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By K. C. Nathsarma

An attempt was made to extract niobium oxide from ~98.5% Nb2O5 using solvent extraction processes. Nb2O5 is used as the feed material in carbothermic reduction processes aimed at producing high-homogeneity, superconductor-grade niobium on a laboratory scale. The Nb metal used for superconductor applications requires a residual resistivity ratio (RRR) > 300, which in turn needs a stringent purity of Nb and allows impurities (substitutional and interstitial) in ppm levels only. In this paper, solvent extraction of niobium was studied under various experimental conditions, such as effect of different extractants, concentration of methyl isobutyl ketone (MIBK) in the organic phase and concentration of various acids. The concentrate was digested with hydrofluoric acid, with ammonium fluoride (NH4F) as a stripping agent. The extraction of niobium from low hydrofluoric- (HF-) bearing solution was found to be low. Thus, various concentrations of hydrofluoric acid and sulfuric acid, as well as hydrofluoric acid and hydrochloric acid, were investigated towards obtaining a maximum amount of niobium in the filtrate and a minimum amount of niobium in the residue. A McCabe - Thiele plot for extraction of niobium from the aqueous phase, HF-bearing solution using HCl with 85% MIBK in kerosene has been constructed to determine the O:A ratio and the number of stages of the process.

Nov 1, 2011

By Akio Ohta

The Hyuga smelter has been producing ferronickel by a rotary kiln-electric furnace process in Miyazaki, Japan. Several approaches to improve our operation have decreased the electrical energy consumption. A new process was developed to decrease the cost of energy even further. Oil and technical oxygen are injected through lances to heat up the calcined ores (calcine) instead of the electric power. Main problems during the development of the process were the short life of the water-cooled lances, the check on security of the safety system and the eruption of combustion gases through the calcine bed. These problems have now been overcome successfully, and stable operation can be maintained. The addition of 1 Litre of heavy oil per tonne of ore can save the electrical energy requirement by 8.6 kwh per tonne of ore. The new process has resulted in a reduction of the electrical energy consumption by more than 10 percent

Jan 1, 1992

By Hubert Bril, Priscilla Pareuil, François Bordas, Emmanuel Joussein, Jean-Claude Bollinger

"According to the legislation, valorization type, origin and characteristics of waste material, various standard procedures are available to evaluate environmental impacts. A Mn-rich slag was sampled from a metallurgical plant. After its characterization (elementary analysis and mineralogy), five standard procedures were carried out (i.e. TCLP, EN 12457-1). Each fixed parameter of the standards was systematically studied in a large range: pH, Liquid/Solid ratio, contact time. For example, EN 12457-1 led to a low ME mobilization, increasing with the L/S ratio, the contact time and an acidic pH. As a conclusion, the representativeness of the considered parameters and their potential variations are predominant to assess of the real environmental impact during slag reuse. Introduction Recent studies have been carried out about environmental impacts of waste containing metallic elements (ME) because of their potential mobility [1-7]. Indeed, slags are either dumped or valorized in various activities such as building materials. In order to assess environmental risk, various standard procedures are used depending on country legislation, origin of waste and valorization way. Results of leaching tests are linked either to special legislation (e.g. Dumping: EC, Council Decision 2003/33/EC, Construction products: EC, Council Directive 89/106/EEC) or to legal levels used in drinking water (Directive 98/83/CE) when leachates could migrate to groundwater. If ME in leachates are lower than drinking water authorized levels, the waste will be considered as non-hazardous. On the contrary, if the leachable amounts exceed them, the question about the risk has to be posed. Beyond the abundance of leaching tests available, variety of operational conditions induced by these regulatory tests does not make the choice easier. According to operational conditions induced, ME release could vary from one test to another one. ME concentrations in leachates depend on pH, Liquid/Solid ratio, contact time and particle size [3]. To highlight the importance of these operational parameters, potential risk for valorization of a manganese-rich slag was assessed by comparing several standard leaching protocols [8-12] with a global study dealing with the influence of operational conditions. For each regulatory protocol, the most influential parameters (L/S ratio, pH, particle size and contact time) have been studied in a large range."

