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By J. C. Agarwal

Most metals are produced from minerals containing one or more of the desired metals, some contaminating metals, silicate, oxides, carbonates, and sulfides. Therefore, in the production of metals, there is generally a gaseous effluent in pyrometallurgical processes and a liquid effluent in hydrometallurgical processes. There are also solid residues such as waste ore, tailings, dust, and slag, created by the metal recovery processes. There are two important distinctions between the effluents and the residues: I. Effluents ? gases and liquids ? affect the neighboring environment for miles from the point of emission, while residues affect only the soil on which they are stored or dumped. 2. The environmental and economic effects of effluents are known and felt essentially immediately. By contrast, the environmental effects of the residues may not be known for a long time. For these reasons, the economic impact and the potential corrective actions required are very different for effluents and residues.

Jan 1, 1992

By Batric Pesic

Recovery of gold from refractory ores was studied by pressure oxidation as the method of ore pretreatment followed by bromination of oxidized residues. Three different ores were examined, Au-Ag, Au-Ag-Te, and Au-silver free ore. Pyrite was the major host mineral for gold in these ores. The effect of pressure oxidation parameters (temperature, pressure of oxygen, time, and pulp density) on subsequent bromination under standard conditions was examined. Bromination of residues produced under standard pressure oxidation conditions was examined as a function of: temperature, bromine and sodium bromide concentration, and time. Recovery of gold on activated carbon, from the pulp after bromination, was studied too. Recovery of gold from silver containing ores was lower (87-91%) than the recovery of gold from silver free gold ore (97%). In each studied case, the presence of activated carbon in the pulp further increased the recovery of gold.

Jan 1, 1992

By Errol D. Sehnke

This U.S. Bureau of Mines report provides detailed information on worldwide alumina production capacity by plant and country. The information was compiled from a variety of domestic and international sources and was based on information available to the Bureau through December 31, 1993. Capacity data represent announced installed and planned capacities and do not necessarily reflect a Bureau of Mines judgment of actual plant operating levels or timing of planned expansions, The year-end capacity is the ?nameplate" capacity or estimated production capacity, whichever is larger.

Jan 1, 1993

By S. Wallden, R. Lindstrom

The electrolytic copper refining process is an excellent method for producing high-purity metal for electric conductors and other demanding applications. However, the process involves very high capital expenditure, especially the amounts of metals bound in the process. Efforts have therefore been made for many years to increase the production rate by increasing the current density, without impairing the quality of the copper. One of the approaches has been to diminish the polarization by mechanical means, while another was to "polish" the cathode surface by periodic brief reversals of the current. Reversed current electrolysis was first developed for electro- plating purposes and in 1952 Boliden AB and the Dept. of Electrochemistry at the Royal Inst. of Tech., Stockholm tested the method for copper refining with good results. However, no suitable electrical equipment for current reversal was then available. The thyristor-controlled silicon rectifier became available during the '60s and provided the scope for industrial application of the process and the first large-scale development was made by the Bulgarian copper refinery in Pirdop. Many copper refineries are now studying or adapting the reverse current process. Further lab and pilot investigations have been carried out at Boliden AB during the past 4 years and these were mainly aimed at studying the optimization of factors influencing the quality of copper. A production unit containing two tank sections with a total of 56 cells and equipped with a rectifier for cur- rent reversal has been installed and will be started during 1973.

Jan 1, 1973

By R. A. Beall

A series of 45 zirconium ingots has been cast by the consumable electrode arc melting process with the object of analyzing the effects of power input from 50 to 230 kilowatts and reduced pressure furnace atmosphere to improve the quality of regular 8-inch-diameter production ingots made thereby. Electrode consumption rate, molten pool volume, melting efficiency, sidewall quality, arc stability, and yield efficiency are considered. The use of direct current and alternating current is studied. In conclusion, reduced pressure furnace operation is shown to promote electrical efficiency, ingot homogeneity, high metal yield, and are stability. INTRODUCTION Zirconium is a particularly difficult metal to melt because of its affinity for atmospheric gases and its solvent properties when molten. In addition, zirconium sponge as produced by the boll process contains minor amounts of magnesium chloride, which cause severe spattering luring melting, because of these difficulties with zirconium, and its sister metal titanium, near techniques have been developed to permit production of commercial size ingots. Among the more promising is the consumable electrode arc melting method.

