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By Gordon D. Jarvinen

Polymer Filtration (PF) Is an innovative, selecthle metal removal technology. Chelating, water-soluble polymers are used to selectively bind the desired metal ions and ultrafiltration is used to concentrate the polymer-metal complex producing a permeate with low levels of the targeted metal ion. When applied to the treatment of, Industrial metal-bearing aqueous process streams, the permeate water can often be reused within the process and the metal ions reclaimed. This technology is applicable to many types of industrial aqueous streams with widely varying chemistries. Application of PF to 'aqueous streams from nuclear materials processing and electroplating operations will be described.

Jan 1, 1999

By Umay Cinarli, Ahmet Turan

High-energy consumption in primary aluminum production (from bauxite ores) makes secondary aluminum production (from metallic raw materials such as scrap and dross) very critical. Aluminum dross, as a waste, arises in pyrometallurgical processes, and it is the mixture of metallic Al, Al2O3, other metal oxides, metal halides, and some other compounds like AlN. Aluminum dross has two subgroups (white and black) with respect to its metallic aluminum content. White dross is a secondary aluminum resource because of its high metallic aluminum content, whereas black dross, having low metallic aluminum content, is generally disposed in dumping areas. In the present study, it was aimed to develop a simple technique to valorize aluminum black dross in the form of alumina-based ceramic materials through pyrometallurgical (calcination) and hydrometallurgical (leaching) operations. Moreover, thermochemical simulations were conducted by using HSC Chemistry 6.12 software to simulate calcination conditions. After leaching experiments, an alumina-based ceramic containing approximately 36.8% Al2O3, 61.4% MgAl2O4 with 1.8% Na2FeO4, which might be available to use as a spinel refractory in steel smelting furnaces, was obtained in the experiment carried out in a solution containing 10 mLH2SO4 and 40 mL distilled water (3.5 M). Moreover, the sinterability of the alumina-based ceramic was investigated at the temperatures from 1350 to 1550 °C. In the sample which was sintered at 1550 °C, a density value of 3.15 g cm−3 and a hardness value of 69.58 HV were measured.

Oct 26, 2020

By Lev Filippov, Vyacheslav Severov, Inna Filippova

"Reverse cationic flotation is a very efficient method of beneficiation of oxidized iron ores when you need to separate hematite and quartz. This method can be also applied to reduce silica content in the magnetite concentrates obtained by wet low-intensity magnetic separation. However, cationic flotation in this case is less effective due to the presence of Fe-Mg-Al-bearing silicates as amphiboles in magnetite ores. These silicates are concentrated in magnetic products and determine the difficulties of their separation from iron oxides when amines and starches are used as collectors and depressants, respectively. The recalculation of the results of the electron microprobe analysis of three calcic Fe-Mg-Al-bearing amphiboles used to characterize cation distributions in structural units and to obtain structural formulas in accord with stoichiometric limits was conducted. The Mössbauer spectroscopy was used to examine the validity of the empirical estimation of cation distributions in amphiboles. The studied samples are metamorphic pargasite and ferrotschermakite and volcanic magnesiohornblende. The crystallographic analyses of the amphibole samples exhibited their heterogeneous surfaces explaining worse floatability of amphiboles with dodecylamine at pH 10. The electrokinetic measurements showed that the position of the isoelectric point of amphiboles is related to a substitution of Al3+ for Si4+ in tetrahedral sites and to an amount of Mg2+ cations in octahedral sites. Thus, the dodecylamine adsorption onto amphiboles through electrostatic interactions is mainly affected by a distribution of these cations in tetrahedral and octahedral sites of amphiboles. In addition, the effect of starch on the depression of Fe-Mg-Al-bearing amphiboles during flotation can be attributed to the presence of metal ions on the amphibole surface, which are capable of forming strong chemical complexes with starch molecules."