Jan 1, 2008

By C. C. Huang

Rare earth compounds, such as samarium-cobalt compounds and neodymium-icon compounds, are being used more often for the manufacture of permanent magnets, because these materials permit the production of permanent magnets with higher magnetic energy potential than the conventional ferrite magnets. Especially, the recent rapid developments in the field of electronics and electro-technology have demanded an increased production of rare earth magnets. Unlike ferrite, which is typically produced by a wet process, rare earths can be ground and classified either in a wet or dry process. In the past, batch ball mills, through-pass ball mills in circuit with air classifiers, and conventional jet mills were primarily employed for the dry processing. These methods, however, have suffered from the problems, for example, wear and contamination, low product quality In particle size distribution, difficult to adopt inert-gas operation, and high specific energy consumption. In this report, dry processing of rare earth powders will be presented, especially ultrafine grinding with fluidized bed jet mill.

Jan 1, 1993

By Richard A. Mullins, James J. Merle

Systematic sampling and analysis in coal-washing plants results in product control and economical operation. A well-organized laboratory system reduces operating costs and increases sales if the operating and sales companies make full use of information it supplies. The operating cost of a control laboratory is less than 1 pct per ton of coal produced. THE system of laboratory control as practiced by the Ayrshire group of mines was begun with the construction and organization of the first laboratory in conjunction with the completion of its first wash-ery in 1941. The primary purpose of this laboratory was to maintain a check on the quality of the coal produced from the washing plant. The laboratory was equipped to determine proximate analyses, float-and-sink tests, and screen analyses, and was staffed by a chemist. an assistant. and a technician. Members AIME, are Assistant Preparation Manager and Chief Chemist, respectively, Ayrshire Collieries Corp. and Subsidiaries, Danville, Ill. Joint AIME-ASME Fuels Conference. French Lick. October 1949. TP 2855 F. Discussion (2 copies) may be sent to Transactions AIME before June 30, 1950. Manuscript received Aug. 22, 1949. Soon it became apparent (1) that product control could be accomplished, (2) that a substantial reduction in operating costs could be effected by close control of coal losses in the rejects, and (3) that information furnished by the laboratory was of continuous value to the operating and sales companies. Consequently the laboratory function was expanded to supply them with additional data as required. As the parent company expanded and new mines were added, control laboratories were established at each mine equipped with washeries, and a central laboratory was maintained at one of the mines that was located equally convenient to all of them. A well-planned control laboratory assures production of a uniform, high-quality product. Whenever coal of substandard grade is loaded inadvertently, the sales company can be informed and the proper channel of distribution made. Conversely only constant and strict laboratory supervision can insure proper production of the various grades. Knowing the product, the producer can keep out of many customers' arguments that may be both awkward and expensive. Double checking between customers and mine laboratories have solved many disputes' Some nager insist On buying coal On the analysis basis only, with penalties for substandard coal and premiums for coal above normal quality. A substantial percentage of the coal sold by the Ayrshire group is of this nature. The usual procedure is for the customer to sample and analyze the coal as it is unloaded at the plant, and the mine laboratory samples it as it is loaded at the mine for subsequent analysis by the central laboratory. Only the unloaded moisture is considered, rather than the average of mine and plant moisture, and the buyer sends duplicate samples to the central mine laboratory for this determination. The average of the two analyses determines the price of coal at the mine. In this particular case, the laboratory plays an important part in increasing realization for two reasons: (1) every attempt is made to maintain plant efficiency and product quality as high as possible, (2) check on analyses and sampling by the buyer or seller.

