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By A. P. I. Popoola, T. J. Olaniyi, A. A. Adeleke

"A laboratory froth flotation experiment was conducted on a low-grade carbonatite copper ore sample obtained from Phalaborwa in the Limpopo province of South Africa. The sample was a homogenous hydrocyclone overflow which serves as the feed to the flotation cells at Palabora Mining Company (PMC). The sample has an average copper assay of 0.59% with predominant copper-bearing minerals being chalcopyrite, bornite and cubanite. The carbonatite nature of the ore comes from the high content of calcium (28.85%) and magnesium (6.84%) minerals. Collectors used were sodium diethyl dithiocarbamate and potassium ethyl xanthate alongside Senfroth 38 supplied by Senmin. The results showed that at 200 g/t mixture of collectors (50:50), an optimum grade of 8.03% Cu in the rougher flotation concentrate was achieved at 74% recovery, while during the second flotation, 24.65% Cu was obtained at 74.4% recovery using a Senfroth 38 dosage of 6 L/t with 100 g/t mixed (50:50) collectors. The particle size and pH value of the pulp played a significant role in that the mixed collectors performed efficiently at pH above 8.3 and at room temperature while particle sizes greater than 53 µm were well concentrated when compared with those of less than 53 µm. INTRODUCTION The need for copper ore concentration research is on the rise as a result of the depletion of deposits and the advent of low-grade copper ores. Although most copper ore deposits have other valuable minerals that support their economic extraction, the increase in technological innovations as regards copper usage and applications has increased the demand for copper. Several factors influence concentration results in a froth flotation column, of which the reagent used is most influential."

Jan 1, 2015

By Jan Smit

Sulphidic copper concentrates are generally processed by pyrometallurgical means; while oxidative pressure leach processing of such materials has been shown to be technically feasible, there has traditionally been little incentive to choose this route in favour of a smelting option. However, for concentrates with elevated arsenic levels, oxidative pressure leaching offers distinct advantages, as smelter air emission standards and restrictions on concentrate importation have tightened. The current state of pressure leach technology allows for high copper extractions from arsenical copper concentrates, while producing an environmentally stable process residue, without atmospheric emissions of sulphur dioxide or arsenic. In its studies on pressure leaching of copper concentrates, Sherritt has shown that arsenical feed materials can be converted into environmentally stable residues, with excellent copper extractions. The results of recent batch and pilot plant test work are discussed, including the deportments of copper, arsenic and precious metals.

By A. Zorkovská, S. Castro, P. Baláž, Z. Bujnáková

Enargite (Cu3AsS4) belongs among refractory copper minerals with very low hydrometallurgical extractability of copper. An application of enargite leaching in acid solutions leads to simultaneous dissolution of copper and arsenic and the final leach solutions have to be treated for the separation of both elements. However, the alkaline leaching of enargite is selective. Arsenic passes into leach while produced copper sulphide represents the raw material suitable for pyrometallurgy. The hydrometallurgical processing of mineral can be influenced positively by mechanochemical route. We have shown that more than 80 % of arsenic can be extracted from enargite concentrate by atmospheric alkaline leaching at 95 °C when mechanical activation in an attritor is applied. The produced Cu2S can be further treated with elemental iron where mechanochemical intervention is applied in the second stage of enargite processing. The final product forms Cu/FeS nanocomposite from which copper nanoparticles can be easily separated. The illustrated concept of copper obtaining from copper sulphide is an example of so-called “dry” processing, as reactions in gas and liquid phases are excluded. This concept of environmentally friendly metallurgical processing can be classified as an impetus for novel technology to produce copper from enargite concentrates.