Jan 1, 1955

By Muriel S. Robinette

Ground-water contamination from uranium operations could be avoided with proper site analysis techniques. Contamination from tailings disposal sites is carried downgradient within permeable hydrostratigraphic units which can be located and delineated with a combination of drill holes, borehole geophysical logs and surface geophysics. Several case studies are presented to illustrate this application.

Jan 1, 1980

By Ravi S. Bellur-Ramaswamy, Daniel A. Tortorelli, Robert Haber, Nahil A. Sobh

We optimize continuous quench process parameters to produce functionally graded aluminum alloy extrudates. To perform this task, an optimization problem is defined and solved using a standard nonlinear programming algorithm. Ingredients of this algorithm include 1) the process parameters to be optimized, 2) a cost function: the weighted average of the precipitate number density distribution, 3) constraint functions to limit the temperature gradient (and hence distortion and residual stress) and exit temperature, and 4) their sensitivities with respect to the process parameters. The cost and constraint functions are dependent on the temperature and precipitate size which are obtained by balancing energy to determine the temperature distribution and by using a reaction-rate theory to determine the precipitate particle sizes and their distributions. Both the temperature and the precipitate models are solved via the discontinuous Galerkin finite element method. The energy balance incorporates nonlinear boundary conditions and material properties. The temperature field is then used in the reaction rate model which has as many as 105 degrees of- freedom per finite element node. After computing the temperature and precipitate size distributions we must compute their sensitivities. This seemingly intractable computational task is resolved thanks to the discontinuous Galerkin finite element formulation and the direct differentiation sensitivity method. A three-dimension example is provided to demonstrate the algorithm.

Jan 1, 2001

By Mim Li, Huimin Lu, Lisha Yang

"CuInS2 thin films solar cells have drawn much attention for their low-cost, stability and high conversion efficiency. The electrodeposition of Cu-In precursor films, as the first step in making CuinS2 solar cells electrochemically in the air-and water-stable ionic liquid based on choline chloride/urea eutectic mixture has been investigated at constant potential. Compared with aqueous electrolytes, the large electrochemical window as well as the high thermal stability of this ionic liquid allow the direct electrodeposition of Cu-In precursor films. Then the precursor films were sulfuretted in a tube furnace at different sulfurization temperatures to optimize the films properties. The films obtained were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS).IntroductionCuInS2 is one of the most prospective absorber materials for low cost thin film solar cells, with a high conversion efficiency that exceeds 32% in terms of theory and nearly 13% in laboratory level [1-2]. In addition to its long-term stability, CuinS2 has a band gap energy Eg ranging from 1.3 to 1.55 eV and an optimal optical absorption coefficient reaching 105cm-1 [3-4]. CuinS2 thin films have been prepared by several methods such as spray pyrolysis [5-6], r.f.sputtering [7], vacuum evaporation [8-9] and electrodeposition. Comparing with vacuum methods, electrodeposition has lots of advantages such as less energy consumption, preparation big area thin film, stable system and enabling cheaper films.The electrodeposition of most technologically important metals has been shown to be possible from a wide range of ionic liquids. These ionic liquids are currently applied in a wide variety area. It is reported that the cell efficiency of chalcopyrite absorber layer (CIS, CISeS, and CIGS) via an electrodeposition route in laboratory condition has reached 11.3% [10]. Copper and indium alloy film is regarded as important precursor for the production of compound semiconductors with sulfur. The electrodeposition of the alloy film from room temperature ionic liquid (RTIL) has not been widely investigated. Only few alloy films, such as ZnTe, CdTe, GaAs and AlSb have been electrodeposited."

Jan 1, 2011

By Takashi Sasaoka, Hiroshi Takamoto, Akihiro Hamanaka, Pongpanya Phnthoudeth, Hideki Shimada, Jiro Oya