Jan 1, 2014

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"The effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases.Electrokinetic methods were used to elucidate the mechanism of surfactants adsorption and to correlate these findings with the optimum flotation conditions. The polymeric surfactants would reduce the negative values of zeta potential of quartz while the reverse is true for feldspar. After treatment of microcline with HCl, its electrokinetic behavior in the presence of Tritons X surfactants became similar to that of quartz.The obtained results would suggest that separation of quartz from feldspar using nonionic surfactants of octylphenoletoxylated alcohols having shorter oxyethylenic chain length at low pH could be achieved"

Jan 1, 2003

By Léo Daiki Shinomiya

O planejamento de cenários é uma ferramenta empregada como um mecanismo competitivo que entrega uma visão para um futuro passível de acontecer, baseado em fatos atuais e históricos. Adaptado para ser aplicado a resíduos industriais, este método de planejamento de cenários pode ser descrito em oito etapas. Neste trabalho é apresentada a 1ª etapa, que mostra o uso de pesos e critérios para definir as aplicações mais adequadas para a Lama Vermelha a partir de uma infraestrutura disponível localmente. A Lama Vermelha é gerada em larga escala pela indústria do Alumínio, somente no estado do Pará são gerados 5,4 milhões de toneladas anualmente, que impacta diretamente nos custos desta indústria em função de seu tratamento e estocagem. Os resultados guiam definições para as aplicações mais adequadas para a Lama vermelha, sendo destacado o emprego na fabricação de cerâmica vermelha e na produção do cimento.

Aug 17, 2017

By Alan B. Wagner

Data from seven instrumented pile load tests in Milwaukee, Wisconsin and two other instrumented load tests reported in the literature, one in Evanston, Illinois and one in Houston, Texas were reviewed. The data were for pipe piles having diameters from 9-5/8 inches to 18 inches, driven to depths between 36 and 96 feet. These data were used to develop a relationship between effective vertical stress and unit side friction and unit end bearing. These relationships were based on readily measured soil parameters, undrained shear strength, Cu, and Standard Penetration Test (SPT) values. This Beta (ß) and Nt approach and four other methods were then used to calculate the bearing capacity of the nine cases analyzed. The results from each of the methods are compared with the measured results.

Jan 1, 1991

By George H. Willis

In the second half of the 19th century, bimetallism progressively was replaced by gold standard. After World War I and the 1931-33 depression, gold was mainly reserved for official international transactions and internal use was restricted. Changes since 1971 have shrunk official international use of gold. International payments deficits and surpluses are now financed by Private and official credit, rarely by gold. This historical review covers evolution of: (1) internal and external private use, (2) internal official use, (3) external official use, (4) its role in the International Monetary Fund, and (5) use as unit of account. For this paper I have tried to take a longer perspective than is usually possible, and to look, even if very briefly, at the changing relationship of gold to the monetary system over the last 200 years or so. There are, I believe, some long-term trends, continuing down to the present day. These trends have seen gold replaced by some form of paper assets in one monetary function after another. These past trends may help us to understand where gold stands now, and possibly will throw some light on the future. Because it seems to me that gold in the past has performed various functions related closely or marginally to money, I have divided this rapid historical review into several sections: (1) the internal and external private use of gold, (2) the internal official use of gold, (3) the external official use of gold, (4) gold and the International Monetary Fund, and (5)gold as a unit of account.

Jan 1, 1980

By J. M. Stuve

Provisional values for the heat of formation of europium trichloride and europium sesquioxide were determined by solution calorimetry utilizing europium metal of more than 99-percent purity. The resulting values for the heats of formation of Eu203 (cubic) and EuCls (hexagonal) were -386,970 ±l,200 cal/mole and -218,740 ±650 cal/mole, respectively, measured at 298.15° K.

