing on completion practices in new wells and also provides information on the production characteristics of the well. Many hours of engineering time are spent in planning and completing wells but knowledge as to whether or not the original planning has produced the desired results has not always been complete. Many questions such as the following often arise: Why is it that two wells are completed under supposedly identical conditions, yet one well is a good one and the other is a poor one? Are the sands that look the best on the electric log contributing to the production? These and many other conditions in the producing well need to be under- stood in order to develop more efficient production practices and to improve on methods of completing new wells. It is the purpose of this paper to briefly describe one type of instrument, outline the methods of running the equipment and show the results of surveys made under various conditions. With an understanding of the use of this type of survey its importance can be evaluated in relation to the problems encountered by the operator. DESCRIPTION OF INSTRUMENT The instrument is a velocity recorder employing a clock-controlled 16mm film for recording the rpm of an extremely sensitive rotor which is rotated by the flow of fluids or gas in a well. The helical-vaned rotor and shaft, weighing one-half of one ounce are an integral unit exposed to the well fluids and are the only moving parts not enclosed in the fluid-tight housing. No packing or fluid seal of these parts is necessary and the shaft is mounted top and bottom on special jeweled bearings. Fig. A is the lower part of the instrument showing rotor and shaft with the protecting housing sleeve removed. The rpm of the rotor is recorded on the moving film by a combination electrical and optical system. The record is a series of dashes on the film, each dash and space representing twenty (20) revolutions of the rotor. (Film record of survey made in California well showing station recordings at various depths.) As the movement of the film is controlled by the clock the number of dashes and spaces in one minute of film travel represents the rpm of the rotor. The range of the instrument is from 0 to 2,500 rprn. The barrel or housing is 1-11/16 in. OD and seven feet long. Various types of expanding fluid traps are attached to the lower end of the instrument to direct the flow through the 1 in. orifice containing the rotor. The fluid trap for upward flow is shown in Figs. B and C. This assembly consists of eight arms with light spring

Jan 1, 1949