Jan 1, 2012

By C. C. Hwang

The Bureau of Mines made time-dependent calculations to determine the size of a stationary source fire within a ventilated duct (or passage-way) necessary to ignite a combustible duct liner. The objective of this work was to gain more understanding of what occurs in duct fires and to determine critical conditions for ignition and propagation of mine fires. Heat transfer to the combustible surface includes both convective and radiated components, while the heat is conducted into the combustible and reradiated to the surroundings. The combustible is assumed to ignite when the net heat transfer to its surface is sufficient to raise the surface temperature to some minimum temperature, defined as the ignition temperature. A nondimensional parameter, which characterizes the source-fire intensity in the presence of ventilation flow, emerges as a parameter for a criterion of the critical conditions. The results of these calculations indicated that the minimum fire size necessary for ignition increases with the ventilation rate and duct cross section. These results are compared with experimental results obtained from fires in a 0.8-by 0.8-by Il-m-long duct and a full-scale gallery (2.4-by 2.4-by 65-m). Agreement between the theory and the experiment is good.

Jan 1, 1988

By Juhyung Lee

Recently, large diameter drilled shafts are often used for foundations of large-scale marine bridges with high capacity and required to resist lateral loads. Steel casings are essential in supporting the hole-diving concrete installation of the drill shafts constructed in the sea. The casings, however, are usually not considered as the structural elements and their load bearing capacity is often overlooked in the design of drilled shafts. As the diameter of drilled shafts becomes larger, there are higher demands for more efficient and economical design of large-scaled drill shafts in the sea. Steel-concrete composite columns are popular for the superstructure of bridges, and the outer steel attached to the shaft increases the shaft resistance through confining the concrete. In this study, the lateral resistance of steel-concrete composite drilled shafts was evaluated quantitatively based on the numerical analysis. When steel casings are used as structural elements such as the composite columns. Ultimate lateral bearing capacity of composite drilled shafts with various diameters was numerically calculated through the 3D finite element analysis. For that, elasto-plastic model with the perfect plasticity is involved to capture the ultimate load. A commercial FEA program, MIDAS-GTS, is used in this study. Real field conditions of the west coast, Korea were examined to set up the ground conditions and pile lengths required for this parametric studies. Detailed characteristics of the stress and displacement distributions are evaluated for the better understanding on the mechanisms of the composite shaft behavior.

Jan 1, 2008

By Jr. Sillers

This is the third report of investigations dealing with the application of electrolytic manganese to steel-foundry practice and the seventh in a series of reports dealing with tests to establish the technological acceptability of electrolytic manganese in the iron and steel industries. The work was carried out by Metallurgical Division of the Bureau of Mines as part of an extensive program for the development and utilization of domestic ores. The electrolytic manganese used in the tests was produced by the Bureau at its Boulder, City, Nev., pilot plant by the process developed by the Bureau of Mines.

Jan 1, 1949

Development of the Boleo Process Flow Sheet and the Direct Solvent Extraction (DSX) Circuit for Cobalt and Zinc Recovery The metallurgical process designed to treat the El Boleo Cu-Co-Zn-Mn ore involves a sulphuric acid leach in seawater under oxidative and then reductive conditions to maximise metal extraction. Copper and cobalt are recovered as cathodes by electrowinning, zinc and manganese as zinc sulphate monohydrate and high quality manganese carbonate, respectively, by precipitation after a number of separation and purification stages. One of the key purification stages of the Boleo metallurgical process is the CSIRO DSX circuit. The DSX circuit was developed using the synergistic solvent extraction (SSX) technology. Initially, a synthetic solution was studied, and by adding 0.4 M LIX63 to 0.5 M Versatic 10 in Shellsol D70, large synergistic shifts were obtained for cobalt (?pH50 4.24) and zinc (?pH50 1.62). After a single contact, the separation factor of metals over manganese reached over 6,000 for cobalt and over 380 for zinc, indicating excellent separation of cobalt and good separation of zinc from manganese, magnesium and calcium. The SSX system was further optimised with the modified synthetic pilot plant solution. The extraction of cobalt and Zn after a single contact was 93 per cent and 70 per cent, respectively, while the Mn concentration in the loaded organic solution was only 0.28 g/L. A proof of principle pilot plant operation was conducted in 2004 and a demonstration pilot plant for final engineering design in 2006 with outstanding performance of the DSX circuit. For the demonstration pilot plant, the overall recovery of cobalt and zinc exceeded 99 per cent with a raffinate containing only 4 mg/L Zn and 1 mg/L Co. The DSX organic system showed no sign of degradation during the pilot plant operation, indicating good chemical stability under the anticipated commercial operating conditions. The DSX circuit will be implemented in the future Boleo processing plant.

