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By A. J. Forney

Recent experiments used catalysts of plate assemblies in synthesizing high-Btu gas and gasoline indirectly from coal. A gas with a heating value of 925 to 943 Bt-: per cubic foot has been prod u la the hot-gas-recycle pilot plant from synthesis gas (3H2+100) with lathe turnings used as catalyst in the first reactor, and assemblies of parallel sprayed plats of nickel in the second. Solid plates made of Raney nickel, and steel and aluminum plates sprayed with Raney nickel or nickel oxide were tested. Those catalysts had very low resistance to gas flow; 90 percent lower than nickel granules used in previous experiments. In a single stage of synthesis thee nickel plates were only partially successful. Although the heating values of the product gas ranged from 856 to 941 Btu per cubic foot, the carbon monoxide content of he gas was above 0.1 percent. Both steel and wrought turnings were tested in single-stage synthesis, but the conversion of hydrogen and carbon monoxide was too low to attain the desired heating value of 900 Btu per cubic foot in the product gas. Assemblies of plates thermally sprayed with fusel iron were tried in an experiment to make gasoline. A gasoline yield of 52 percent (of the hydro¬carbons produced) was obtained using a 1H2-10O feed These sprayed assemblies were in service for 1,500 hours, the longest that this type of catalyst has been used. When a second reactor containing Raney nickel catalyst was added in series with the first reactor, complete utilization of the feed gas was obtained because in addition to the liquid product, a high-Btu gas with a heating value of 800 Btu per cubic foot was made.

Jan 1, 1965

By Arthur L. Crawford, R. E. Head, Fred E. Thackwell, A. Lee Christensen

"The data in this report are the result of a detailed, microscopic study of composite samples of mill products collected over a 14 day period. The samples were collected and assembled under the direction of W. R. Lindsay, superintendent of the Anyox plant, and are fairly representative of the heads, middlings, tailings, and products peculiar to the scheme of concentration practiced at Anyox in 1930.The work was done in the Cooperative Microscopic Laboratory at Salt Lake City, Utah. This laboratory was equipped by the mine and mill operators of the Salt Lake Valley and functioned under a cooperative agreement between the United States Bureau of Mines the University of Utah. This is the fourth of a series of papers 6/ dealing with a microscopic study of mill products."

Oct 1, 1935

By G. Knight

"Results of a program of dust research carried out at the Mines Branch Laboratory, Elliot Lake, indicate that dust-concentration estimates vary greatly, depending on the sampling instrument, the assessment technique and the properties of the dust cloud. The wide range of the ratio between the estimates by any pair of instruments shows that the correlation between the health hazard and dust-concentration estimates by most existing sampling instruments must be questionable. Important studies are being carried out to permit the definition of mine environments in more precise technical terms. The influence of size selection, the physical property measured, composition and sampling period on the assessment of the health hazard are discussed."

Jan 1, 1969

By A. Opara

The weathering of coal mine waste rock releases iron, calcium, sulfate and associated trace elements like selenium [Se], which are introduced to seepage waters. Nitrogen species, such as nitrate and ammonia, are also found in association with coal-mining drainages mainly due to leaching of residual blasting compounds. Elevated concentrations of Se are a ubiquitous occurrence in coal mining environments in British Columbia, with values ranging from below 50 to over 500 µg/L in site waters. Selenate is the most common form of selenium found in waste rock seepages, and is exceedingly mobile in aerobic freshwaters. A major concern with waterborne Se in British Columbia is the potential for its bioaccumulation in aquatic food chains. Treatment to remove Se from coal-mining wastewaters has proven to be challenging for conventional water treatment technologies. Compounding this challenge, many streams are characterized by high flows and low selenium concentrations. Conventional membrane and ion exchange treatments produce concentrated brine streams that are difficult to treat or require disposal. Conventional biotreatment systems use excess nutrients to provide the required electrons to compensate for inefficient and variable electron availability, as well as to adjust reactor chemistry. The Electro-Biochemical Reactor (EBR) technology provides electrons to the microbes directly at a low voltage potential (1-3 V), supplying a controllable and consistent supply of useable electrons to the system and microbes at low current. In this manner, the EBR technology overcomes the shortcomings found in conventional systems, as it reduces the required nutrient addition and provides a more controllable, efficient, economical, and robust biotreatment system than found in past generations of biological treatment systems. Additionally, the EBR process does not produce excess solids or biomass; therefore, solids management post-treatment is not required. Laboratory EBR bench-scale and on-site pilot-scale systems were used to treat five British Columbia coal mine wastewaters; influent Se concentrations ranged from 35 µg/L to 531 µg/L. Se treatment targets for the tested waters ranged from 5 to 10 µg/L. Mean Se concentrations in EBR effluents ranged from 0.5 µg/L to 1.4 µg/L, while reducing sulfate concentrations. The test data demonstrate that the EBR technology is an effective Se removal option for British Columbia?s coal-mining wastewaters.