Jan 1, 1965

By Huimin Lu, Qiang Li, Jingbo Xu

"The smelting reduction of V-Ti bearing beach placer by combined rotary hearth furnace and direct current arc furnace was studied in laboratory. It takes the aid of back propagation (BP) neural network theory to build the nonlinear mapping relations between the crucial process variables such as content of carbon, temperature and time and the degree of reduction. Then by the integrating BP neural network and genetic algorithm (GA), the optimized process parameters for the high degree of reduction were searched. The comparisons between experiment results and neural network simulation results show that GA-based on BP method can predict the degree of reduction with higher prediction accuracy. Calculations show that the integrated energy consumption of new technology is 580kgce/tHM, less than the current existing blast furnace.IntroductionThese V-Ti bearing beach placers (VTBBP) are secondary Fe-rich minerals formed by rivers, ocean waves, ocean tides and ocean currents on beach zones, their useful minerals are V-Ti magnetite ores. On Asia Pacific zone, such as Japan, China, Philippines, Indonesia, Australia and New Zealand, the VTBBP have large reserves and wide distribution. But so far, the VTBBP are not still comprehensively utilized. Therefore, in this paper, a combined rotary hearth furnace technology and arc furnace smelting method is studied for comprehensive utilization of the VTBBP. The main objective of this paper is to find optimum operation conditions for the production ofV-bearing iron and titania-rich slag from the VTBBP by means of the laboratory testing.Recently, neural network (NN) expected to be able to provide an effective tool because of its advantages, which describe nonlinear mapping relations. With the characteristics of strong selflearning, self-organization, robust error toleration and accurate nonlinear relation approximation, artificial neural network can be applied to nonlinear process modeling based on sufficient training. Back-propagation (BP) training algorithm is probably the frequently used one in practical application. Genetic algorithm has parallel search strategy and global optimization characteristics, which makes the trained neural network being higher classification accuracy and faster convergence speed. So it is necessary to combine neural network and genetic algorithm. The nonlinear relationship between input and output presented by NN and the global optimal function of GA are abroad applied in the engineering and scientific research [1, 2]. So these methods supply an efficient path to solve the above problems. At present, it is common to study the optimization of process parameters by orthogonal experimental design, the method combining neural network and genetic algorithm is a novel and better method than orthogonal experimental design. Tills study organized the above advantages to optimize the process parameters for comprehensive utilization of the VTBBP."

Jan 1, 2012

Standards in the public reporting of resources and reserves in Australia have dramatically improved since the implementation of the Australasian Code for Reporting of Mineral Resources and Ore Reserves (The JORC Code) in 1989. Whilst the JORC Code states clearly that Mineral Resources and Ore Reserves are imprecise calculations and should be treated as estimates, there is strong evidence that many people regard them as fact, including some accountants, directors, auditors and investors. Mineral Resources and Ore Reserves are key inputs in the valuation of a mining company and the determination of financial performance. Geological knowledge is the foundation upon which Mineral Resources, Ore Reserves and investment decisions are made, however this information carries with it substantial uncertainty. Case studies and company reports have established that errors derived from inadequate geological inputs have led to reduced profitability in operating mines and in extreme cases the premature closure of mine operations. Whilst there are many causes of mine closure and reduced profitability, including commodity prices and exchange rates, the cumulative effect of all geological uncertainty contributes significantly to the erosion of the credibility of mining within the investment community. There are a number of methods used to characterise and model uncertainty in Mineral Resource and Ore Reserve estimation. Empirical mining indexes, sensitivity analyses, Monte Carlo simulations and Conditional simulations are used to identify and estimate geological uncertainty, notably the quantification of uncertainty in grade and tonnage estimates. These techniques have not generally been applied to estimating geological uncertainty associated with key Ore Reserve inputs such as appropriate mining technique, equipment selection, production rate, mining dilution, stability requirements, materials handling, metallurgical processing, product quality and waste storage. New software tools are needed to model the entire mining process with all its geological and other interdependencies, enabling all uncertainties to be separately identified and estimated. By its very nature, mining involves the assumption of significant technical, financial, political, environmental and social risk. Success comes by understanding and managing these risks and consequently the mining industry will never choose to reduce the level of geological uncertainty to nil. The ultimate aim of improved identification and estimation of geological uncertainty is to quantify inputs into the Ore Reserve process, allowing a company to assess the risks and manage these accordingly. This approach is relevant to feasibility studies for new projects as well as life-of-mine planning through to the weekly schedule at existing mines.