Sep 13, 2010

By Marcus A. Wiley, Gregory Abramov

Borehole mining (BHM) is a remotely operated method of extracting rock material through boreholes by high-pressure water jets. Figure 1 illustrates a BHM tool and fluids circulation. The tool consists of at least two pipes, one for pumping down high-pressure water, the second for delivering slurry to the surface. This article reviews the BHM process. It discusses current and new applications for borehole mining and help the readers determine if BHM is applicable in their situations. Previous articles in ME about BHM explained either a particular project (ME, April 2001, pp. 33-36) or a newest patent in this area (ME, March 1991, pp. 313-318). However, neither one provided an overview on the modern BHM technology.

Jan 1, 2004

By John Nadolski

Intensive hydrologic monitoring of the Powder river basin has been on-going since the early 1970's. Data were used in environ- mental assessments and for determination of hydrologic consequences associated with coal mining activities. For most coal mine operators, data collection has continued in this baseline mode with little or no statistical analysis of the data and with no statistical procedure established to detect changes in groundwater quality. For the past four years Powder River Coal Company has studied several statistical techniques to analyze groundwater quality. Three objectives were pursued: 1) to determine the baseline water quality for key aquifers; 2) to determine which wells could be deleted from the monitoring program without reducing monitoring effectiveness; and 3) to define a statistical test to determine water quality changes. Knowledge of the regional geo-hydrologic system was combined with an analysis of the water quality monitoring in order to identify homogeneous aquifer zones. All wells within an aquifer zone were treated as one population, and a t-test was used to determine the minimum number of samples needed to define the water quality for each aquifer zone. Results indicate that the data for each aquifer zone were nor- mally distributed and that groundwater quality could be defined using a fairly small number of samples. Because of the minimum sample size test, groundwater quality sampling was reduced by between 75 and 85 percent.

Jan 1, 1989

By H. Vermette, J. Demers, R. Leclerc, P. Bergeron, P. Hudon, A. Lessard

The Arvida Smelter marked its 80th anniversary in 2006. Arvida currently operates 6 potrooms equipped with prebaked side-feeding pots producing 160 000t of aluminum per year, requiring the supply of 300 000t of alumina per year. In the past, to ensure reliable alumina supplies to the pots, especially in winter, a safety stock of alumina was kept inside the plant. The improved reliability of shipping on the Saguenay River has cut the need for such a stock. However, the stoppage of 8 Soderbergtechnology potrooms, starting in the 1980s up to 2003, generated alumina from the cleaning of pot pits, totaling 18000t and leading to the building-up of a significant alumina stock again. Concerns over working conditions, effect on potroom operations, and dust emissions prevented Arvida from tackling effectively this impressive alumina stock. Yet the increasing cost of alumina has created a strong motivation to use the stored alumina. In 2004 Arvida launched a project to recycle the stored alumina. This 4-year project aimed at clearing the alumina stock without affecting the operation of the smelter. It involved changing work organization, improving equipment and controlling the effect of the recycled alumina on the smelting process and working conditions.