Feb 23, 2014

By A. Opara

The weathering of coal mine waste rock releases iron, calcium, sulfate and associated trace elements like selenium [Se], which are introduced to seepage waters. Nitrogen species, such as nitrate and ammonia, are also found in association with coal-mining drainages mainly due to leaching of residual blasting compounds. Elevated concentrations of Se are a ubiquitous occurrence in coal mining environments in British Columbia, with values ranging from below 50 to over 500 µg/L in site waters. Selenate is the most common form of selenium found in waste rock seepages, and is exceedingly mobile in aerobic freshwaters. A major concern with waterborne Se in British Columbia is the potential for its bioaccumulation in aquatic food chains. Treatment to remove Se from coal-mining wastewaters has proven to be challenging for conventional water treatment technologies. Compounding this challenge, many streams are characterized by high flows and low selenium concentrations. Conventional membrane and ion exchange treatments produce concentrated brine streams that are difficult to treat or require disposal. Conventional biotreatment systems use excess nutrients to provide the required electrons to compensate for inefficient and variable electron availability, as well as to adjust reactor chemistry. The Electro-Biochemical Reactor (EBR) technology provides electrons to the microbes directly at a low voltage potential (1-3 V), supplying a controllable and consistent supply of useable electrons to the system and microbes at low current. In this manner, the EBR technology overcomes the shortcomings found in conventional systems, as it reduces the required nutrient addition and provides a more controllable, efficient, economical, and robust biotreatment system than found in past generations of biological treatment systems. Additionally, the EBR process does not produce excess solids or biomass; therefore, solids management post-treatment is not required. Laboratory EBR bench-scale and on-site pilot-scale systems were used to treat five British Columbia coal mine wastewaters; influent Se concentrations ranged from 35 µg/L to 531 µg/L. Se treatment targets for the tested waters ranged from 5 to 10 µg/L. Mean Se concentrations in EBR effluents ranged from 0.5 µg/L to 1.4 µg/L, while reducing sulfate concentrations. The test data demonstrate that the EBR technology is an effective Se removal option for British Columbia?s coal-mining wastewaters.

Feb 23, 2014

By P. L. Crouse, S. J. Lubbe, M. J. Kabangu

A selective extraction and separation of zirconium by solvent extraction with 1-octanol is proposed. The process is based on the dissolution of the metal basic carbonates in hydrochloric acid in the presence of potassium fluoride, using 1-octanol as extractant. The effect of several process parameters, including hydrochloric acid and potassium fluoride concentrations, reaction time, and phase ratio between the aqueous and the organic phase was investigated. Zirconium is enriched in the organic phase. The best extraction and separation results were obtained with the basic carbonate dissolved in 10% hydrochloric acid and 1.5 M potassium fluoride. The optimum reaction time was 15 min with an organic to aqueous phase ratio of 2:1. Based on the selectivity of zirconium over hafnium in the organic phase, a McCabe-Thiele diagram was constructed. A near complete stripping of zirconium from the organic phase was achieved using a 3 M sulphuric acid solution. Additional studies are required in order to determine the reaction mechanism and the chemical speciation of the current investigation.