Jan 1, 2003

By Paponetti B. . A.

Gold is usually recovered by cyanidation, thiourea leaching and amalgamation, however the efficiency of these technologies, in the case of refractory ores, is low ever when fuie grinding is practised. For example, .if the gold particles are included in sulphide minerals, the leachant cannot reach them, so they are often lost in the tailings. Hence .it is first necessary to break the sulphide crystals by preliminary treatment such as roasting, nitric .acid oxidation, pressure leaching and bacterial oxidation and then apply a conventional extractive technique for satisfactory gold recovery. This paper describes the effect of biological pre-treatment with Thiobacillus ferrooxidans) on the? extraction ? and? recovery of gold by conventional cyanidate. leaching from; a refractory arsenopyrite ore from Golcuck (Turkey).

Jan 1, 1991

By M. Oliazadeh, A. Vazirizadeh

"The inclusion of small amounts of silicon, phosphorus and sulphur in iron ores or concentrates can have a profound effect on the steel making process and thus on the final iron and steel products. In nature however, it is inevitable that iron deposits contain unwanted elements. Each element has its own distinct effect on the final steel product. The effect of high silicon is the formation of gray iron. Phosphorus mainly increases hardness and strength, lowers solidus temperature and increases fluidity and cold shortness. Finally sulphur contamination causes cracks in the iron texture when smelting and forms white iron when casting. Overall, the acceptable level of phosphorus, sulphur and silica in the iron concentrate should be less than 0.04%, 0.15 % and 1.5 % respectively.Scarcity of high grade iron ores necessitates using lower grade ores with higher amounts of impurities. The purpose of iron concentrators is to increase iron grades to an appropriate level suitable for steel making as well as removing impurities. Although many impurities can be traced in the ore, the most predominant impurities are limited to one or two elements. In this paper the beneficiation methods for removing SiO2, P and S are presented, including flotation, and the parameters that need to be considered in the design of beneficiation plants are discussed. Finally industrial cases are discussed along with their metallurgical performance.INTRODUCTIONIn metal sector, value of iron ores and concentrates is determined by iron percentage as well ascontent of:• Useful elements (Mn, Ni, Cr, V, Ti): natural alloying elements in steel• Deleterious impurities (S, P, As, Zn, Pb, K, Na): impair metal properties or complicate operational process in blast furnace• Fluxing components (Si, Ca, Mg,, Al)Sulphur and copper result in red-short, phosphorus is the cause of cold brittleness and arsenic and copper decrease welding characteristics. Sulphur should not exceed 0.15 in commercial ore. Acceptable sulphur content in ores and concentrates for producing sinter and pellets is 0.6%max, as sintering and heat hardening of pellets remove sulphur 60-90%. Phosphorous content in ores, sinter and pellets is limited to 0.07%-0.15%. 0.00.1% As max, 0.1-0.2% Zn max and up to 0.2% Cu are allowed in iron-ore part of the blast furnace burden for the production of standard conversion pig iron. Slag-forming components are divided into basic oxides (Ca, Mg) and acidic (Si, Al). Higher ratios of basic to acidic oxides are preferred since this reduces raw fluxing material."

Jan 1, 2016

By Peter Zhang, Gary Deemer, Rod Lawrence, Scott Peterson, Scott Wade, Mike Mishra, Rick Smith, Robert Bottegal, Ed Zeglen