Jan 1, 1951

By Richard A. Mullins, James J. Merle

Systematic sampling and analysis in coal-washing plants results in product control and economical operation. A well-organized laboratory system reduces operating costs and increases sales if the operating and sales companies make full use of information it supplies. The operating cost of a control laboratory is less than 1 pct per ton of coal produced. THE system of laboratory control as practiced by the Ayrshire group of mines was begun with the construction and organization of the first laboratory in conjunction with the completion of its first wash-ery in 1941. The primary purpose of this laboratory was to maintain a check on the quality of the coal produced from the washing plant. The laboratory was equipped to determine proximate analyses, float-and-sink tests, and screen analyses, and was staffed by a chemist. an assistant. and a technician. Members AIME, are Assistant Preparation Manager and Chief Chemist, respectively, Ayrshire Collieries Corp. and Subsidiaries, Danville, Ill. Joint AIME-ASME Fuels Conference. French Lick. October 1949. TP 2855 F. Discussion (2 copies) may be sent to Transactions AIME before June 30, 1950. Manuscript received Aug. 22, 1949. Soon it became apparent (1) that product control could be accomplished, (2) that a substantial reduction in operating costs could be effected by close control of coal losses in the rejects, and (3) that information furnished by the laboratory was of continuous value to the operating and sales companies. Consequently the laboratory function was expanded to supply them with additional data as required. As the parent company expanded and new mines were added, control laboratories were established at each mine equipped with washeries, and a central laboratory was maintained at one of the mines that was located equally convenient to all of them. A well-planned control laboratory assures production of a uniform, high-quality product. Whenever coal of substandard grade is loaded inadvertently, the sales company can be informed and the proper channel of distribution made. Conversely only constant and strict laboratory supervision can insure proper production of the various grades. Knowing the product, the producer can keep out of many customers' arguments that may be both awkward and expensive. Double checking between customers and mine laboratories have solved many disputes' Some nager insist On buying coal On the analysis basis only, with penalties for substandard coal and premiums for coal above normal quality. A substantial percentage of the coal sold by the Ayrshire group is of this nature. The usual procedure is for the customer to sample and analyze the coal as it is unloaded at the plant, and the mine laboratory samples it as it is loaded at the mine for subsequent analysis by the central laboratory. Only the unloaded moisture is considered, rather than the average of mine and plant moisture, and the buyer sends duplicate samples to the central mine laboratory for this determination. The average of the two analyses determines the price of coal at the mine. In this particular case, the laboratory plays an important part in increasing realization for two reasons: (1) every attempt is made to maintain plant efficiency and product quality as high as possible, (2) check on analyses and sampling by the buyer or seller.

Jan 1, 1951

By R. V. Ramani, K. Bode

"IntroductionIn part 1 of this paper, the results of the experimental work in a wind tunnel under controlled conditions were presented. To understand the spatial and temporal behaviour of airborne dust under mine conditions, experiments were performed in the Lake Lynn Experimental Mine of the US Bureau of Mines. The mine airway experiments were designed to study the variations of ambient concentrations along the length of an airway, and the deposition rates and deposition velocities in an airway cross section. Other objectives of the study were to investigate the spatial and temporal behaviour of airborne dust with regard to air velocity and particle density, the size distribution of the airborne dust cloud as it travels in the airway, and the size distribution of the dust particles deposited along the airway. Other objectives of the study were to compare wind tunnel results with In-Mine results, whenever appropriate.Experimental ProcedureLocationA complete description of the Lake Lynn Laboratory Mine of the US Bureau of Mines (USBM) can be found in the US Bureau of Mines Information Circular 8911 (Mattes et al., 1983). This mine provides excellent facilities for dust experiments. The airway dimensions are similar to those of a coal mine airway. The mine has a drift (D Drift, see Figure 1) that extends almost 500 meters without interconnecting airways, stoppings, or bends. The D drift measures approximately 6m in width and 2,25m in height.The Lake Lynn Laboratory Mine· is ventilated by a variable speed, 75 kW (100 hp), 28,3 m3/s (60 000 cfm) blower fan installed on the top of the ventilation shaft. Air velocities of 1, 1,3 and 1,8 m/s, respectively, could be obtained in the D Drift. However, the temperature changes at the surface can cause small variations in air quantities and velocities underground. The low background dust level in the mine reduces the problem of sample contamination from other sources of dust. Extended periods of uninterrupted data collection can also be scheduled. Mine airway parameters which are important for the analysis include the dimensions of the airway and the ventilation data such as the air velocity, and the pressure loss in the drift. All these data were acquired during altimeter surveys which were conducted prior to each of the experiments."