Effect of Iron on ash fusion temperature and waterwall deposits FeS, H2S on tube material corrosion and erosion [ ]

Jan 1, 2005

By M. C. van Eeden, R. Vermeulen, K. B. Le Bron

This paper presents the lessons learnt during the transition from an open pit method to a sub-level open stoping method at the Koidu Limited kimberlite pipe. These learnings may assist other mines with planning, both from a practical implementation perspective (layout, charging up challenges), and a method for estimating potential dilution and stability challenges associated with the interaction between the surface and underground excavations. Predictive geotechnical stability modelling was successfully applied to highlight potential failure zones, which allowed modification and enhancement of the mining layouts and quantification of the potential dilution of the kimberlite from indicative instabilities.

Sep 1, 2025

By J. G. Reid

Nickel is second only to aluminium, of all non-ferrous metals, in energy required to convert the ore to metal. Nickel Laterite ores, which constitute the feed source for approximately 40% of world nickel production, are at a particular disadvantage because of the absence of sulphur, as an energy source, in the ore and because lateritic ores general 1 y are not amenable to beneficiation. The dramatic escalation of oil prices which commenced in 1973 and continued for a decade meant that Nickel Laterite refineries using oil as a primary energy source were placed at a distinct disadvantage relative to refineries utilizing nickel sulphide concentrate feeds. By the late 1970's the continuing large difference in oil and coal prices caused Greenvale to consider converting certain high oil consuming areas of the refinery to coal. These investigations confirmed that the areas of ore drying and power generation, which together consumed 50% of total Plant oil requirements, could be economically converted from oil to coal firing. Construction of the coal conversion facilities commenced in October 1980 and the first ore drying air heater came on line in August 1981. Construction was completed with the commissioning of the coal fired boiler in June 1982. This paper outlines the additions required to receive and utilize coal in ore drying and power generation and how the changeover was completed with minimal process disruption.

Jan 1, 1988

By D. B. Dreisinger, D. G. Dixon, G. Nazari

"The kinetics of chalcopyrite leaching in acidic ferric/ferrous sulfate media under atmospheric conditions in the presence of pyrite has been investigated. It has been found that pyrite samples from different sources affect the rate of chalcopyrite leaching differently. A strong correlation between the amount of silver associated with the pyrite and its effectiveness has been noted. In this study, improvement of the catalytic properties of pyrite such that all pyrite samples accelerate the rate of copper extraction regardless of their sources is demonstrated, and a detailed discussion of the mechanisms involved in the process of chalcopyrite leaching in the presence of silverenhanced pyrite is presented. INTRODUCTIONIt is well known that chalcopyrite resists leaching in sulfate media. It has been proved that pyrite facilitates the leaching of chalcopyrite (Berry et al., 1978; Dixon et al., 2008; Mehta and Murr, 1983; Muñoz et al., 2008; Nowak et al., 1984, Tshilombo, 2004). Considering the catalytic effects of pyrite on accelerating the kinetics of chalcopyrite leaching, Dixon and Tshilombo (2005) have developed a new process, known as Galvanox™, which has several advantages over other hydrometallurgical processes. Galvanox™ runs under atmospheric conditions, so it requires only low-cost leaching tanks. The sulfur yield at this temperature is high (>95%) which leads to low oxygen consumption and low sulfuric acid generation. The operating temperature is below the melting point of sulfur which eliminates the use of surfactants. This process also does not require fine grinding. Reaction 1 shows the overall leaching reaction in the Galvanox™ process.CuFeS2 + O2 + 2 H2SO4 = CuSO4 + FeSO4 + 2 S0 + 2 H2O (1)Complete copper recovery from the Galvanox™ process can be achieved at a considerably higher rate than other atmospheric ferric sulfate leaching processes (Dixon et al., 2008). Recycling pyrite and recovering copper from tailings with the Galvanox™ process have also been evaluated in continuous pilot leaching campaigns (Dixon et al., 2007)."