Jan 1, 2006

By Alistair James, Mo Shahsavari, Leon Botham

Recent catastrophic failures of heap leach facilities have revealed fundamental weaknesses in prevailing design paradigms, modeling toolkits, and oversight practices that continue to treat heaps as static, free-draining earthworks despite compelling evidence to the contrary. The core proposition advanced in this paper is that heap materials are intrinsically dynamic: their structure, permeability, and shear strength evolve under the sustained influence of irrigation, climate, and geochemical reactions, and these timedependent changes can precipitate abrupt transitions from granular stability to flow-like failure. Drawing on investigations of recent failures at Çöpler Mine in Turkey and Eagle Gold Mine in the Yukon, alongside earlier incidents in Peru, Arizona, Nevada, and Chile, the analysis identifies a recurrent sequence driving catastrophic behavior: progressive weathering elevates fines and suppresses permeability; drainage systems designed for initial conditions become overwhelmed; pore pressures rise heterogeneously within the heap; and static liquefaction initiates rapid mass movement with long runout. Current guidance, including ICOLD and ANCOLD frameworks and ASTM testing standards, provides a necessary foundation but is tailored to tailings and conventional soil mechanics. These documents offer insufficient direction for characterizing timedependent material degradation, quantifying rheology of weathered ore, and modeling post-failure mobility. To address this deficit, the paper proposes an integrated framework combining enhanced characterization, multi-physics numerical modeling that couples hydro-geochemical processes with large-deformation mechanics, and comprehensive monitoring with Trigger Action Response Plans. The conclusion argues for a heap-specific standard that embeds these elements from concept to closure, aiming to materially improve safety performance and reduce the likelihood and consequences of future failures.

Feb 22, 2026

By Paul J. Axtell

Two new railroad bridges in Kansas City, Missouri are founded on drilled shafts embedded into the soil and underlying shale. The uncertainty arising from the non-homogeneous, anisotropic nature of most shales, and the variability of shales across the U.S., makes it a difficult material to assign appropriate design properties. As was the case on this project, the uncertainty of foundation performance in shale can lead to overly conservative designs, particularly with drilled shaft foundations. An extensive Statnamic axial testing program was performed to verify that the load-settlement behavior of the drilled shafts would be acceptable for the intended railroad traffic. Axial Statnamic testing was applied in three increasing cycles of 927 kips, 1007 kips, and 3177 kips, respectively. The maximum movements recorded at the shaft head during each of the loadings were 0.052 inches, 0.062 inches, and 0.257 inches, respectively. The loads applied in each of the respective Statnamic tests were not sufficient to reach the capacity of the shaft; so direct comparison of measured and calculated capacities is not possible. However, evaluation of the estimated design capacity can be accomplished based on results from the Statnamic testing program by utilizing normalized load transfer relations presented by O?Neill and Reese (1999). Such comparisons necessarily require extrapolation of the data measured in the Statnamic tests following typical load-displacement response. Results indicate the Kulhawy and Phoon (1993) method for estimating side resistance in Pleasanton shale rock sockets, assuming a smooth socket, appears to agree well with observed behavior during Statnamic testing. Accordingly, the O?Neill and Reese (1999) method for estimating the toe resistance in intermediate geomaterials, assuming cohesive rock with Rock Quality Designation (RQD) between 70 and 100, appears to agree well with observed behavior during Statnamic testing. Finally, based on Statnamic testing at varying load magnitudes and normalized curves developed by O?Neill and Reese (1999), the contribution of side resistance to the capacity of a deep foundation can be determined assuming no load is transferred to the base of the foundation during lower magnitude testing. Furthermore, higher magnitude testing can provide a means to evaluate the accuracy of design end bearing calculations.

Jan 1, 2006

By K. V. Raj, C. A. Berry, A. T. Weakley, A. L. Miller, P. R. Griffiths, D. A. Parks

Diesel particulate matter (DPM) has been classified as a carcinogen to humans by the International Agency for Research on Cancer. As a result of its potential carcinogenic nature, DPM exposure is regulated by the Mine Safety and Health Administration. Currently, diesel emissions in the workplace are monitored by collecting the aerosol onto filters, which are then sent to a laboratory for thermal-optical analysis using the NIOSH method 5040. This process can take days or even weeks, and workers can potentially be exposed to excessive levels of DPM before the problem is identified. Moreover, the delay involved in getting the loaded filter to the lab inevitably means the loss of some of the more volatile organic carbon. To remedy this delay, researchers from the National Institute for Occupational Safety and Health are seeking to develop a field-portable, real-time method for measuring elemental and organic carbons in DPM aerosols. In the current study, the use of mid-infrared spectrometry was investigated. It is believed that mid-infrared spectroscopy is more suitable for use in a real-time field-portable device than thermo-optical analysis methods. This article presents a method for measuring organic carbon (OC) and elemental carbon (EC) in DPM for a broad range of OC/EC ratios. The method has been successfully applied to laboratory-generated and mine samples.