Dec 1, 1995

By A. Vilinska

Microorganisms have a tremendous influence on their environment through the transfer of energy, charge, and materials across a complex biotic mineral-solution interface. Recent developments in biotechnology have not only aided hydrometallurgical leaching operations but also shown great promise in mineral beneficiation processes. The adhesion of bacteria on minerals alters the surface properties relevant to flotation and flocculation of minerals. The biomodification of mineral surfaces occurs through the attachment of microbial cells, oxidation reactions and adsorption or chemical reaction with the metabolite products. Several types of heterotrophic and chemolithotrophic bacteria have been successfully applied in flotation and flocculation processes for the last two decades. Al-though the potential of microorganisms in minerals beneficiation has been realised by several re-searchers from their laboratory investigations, the studies were mostly confined to pure mineral systems and there is hardly any sincere effort to apply the methodologies on ores. This paper presents a brief summary of the literature in bioflotation and bioflocculation, and attempts to outline new dimensions of research for a practicable application of this technology in mineral industry.

Jan 1, 2014

By George Machan

Bitumen coatings have been successfully used to significantly reduce downdrag on piles. Thicker coatings of "soft" bitumens can accommodate downdrag so well that very little downdrag load is transferred to the pile. Many of the case histories describe better than 80 percent downdrag load reduction. Bitumen coatings have been used on several projects in Oregon. On the Mocks Bottom Bridge project (see Reference 1), experimentation and instrumentation confirmed the viability of bitumen coatings and provided insights for design and construction. Subsequent bridge projects have used this information and have raised issues to be resolved.

Jan 1, 1989

By James A. Finch, Robert E. McIvor

"This paper presents the development of a new grinding circuit steady-state modeling system. It is fundamentally based on the “functional performance equation”, which has now been used to improve the performance of numerous grinding circuits. This equation characterizes the two distinct efficiencies that are at work in a ball milling circuit, and how these relate to overall circuit productivity. It does so based on the particle size chosen to distinguish between coarse and fine (product size) material. Now, by applying it to all the material size classes, a simple yet reliable ball mill model was created. Combined with cyclone recoveries, the complete, detailed grinding circuit performance can be exactly reproduced mathematically by the computer program. It can then be used with separate process equipment application engineering methods to systematically engineer grinding circuit improvements. The development, features, uses and limitations of the system are described.INITIAL DEVELOPMENT OF THE CIRCUIT MODELThe Functional Performance Equation for Closed Circuit Ball (or Pebble) MillingIt has been shown that closed grinding circuit performance can be effectively characterized by the “functional performance equation” for closed ball or pebble milling circuits (McIvor, 2006a). One method of its derivation is summarized here for convenient reference.First select a cut-off size to define “coarse” versus “fine” or product size material for the grinding circuit. Any particle mesh size can be used to differentiate between coarse material and fines, but the circuit target P80 is often an effective choice for these purposes.Any energy expended on “fines” is wasted. It also generates “extreme fines” often detrimental to downstream processing (McIvor and Finch, 1991). Only the portion of the mill power draw that is expended on coarse material is effectively used. This portion can be estimated from the mill feed and discharge size distributions (McIvor, 1988a) by taking the average of the percentage of “coarse” material in the mill feed and discharge. We can define the thusly calculated percentage of the mill power that is expended on coarse material in the mill as the ball mill circuit “classification system efficiency” (CSEff). The “effective mill power” (EMP) can be calculated from the total mill power (TMP) as follows."

Jan 1, 2007

By Nomuqhele N. Nkosi, Yasuo Yabe, Musa D. Manzi, Raymond J. Durrheim, Siyanda B. Mngadi

This study examined rock failure in brittle rocks hosting the deep gold-bearing ore bodies on scales between millimeters and kilometres. This research study is part of the International Continental scientific Drilling Program (ICDP) project, “Drilling into Seismogenic Zones of M2.0-M5.5 earthquakes in deep South African gold mines” (DSeis). The broader ICDP-DSeis project aims include the examination of the extent of damage, the stress state around the fringes of the earthquake, and the potential existence of living organisms associated with deep-level earthquakes. Nevertheless, this study focused on two seismogenic zones – the Cooke 4 mine and Moab Khotsong mine. At Cooke 4 mine, the study examined the evolution of mining-induced fractures (M1-4) occurring ahead of the stope face during the extraction of the remnant shaft pillar. These fractures were monitored and delineated by a dense array of acoustic emission sensors that allowed hypocentres to be located with decimeter accuracy. Using this acoustic emission data, the DSeis team drilled and recovered the fractures, rock breccia and gouge using a sophisticated triple-tube drilling rig.