Jan 1, 2012

By H. Hitchen

THE object of this paper is to present the various facts that l1ave been revealed during lengthy investigations into the performance of all types of ropes on different hoisting installations. It then goes on to suggest means by which most of these findings could be usefully employed to obtain more economical rope lives with increased safety. SHAFT HOISTING ROPES Four basic designs of ropes are now employed for hoisting duties: (1) Six-strand, round strand ropes with fibre cores. (2) Six-strand, triangular strand ropes with fibre cores. (3) Non-rotating, multi-strand ropes. 0) Locked coil ropes. Round Strand Ropes (Figure 1) Very solid and reliable ropes can be obtained with this simple geo-metric design of strand. 1'1?iangula1? Strand Ropes (Figure 2) Owing to the fact that the wires in the strands are bent over a triangle, they do not seat quite so solidly as when they are bent over a circular core wire, as is the case with

Jan 1, 1963

By Lianjun Liu, Ying Li, Qianyi Zhang

"Photocatalytic reduction of CO2 by H2O for production of Cl fuels (CO and CH4) was studied using copper and iodine co-modified TiO2 (Cu-IffiO2) nanocomposites, with copper deposited on the surface and iodine doped in the lattice. The nanocomposites were prepared via a combined hydrothermal and wet impregnation process. All I-doped samples demonstrated visible light activity. Under UV-vis irradiation, co-modification of Cu and I significantly increased TiO2 photoactivity compared with bare TiO2 or those modified with only one species.IntroductionThe photoreduction of CO2 into fuels on photocatalysts such as TiO2 has been regarded as an important approach to solve both energy shortage and globe warming problems [1]. However, the wide band gap and fast recombination ofphotoinduced hole (h+) and electrons (e"") limited the application of TiO2 in CO2 photoreduction reaction. Extensive research has been conducted to improve the photocatalytic ability ofTiO2 by depositing or doping foreign ions that can enhance charge transfer and/or creates intra-band-gap states to induce visible light absorption at the subband- gap energy. Compared with mono-doping, co-doping of metal/nonmetal species has been reported to have higher photocatalytic activity for TiO2 [1-3]. Our previous studies showed that Cu deposited on TiO2 [4] or iodine doped in TiO2 [5] significantly enhanced the catalytic efficiency for CO2 photoreduction and increased the response to visible light. We hypothesize that there could be a synergetic effect if TiO2 is co-modified by both Cu and I species resulting in further improvement in CO2 reduction efficiency. In this work, we synthesized and characterized Cu-IffiO2 samples and investigated their activity toward CO2 reduction under visible and UV-vis illumination, respectively.Experimental MethodsMaterialsTitanium tetra-isopropoxide (TTIP, 98%) and isopropanol (C3HsO, 99.8%) were purchased from Acros Organic. Iodic acid (HIO3,99.8%) and Copper Chloride (CuCh, 99.9%) were purchased from Alfa Aesar. All other chemicals were analytical grade and used without further treatment."

Jan 1, 2012

By David Schlain

The galvanic corrosion properties of titanium and zirconium were investigated by the Bureau of Mines. The dissimilar metals involved in these experiments included magnesium, magnesium alloy FS1, aluminum alloys, zinc, steel, tin, lead, copper, Monel, nickel, and several stainless steels. Couples were immersed in synthetic ocean water, tap water, 5-percent ammonium sulfate solution, 5-1/2-percent sodium chloride solution, sodium hydroxide solution, 0.1 N hydrochloric acid, and various concentrations of sulfuric acid.