By George E. Aikens

Prolonged subzero climatic conditions impose some unique engineering problems for the developer and operator of open-pit mines in the Far North. The remoteness of the job site and the extremely cold, long, dark winters severely tax both man and machine in the quest for the Arctic's rich mineral wealth. Undoubtedly the singular most troublesome problem for the engineer is Permafrost which underlies about 201o of the land area of the world and about 85% of the state of Alaska. Permafrost has its impact on building construction and mine excavation, while posing a more pervasive threat to the-delicate ecologic balance within the Arctic wilderness. Yet the difficulties associated with mining up North may not be as overwhelming as has been previously supposed. For example, the lowest temperature recorded at Point Barrow is -560F, whereas Montana has recorded -69.7° F.. There are no specially designed machines for mining and construction in the Arctic, and efficient equipment utilization is maintained through proper operation and servicing techniques. However, neither equipment or people can be assumed to function normally at -40°F. Special techniques in drilling, blasting, and ripping are being used to yield economically competitive ores. Overall, a fundamental understanding of the nature of Permafrost will allow the engineer to deal expeditiously with an Arctic mining venture and at the same time to deal fairly with Arctic environment.

Jan 1, 1972

By Walter I. Enderlin

To economically extract ore from great depths in the earth while sustaining an acceptable working environment will require the development of new technology and equipment, involving large capital expenditures. Moreover, careful analysis and advance planning will be required. But, the literature is lacking in data pertaining; to the thermal properties of various host rocks and to quantities of heat generated by various underground heat sources. This types, of data is required to forecast nine heat loads during advanced planning and design. This thesis sets forth a practical method for evaluating underground sources of heat in deep mines and provides an improved information base. Moreover, seven topics for further research are recommended. The heat sources considered are: wall-rock, ground water, adiabatic compression, equipment, service lines, blasting, metabolism, curing of cement, and oxidation of sulfides and timber. Seven deep metal mines with high production rates and high heat loads were visited to obtain data necessary to assess their thermal environments. Mine records were examined, wall-roc:, temperatures were measured and a survey of the mine ventilating air and mine drainage was performed. Also, the thermal conductivity of wet and dry specimens of the host rock were measured in the laboratory. Data analysis disclosed that rock heat and adiabatic compression account for stout 60 per cent of the mine heat load at depth. Equipment currently contributes approximately 20 per cent; however, to offset increasing costs with depth, increased mechanization is anticipated. The treat from ground water averages 19 per cent and the contribution from blasting, metabolism and cement is negligible. Also, approximately [0] per cent of the increase in the enthalpy of the ventilation air is in the form of latent heat. Moisture, however, did not significantly affect the thermal conductivity of the rock specimens measured in the laboratory. Also, from the data, it is evident that a negative correlation exists between the thermal conductivity of the host rocks and the per cent of the heat load derived from the wail-rock. Furthemore, steady state heat flow renditions may be assumed in airways where there has been no major changes in the ventilation system for a period of two years or more. Under these conditions, the author found it more convenient and reliable to compute heat influx using the steady state equation for heat flow into a cylinder, rather than Carrier's method for transient heat flow, which is so often used.

Jan 1, 1973

By B. J. Moore

This publication contains routine analyses and related source data for 419 natural gas samples from 22 States collected during calendar year 1964 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863/ and 576.4/ Six previous publications have been made to present the results of 6,293 gas analyses made by the Bureau of Mines, Helium Activity, prior to 1964. The first three, Bulletins 486,5/ 576,6/ and 617,7/ contain analyses and related source data on 5,214 gas samples collected from