"Thinly-laminated silty shale that falls like ""stack rock"" is always difficult to support in underground coal mines. With thin laminations of 2.5 to 52 mm (0.1 to 2 in) thick and weak bonding between laminations, the roof is much weaker under horizontal stress than under vertical load. Buckling of thin laminations and cutters are common signs of initial failure for this type of roof. When a roof fall occurs, it is mostly above the primary bolted horizon with a fiat top and steep breaking angle above the pillar ribs. Because silty shale is brittle, roof falls mostly develop without significant roof sagging. With thick, laminated silty shale, it is difficult to build a strong solid beam with short primary bolts. Longer bolts, straps, and supplementary cable bolts are required. Since installation of longer primary bolts in low seam mining is operationally inefficient, supplementary bolting is important to maintain overall roof stability. The bolting plan should also be chosen based on the geologic hazard map, which indicates the distribution and thickness of laminated silty shale, as well as the transition areas.To effectively support the thinly-laminated silty shale roof, an area with the same type of roof in a low seam mine was monitored for approximately four months. The mine had experienced roof falls while using different bolting systems and mine orientations in past years. The roof support in the area was studied through geologic mapping, roof scoping, and testing of different bolting plans. This paper presents the roof failure characteristics of the thinly-laminated silty shale, the correlation between failure and geologic condition, an evaluation of different bolting plans, and the requirements for primary and supplementary bolting for the silty shale roof.INTRODUCTIONThinly-laminated silty shale that falls like ""stack rock"" is always difficult to support in underground coal mines (Peng, 2007). With thin laminations of 2.5 to 52 mm (0.1 to 2 in) thick and weak bonding between laminations, the roof is much weaker under horizontal stress than under vertical load. Buckling of thin laminations and cutters are common signs of initial failure for this type of roof. When a roof fall occurs, it is mostly above the primary bolted horizon with a fiat top and steep breaking angle above the pillar ribs. Because silty shale is brittle, roof falls mostly develop without significant roof sagging. In low seam mining, it is difficult to install longer primary bolts, so supplementary bolts have to be installed to maintain overall roof stability. To effectively support the thinly-laminated silty shale roof, an area with the same type of roof in a low seam mine in western Pennsylvania was studied for approximately four months."

Jan 1, 2010

By P. R. Jones

A computer program was written for design and cost of a shell and tube heat exchanger in which the total cost, which includes annual fixed charges and annual operating costs, was minimized. The program was written for the type of heat exchanger in which only the tube side pumping costs were significant and for triangular pitch, single or multiple pass, heating or cooling, and no change in phase. Tube diameter was not optimized since the tube dimensions do not affect the cost very much. However, the tube dimensions do affect the shell diameter, number of tubes, and length of tubes; and price optimum design was obtained for four standard tube diameters. Standard heat exchangers having at least the required area are also listed. The program was made adaptable to various fluids and to various tube dimensions by including many of the required data such as physical properties of the fluids, tube data, and standard shell data as input data.

Jan 1, 1969

By V. Aprahamian, T. Cheng, M. Tangen, R. Beauprie

The Royal Canadian Mint has implemented significant process additions since 2005. Installation of a whole new highly automated silver refining circuit has allowed recovery of physical silver from gold and silver dorés . To complement this change, a small Top Blown Rotary Converter has been in operation. On the gold refining side, a new hydrometallurgical process to recover precious metals from Miller Chlorination slag has been developed. Finally, new systems have been put in place to improve treatment of waste water, wet and dry fume and dust.

Jan 1, 2011

By Paul Hagan

A diverse range of rockbolt designs and resin anchors are available for use in underground mines. Despite their wide spread use, the factors that affect the performance a rockbolt is not fully understood. The laboratory-scale rockbolt test facility at the UNSW Mining Research Centre is being used to gain a better understanding of the behaviour of rockbolts leading to an improvement in ground support. A test program investigated the nature of load transfer between a fully encapsulated rockbolt and the surrounding rock mass. It was found that with all other factors held constant, there were differences in the behaviour of load transfer depending on the method of loading. The typical pull-out arrangement as used in most field test work resulted in a different load transfer function to that observed when the load on the rockbolt was induced through bed separation.