Apr 26, 2022

By Samuel A. Reipas

Introduction The ore mining industry has been successful because of technological progress and huge sums of capital investment. But new technology and plants have not come cheap. The problem now is companies will run out of money before they run out of ideas. Survival Strategies Industry survival strategies demand restructuring and new plans. Inland's prescription for the future includes: • Continued emphasis on technological improvements to upgrade pellet quality and lower costs; • Effective use of human resources resulting in employee satisfaction and improved planning and productivity; • Deliberate, well planned, and documented cost-control programs for the short- and long-term; and • Capital investments to support the first three initiatives. Technology Technological changes are not only required by the need for operational improvements, but by product quality improvement dictated by the user - usually the blast furnace operator. Established ambient measurements of pellet quality, such as tumble index, compression strength, porosity, size distribution, and chemical composition, are no longer considered meaningful in predicting pellet performance in a blast furnace. New specifications, called low temperature and intermediate temperature properties, have been recently introduced. Low temperature specifications are characterized by disintegration of pellets in the 500°C (930°F) range in the upper portion of the granular zone during the hematite-to-magnetite transformation in blast furnace stack. Intermediate temperature properties (measured by 1000°C or 1800°F) are characterized by swelling, reducibility, and compression strength after reduction, reflecting conditions in the lower portion of the granular zone of the furnace. These new parameters are being used for pellet quality evaluation at Inland, and will be introduced at its Minorca mine for more routine analysis and correlation with the pellet furnace operation. With increased emphasis on quality, effective communication between the blast furnace operator, research, and the pellet plant operator is critical. At Inland, this is accomplished through technical meetings where the opportunity is provided to solve problems, establish a common understanding on the value of quality, and develop future quality standards and programs. With the degree of sophistication in determining pellet quality as it affects blast furnace operation, the future pellet plant operator will actually be producing a custom pellet. Human Resources Technological change has been a strong point at Inland, and will continue to be. However, human resource management is equally important. Is management giving sufficient attention to employee motivation and involvement? It is a way to improve productivity, reduce costs, and enhance employee job satisfaction. The industry is beginning to understand the principles and the potential for tapping employee brainpower. The payoff can be handsome. Management has to be willing to share both information and power if participative management is to live up to its potential. It has to become more flexible and be willing to adapt to change on the human side. Management should embrace rather than fear employee involvement. Given time, joint problem solving will replace adversarial attitudes and pay dividends for both sides. Productivity and product quality will improve and new dimensions of employee job satisfaction will be achieved. But, it will not happen overnight. Attitudinal change must permeate the organization from top to bottom. This change is needed to support the working relationships and give everyone a sense of direct and meaningful involvement.

Jan 11, 1983

By T. Laxmi

This paper details the optimization of rougher Wet High Intensity Magnetic Separator (WHIMS) using response surface methodology. The optimization is in parametric form and takes account of the major operating variables in WHIMS operation such as current in ampere and grid gap, in inch. The objective is to recover ilmenite mineral from red sediment deposits of Srikakulam, India by optimizing the rougher WHIMS. We predict mineral recoveries as a function of current and grid gap. Combination of these predictions with assay data provides predictions of mineral grades and recoveries. The optimized response was validated against data derived from laboratory-scale rougher WHIMS test work, comprising (i) mineral grade, (ii) mineral recovery, and (iii) separation efficiency of the process. We observed close match between the experimental and the predicted data over most of the operational range. This paper describes how the optimization was carried out using the response surface methodology along with MATLAB. The response surface was used to closely investigate the separation of ilmenite mineral by varying ampere and grid gap. The results show that under optimum conditions, such as 3.5 amp current (0.53 Tesla) and 2 inch grid gap, the mineral grade could reach, as high as 87.9% in the concentrate with 74.3 % recovery and 74.4% yield. Keywords: red sediment, wet high intensity magnetic separator, optimization, ilmenite, placer heavy minerals

Sep 1, 2012

By R. P. Jewett

The object of this investigation was to correlate the crushing strength of green pellets prepared from magnetite, specular and earthy hematite with the particle size of these respective raw materials. In this study no attempt was made to correlate the strength of fired pellets and particle size. The effect of particle size upon a number of fine ores and concentrates was studied. Much of the low-grade ore reserves in the Lake Superior Region must be finely ground before concentration and then agglomerated for iron and steelmaking processes. Fine natural ores also must be agglomerated. Pellets constitute an important type of agglomerate. Considerable handling occurs during screening to remove undersize and oversize pellets, and in transfering green unfired pellets from the balling machines to the heat-hardening equipment. As a result the strength of the green pellets is a factor of great importance.