Jan 1, 1966

By Everett D. Jackson

The largest deposits of chromite in the United States occur in tabular layers in the lower part of the Stillwater Complex, Montana. Nearly 900,000 long tons of chromite concentrates have been produced from mines and mills in this area, and reserves equivalent to more than 2,500,000 long tons of Cr2O3 remain in the ground. Layered concentrations of chromite (known as chromitite zones) occur only within olivine-rich layers of the Peridotite member of the Ultramafic zone of the Stillwater. As many as thirteen chromitite zones, lying conformably one above another, have been found, but only five of them are thick enough to be of any conceivable economic interest, and only two of them have been mined to date. Individual chromitite zones can be recognized by their distinctive internal character and by their stratigraphic position in the Peridotite member. The chemical composition of chromite varies consistently between and within the different chromitite zones. The zones range in thickness from about an inch to more than 12 feet, and the Cr2O3, content of their chromite ranges from 36.6 to 49.2 weight per cent. In any given area, the G chromitite zone is the thickest, but the chromite of the H chromitite zone has the highest grade. Laterally, the thickness of the chromitite zones is related to the thickness of the Peridotite member; in general all are thicker in the eastern part of the Stillwater than in the western part.

Jan 1, 1968

By Suresh K. Bhatt

This U.S. Bureau of Mines report reviews major developments in continuous haulage technology for underground coal mines. Haulage systems, both in use and under development, were investigated through a comprehensive literature search and visits to mines and manufacturers. The systems include flexible conveyor train, mobile conveyor, monorail bridge conveyor, multiple-unit continuous haulage, extensible, and belt turning systems. Strengths and weaknesses of the systems are assessed in light of their operating under remote control and their application to the computer-assisted continuous mining machine research being conducted by the Bureau. Through mining scenarios, candidate haulage systems are conceptualized to be consistent with the capabilities of the mining machine.

Jan 1, 1991

By Julian Brown, Steve Hicks, Zach Agioutantis, Zachary Wedding

Analysis of Coal Pillar Stability (ACPS) software, released in 2018, integrates numerous empirical pillar design techniques. The ACPS program incorporates methodologies originally available as design tools from the National Institute for Occupational Safety & Health (NIOSH), including Analysis of Longwall Pillar Stability (ALPS), Analysis of Retreat Mining Pillar Stability (ARMPS), Analysis of Multiple Seam Stability (AMSS), and concepts including Coal Mine Roof Rating (CMRR), the Mark-Bieniawski pillar formula, and pressure arch loading. The design methodologies that are the basis of ACPS were developed via analysis of significant amounts of real-world data and have been standards of the United States coal industry for decades. While there are empirical factors built into ACPS, making it ideal for use in U.S. coalfields, the concepts in the program have proven to be applicable in variable mine settings, and the software was developed to allow for user-based, site-specific modifications of key design inputs. Application of ACPS to cases outside the regions for which it was developed must be approached carefully, and continuous development of site-specific data is mandatory. A case study is presented involving the application of ACPS to assess pillar stability and assist future design for an underground lignite mine in Eastern Europe. Assessment of in-mine observations, review of the geology of the lignite mine, and evaluation of specific conditions associated with a failure event resulted in “calibration” of key input factors to ACPS. Scenarios evaluated with ACPS suggest that pillar strength and overburden depth are key factors for the determination of pillar stability and design in future areas.

Jun 25, 2024

By D. Harrington, F. E. Cash

For a number of years the efforts of the coal -mining industry , as well as of the Bureau of Mines , have been directed largely towards the limitation and prevention of explosions in coal mines . The origin of most explosions is ignition of methane or marsh gas , but the extent and violence of these explosions depend chiefly on the combustible dust present . The Bureau of Mines has conducted a large number of tests on the use of incombustible materials in limiting or preventing widespread explosions . The result of these tests , published in Bulletins 167 and 268 and Technical Paper 386 , proves that incombustible dust can be so applied and maintained in coal mines that the ignition of the mixture of incombustible and combustible dusts , or the propagation of flame by the dust mixture , is impossible ; on the other hand , experience and experiment indicate that watering methods are not reliable as a preventive of general or widespread coal-mine explosions . This report describes the use of " mudite , " a mixture of water and finely divided incombustible soil or dirt applied in some coal mines as a means of attempting to limit or prevent widespread explosions .

Jan 1, 1929