"Indonesia is the second largest coal exporter to Japan, accounting for about 30 Mt annually. They produced over 400 Mt in 2015, over 99% of which is from open-cut mines. However, the conditions of surface mining are becoming worse year by year: the stripping ratio is increasing, the economy is worsening, and the infrastructure for coal transportation from inland mining areas is not being maintained. To meet the demand for coal in Indonesia and the rest of the world, underground mines have to be developed. In consideration of growing need, our research program is conducting a study on the potential for an underground coal mine in Indonesia. This research is being done through the roadway heading research program, which is looking into developing an underground coal mine from an open pit highwall. The greatest challenge for underground coal mine development in Indonesia is the maintaining the safety of the mine roadway during heading because the roof rock is exceptionally weaker. There is a potential for heading below mobile, unconsolidated soft sediment, and instead mining a deep area. This increases the likelihood for problems in the stability of the support system due to increasing ground pressure. The ground behavior around the roadway was measured using telltales, extensometers, and convergence measurements. Moreover, rock property tests were also conducted on exploration drilling cores. Based on the geological dates and monitoring data, a series of numerical analyses were conducted in order to assess support needs in the main roadway under different depths. Results of numerical analyses indicate that the current arch support design is effective when the mining depth is lower than 100m. However, if the mining depth is larger than 100m, the current arch support design should be changed to include the application of higher yield strength material, shorter spacing, etc. Moreover, bolting may also be useful if ground pressure is high locally. Based on a series of measurement data of ground and support behavior, a control criterion for main roadways under weak geological conditions is proposed in this paper."

Jan 1, 2017

By M. Smit, N. C. J. Dempers, S. Lunkov, C. Saguru, J. Nel

A common method for the recovery of copper is by heap leaching, solvent extraction, and electrowinning. During solvent extraction, the solution is continuously recycled, and it is necessary to remove impurities that build up in the raffinate. For the process investigated in this study, the main impurities include Fe, Co, As, and Zn. Recovery of these impurities can provide economic benefits while adhering to legal and environmental constraints. Such impurities are often removed by precipitation utilizing a neutralizing agent, such as limestone or lime, but it is also possible to remove the impurities by sulfide precipitation. Sodium hydrosulfide (NaHS) is used to selectively precipitate copper, arsenic, and zinc from a solvent-extraction raffinate stream. The resulting sulfide precipitate is bagged and sent to a roaster for further treatment. The design of the sulfide precipitation was investigated to optimize the processing conditions (including temperature, pressure, and residence time), the materials of construction, and the toxicity and explosive nature of the hydrogen sulfide gas produced

Jan 1, 2023

By T. Nishimura, H. Kiyama, K. Wakimoto

Discussion on the load bearing capacity of ground and the stability of tunnel is presented. We derive a simplified solution of a circular lined-tunnel in an elastic ground. The solution results in a better understanding of characteristic curves. Use of DEM allows us to consider effects of possible yield of the overstressed zone around the tunnel and inherent discontinuity of ground on the curves. Diskussion auf der Last Tragfähigkeit Bodens und die Stabilität des Tunnels wird dargestellt. Wir leiten eine vereinfachte Lösung eines kreisförmigen Ausbautunnels in einem elastischen Boden ab. Die Lösung ergibt ein besseres Verständnis der Kennlinien. Um Gebrauch DEM erlaubt uns, zu betrachten Effekte des möglichen Ergebnisses der überbetonten Zone den Tunnel und zugehörige Unstimmigkeit des Bodens auf den Kurven. La discussion sur la portance de charge de la terre et de la stabilité du tunnel est présentée. Nous dérivons une solution simplifiée d'un revêtement-tunnel circulaire dans une terre élastique. La solution a comme conséquence une meilleure compréhension des courbes caractéristiques. L'utilisation de DEM nous permet de considérer des effets du rendement possible de la zone surchargée autour du tunnel et de la discontinuité inhérente de la terre sur les courbes.