Jan 1, 1961

By S. B. Kang

Magnesium has poor ductility at temperatures lower than 225°C and, as a result, Mg alloy sheets are produced via fairly complex thermomechanical processes consisting of numerous sequential steps of hot (warm) rolling with low reduction and intermediate recrystallization annealing operations. In context of the present study, a simple technology for the fabrication of magnesium sheets by hot (warm) rolling was applied to various magnesium alloys. The misch metal addition in those AZ alloys was done to evaluate the deformation behavior. Tensile tests were carried out for those AZ alloys after applying different heat treatments. The precipitation of ß phase (Mg17Al12 phase) induced different microstructures with various cooling method from solution treatment temperature, and also with various annealing treatment temperatures.

Jan 1, 2006

By George S. Rice

GROUND movement from mining, whether it be for coal, metal, industrial minerals, or .oil, will always present many difficult problems. These are especially serious when valuable surface improvements may be badly damaged. The mine itself, if mining methods are not suitable to the formation, is subject to heavy falls of the main roof in the working places; and with certain structural conditions the movements may cause in coal mines disastrous bumps and outbursts of gas, and in deep metal mines rock bursts. In open-cut work rock and earth slides may result. Absolute prevention of ground movement from mining is impossible unless large pillars are left unmined,

Jan 1, 1937

By J. L. Young

The McLaughlin Mill started operating in January, 1985. For the first eighteen (18) months start-up, initial operation, and circuit debottlenecking have been done. The mill was designed to recover gold from a refractory ore requiring acid autoclaving pretreatment. This paper discusses the problem associated with bringing this complex hydro-metallurgical plant to consistently achieve design tonnages. Also, briefly described are the mill flowsheet, training program, permitting, and process and project development.

Jan 1, 1987

During the hydrometallurgical processing of the major base metals Cu, Zn, Ni and Co, the presence of iron is normally a serious complication, and iron separation from the pay metals usually constitutes one of the main challenges for the metallurgist. There are many instances, however, where the presence of iron is beneficial, or is even required. Two cases are presented where iron is required during the processing of base metals. The first example deals with the use of ferric sulphate to oxidize sulphides, more particularly copper and zinc sulphides, under atmospheric conditions. The results presented confirm that ferric ion leaching is efficient, particularly when the oxidant is regenerated during the process. The second case is the use of iron to solubilise refractory cobalt oxide minerals; examples, including pilot plant results, are presented for various ores from Africa and Central America. In both cases, this paper reviews the basic concepts involved and provides details of their application.

Jan 1, 2006

By I. E. Lewis, W. R. Hopkins

Flowsheet improvements, such as series/parallel SX plant configurations, discontinuation of plant sumps and improved filter pumping concepts, the use of in-settler baffle systems, and the Krebs and combined mixer-settler designs offer opportunities to reduce SX plant cost. Today's plants employ permanent cathodes and mechanical stripping, and the increased capital cost can be offset by labor savings and higher current densities. The wider use of HDPE and new cell construction materials also reduce capital cost. The "Portelex" type of relocatable design embodies such new, cost-saving measures in a simple basic plant. Organic inventory and losses are reduced by new, fast-settling, hybrid organic reagents with improved kinetics and selectivity.

Jan 1, 1991

By Stephen D. Cramer

A nondestructive procedure for measuring electrodeposit porosity has been developed which records the location and number of deposit defects including pores, pits, and voids. The procedure involves the passage of an X-ray beam through the deposit-substrate system onto suitable film. The defects are recorded as images on the film. Variables studied included intensity and spectra of the X-ray beam, composition and thickness of deposit and substrate, film type and developing procedure, and limits for detecting defects. At an X-ray tube voltage of 40 kv, pores several mils thick were easily detected in copper-nickel specimens more than 20 mils thick. To illustrate the utility of the procedure, the effect of substrate oxidation and of current density on electrodeposit porosity was briefly studied.

Jan 1, 1970