Jan 1, 1956

By Timothy L. Roberts

For many years practicing geotechnical and structural engineers in Texas and Louisiana were reluctant to include augered cast-in-place (ACIP) piles as a viable deep foundation alternate. Three primary concerns were the lack of a final driving resistance to confirm adequate capacity, the inability to inspect ACIP piles prior to installation, and the fact that pile integrity is highly dependent on the skill of the ACIP pile contractor's field personnel. The Deep Foundations Institute (DFI) Committee on Augered Cast-In-Place Piles has responded to these quality control concerns by establishing standards of practice for ACIP pile installation and ACIP pile inspection. Regional areas of the country have different subsurface soil and rock conditions and many times this will influence local installation and inspection requirements. The best way structural and geotechnical engineers can address quality control concerns is to be familiar with the DFI standards of practice, to know the special requirements for a particular project site, and to incorporate them into a well-written ACIP pile specification. The purposes of this paper are to: 1) review the main fundamentals of a successful quality control program, 2) describe how these fundamentals can be applied to the installation of ACIP piles, and 3) add personal experiences from ACIP pile projects in Texas and Louisiana. Nondestructive test methods are frequently used as a quality control tool to evaluate questionable piles. An additional brief discussion of two nondestructive test methods is presented to complete the paper.

Jan 1, 1998

By Li. Jiarong, Zuojian Liang, Qingyan Xu, Baicheng Liu, Shizhong Liu, Hailong Yuan

Single crystal solidification of turbine blades is a key technology for the production of reliable and high efficiency gas turbines. The solidification process of single crystal investment castings causes a number of problems that have to be solved such as the increase of casting defects and complexity of production process. Computer modeling and simulation is helpful to predict the defects and improve the process design. In the paper, a mathematical model for three dimensional simulation of solidification and single crystal growth of investment castings was developed based on CA, mechanism of crystal growth and basic transfer equations such as heat, mass transfer equations. Many factors including constitutional undercooling, curvature undercooling and anisotropy, which had vital influences on microstructure evolution, were considered in the model. Temperature, crystal growth interface and structure defects of investment castings of single crystal superalloy were investigated at withdrawal rates of 4.5mm/min and 7mm/min. Simulated results showed that microstructure evolution and structure defects were predicted reasonably and calculated results were coincident with experimental ones. The study indicated that three dimensional solidification simulation technique is a powerful tool for understanding the fundamental of solidification and the formation of structure defects in single crystal investment castings and finally for optimizing process design.

Jan 1, 2004

By A. E. Isaacson

Bureau of Mines researchers developed and tested equipment to measure corrosion rates on a commercial-scale mill as an aid in predicting the effect of corrosion on minerals and how this effect relates to downstream processing. Bench-scale experiments were designed for duplicating ore grinding conditions closely enough that realistic rate determinations can be made in laboratory tests. Rates measured in a laboratory system compared favorably with those measured in the field. Cast steel was found to have corrosion rates in a copper mill and laboratory test cell of 22 and 21 mpy, respectively. Corrosion was found to account for less than 5% of the total grinding media wear in the operations studied.

Jan 1, 1987

By C V. Deutsch

"Geometallurgical variables often cause problems to conventional geostatistical workflows. There are many variables; some are compositional and some are non-additive. They often show: complex multivariate relationships undersampling relative to conventional grade variables unequal sampling; that is, all variables are not available at all data locations.A variety of approaches have been developed over the years, but geostatisticians remain mostly focused on modelling rock types and a few grade variables with an abundance of data. The problems are reviewed and a chained workflow is presented where appropriate techniques are employed in sequence to permit reliable spatial prediction of geometallurgical variables. The spatial models may be used to assess the value of additional data, for prediction of process performance, for improved mine planning and other optimisation tasks. The chained workflow will include data transformations such as ratios and normal scores that make the variables amenable to geostatistical modelling. Data imputation techniques to account for missing values are considered with special consideration to spatial correlation with the available data. Decorrelation techniques such as the principal components, min/max autocorrelation factors and projection pursuit multivariate transformation are employed to manage massively multivariate modelling. Full distribution modelling must be considered to avoid biases in the prediction of non-additive variables. The post-processing of geometallurgical models must be streamlined for robustness and efficiency. The precise workflow varies according to the specific purpose of the study. Guidelines and thoughts on best practice are presented.CITATION:Deutsch, C V, 2013. Geostatistical modelling of geometallurgical variables - problems and solutions, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 7-16 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By Yoginder P. Chugh