Jan 1, 2003

By K. V. Raj, A. Miller

"Workers at mineral processing facilities are often exposed to high levels of dust generated when ores are processed. Crushing, grinding, screening, and other processes generate large quantities of dust, which can exceed the threshold VALUES (prescribed by the Mine Safety and Health Administration (MSHA). Many ores contain quartz (silica), which has been known to cause serious health problems in workers over time. Given the structure of mineral processing plants, the airflow regime is not coherent inside the building, which may lead to multiple recirculation zones. These recirculation zones can trap dust, and concentrations of dust can then rise over time. Therefore, there is a need to understand the airflow phenomenon that occur inside of mineral processing facilities and how these occurrences interact with the dust generation processes to identify zones of potentially high dust concentration. Computational fluid dynamics (CFD) modeling can give a better understanding of the airflow and help recommend designs and methods to mitigate the high dust concentrations in a mineral processing plant. This paper presents the CFD modeling of airflow inside of a mill building to demonstrate airflow patterns that will affect the generation and subsequent dispersion of dust due to crushing, grinding, and other activities. This study was conducted by researchers from the National Institute for Occupational Safety and Health (NIOSH). INTRODUCTION In a mineral processing facility, minerals go through various mechanical processes in order to reduce their size for separation of economic minerals from gangue minerals to produce a final marketable product. This research, conducted by the National Institute for Occupational Safety and Health (NIOSH), focuses on ore mills in metal and nonmetal mining (MNM) operations, but the applicability of the approach will be valid for any large structure where workers are exposed to airborne contaminants. The processes of crushing, grinding, cleaning, drying, and product sizing in these facilities generate a large amount of dust, creating hazardous conditions for the workers in these facilities. This is highlighted by the fact that MSHA sampling data for the years 1997–2012 indicate that 12.3% and 15.9% of the gathered samples were over 100 µg/m3 for silica for metal and nonmetal mills, respectively [1]. Mineral processing operations typically use some type of engineering control to address their most significant dust sources. Engineering controls include such approaches as bag-house-type dust collectors, scrubbers, and electrostatic precipitation [2]."

Jan 1, 2018

By Klas G. Hultbom

Mercury is present as trace contaminant in many raw materials for metallurgical plants. When such materials are treated with pyrometallurgical processes the mercury is volatilised. Mercury has a high vapour pressure, even at low temperatures, and therefore it is removed only partly by normal gas cleaning processes. The Boliden Norzink scrubbing process removes elemental mercury by converting it to calomel. It is widely used in the base metals industry. This paper gives examples of the application, and also outlines the background for the development of the process. Another technology developed by Boliden for mercury removal is the Selenium filter. This is a fixed bed filter based on the reaction between elemental gaseous mercury and selenium, by which mercury selenide, HgSe, is formed. The mercury selenide is a highly stable compound with extremely low solubility in water and very low vapour pressure. Mercury is removed selectively without any side reactions. Special applications for the selenium filter technology include mercury removal from gases containing sulphur dioxide and geothermal off-gases.

Jan 1, 2003

By James H. Bechtold

The yield strength of annealed tungsten was found to have a strain rate exponent 12 times as great as that of low carbon steel. The effects of temperature and strain rate could be correlated through the Zener-Hollomon parameter with a heat of activation associated with yielding of 32,000 cal per g-atom. This heat of activation is independent of strain although both the temperature and strain rate dependence of the yield strength vary with strain. MOST metals have mechanical properties that are relatively insensitive to strain rate, especially at temperatures below that at which creep is important. In iron and molybdenum," however, relatively large strain rate effects are observed in the temperature range where the rapid increase in yield strength occurs which leads to the ductile to brittle transition. In this temperature range Zener and Hollomon' have suggested that the effects of strain rate and temperature T on the yield strength could be correlated through a single parameter, P, in the following manner where Q is a heat of activation characteristic of the metal and associated with some unspecified relaxation process. They also observed that if the temperature is restricted to a relatively narrow range— below room temperature for steel—that the logarithm of the yield strength could be expressed as a linear function of the logarithm of P. From this relation the logarithm of stress should be a linear function of the logarithm of the strain rate at constant temperature: where r will be referred to herein as the strain rate exponent. At a constant strain rate the logarithm of stress should be a linear function of l/T, ay(e = C) ~ eT [4] where q = Qr [5] and is referred to herein as the temperature exponent. These equations have been found to relate the effects of temperature and strain rate on the yield strength of molybdenum in the temperature range wherein the ductile to brittle transition occurs, —75° to +150°C.2 Bechtold and Shewmon3 have shown recently that the ductile to brittle transition in annealed tungsten occurs in the temperature range +150° to +350°C. In this temperature range the yield strength in-