Jan 1, 2004

By R. P. Fischer

The Colorado Plateau region has been the principal domestic source of uranium, vanadium, and radium. The value of these commodities produced from the region through 1964 slightly exceeds $2 billion. Most of the deposits occur in streamlaid lenses of sandstone in the Chinle and Morrison Formations. The ore minerals below the zone of oxidation are low-valent oxides and silicates of uranium and vanadium; all of these, except the quite stable vanadium silicates, oxidize readily to a variety of high-valent uranium and vanadium minerals. The ore minerals partly replace fossil wood but mainly impregnate sandstone, typically forming tabular ore bodies that are nearly concordant to the bedding of the host rock. The deposits range in size from those containing only a few tons of ore to those containing more than 1 million tons. Stratigraphic, lithologic, and sedimentary structural factors obviously influenced the localization of these deposits, but igneous activity, hydrothermal mineralization, and tectonic structures show no similarly consistent influence on localization. The deposits are epigenetic, but the source of the ore metals, the nature of the ore-bearing solutions, and the time of ore emplacement are uncertain. A few uranium deposits in the region are dominantly discordant to bedding and occur in collapsed breccia pipes or along linear fractures. Their origins are also uncertain.

Jan 1, 1968

By W. Noel O?Brien

Introduction Since 1930 numerous improvements have been made in equipment designed for the mechanical removal of broken ore in underground mining operations. New applications of mechanical equipment, as? well as improvements and adaptations of well established systems, are being made continually. It is the purpose of this paper to discuss present-day equipment for the removal or transfer of broken ore by means of a powered hoist and scraper arrangement. The terms used throughout the paper are those commonly employed in the trade literature and by mining men. The terms slusher hoist, hoist, and scraper hoist are used inter-changeably to mean a machine, powered by compressed air or electricity, with drums for the winding of wire rope. The tail rope, also known as the pull-back rope or return rope, drags the empty scraper toward the tail-sheave, that is, back to the loading point. No attempt is made to cover the entire field of application of scraping methods. Rather it is the? writer's desire to emphasize the fundamental principles of scraping practice and design and to relate them to some modern applications. The available literature on scraping practice has been freely used. together with personal observation and information and advice of practising engineers and representatives of companies manufacturing slushing equipment.

Jan 1, 1951

By John C. Brulia

Blasting is both an art and a science with the primary objectives being safety and performance. Safety, the paramount objective, is a process that has limitless opportunities for improvement. Quality, a concept espoused by world-class corporations to competitively meet the needs of customers for goods and services, can be adapted to the explosives industry to improve blasting safety.

Jan 1, 1993

By David White

"When finished (projected completion in 2016) the Hong Kong-Zhuhai-Macau Bridge Project will comprise three cable-stayed span bridges and a 4.15 mile immersed tube tunnel - linking Hong Kong to Macau and the mainland Chinese city of Zhuhai. The design included two artificial Islands to serve as the transition structures for the tunnel to bridges, entailing a massive seaborne land reclamation project, and the use of thousands of sheet piles, and man-hours. The challenges of driving individual steel sheet in 100’ of water are well known, let alone in the open waters of the South China Sea.In 2010 a joint effort between American Piledriving Equipment (APE) and Allnamics Pile Testing Experts convinced the Chinese contractor First Harbor Marine Group China that a massive multi-vibro hammer can be used to drive 130’ long, 72’ diameter steel pipe piles weighing 662 US tons each into the sea bed of the South China Sea for the Hong Kong - Zhuhai - Macau bridge artificial islands. Combining APE’s hammer design, production and operation know-how with the pile driving simulation and installation know-how of Allnamics made it possible to show the feasibility of driving these gigantic piles into bottom of the sea to the required depth.INTRODUCTIONThe challenges of driving individual steel sheets in deep water are well known, let alone in the open waters of the South China Sea. Often the challenges of construction are overcome with engineering or equipment. The challenges of China’s Hong Kong-Zhuhai-Macau Bridge, on the drawing board since 1983, were to overcome both. The challenges of overcoming the skepticism of the Chinese Engineering community would be another story.The finished project will comprise three cablestayed span bridges and a 4.15 mile immersed tube tunnel linking Hong Kong on an eastern span to the China mainland cities of Zhuhai and Macau via two western spans."

Jan 1, 2017