The term "fatigue" in mechanics, is used to refer to reduction in the strength of a material subjected to fluctuating or alternating stresses. Stresses that vary with time are called fluctuating stresses and if during fluctuation the stresses also change sign, they are called alternating stresses. In the field of rock mechanics, the term fatigue (static fatigue) has often been misused to refer to failure of geologic materials in time domain under constant load. To avoid confusion, we use the ten cyclic fatigue here to refer to failure of rock under alternating or fluctuating stresses. Fatigue in metals has been studied for over 100 years. Fatigue properties of geologic materials have, however, received little attention in the past. This is probably because until recently very little was known in regard to the behavior of geologic materials even under static loading. Secondly, suitable equipment for conducting cyclic fatigue experiments was not available until quite recently. A few cyclic fatigue studies have been undertaken on geologic materials to relate it to percussive or rotary drilling mechanisms (e. g. Grover et a11*; Burdine2). The results of these studies were inconclusive due to limited effort. Cyclic fatigue in concrete has been studied more extensively than geologic materials (e.g. Nordby3, Gray et al 4 and Bennett et a15) and mechanisms of fatigue in concrete are better understood than in geologic materials.

Jan 1, 1975

By M. Matthias

A study, part of a doctoral dissertation (Matthias, 1991), was conducted during 1987 and 1988 to establish the means by which professionals assess and maintain their competence during the various stages of their careers. The study elicited responses from fifty-nine subjects representing engineering, pharmacy and medicine (twenty subjects from engineering, nineteen from pharmacy and twenty from medicine) on their perception and assessment of continuing competence. The findings revealed a wide variation of how professionals perceived their continuing competence and the means they adopted to keep current. The implications of the study are significant for adult education practice and theory building. The author strongly believes that now, more than ever, engineers must take ownership of their careers and professional development activities. While management and supervision have a key role to play, it is the engineer, who is ultimately responsible for the scope, planning and implementation of her/ his professional development needs. An example from one high technology company will illustrate these points.

Jan 1, 1999

By C. S. Allbright

This report gives the results of analyzing three groups of crude shale oils by the Bureau of Mines procedure:4/ (1) Oils produced by standard Fischer assay determinations on oil shales from Brazil (Paraiba Valley) and the United States (Colorado); (2) oils produced from Brazilian shale by different retorting methods; and (3) oils from high-temperature retorting of Colorado oil shale in the Entrained Solids retort. It is the second in a series presenting data obtained by analyzing crude shale oils from various sources. The series furnishes information on the general characteristics and compositions of a wide variety of shale oils. Use of a standard analytical method on all samples facilitates comparison of different oils. The 18 oil samples analyzed in this project comprised 3 from assays of Brazilian and Colorado oil shales in the Fischer retort, 9 obtained by processing Brazilian shale in various other units, and 6 from entrained solids retorting of Colorado shale at 1,000° to 1,500° F. The crude oils from Brazilian shale contained about half as much nitrogen as the Colorado oils. Properties of the Fischer assay oils from Colorado shales agreed with some data that relate grade of the oil shale with properties of the crude oil from the Fischer assay. Comparison of results from Fischer assays of oils from the foreign and domestic shales shows that the oil from Brazilian shale contains more low-boiling material and less residuum than either of the two from Colorado shale. This fact is reflected in lower specific gravity, viscosity, and carbon-residue values for the Brazilian oil. Retorting Brazilian shale in the Entrained Solids unit at 1,120° F. produced an oil whose boiling range was generally lower than the boiling ranges of oils obtained by processing in three other retorts at conventional temperatures. The quality of crude oils from high-temperature retorting of Colorado shale in the Entrained Solids process varies with retorting temperature. As the temperature is raised within the range 1,000° to 1,500° F., the amount of the naphtha fraction in the crude oil increases to about 35 percent and the aromaticity to 98 percent.

Jan 1, 1956