Jan 1, 1957

By M. Yamine, R. J. Ring, D. J. Waters

"An experimental program has been carried out by the Australian Atomic Energy Commission to compare the effectiveness of Caro's acid as an alternative oxidant to pyrolusite in the leaching of uranium ores from the Alligator Rivers region of northern Australia. Batch leaching tests on Ranger, Nabarlek, Koongarra and Jabiluka ores showed that uranium extraction was unaffected by choice of oxidant, but that Caro's acid reduced acid requirements by 15 - 25%. Lime requirements for neutralization of tailings liquors were reduced by 20 - 30%.The batch studies were extended to a four-stage continuous leaching circuit with a capacity of 400 gore h-I. Comparative leaching tests confirmed the reagent savings obtained in the batch tests. Following these encouraging laboratory results, lnterox Chemicals Pty Ltd carried out plant trials using Caro's acid. Reagent savings in the mill were similar to, or better than, those obtained in laboratory test work. The trials also established that Caro's acid has a number of operational advantages over pyrolusite.IntroductionUranium is most commonly extracted from its ores by leaching in sulphuric acid. Simple hexavalent uranium oxides and compounds are readily soluble but uranium in the tetravalent form is insoluble and must be oxidized for dissolution to occur. The most commonly used oxidants have been sodium chlorate and manganese dioxide. They act indirectly by maintaining iron as the ferric ion which oxidizes uranium by a surface electro- chemical reaction. An Fe3+ concentration of about 1 - 2 g L-I is usually considered adequate for the effective dissolution of uraninite(1)."

Jan 1, 1984

FREderick H. Davis, Electrical Engineer of the Westinghouse Electric and Manufacturing Co., in charge of the plant at Bodie, Cal. (communication to the Secretary): I beg to offer, to complete the information conveyed in Mr. Leggett's paper, the following report of tests of the electrical efficiency of the power-transmission he has described:

Jan 1, 1895

By Sridhar Seetharuman

Sulfur and oxygen dissolved in nickel and cupronickel melts can be removed as gaseous oxides of sulfur by a vacuum treatment. Presented in this paper is a new matched thermochemical diagram that permits direct evaluation of the equilibrium partial pressure of SO, as a function of temperature over an alloy of specified composition. The matched thermochemical diagram consists of a central plot which shows the integral Gibbs' energy of mixing for the binary system S-O2, at different temperatures. The central plot is flanked on either side by terminal plots of the chemical potentials of oxygen and sulfur, as functions of temperature, for different alloy compositions. By projecting the chemical potentials of oxygen and sulfur from the terminal plots on to the central diagram, the equilibrium pressure of SO2,can be directly read on the nomograms on the central plot at different temperatures. The matched thermochemical diaerams are - useful in assuring the efficiency of vacuum refining.

Jan 1, 1993

By E. B. Jensen

The results of an extensive one- year test period of a nonelectric explosives detonating system led to the mine-wide adoption of this system at the Henderson Mine in early 1978. Since that time, extensive experience with nonelectric initiation has verified the earlier results which include the following benefits: 1. Increased blasting safety 2. Improved productivity 3. Cost effectiveness 4. High reliability At the present time, while electric blasting caps still experience a limited use restricted to trunkline initiation, all heading rounds as well as the longhole bell, undercut, boundary cutoff and raise blasting are detonated non-electrically. The primary blasting agent used is AN/FO, and primers are typically one of the following products (depending on application): PETN, semi-gelatin dynamites or a nonnitroglycerin water-gel slurry.

Jan 1, 1982

By J. P. Rider

Average production from longwall mining operations in the United States has risen from approximately 800 tons per shift in 1980 to over 4,600 metric tons per shift in 1999. Such a large increase in production has the potential to generate significantly more dust. Previous NIOSH research has shown that, on average, respirable dust levels generated by the shearer accounts for 50% of the airborne dust generated during longwall mining. Ventilating air and water are primary controls being used in an effort to reduce longwall dust levels. Longwall operators are applying more air and water than ever before and have expressed concern over reaching maximum practical limits for these controls. Full-scale laboratory tests are being conducted to evaluate the impact on shearer-generated dust levels for changes in face air velocity, water quantity at the shearer, water spray pressure, spray system design, mining height and cutting direction. Results of this research should identify the most appropriate control levels for various operating conditions. In addition, general recommended dust control practices for longwall mining will be discussed. KEYWORDS Longwall, coal dust

Apr 1, 1975

By Henry D. Hibbard

THIS article aims to clarify the use of some terms often occurring in writings on iron and -steel, and also to suggest several new short abbreviated names for some of the things related to the subject which now are indicated by phrases. Crude or Crude Iron The name crude or crude iron is recommended for the iron produced from ore by the blast furnace. When necessary it can be specified as pig iron when in the form of pigs (usually cold), or as molten iron, commonly called hot metal to distinguish it from cold iron in pigs. The product of a direct process of making wrought or malleable iron from ore is not included.

Jan 1, 1924